Doc.No.

T19B07-38-PS51
BATTERY LIMIT Rev. 0
DEFINITION & INTERFACE Date Aug 3, 2020
Page 1/7
Project No. T19B07
Project Title Petrokemya CLC Project
Client Arabian Petrochemical Company (Petrokemya)
Location Jubail Industrial City, KSA

Petrokemya CLC Project

BATTERY LIMIT DEFINITION & INTERFACE FOR

NEW CELL HOUSE

rd
0 Aug 3 , 2020 IFC CT LJ LQS
st
D Jul 31 , 2020 IFD CT LJ LQS
st
C Jul 11 , 2020 IFD CT LJ LQS
st
B Jun 11 , 2020 IFR CT LJ LQS
st
A May 1 , 2020 IFR CT LJ LQS

Rev Date Description Prepared by Reviewed by Approved by

No part of this document or the information it contains may

be reproduced or transmitted in any form or by any means
electronic or mechanical, including photocopying recording
or by any information storage and retrieval system, without
permission in writing from SABIC.
 Doc.No. T19B07-38-PS51
BATTERY LIMIT Rev. 0
DEFINITION & INTERFACE Date Aug 3, 2020
Page 2/7
Project No. T19B07
Project Title Petrokemya CLC Project
Client Arabian Petrochemical Company (Petrokemya)
Location Jubail Industrial City, KSA

TABLE OF CONTENT
1. PURPOSE ................................................................................................................. 3

2. INTRODUCTION ....................................................................................................... 3

2.1 GENERAL INTRODUCTION OF PETROKEYMA CLC PROJECT .......................... 3

2.2 EARLY WORK FUNCTION FOR CLC PROJECT .................................................... 4

3. BATTERY LIMIT DEFINITION & INTERFACE ......................................................... 4

3.1 PROCESS ................................................................................................................. 4

3.2 UTILITY ..................................................................................................................... 7

No part of this document or the information it contains may

be reproduced or transmitted in any form or by any means
electronic or mechanical, including photocopying recording
or by any information storage and retrieval system, without
permission in writing from SABIC.
 Doc.No. T19B07-38-PS51
BATTERY LIMIT Rev. 0
DEFINITION & INTERFACE Date Aug 3, 2020
Page 3/7
Project No. T19B07
Project Title Petrokemya CLC Project
Client Arabian Petrochemical Company (Petrokemya)
Location Jubail Industrial City, KSA

1. PURPOSE

The purpose of this document is to describe the Battery limit Definition & Interface of New Cell
House for the Petrokemya CLC project.

2. Introduction

2.1 General Introduction of Petrokeyma CLC project

Arabia Petrochemical Co. (Petrokeyma North) owns and operates Chlor-Alkali (CA) and EDC
production facilities in Al-Jubail, Kingdom of Saudi Arabia.

The CA unit of PETROKEMYA produces both membrane and diaphragm grades of chlorine and
caustic. Chlorine product is used for the production of Ethylene Di-chloride (EDC). Commercial
production of this unit was started in 1986 and was expanded in 1997. Diaphragm cell lines were
designed by Eltech and membrane cell line was designed by UHDE.

The brine unit of CA receives raw brine from salt mines located 52 km from the plant. Raw brine is
treated separately for membrane and diaphragm electrolyzers.

Two trains of Diaphragm cells, Train #1 & #2, (MDC-55 Diamond Shamrock) produce liquid chlorine
which is used in two Low Temperature Conversion (LTC) Reactors for EDC production. The original
rated installed plant capacity was 460 KMT EDC per year. The plant was subsequently modified to
increase its capacity by approximately 25% to 560 KMT EDC per year in 1987. A major expansion
project was commissioned in 1997, which further increased the EDC production capacity by 50% to
840 KMT EDC per year. The increased capacity was achieved by adding one train of membrane
cells (Train #3) using Bi-polar electrolyzers (UHDE technology) to produce the additional
vapor-phase chlorine for feeding a new European Vinyl Corporation (EVC) technology's high
temperature conversion (HTC) reactor.

