SAFETY DATA SHEET

GENAPOL LA 090 Page 1

Substance key: 000000150096 Revision Date: 05/12/2015

Version : 2 - 1 / USA Date of printing :05/29/2015

SECTION 1. IDENTIFICATION

Identification of the Clariant Produkte (Deutschland) GmbH

company: Frankfurt am Main, 65926
Telephone No.: +49 69 305 18000

Information of the substance/preparation:

Product Safety 1-704-331-7710
Emergency tel. number: +1 800-424-9300 CHEMTREC

Trade name: GENAPOL LA 090

Material number: 191788
CAS number: 68551-12-2
Synonyms: Product Has No Synonyms

Primary product use: Emusifier for the techno-chemical industry

Chemical family: Ethoxylated Fatty Alcohol

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Acute toxicity (Oral) : Category 4

Serious eye damage : Category 1

GHS Label element

Hazard pictograms :

Signal word : Danger

Hazard statements : H302 Harmful if swallowed.

H318 Causes serious eye damage.

Precautionary statements : Prevention:

P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear eye protection/ face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER or doctor/ physician if you feel unwell. Rinse mouth.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor/ physician.
Disposal:
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Substance key: 000000150096 Revision Date: 05/12/2015

Version : 2 - 1 / USA Date of printing :05/29/2015

P501 Dispose of contents/ container to an approved waste

disposal plant.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components
Chemical Name CAS-No. Concentration (%)
Ethoxylated C12-16 Alcohols 68551-12-2 100
Any concentration shown as a range is to protect confidentiality or is due to batch variation.

SECTION 4. FIRST AID MEASURES

General advice : Remove/Take off immediately all contaminated clothing.

If inhaled : Move the victim to fresh air.

Give oxygen or artificial respiration if needed.
Get immediate medical advice/ attention.
Never give anything by mouth to an unconscious person.

In case of skin contact : Immediately flush skin with plenty of water while removing
contaminated clothing. Wash contaminated clothing before
reuse. If redness or irritation occurs, seek medical attention.

In case of eye contact : Immediately flush eyes with large amounts of water for at least
15 minutes, holding lids apart to ensure flushing of the entire
surface. Washing eyes within 1 minute is essential to achieve
maximum effectiveness. Seek medical attention immediately.

If swallowed : If conscious, give the patient 1-2 glasses of water (8-16 oz.)
and call a doctor. Never give anything by mouth to an
unconscious person. Induce vomiting only at the instructions
of a doctor or nurse.

Most important symptoms : The possible symptoms known are those derived from the
and effects, both acute and labelling (see section 2).
delayed No additional symptoms are known.

Notes to physician : None known.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray jet

Alcohol-resistant foam
Carbon dioxide (CO2)
Dry powder
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Substance key: 000000150096 Revision Date: 05/12/2015

Version : 2 - 1 / USA Date of printing :05/29/2015

Unsuitable extinguishing : High volume water jet

media

Specific hazards during : Burning produces noxious and toxic fumes.

firefighting

Emits toxic fumes under fire conditions. Product floats on

water creating a potential floating fire hazard..

Further information : Apply alcohol-type or all purpose-type foams by

manufacturers' recommended techniques for large fires. Use
carbon dioxide or dry chemical media for small fires. Do not
direct a solid stream of water or foam into hot burning pools;
this may cause frothing and increase fire intensity. Use self-
contained breathing apparatus and protective equipment.

Apply alcohol-type or all purpose-type foams by

manufacturers' recommended techniques for large fires. Use
carbon dioxide or dry chemical media for small fires. Do not
direct a solid stream of water or foam into hot burning pools;
this may cause frothing and increase fire intensity. Use self-
contained breathing apparatus and protective equipment.

Special protective equipment : Use breathing apparatus.

for firefighters Wear flame-proof clothes, flame-proof gloves, and, if
necessary, flame-proof hood as well as helmet and fire-
brigade boots when fighting fire.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Stay upwind/ keep distance from source.

protective equipment and Wear suitable protective equipment.
emergency procedures Wearing appropriate personal protective equipment, contain
spill, collect into suitable container. For large spills, contain
spills with dikes of soil or commercially available diking
material and collect into suitable containers for disposal.
Avoid washing spills into sewers and waterways. This product
is toxic to fish in concentrations of 1 to 10 mg/l.

