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MATERIAL SAFETY DATA SHEET

LEAD ACID BATTERY WET, FILLED WITH


ACID
(US, CN, EU Version for International Trade)

! SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Lead Acid Battery Wet, Filled With Acid


OTHER PRODUCT Electric Storage Battery, SLI or Industrial Battery, UN2794
NAMES:

MANUFACTURER: East Penn Manufacturing Company , Inc.


DIVISION : Deka Road
ADDRESS : Lyon Station , PA 19536 USA

EMERGENCY TELEPHONE NUMBERS: US: CHEMTREC 1-800-424-9300


CN: CHEMTREC 1-800-424-9300
Outside US :+ 1-202-483-7616

NON-EMERGENCY HEALTH/SAFETY INFORMATION: + 1-610-682-6361

CHEMICAL FAMILY: This product is a wet lead acid storage battery. May also include gel/absorbed electrolye
type lead acid battery types.

PRODUCT USE: Industrial/Commercial electrical storage batteries.

This product is considered a Hazardous Substance , Preparation or Article that is regulated under US-OSHA; CAN-WHMIS ;
IOSH ; ISO; UK-CHIP ; or EU Directives (67/548/EEC-Dangerous Substance Labeling , 98/24/EC-Chemical Agents at Work,
99/45/EC-Preparation Labeling , 2001 /58/ EC-MS DS Content, and 1907/2006/EC-REACH), and an MSDS/SDS is requ ired for
this product considering that when used as recommended or intended , or under ordinary conditions, it may present a health
and safety exposure or other hazard.

Additional Information
This prod uct may not be compatible with all environments, such as those containing liquid solvents or extreme temperature or
pressure. Please request information if con sidering use under extreme conditions or use beyond current product labeling .

! SECTION 2: HAZARDS IDENTIFICATION


GHS Classification:
Health Environmental Physical
Acute Toxicity - Not listed (NL) Aq uatic Toxicity - NL NFPA - Flammable gas , hydrogen (during
Eye Corrosion - Corrosive* charging)
Skin Corrosion - Corrosive* CN - NL
Skin Sensitization - NL EU - NL
Mutagenicity/Carcin ogenicity - NL
Reproductive/Developmental - NL
Taraet Oraan Toxicity (Repeated) - NL
*as sul furic acid

Symbols :

Hazard Statements Precautionary Statements


Contact with internal components may cause irritation of Keep out of reach of children . Keep containers tightly closed .
severe burns . Irritating to eyes , respiratory system , and Avoid heat, sparks , and open flame while charging batteries .
skin . Avoid contact with internal acid .

EMERGENCY OVERVIEW: May form explosive air/gas mixture during charging . Contact with internal components
may cause irritation or severe burns . Irritating to eyes, respiratory system , and skin.

PAGE 1 OFB East Penn Manufacturing Co.• Inc.


MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY WET, FILLED WITH
ACID
(US, CN, EU Version for International Trade)

Prolonged inhalation or ingestion may result in serious damage to health. Pregnant


women exposed to internal components may experience reproductive/developmental
effects.

POTENTIAL HEALTH EFFECTS:


EYES : Direct contact of internal electrolyte liquid with eyes may cause severe burns or blindness.
SKIN : Direct contact of internal electrolyte liquid with the skin may cause skin irritation or damaging burns .
INGESTION: Swallowing this product may cause severe burns to the esophagus and digestive tract and harmful or
fatal lead poisoning . Lead ingestion may cause nausea, vomiting , weight loss, abdominal spasms,
fatigue , and pain in the arms , legs and joints .
INHALATION : Respiratory tract irritati on and possible long term effects.

ACUTE HEALTH HAZARDS:


Repeated or prolonged contact may cause mild skin irritation .
CHRONIC HEAL TH HAZARDS:
Lead poisoning if persons are exposed to internal components of the batteries . Lead absorption may cause nausea ,
vomiting , weight loss, abdominal spasms , fatigue, pain in the arms, legs and joints. Other effects may include central nervous
system damage , kidney dysfunction, and potential reproductive effects. Chronic inhalation of sulfuric acid mist may increase
the risk of lung cancer.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE :
Respiratory and skin diseases may predispose one to acute and chronic effects of sulfuric acid and/or lead . Children and
pregnant women must be protected from lead exposure . Persons with kidney disease may be at increased risk of kidney
failure .

Additional Information
No health effects are expected related to normal use of this product as sold.

I SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS


INGREDIENTS (Chemical/Common Names): CAS No.: % byWt : EC No.:
Lead, inorganic 7439-92-1 43-70 (average : 65) 231 -100-4
Sulfuric acid 7664-93-9 20-44 (average : 25) 231 -639-5
Antimony 7440-36-0 0-4 (average : 1) 231-146-5
Arsenic 7440-38-2 <0.01 231-148-6
Polypropylene 9003-07-0 5-10 (average: 8) NA
NA - Not applicable/ND - Not determined

Additional Information
These ingredients reflect components of the finished product re lated to performance of the product as distributed into
commerce.

I SECTION 4 : FIRST AID MEASURES


EYE CONTACT : Flush eyes with large amounts of water for at least 15 minutes. Seek immediate medical attention if
eyes have been exposed directly to acid.
SKIN CONTACT: Flush affected area(s) with large amounts of water using deluge emergency shower, if available,
shower for at least 15 minutes. Remove contaminated cl othing . If sym ptoms persist, seek medical
attention .
INGESTION : If swallowed , give large amounts of water. Do NOT induce vomiting or aspiration into the lungs may
occur and can cause permanent injury or death.
INHALATION : If breathing difficulties develop, remove person to fresh air. If symptoms persist, seek medical
attention .

I SECTION 5 : FIRE-FIGHTING MEASURES


SUITABLE/UNSUITABLE EXTINGUISHING MEDIA:

PAGE20F8 East Penn Manufacturing Co. , Inc.


MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY WET, FILLED WITH
ACID
(US, CN, EU Version for International Trade)

Dry chemical . carbon dioxi de, water, foam. Do not use water on live electrical circuits .

SPECIAL FIRE FIGHTING PROCEDURES & PROTECTIVE EQUIPMENT:


Use appropriate media for surrounding fire. Do not use carbon dioxide directly on cells . Avoid breathing vapors . Use full
protective equipment (bunker gear) and self-contained breath ing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS :
Batteries evolve flammable hydrogen gas during charging and may increase fire risk in poorly ventilated areas near sparks ,
excessive heat or open flames .
SPECIFIC HAZARDS IN CASE OF FIRE :
The rm al shock may cause battery case to crack open. Containers may explode when heated.

Additional Information
Firefighting water runoff and dilution water may be toxic and corrosive and may cause adverse environmental impacts.

I SECTION 6 : ACCIDENTAL RELEASE MEASURES


PERSONAL PRECAUTIONS:
Avoid Contact with Skin . Neutralize any spilled electrolyte with neutralizing agents, such as soda ash , sodium bicarbonate, or
very dilute sodium hydroxide solutions.
ENVIRONMENTAL PRECATIONS:
Prevent spilled material from entering sewers and waterways .
SPILL CONTAINMENT & CLEANUP METHODS/MATERIALS :
Add neutralizer/absorbent to spill area. Sweep or shovel spilled material and absorbent and place in approved container.
Dispose of any non-recyclable materials in accordance with local , state, provincial or federal regulations .

Additional Information
Lead acid batteri es and their plastic cases are recyclable. Contact your East Penn representative for recyc ling
information.

I SECTION 7 : HANDLING AND STORAGE

PRECAUTIONS FOR SAFE HANDLING AND STORAGE:


• Keep containers tightly closed when not in use.
• If battery case is broken . avoid contact with internal components.
• Do not handle near heat, sparks, or open flames.
• Protect containers from physical damage to avo id leaks and spills.
• Place cardboard between layers of stacked batteries to avoid damage and short circuits .
• Do not allow conductive material to touch the battery term inals. A dangerous short-circu it may occur and cause battery
failure and fire.
OTHER PRECAUTIONS (e.g.; Incompatibilities):
Keep away from combustible materials, organic chemicals , reducing substances , metals , strong oxidizers and water.

I SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS/SYSTEM DESIGN INFORMATION :


Charge in areas with adequate ventilation.
VENTILATION :
General dilution ventilation is acceptable .
RESPIRATORY PROTECTION :
Not required for normal conditions of use. See also special firef ighting procedures (Section 5).
EYE PROTECTION :
Wear protective glasses with side shields or goggles.
SKIN PROTECTION :
Wear chemical resistant gloves as a standard procedure to prevent skin contact.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Chemically-impervious apron and face shield recommen ded when
adding water or electrolyte to batteries .
Wash Hands after handling.

PAGE30F8 East Penn Manufacturing Co.• Inc.


