SDS 01 - Efficascent Oil Extreme

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SAFETY DATA SHEET

Section 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


Identity EFFICASCENT OIL LINIMENT – EXTREME
Company Name International Pharmaceuticals, Inc.
Golam Drive, Pope John Paul II Avenue, Kasambagan, Cebu City,
Company Address
Cebu, Philippines
Telephone Number + 63 32 412-7772
Fax Number + 63 32 233-4143
Pharmaceutical product used for the relief of back, muscle and joint
Intended Use pains caused by rheumatism, lumbago and arthritis. For stiff neck,
headache, insect bites, minor sprains and strains.

Section 2. HAZARD(S) IDENTIFICATION


GHS Classification
Flammable liquid Category 4
Skin corrosion/irritation Category 3
Serious eye damage/ eye Category 2A
irritation
Acute toxicity (oral) Category 4
Specific target organ Category 2
Toxicity, single exposure

GHS Label Element

Hazard Pictogram(s)

Signal Word(s) Warning


Hazard Statement(s) Combustible liquid (H227)
Harmful if swallowed (H302)
May cause an allergic skin reaction (H317)
Causes serious eye irritation (H319)
May cause damage to organs (H371)

Precautionary Statement(s)
Prevention Do not breathe dust/fume/gas/mist/vapors/spray. (P260)
Wash hands thoroughly after handling. (P264)
Do not eat, drink or smoke when using this product. (P270)
Wear protective gloves/protective clothing/eye protection/face
protection. (P280)

Response IF SWALLOWED: call a POISON CENTER or doctor/physician IF


you feel unwell. (P301+ P312)
Rinse mouth. (P330)
IF exposed or if you feel unwell: call a POISON CENTER or doctor/
physician. (P309+P311)

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IF SKIN irritation occurs: Get medical advice/attention. (P332+P313)
Take off contaminated clothing and wash before reuse. (P362)

IF IN EYES: Rinse cautiously with water for several minutes.


Remove contact lenses, if present and easy to do. Continue rinsing.
(P305+P351+P338)
IF eye irritation persists: Get medical advice/attention. (P337+P313)
Storage Store locked up. (P405)
Disposal Dispose of contents/container to an approved waste disposal plant.
(P501)
Other hazards None

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS


Chemical Identity Mixture

Ingredients CAS Number EC Number Concentration


Camphor 76-22-2 200-945-0 7.5 %
Menthol 2216-51-5 201-939-0 6.0 %
Methyl Salicylate 119-36-8 204-317-7 30.0 %
Eucalyptus Oil 8000-48-4 283-406-2 2%
* Other Non-Hazardous Ingredients N/A N/A ≤ 65%
In accordance with the paragraph (i) of Sec. 1910.1200, the specific chemical identity and/or exact
percentage (concentration) of mixture has been withheld as a trade secret.
* Unidentified ingredients are not considered hazardous under the Federal Hazard Communication Standard
(28 CFR Sec. 1910.1200)

Section 4. FIRST AID MEASURES


Necessary first-aid measures
Inhalation Overexposure is most likely to occur dealing with large quantities
and in an enclosed space with inadequate ventilation. Remove to
fresh air. Allow patient to rest in a well-ventilated area. Seek medical
attention.
Skin Contact Prolonged and excessive application to large areas of skin may
cause contact dermatitis. Wipe off and wash exposed area with soap
and water. Get medical attention if irritation develops.
Eye Contact Check for and remove any contact lenses. Rinse immediately with
clean water for at least 15 minutes. Seek medical attention.
Ingestion Do not induce vomiting. Loosen tight clothing such as a collar, tie,
belt or waistband. Perform gastric lavage. Treat symptomatically.
Seek medical attention.
Most important symptoms / No information available.
effects, both acute and
delayed
Note(s) to physician Treat symptomatically.

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Section 5. FIRE-FIGHTING MEASURES
Suitable extinguishing Use dry chemical powder, water spray, fog or foam.
media
Unsuitable extinguishing High volume water jet
media
Specific hazards arising Fire Hazard.
from the chemical Irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Do not breathe fumes. Keep product
and empty container away from sources of ignition.
Hazardous combustion Carbon oxides
products
Special protective actions Fire fighters should wear positive pressure self-contained breathing
for fire-fighters apparatus.
Specific extinguishing Cool containers exposed to flame with water spray. Spray
methods extinguishing media directly into base of fire.