Environmental precautions : Do not allow to enter drains or waterways

Methods and materials for : Pick up with sand or oil absorbing material.
containment and cleaning up Take up mechanically

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Observe the general rules of industrial fire protection
fire and explosion

Advice on safe handling : Avoid contact with skin and eyes.

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Substance key: 000000150096 Revision Date: 05/12/2015

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Technical : Keep container closed.

measures/Precautions

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

No level has been established by OSHA, NIOSH, ACGIH.
Engineering measures : Local ventilation recommended - mechanical ventilation may
be used.

Personal protective equipment

Respiratory protection : If aerosols, mists, or dusts are generated from the use of this
product or in conjunction with spill cleanup or emergency
response, use NIOSH /MSHA approved respiratory
protection.

Hand protection

Remarks : Butyl Rubber, PVC Or Neoprene.

Eye protection : Tightly fitting safety goggles

Skin and body protection : Protective clothing to minimize skin contact should be worn.
Chemically resistant safety shoes. Wash contaminated
clothing with soap and water and dry before reuse. Safety
showers and eyewash stations should be provided in all
areas where this material is handled.

Protective measures : Avoid contact with skin.

Avoid contact with eyes.

Hygiene measures : When using do not eat or drink.

When using do not smoke.
Keep away from food and drink.
Wash hands immediately after work, if necessary take a
shower
Keep working clothes separately.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Liquid

Colour : white

Odour : characteristic

Odour Threshold : not tested.

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Substance key: 000000150096 Revision Date: 05/12/2015

Version : 2 - 1 / USA Date of printing :05/29/2015

pH : 6 - 8, 1 % (20 °C)Isopropanol/Water 3:1

Melting point : not determined

Boiling point : not determined

Flash point : > 237 °C

Evaporation rate : not tested.

Upper explosion limit : not tested.

Lower explosion limit : not tested.

Vapour pressure : not tested.

Relative vapour density : not tested.

Density : 0.97 g/cm3 (25 °C)

Bulk density : Not applicable

Solubility(ies)
Water solubility : soluble (20 °C)

Solubility in other solvents : not tested.

Solvent: fat

Partition coefficient: n- : not tested.

octanol/water

Auto-ignition temperature : approx.

230 °C
Method: DIN 51794

Decomposition temperature : No decomposition if used as directed.

Viscosity
Viscosity, dynamic : not determined

Viscosity, kinematic : not tested.

Explosive properties : no data available

Oxidizing properties : Not applicable

Molecular weight : Method: <** Phrase does not exist: No di - **>

SECTION 10. STABILITY AND REACTIVITY

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Substance key: 000000150096 Revision Date: 05/12/2015

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Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions Stable

Conditions to avoid : Strong acids and oxidizing agents

Strong bases

Incompatible materials : Strong oxidizing agents

Hazardous decomposition : Toxic gases/vapours

products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat): 500 - 2,000 mg/kg

Acute inhalation toxicity : Remarks: not tested.

Acute dermal toxicity : Remarks: not tested.

Skin corrosion/irritation
Product:
Species: Rabbit
Result: No skin irritation

Serious eye damage/eye irritation

Product:
Species: rabbit eye
Result: Risk of serious damage to eyes.

Respiratory or skin sensitisation

Product:
Remarks: not tested.

Germ cell mutagenicity

Product:
Germ cell mutagenicity - : No information available.
Assessment

Carcinogenicity
Product:
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Substance key: 000000150096 Revision Date: 05/12/2015

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Carcinogenicity - : No information available.

Assessment

IARC Not listed

OSHA Not listed

NTP Not listed

Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment

No indications of toxic effects were observed in reproduction

studies in animals.

STOT - single exposure

Product:
Remarks: not tested.