Petrokemya plans to replace its diaphragm cell lines with Membrane cells in order to comply with
Asbestos phase out directive from ministry as well as for business continuity purpose due to the
declining market for diaphragm caustic. The Cell Line Conversion project has been named as CLC
project. After detailed technology assessment, PETROKEMYA has opted to go for the
latest Generation 6 bipolar membrane electrolyzers technology from tkUCE, to replace the existing
diaphragm technology.

No part of this document or the information it contains may

be reproduced or transmitted in any form or by any means
electronic or mechanical, including photocopying recording
or by any information storage and retrieval system, without
permission in writing from SABIC.
 Doc.No. T19B07-38-PS51
BATTERY LIMIT Rev. 0
DEFINITION & INTERFACE Date Aug 3, 2020
Page 4/7
Project No. T19B07
Project Title Petrokemya CLC Project
Client Arabian Petrochemical Company (Petrokemya)
Location Jubail Industrial City, KSA

2.2 New Cell House Function for CLC project

During study in FEED stage, Petrokemya has opted to go for the latest bipolar membrane
electrolysers technology, to replace the existing diaphragm technology. For each train, the cell
room is designed to produce 590 MTPD Chlorine gas, Caustic Soda (NaOH 32% w/w solution)
and hydrogen gas using membrane electrolysers containing bipolar cell elements with an active
area of 2.72m2 per membrane.

3. Battery limit definition & Interface

Outside battery limit (OSBL) facilities are required to support the Petrokeyma CLC Project. The
purpose of this document is to record the Battery limit definition & Interface of the New Cell House.

3.1 Process
Battery Limit Description Battery Limit Condition Marks

Line Number Case

Line Tempera
Pressure Flow Rate Hydraulic
Stream Connecting Tie-in Unit Size ture
(KpaG) (m3/hr) Calculation
OSBL New Cell (Inch) (℃)
House
TO 31TK25 Refer to pump
New
Waste 38-1445-A 38P801AB
N/A 4 Cell 38 272.8 40
Brine 38A1000/ J-4" hydraulic
House
31A1023 calculation
TO 33SU801 Refer to pump
New
Waste 38-1446-A 38P801AB
N/A 3 Cell 38 487.4 40
Brine 38A1000/ E-3" hydraulic
House
33A1061 calculation

No part of this document or the information it contains may

be reproduced or transmitted in any form or by any means
electronic or mechanical, including photocopying recording
or by any information storage and retrieval system, without
permission in writing from SABIC.
 Doc.No. T19B07-38-PS51
BATTERY LIMIT Rev. 0
DEFINITION & INTERFACE Date Aug 3, 2020
Page 5/7
Project No. T19B07
Project Title Petrokemya CLC Project
Client Arabian Petrochemical Company (Petrokemya)
Location Jubail Industrial City, KSA