Section 6. ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures
Non-emergency Before cleaning any spill or leak, individuals involved in spill cleanup
personnel must wear appropriate Personal Protective Equipment (i.e. goggles,
gloves). Remove spilled material with absorbent material (I.e. sand,
earth, diatomaceous earth, vermiculite) and place into appropriate
closed container(s) for disposal.
Emergency responders Before cleaning any spill or leak, individuals involved in spill cleanup
must wear appropriate Personal Protective Equipment. Deny entry
to all unprotected individuals. Maximize ventilation (open doors and
windows).
Environmental precautions Keep spills and cleaning runoffs out of nearby sewers and open
bodies of water.
Methods and materials for Dike and contain spill with inert material (e.g. sand or earth).
containment and cleaning Transfer soiled material to containers for recovery or disposal and
up solid diking material to separate containers for proper disposal.
Dispose of properly in accordance with local or national regulations.
Wash all affected area and outside of container with plenty of warm
water and soap. Remove any contaminated clothing and wash
thoroughly before reuse.

Section 7. HANDLING AND STORAGE


Precautions for safe No special control measures required for normal handling. Normal
handling room ventilation is expected to be adequate for routine handling.
Follow good industrial practice as to housekeeping, personal hygiene
and avoidance of prolonged or repeated contact with the skin or eyes.
Keep away from fire, sparks and heated surfaces.
Conditions for safe Keep away from heat and sources of ignition. Keep in a cool, well-
storage ventilated place. Keep away from oxidizing agents. Keep out of reach
of children. Keep container tightly closed. Store in suitable labeled
0
containers at temperatures not exceeding 30 C.
Materials to avoid No special restrictions on storage with other products.

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Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters
If a component is disclosed in Section 3. (Composition/Information on Ingredients) but does not appear in
the table below, an occupational exposure limit or recorded limit is not available for the component.

Exposure Limits
Chemical Name
OSHA [A] NIOSH [B]
 PEL-TWA: 2 mg/m  REL-TWA: 2 mg/m
3 3
Camphor
A] Occupational Safety and Health Administration (OSHA)
[B] The National Institute of Occupational Safety and Health (NIOSH)

Appropriate engineering Provide exhaust ventilation or other engineering controls to keep the
controls airborne concentrations of vapors below their respective threshold limit
value. Ensure that eyewash stations and safety showers are proximal to
the work-station location.
Individual protection measures
Eye / face protection Not required under normal conditions of use. Wear safety glasses or
goggles if eye contact is possible.
Hand protection Not required for the normal use of this product. Wear gloves when
working with large quantities. The glove material has to be impermeable
and resistant to the product such as nitrile rubber, neoprene gloves,
butyl rubber or natural rubber gloves.
Skin / body protection Not required for the normal use of this product. Use protective clothing
(lab coats, disposable coveralls, etc.) in both production and laboratory
areas.
Respiratory protection Not required for the normal use of this product. If the applicable
Occupational Exposure Limit (OEL) is exceeded, wear an appropriate
respirator with a protection factor sufficient to control exposures to below
the OEL.

Thermal hazards No special protective equipment required.


Hygiene measures General industrial hygiene practice.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance Clear, oily liquid
(physical state, color, etc.)
Odor Characteristic
Odor threshold No data available.
pH 6.50
Melting point / freezing point No data available.
Initial boiling point and No data available.
boiling range
Flash point No data available.
Evaporation rate No data available.
Flammability (solid, gas) No data available.
Upper / lower flammability No data available.
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or explosive limits
Vapor pressure No data available.
Vapor density No data available.
Specific gravity 0.938
Solubility(ies) Insoluble in water.
Partition coefficient No data available.
(n-octanol / water)
Auto-ignition temperature No data available.
Decomposition temperature No data available.
Viscosity No data available.

Section 10. STABILITY AND REACTIVITY


Reactivity Stable under recommended storage conditions.
Chemical stability No decomposition if stored and applied as directed.
Possibility of hazardous No hazards to be specially mentioned.
reactions
Conditions to avoid Avoid contact with sparks, flame and heat.
Incompatible materials Avoid contact with strong oxidizing agents and avoid hot work and
sources of ignition on or near empty containers
Hazardous decomposition CO, CO2, smoke and unidentified organic compounds may be formed
products during combustion.