MATERIAL SAFETY DATA SHEET
LEAD ACID BATTER Y WET, FILLED WITH
ACID
(US, CN, EU Version for International Trade)

EXPOSURE GUIDELINES & LIMITS:


3
OSHA Permissible Exposure Limit (PEL/TWA) Lead , inorganic (as Pb) 0.05 mgtm
Sulfuric acid 1 mg/ m
Antimony 0.5 mg/m3
Arsenic 0.01 mg/m3
ACGIH 2007 Threshold Limit Value (TLV) Lead , inorganic (as Pb) 0.05 mg/m3
Sulfuric acid 0.2 mg/m3
3
Antimony 0.5 mg/m
Arsenic 0.01 mg/m3
3
Quebec Permissible Exposure Value (PEV) Lead , inorganic (as Pb) 0.15 mgtm
Sulfuric acid 1 mg/m TWA
3
3 mg/m STEV
Antimony 0.5 mg/m3
Arsenic 0.1 mg/m3
3
Ontario Occupational Exposure Level (OEL) Lead (designated substance) 0.10 mgtm
Sulfuric acid 1 mg/m TWAEV
3
3 mg/m STEV
Antimony 0.5 mg/m3
Arsenic (designated 0.01 mg/m3
substance)
3
Netherlands Maximaal Aanvaarde Concentratie (MAC) Lead . inorganic (as Pb) 0.15 mgtm
Sulfuric acid 1 mg/m
Germany Maxi male Arbeitsplatzkon zentrationen (MAK) Lead , inorganic (as Pb) 0.1 mg/m3
3
Sulfuric acid 1 mg/m TWA
3
2 mg/m STEL
Antimony 0.5 mg/m3
United Occupational Exposure Standard (OES) Lead 0.15 mg/m3
Kingdom Antimony 0.5 mg/m3
Arsenic 0.1 mg/m3

TWA - 8-Hour Time Weighted Average/ STE - Short Term Exposu re / mg/m 3 - milligrams per cubic meter of air/ NE - Not Established

Add itional Information


• Batteries are ho used in polypropylene cases which are regulated as total dust or res~irabl e dust only when they are
ground up during recycling . The OSH A PEL for dust is 15 mg/m3 as total dust or 5 mg/m as respirable dust.
• May be required to meet Domestic Requirements for a Specific Destination(s).

! SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE : Industrial/commercial lead acid batte ry


ODOR: Odorless
ODOR THRESHOLD : NA
PHYSICAL STATE : Sulfuric Acid : Liquid ; Lead : solid
pH: <1
BOILING POINT: 235-240 ° F (as sulfuric acid)
MELTING POINT : NA
FREEZING POINT : NA
VAPOR PRESSURE : 10 mmHg
VAPOR DENSITY (AIR= 1): > 1
SPECIFIC GRAVITY (H20 = 1): 1.27-1 .33
EVAPORATION RATE (n-BuAc: 1): < 1
SOLUBILITY IN WATER : 100% (as sulfuric acid)
FLASH POINT: Below room temperature (as hydrogen gas)
AUTO-IGNITION TEMPERATURE : NA
LOWER EXPLOSIVE LIMIT (LEL): 4% (as hydrogen gas)
UPPER EXPLOSIVE LIMIT (UEL): 74% (as hydrogen gas)
PARTITION COEFFICIENT: NA
VISCOSITY (poise @ 25 ° C) : Not Available

PAGE40F8 East Penn Manufacturing Co., Inc.


MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY WET, FILLED WITH
ACID
(US, CN, EU Version for International Trade)

DECOMPOSITION TEMPERATURE: Not Available

FLAMMABILITY/HMIS HAZARD CLASSIFICATIONS (US/CN/EU): As sulfuric acid


HEALTH: 3 FLAMMABILITY: 0 REACTIVITY: 2

j SECTION 10: STABILITY AND REACTIVITY

STABILITY: This product is stable under normal conditions at ambient temperature .


INCOMPATIBILITY (MATERIAL TO AVOID): Strong bases , combusti ble organ ic materials, reducing agents, finely
divided metals , strong oxidizers, and water.
HAZARDOUS DECOMPOSITION BY- Thermal decomposition will produce sulfur dioxide, sulfur trioxide,
PRODUCTS: carbon monoxide , sulfuric acid mist, and hydrogen.
HAZARDOUS POLYMERIZATION: Will not occur
CONDITIONS TO AVOID: Overcharging, sources of ignition

j SECTION 11: TOXICOLOGICAL INFORMATION

ACUTE TOXICITY (Test Results Basis and Comments) :


Sulfuric acid : LD 50 , Rat: 21409 mg/kg
LCso, Guinea pig: 510 mg/m3
Lead : No data available for elemental lead
SUBCHRONIC/CHRONIC TOXICITY (Test Results and Comments):
Repeated exposure to lead and lead compounds in the workplace may result in nervous system toxicity. Some toxicolog ists
report that abnormal conduction ve locities in person with blood lead levels of 50 µg/100 ml or higher. Heavy lead exposure
may result in central nervous system damage, encephalopathy and damage to the blood-forming (hematopoietic) tissues.