FROM
Refer to pump
Ultra 31P1002A/B New
31-1044-J 31P1002AB
Pure N/A 12 Cell 62.7 480 370
BR-12" hydraulic
Brine 38A1106-sh1/ House
calculation
31A1129
TO 31TK1002
Ultra New Refer to Pipe
38-1047-J
Pure N/A 6 Cell 75 100 27.8 hydraulic
38A1106-sh2/ BR-6''
Brine House calculation
31A1129
FROM
Refer to pump
32P846A/B New
Sodium 32-7727-J 32P846A/B
N/A 3 Cell 49 327 42
Sulfite K-3" hydraulic
38A1107/2107 House
calculation
32A1119
FROM
Refer to pump
Chlorine 32P1001A/B New
32-1117-J 32P1001A/B
Condens N/A 2 Cell 44 20 8.6
N-2'' hydraulic
ate 38A1108-sh2/ House
calculation
32A1006 SHT2
FROM
33P842A/B Refer to pump
New
32%Nao 38-9578-J 33P842A/B
N/A 3 Cell 90 470.86 0.8
H 38A1109/2109/ BR-3”-1h hydraulic
House
1131/2131~ calculation
33A1060
TO ECS
New Refer to Pipe
Chlorine 38-1141-JI
N/A 10 Cell 88 20 35~2667 hydraulic
Moist 38A1111/1113 -10''
House calculation
32A1191
TO CHLORINE
COOLER
Chlorine New Refer to Pipe
32E1R1 Tie-in 38-1137-JI
Gas 32 Cell 87.5 20 16000 hydraulic
32-525 -32''
Moist House calculation
38A1113/
32A1003
TO
HYDROGEN
New Refer to Pipe
Hydroge COOLER 31C1 Tie-in 38-1138-J
28 Cell 88 22 11821 hydraulic
n 31-513 BR-28''
House calculation
38A1113/
31A1013
TO 32C14
Wet New Refer to Pipe
38-1493-J
Chlorine N/A 6 Cell 46 0 0~60 hydraulic
38A1108-sh1/ N-6"
Gas House calculation
32A1053
TO 32C14
Wet New Refer to Pipe
38-1444-J
Chlorine N/A 4 Cell 38 0 0~10 hydraulic
38A1000/ N-4"
Gas House calculation
32A1053
FROM
Refer to pump
Ultra 31P2002A/B New
31-2044-J 31P2002AB
Pure N/A 12 Cell 62.7 480 370
BR-12" hydraulic
Brine 38A2106-sh1/ House
calculation
31A1134
TO 31TK2002
Ultra New Refer to Pipe
31-2047-J
Pure N/A 6 Cell 75 100 27.8 hydraulic
38A2106-sh2/ BR-6"
Brine House calculation
31A1134
FROM
Refer to pump
32P840/841 New
32% HCl 32-1127-J 32P840/841hyd
N/A 2 Cell 45 334 8.4
Acid B-2'' raulic
38A1133/2133 House
calculation
32A1180
FROM
Refer to pump
Chlorine 32P2001A/B New
32-1250-J 32P2001A/B
Condens N/A 2 Cell 44 20 8.6
N-2'' hydraulic
ate 38A2108-sh2/ House
calculation
32A1006 SHT3

No part of this document or the information it contains may

be reproduced or transmitted in any form or by any means
electronic or mechanical, including photocopying recording
or by any information storage and retrieval system, without
permission in writing from SABIC.
 Doc.No. T19B07-38-PS51
BATTERY LIMIT Rev. 0
DEFINITION & INTERFACE Date Aug 3, 2020
Page 6/7
Project No. T19B07
Project Title Petrokemya CLC Project
Client Arabian Petrochemical Company (Petrokemya)
Location Jubail Industrial City, KSA

TO
Refer to pump
31TK808/818 New
Lean 38-1106-J 38P1002A/B
N/A 12 Cell 83 132 300
Brine H-12" hydraulic
38A1109/ House
calculation
31A1117-sh1
TO
Refer to pump
31TK808/818 New
Lean 38-2106-J 38P2002A/B
N/A 12 Cell 83 132 300
Brine H-12" hydraulic
38A2109/ House
calculation
31A1117-sh2
TO ECS
New Refer to Pipe
Chlorine 38-2141-J
N/A 10 Cell 88 20 35~2667 hydraulic
Moist 38A2113/ I-10''
House calculation
32A1192
TO CHLORINE
COOLER
Chlorine New Refer to Pipe
32E1R1 Tie-in 38-2137-J
Gas 32 Cell 87.5 20 16000 hydraulic
32-526 I-32''
Moist House calculation
38A2113/
32A1003
TO
HYDROGEN
New Refer to Pipe
Hydroge COOLER 31C1 Tie-in 38-2138-J
28 Cell 88 22 11821 hydraulic
n 31-523 BR-28''
House calculation
38A2113/
31A1014
TO
Refer to pump
33TK801/802 New
32%Nao 33-9585-J 38P1007A/B
N/A 8 Cell 88 233.3 66.5
H BR-8”-1h hydraulic
38A1132/2132 House
calculation
33A1060
TO 33TK26R1 Refer to pump
New
32%Nao 33-9681-J 38P1007A/B
N/A 6 Cell 88 233.3 66.5
H 33A1060 BR-8” hydraulic
House
33A1028-sh1 calculation
TO 32V801
Chlorine New Refer to Pipe
38-1093-J
Waste N/A 6 Cell 90 -2.825 29 hydraulic
38A1108-sh2 NA-6''
Air House calculation
32A1191
TO 32V802
Chlorine New Refer to Pipe
38-2093-J
Waste N/A 6 Cell 90 -2.825 29 hydraulic
38A2108-sh2 NA-6''
Air House calculation
32A1192