Section 11. TOXICOLOGICAL INFORMATION


This product has not been tested on animals to obtain toxicological data. There are toxicology data for
the components of this product, which are found in the scientific literature. These data have not been
presented in this document.
Information of the likely Inhalation, eye contact, skin contact, ingestion
routes of exposure
Potential health effects
Inhalation Health injuries are not known or expected under normal use.
Skin contact May cause skin irritation. Not a skin sensitizer.
Ingestion Harmful if swallowed. Possible mild gastrointestinal irritation with
diarrhea, nausea, and vomiting, if large quantities are ingested.
Eye contact Not an expected route of exposure; however, direct contact may
cause eye irritation.

Experience with human exposure


Inhalation No symptoms known or expected under normal exposure.
Skin contact No symptoms known or expected under normal exposure.
Ingestion No symptoms known or expected under normal exposure.
Eye contact No symptoms known or expected under normal exposure.
Acute toxicity
Product Oral toxicity No data available.
Inhalation toxicity No data available.
Dermal toxicity No data available.
Ingredient(s)  Menthol

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Oral toxicity LD50 (rat): 3,180 mg/kg
Dermal toxicity LD50 (rabbit): >5000 mg/kg
3
Inhalation LD50 (rat): 5,289 mg/m / 4h
 Camphor
Oral toxicity LD50 (mouse): 1310 mg/kg
Dermal toxicity No data available.
Inhalation No data available.
 Methyl salicylate
Oral toxicity LD50 (mouse): 1,110 mg/kg
LD50 (rat): 887 mg/kg
LD50 (rabbit): 1300 mg/kg
LD50 (child): 228 mg/kg
LD50 (adult human): 506 mg/kg
Dermal toxicity No data available.
Inhalation No data available.
 Eucalyptus Oil
Oral toxicity No data available.
Dermal toxicity LD50 Dermal - Rabbit - > 5.000 mg/kg
Inhalation No data available.

Skin corrosion / irritation


Product No data available.
Ingredient(s)  Menthol
Causes skin irritation
 Camphor
No data available.
 Methyl salicylate
No data available.
 Eucalyptus Oil
No data available.

Serious eye damage / irritation


Product No data available.
Ingredient(s)  Menthol
Causes serious eye irritation
 Camphor
No data available.
 Methyl salicylate
No data available.
 Eucalyptus Oil
Eyes - Rabbit Result: No eye irritation - 72 h (OECD Test
Guideline 405)

Respiratory or skin sensitization


Product No data available.
Ingredient(s)  Menthol
Shall not be classified as a respiratory or skin sensitizer
 Camphor
No data available.
 Methyl salicylate
No data available.

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 Eucalyptus Oil
May cause sensitization by skin contact.
Germ cell mutagenicity
Product No data available.
Ingredient(s)  Menthol
Shall not be classified as germ cell mutagenic
 Camphor
No data available.
 Methyl salicylate
No data available.
 Eucalyptus Oil
Not mutagenic in Ames Test
Carcinogenicity
Product No data available.
Ingredient(s)  Menthol
Shall not be classified as carcinogenic
 Camphor
Not listed as a carcinogen
 Methyl salicylate
Not listed as a carcinogen
 Eucalyptus Oil
No data available.
Reproductive toxicity
Product No data available.
Ingredient(s)  Menthol
Shall not be classified as a reproductive toxicant
 Camphor
No data available.
 Methyl salicylate
No data available.
 Eucalyptus Oil
No toxicity to reproduction
STOT-single exposure
Product No data available.
Ingredient(s)  Menthol
Shall not be classified as a specific target organ toxicant
(single exposure).
 Camphor
Respiratory system
 Methyl salicylate
No data available.
 Eucalyptus Oil
No data available.

STOT-repeated exposure
Product No data available.
Ingredient(s)  Menthol
Shall not be classified as a specific target organ toxicant
(repeated exposure).
 Camphor

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None known
 Methyl salicylate
No data available.
 Eucalyptus Oil
No data available.

Aspiration hazard
Product No data available.
Ingredient(s)  Menthol
Shall not be classified as presenting an aspiration hazard.
 Camphor
No data available
 Methyl salicylate
No data available.
 Eucalyptus Oil
The substance or mixture (at 100% conc.) is known to cause
human aspiration toxicity hazards or has to be regarded as if it
causes a human aspiration toxicity hazard.

Section 12. ECOLOGICAL INFORMATION


Ecotoxicity
Environmental effects Harmful to aquatic life.
Toxicity to fish
Product No data available.
Ingredient(s)  Menthol
Aquatic toxicity (acute) LD50: 22.3 mg/l
Exposure time 96 hours
 Camphor
Aquatic toxicity (acute) LD50: 36 mg/l
Exposure time 96 hours
 Methyl salicylate
No data available.
 Eucalyptus Oil
No data available.