Additional Information
• Very little chronic toxicity data available for elemental lead .
• Lead is listed by IARC as a 2B carcinogen : possible carcinogen in humans. Arsenic is listed by IARC, ACGIH , and NTP
as a carcinogen , based on studies with high doses overlong periods of time . The other ingredients in this product,
present at equal to or greater than 0.1 % of the product, are not listed by OSHA , NTP, or IARC as suspect carcinogens.
• The 19th Amendment to EC Directive 67/548/EEC classified lead compounds, but not lead in metal form , as possibly toxic
to reproduction. Risk phrase 61 : May cause harm to the unborn child , applies to lead compounds , especially soluble
forms.

j SECTION 12: ECOLOGICAL INFORMATION

PERSISTENCE & DEGRADABILITY:


Lead is very persistent in soils and sediments . No data available on biodegradation.
BIO-ACCUMULATIVE POTENTIAL (Including Mobility) :
Mobility of metallic lead between ecological compartments is low. Bioaccumulation of lead occurs in aquatic and terrestrial
animals and plants , but very little bioaccumulation occurs through the food chain . Most studies have included lead
compounds , not solid inorganic lead.
AQUATIC TOXICITY (Test Results & Comments):
Sulfuric acid : 24-hour LC 5o, fresh water fish (Brachydanio rerio) : 82 mg/I
96-hour LOEC , fresh water fish (Cyprinus carpio): 22 mg/I (lowest observable effect concentration )
Lead (metal ): No data available

Additional Information
• No known effects on stratospheric ozone depletion.
• Volatile organic compounds : 0% (by Volume)
• Water Endangering Class (WGK): NA

j SECTION 13: DISPOSAL CONSIDERATIONS

WASTE DISPOSAL Follow local , State/Provincial , and Federal/National regulations applicable to as-used , end-
METHOD: of-life characteristics to be determined by end-user.

PAGE50F8 East Penn Manufacturing Co.• Inc.


MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY WET, FILLED WITH
ACID
(US, CN, EU Version for International Trade)

HAZARDOUS WASTE
CLASS/CODE: US - Not applicable to finished product as manufactured for distribution into commerce .
CN - Not applicable to finished product as man ufactured for distribution into commerce .
EWC - Not applicable to finished product as manufactured for distribution into commerce .

ose as allowed b local ·urisdiction for the end-of-life characteristics as-dis osed.

i SECTION 14: TRANSPORTINFORMATION

GROUND- US-DOT/CAN-TDG/EU-ADR/APEC-ADR:
Proper Sh ippi ng Name Batteries, Wet, Filled with Acid
Hazard Class 8 ID Number UN2794
Packing Group Ill Labels Corrosive

AIRCRAFT- ICAO-IATA:
Proper Sh ipping Name Batteries, Wet, Filled with Acid
Hazard Class 8 ID Number UN2794
Packing Group II Labels Corrosive
Reference IA TA packing instructions 800
VESSEL - IMO-IMDG:
Proper Sh ippi ng Name Batteries, Wet, Filled with Acid
Hazard Class 8 ID Number UN2794
Packing Group Ill Labels Corrosive
Reference IMDG packing instructions P801
Additional Information
Transport requires proper packaging and paperwork, including the Nature and Quantity of goods , per applicable
origin/destination/customs points as-shipped .

i SECTION 15: REGULATORY INFORMATION


INVENTORY STATUS:
All com onents are listed on the TSCA; EINECS/ELINCS ; and DSL, unless noted otherwise below.

U.S. FEDERAL REGULATIONS:


TSCA Section Sb - Inventory Status : All chemicals comprising this product are either exempt or listed on the TSCA
Inventory.
TSCA Section 12b - Export Notification : If the finished product contains chem icals subject to TSCA Section 12b export
notification , they are listed below:
Chemical CAS #
None NA

CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT)