No part of this document or the information it contains may

be reproduced or transmitted in any form or by any means
electronic or mechanical, including photocopying recording
or by any information storage and retrieval system, without
permission in writing from SABIC.
 Doc.No. T19B07-38-PS51
BATTERY LIMIT Rev. 0
DEFINITION & INTERFACE Date Aug 3, 2020
Page 7/7
Project No. T19B07
Project Title Petrokemya CLC Project
Client Arabian Petrochemical Company (Petrokemya)
Location Jubail Industrial City, KSA

3.2 Utility

Line Description
Battery Limit Condition Marks

Line Number
Case Temperature
Line Size Pressure Flow Rate
Stream Connecting Tie-in Unit (Inch) (℃) (KpaG) (m3/hr)
OSBL New Cell
House
Steam
Header New Refer to Pipe
LP 38-1486-N-
N/A 14 Cell 200 339 4250kg/h hydraulic
Steam 14''-1h
38A2001/ House calculation
35A2024
Steam
Header New Refer to Pipe
LP 38-2486-N-
N/A 14 Cell 200 339 4250kg/h hydraulic
Steam 14''-1h
38A2001/ House calculation
35A2024
Condensate
Steam Header New Refer to Pipe
38-1326-N-
Conden N/A 5 Cell 120 98.7 4250kg/h hydraulic
5''-1h
sate 38A2001/ House calculation
35A2024
Condensate
Steam Header New Refer to Pipe
38-2326-N-
Conden N/A 5 Cell 120 98.7 4250kg/h hydraulic
5''-1h
sate 38A2001/ House calculation
35A2024
Instrument Air
New Refer to Pipe
Instrum System Tie-in 35-9411-L1 400
3 Cell 60 620 hydraulic
ent Air 35-519 -3'' Nm3/hr
House calculation
38A2003
NITROGEN
Header New Refer to Pipe
Nitroge Tie-in 35-9410-A- 830
3 Cell 38 500 hydraulic
n 35-550 3'' Nm3/hr
38A2002/ House calculation
35A2025
Demineralized
Refer to pump
Demine Water Header New
35-9422-JK 31P844A/B
ralized N/A 8 Cell 50 559 62
-8'' hydraulic
Water 38A2004/ House
calculation
35A2104
Intermittent for
New
Demosti Demostic 38-1700-JN Eyewashing
N/A 2 Cell 38 554 5~10
c Water Water System A-2'' Total 16 set,
House
80L/min

CWS Header
New Refer to pump
35-9406-L-
CWS N/A 24 Cell 38.7 410 708 34P801 hydraulic
38A2000/ 24''
House calculation
35A2021

CWR Header
New Refer to pump
35-9407-L-
CWR N/A 24 Cell 49.5 250 708 34P801 hydraulic
38A2000/ 24''
House calculation
35A2021

No part of this document or the information it contains may

be reproduced or transmitted in any form or by any means
electronic or mechanical, including photocopying recording
or by any information storage and retrieval system, without
permission in writing from SABIC.