Toxicity to daphnia and other aquatic invertebrates


Product No data available.
Ingredient(s)  Menthol
Aquatic toxicity (acute) EC50: 26.6 mg/l
Exposure time 48 hours
 Camphor
No data available.
 Methyl salicylate
No data available.
 Eucalyptus Oil
No data available.
Toxicity to algae
Product No data available.

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Ingredient(s)  Menthol
Aquatic toxicity (acute) ErC50: 16.2 mg/l
Exposure time 72 hours
 Camphor
No data available.
 Methyl salicylate
No data available.
 Eucalyptus Oil
No data available.
Persistence and degradability
Product No data available.
Ingredient(s)  Menthol
Theoretical Oxygen Demand 2.97 g/g
Theoretical Carbon Dioxide 2.816 mg/mg
 Camphor
No data available
 Methyl salicylate
No data available.
 Eucalyptus Oil
No data available.
Bioaccumulative potential
Product No data available.
Ingredient(s)  Menthol
Does not significantly accumulate in organisms.
n-octanol/water (log KOW) 3.4 (pH value: 7.2, 37 °C)
BCF ≥0.5 – ≤15 (ECHA)
 Camphor
No data available.
 Methyl salicylate
No data available.
 Eucalyptus Oil
No data available.
Mobility in soil
Product No data available.
Ingredient(s)  Menthol
No data available.
 Camphor
No data available.
 Methyl salicylate
No data available.
 Eucalyptus Oil
No data available.
Other adverse effects
Product No data available.
Ingredient(s)  Menthol
No data available.
 Camphor
No data available.
 Methyl salicylate
No data available.

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 Eucalyptus Oil
Toxic to aquatic life with long lasting effects (at 100%
conc.).

Section 13. DISPOSAL CONSIDERATIONS


Disposal Methods The product should not be allowed to enter drains, water courses or the
soil. Where possible recycling is preferred to disposal or incineration. If
recycling is not practicable, dispose of in compliance with local
regulations. Dispose of wastes in an approved waste disposal facility.
Disposal considerations Dispose of as unused product. Empty containers should be taken to an
approved waste handling site for recycling or disposal. Observe all local
and national regulations when disposing of this product. Do not reuse
empty containers.

Section 14. TRANSPORT INFORMATION


Transport labeling: The shipper/consignor/sender is responsible to ensure that the packaging, labeling,
and markings are in compliance with the selected mode of transport.
Land transport
UN Number Not regulated as dangerous goods.
UN proper shipping Not regulated as dangerous goods.
name
Transport hazard Not regulated as dangerous goods.
class(es)
Packing group Not regulated as dangerous goods.
Environmental hazard Not regulated as dangerous goods.
Sea transport
UN Number Not regulated as dangerous goods.
UN proper shipping Not regulated as dangerous goods.
name
Transport hazard Not regulated as dangerous goods.
class(es)
Packing group Not regulated as dangerous goods.
Environmental hazard Not regulated as dangerous goods.
Air transport
UN Number Not regulated as dangerous goods.
UN proper shipping Not regulated as dangerous goods.
name
Transport hazard Not regulated as dangerous goods.
class(es)
Packing group Not regulated as dangerous goods.
Environmental Not regulated as dangerous goods.
hazard

Section 15. REGULATORY INFORMATION


No data available.

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Section 16. OTHER INFORMATION
Further Information Abbreviations:
PEL – Permissible Exposure Limit
TWA - Time Weighted Average
PEL-TWA – Permissible Exposure Limit – 8-hour Time Weighted Average
REL-TWA – Recommended Exposure Limit – Time Weighted Average
CAPEL-TWA – California Permissible Exposure Limit – Time Weighted Average
IDLH – Immediately Dangerous to Life or Health

NFPA Flammability

2
Health 1 0 Instability

Special Hazard
HMIS
1 0 = not significant
1 = slight
2 2 = moderate
3 = high
4 = extreme
1 * = chronic

Data Sources Publicly available information.


Issue Date 30 September 2020
Prepared by Product Research and Development Department
International Pharmaceuticals Inc.
DSA/JBM

The information and recommendations in this safety data sheet are, to the best of our knowledge,
accurate as of the date of issue. Nothing herein shall be deemed to create any warranty, express or
implied. It is the responsibility of the user to determine the applicability of this information and the
suitability of the material or product for any particular purpose.

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