Chemicals present in the product which could require reporting under the statute :
Chemical CAS #
Lead 7439-92-1
Sulfuric acid 7664-93-9
SARA TITLE Ill (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
The finished product contains chemicals subject to the reporting requirements of Section 313 of SARA Title Ill.
Chemical CAS # % wt
Lead 7439-92-1 65
Sulfuric acid 7664-93-9 25
CERCLA SECTION 311/312 HAZARD CATEGORIES: Note that the finished product is exempt from these regulations,
bu t lead and sulfu ric acid above the thresholds are reportable on Tier II reports.
Fire Hazard No
Pressure Hazard No
Reactivity Hazard No
Immediate Hazard Yes (Sulfuric acid is Corrosive)
PAGE 6 OF 8 East Penn Manufacturing Co., Inc.
MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY WET, FILLED WITH
ACID
(US, CN, EU Version for International Trade)

Delayed Hazard No
Note : Sulfu ric acid is listed as an Extremely Hazardous Substance.
STATE REGULATIONS (US):
California Proposition 65
The following chemicals identified to exi st in the finished product as distributed into commerce are known to the State of
California to cause cancer, birth defects, or other re produ ctive harm :
Chemical CAS # %Wt
Arsenic (as arsenic oxides) 7440-38-2 <0 .1
Strong inorganic acid mists incl uding NA 25
sulfuric acid
Lead 7439-92-1 65
California Consumer Product Volatile Organic Compound Emissions
This Product is not regulated as a Consumer Product for purposes of GARB/OTC voe Regu lations , as-sold for the intended
pu rpose and into the industrial/Commercial supply chain .

INTERNATIONAL REGULATIONS (Non-US):


Canadian Domestic Substance List (DSL)
All ingredients remaining in the fin ished product as distributed into commerce are included on the Domestic Substances
List.
WHMIS Classifications
Class E: Corrosive materials present at greater than 1%
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all the information required by the Controlled Products Regulations.
NPRI and Ontario Regulation 127/01
This product contains the following chem icals subject to the reporting requirements of Canada NPRI +/or Ont. Reg .
127/01 :
Chemical CAS # %Wt
Lead 7439-92-1 65
Sulfuric acid 7664-93-9 25
European Inventory of Existing Commercial Chemical Substances (EINECS)
All ingredients remaining in the finished product as distributed into commerce are exempt from , or included on , the
European Inventory of Existing Commercial Chemical Substances.
European Communities (EC) Hazard Classification according to directives 67/548/EEC and 1999/45/EC.
A-Phrases $-Phrases
35, 36, 38 1/2, 26 , 30 , 45

Additional Information
This product may be subject to Restriction of Hazardous Substances (RoHS) regulations in Europe and China, or may be
regulated under additional regulations and laws not identified above, such as for uses other than described or as-
desiqned/as-intended by the manufacturer, or for distribution into specific domestic destinations.

I SECTION 16: OTHER INFORMATION

OTHER INFORMATION:
Distribution into Quebec to follow Canadian Controlled Product Regulations (CPR) 24(1) and 24(2).
Distribution into the EU to follow applicable Directives to the Use, Import/Export of the product as-sold .
SOURCES OF INFORMATION:
International Agency for Research on Cancer (1987), /ARC Monographs on the Evaluation of Carcinogenic Risks to Humans:
Overall Evaluations of Carcinogenicity: An updating of !ARC Monographs Volumes 1-42, Supplement 7, Lyon, France .
Ontario Ministry of Labour Regulation 654/86 . Regulations Respecting Exposure to Chemical or Biological Agents .
RTECS - Registry of Toxic Effects of Chem ical Substances , National institute for Occupational Safety and Health.

MSDS/SDS PREPARATION INFORMATION:


DATE OF ISSUE : 6 August 2007 SUPERCEDES: 29 January 2007

DISCLAIMER:
This Material Safety Data Sheet is based upon information and sources avail able at the time of preparation or revi sion date.
Information in the MSDS was obtained from sources which we believe are reliable, but are beyond our direct supe rvision or
PAGE 7 OF 8 East Penn Manufacturing Co.• Inc.
MATERIAL SAFETY DATA SHEET
LEAD ACID BATTERY WET, FILLED WITH
ACID
(US, CN, EU Version for International Trade)

control. We make no Warranty of Merchantability, Fitness for any particular purpose or any other Warranty, Expressed or
Implied, with respect to such information and we assume no liability resulting from its use. For this and oth er reasons, we do
not assume responsibility and expressly disclaim liability fo r loss, damage or expense arising out of or in any way connected
with the hand ling , storage , use or disposal of the prod uct. It is the obligation of each user of this product to determine the
su itabil ity of this product and com ply with the requirements of all applicable laws regarding use and disposal of this product.
For additional informat ion concerning East Penn Manufacturing Co., Inc. products or questions concerning the content of this
MS DS please contact your East Penn representative.
END

PAGE 8 OF 8 East Penn Manufacturing Co. 1 Inc.

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