STOT - repeated exposure

Product:
Remarks: not tested.

Repeated dose toxicity

Product:
Remarks: not tested.

Aspiration toxicity
Product:
no data available

Experience with human exposure

Product:
General Information : The possible symptoms known are those derived from the
labelling (see section 2).

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Toxicity to fish : LC50 (Danio rerio (zebra fish)): 1 - 10 mg/l
Exposure time: 96 h
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Substance key: 000000150096 Revision Date: 05/12/2015

Version : 2 - 1 / USA Date of printing :05/29/2015

Method: OECD Test Guideline 203

Toxicity to daphnia and other :

aquatic invertebrates Remarks: not tested.

Toxicity to algae :
Remarks: not tested.

Toxicity to bacteria : EC50: > 1,000 mg/l

Method: OECD Test Guideline 209

Persistence and degradability

Product:
Biodegradability : Biodegradation: > 80 %
Exposure time: 28 d
Method: OECD Test Guideline 301E
Remarks: Readily biodegradable, according to appropriate
OECD test.

Chemical Oxygen Demand : 2,277 mg/g

(COD)

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: not tested.

Mobility in soil
Product:
Distribution among : Remarks: not tested.
environmental compartments

Other adverse effects

Product:
Results of PBT and vPvB : Remarks: no data available
assessment

Additional ecological : By analogy with a product of similar composition

information

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
RCRA - Resource : No -- Not as sold.
Conservation and Recovery
Authorization Act
Waste Code : NONE
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Substance key: 000000150096 Revision Date: 05/12/2015

Version : 2 - 1 / USA Date of printing :05/29/2015

Waste from residues : Must be incinerated in a suitable incineration plant holding a

permit delivered by the competent authorities.

Contaminated packaging : Packaging that cannot be cleaned should be disposed of as

product waste

SECTION 14. TRANSPORT INFORMATION

DOT not restricted

IATA not restricted
IMDG not restricted

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Acute Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting

requirements of SARA Title III, Section 302.

SARA 313 : This product does not contain any toxic chemical listed under
Section 313 of the Emergency Planning and Community
Right-To-Know Act of 1986.

Clean Water Act

Contains no known priority pollutants at concentrations greater than 0.1%.

The components of this product are reported in the following inventories:

TSCA : On TSCA Inventory

Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)

SECTION 16. OTHER INFORMATION

Further information
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GENAPOL LA 090 Page 10

Substance key: 000000150096 Revision Date: 05/12/2015

Version : 2 - 1 / USA Date of printing :05/29/2015

Observe national and local legal requirements

This product may contain trace amounts of Ethylene Oxide (75-21-8) which may accumulate
in the headspace of shipping and storage containers and in enclosed areas where the
product is handled or used and as such may be regulated by OSHA's Ethylene Oxide
standard (29 CFR 1910.1047). Ethylene Oxide is listed as a human carcinogen by OSHA;
and a potential human carcinogen by NTP and IARC. At excess levels, Ethylene Oxide may
present reproductive, mutagenic, genotoxic, neurologic, and sensitization hazards in humans.
Users should monitor personnel to determine levels of exposure and take appropriate action
to protect employees and to comply with the OSHA standard. OSHA Ethylene Oxide
exposure limit: OSHA Action level: 0.5 ppm for 8-hr twa. OSHA Permissible Exposure limit:
1 ppm for 8-hr twa. OSHA Excursion limit: 5 ppm for 15 minutes. ACGIH Threshold Limit
value for Ethylene Oxide: 1 ppm for 8-hr twa.

Revision Date : 05/12/2015

This information is supplied under the OSHA Hazard Communication Standard, 29 CFR
1910.1200, and is offered in good faith based on data available to us that we believe to be true
and accurate. The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable to the material. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are
appropriate for that use. No warranty, express or implied, is made regarding the accuracy of
this data, the hazards connected with the use of the material, or the results to be obtained
from the use thereof. We assume no responsibility for damage or injury from the use of the
product described herein. Data provided here are typical and not intended for use as product
specifications.

US / USA