Safety Data Sheet

Revision Number: 003.1 Issue date: 05/22/2018

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: Loctite PL400 Subfloor Adhesive IDH number: 1652275
Product type: Assembly adhesive, solvent
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.

HAZARD CLASS HAZARD CATEGORY

FLAMMABLE LIQUID 2
EYE IRRITATION 2A

PICTOGRAM(S)

Precautionary Statements

Prevention: Keep away from heat, sparks, open flames, hot surfaces - no smoking. Keep container tightly
closed. No release into water. Use explosion-proof equipment. Use non-sparking tools. Take
action to prevent static discharges. Wash affected area thoroughly after handling. Wear
protective gloves, eye protection, and face protection.
Response: If on skin (or hair): Take off immediately all contaminated clothing. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention. In case of fire: Use foam, dry
chemical or carbon dioxide to extinguish.
Storage: Store in a well-ventilated place. Keep cool.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Component(s) CAS Number Percentage*
Limestone 1317-65-3 20 - 30

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive

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Kaolin 1332-58-7 10 - 20
Acetone 67-64-1 10 - 20
Resin acids and Rosin acids, esters with
8050-26-8 1-5
pentaerythritol
Methyl acetate 79-20-9 1-5
Titanium dioxide 13463-67-7 0.1 - 1
Quartz (SiO2), <1% respirable 14808-60-7 0.1 - 1

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES

Inhalation: If inhaled, immediately remove the affected person to fresh air. If breathing is
difficult, give oxygen. If symptoms develop and persist, get medical attention.

Skin contact: Immediately wash skin thoroughly with soap and water. If symptoms develop
and persist, get medical attention.

Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15
minutes, and seek immediate medical attention.

Ingestion: Do not induce vomiting, seek medical advice immediately.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Extinguishing media: Foam, dry chemical or carbon dioxide. In case of fire, keep containers cool
with water spray.

Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in
pressure-demand or other positive pressure mode. Wear full protective
clothing.

Unusual fire or explosion hazards: Closed containers may explode when exposed to extreme heat. Vapors may
form explosive mixtures with air. Vapors are heavier than air and may travel
along floor to an ignition source.

Hazardous combustion products: Upon decomposition, this product emits carbon monoxide, carbon dioxide
and/or low molecular weight hydrocarbons.

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Eliminate all sources of ignition or flammables that may come into contact with
a spill of this material. Ventilate area. Prevent further leakage or spillage if
safe to do so. Wear appropriate protective equipment and clothing during
clean-up. Do not allow product to enter sewer or waterways.

Clean-up methods: Use noncombustible absorbent material such as sand. Use non-sparking tools
for clean-up. Absorb spill with inert material. Shovel material into appropriate
container for disposal. Dispose of according to Federal, State and local
governmental regulations.

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive

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 7. HANDLING AND STORAGE
Handling: Do not pressurize, cut, heat or weld containers. Empty product containers
may contain product residue. Do not reuse empty containers. Use only in
well-ventilated areas. Keep out of the reach of children. Keep away from heat,
spark and flame. Containers should be grounded and bonded to the receiving
container.

Storage: For safe storage, store between -20 °C (-4°F) and 50 °C (122°F)
Keep away from heat, spark and flame. Keep containers closed when not in
use.

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive

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 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

5 mg/m3 PEL
10 mg/m3 TWA Total Respirable fraction.
Limestone None None
dust. 15 mg/m3 PEL Total
dust.
5 mg/m3 PEL
Respirable fraction.
15 mg/m3 PEL Total
dust.
15 MPPCF TWA
2 mg/m3 TWA Respirable fraction.
Kaolin None None
Respirable fraction. 50 MPPCF TWA
Total dust.
5 mg/m3 TWA
Respirable fraction.
15 mg/m3 TWA Total
dust.
250 ppm TWA 1,000 ppm (2,400
Acetone None None
500 ppm STEL mg/m3) PEL
Resin acids and Rosin acids, esters with
None None None None
pentaerythritol
200 ppm TWA 200 ppm (610
Methyl acetate None None
250 ppm STEL mg/m3) PEL
15 mg/m3 PEL Total
dust.
15 MPPCF TWA
Respirable fraction.
15 mg/m3 TWA Total
Titanium dioxide 10 mg/m3 TWA None None
dust.
50 MPPCF TWA
Total dust.
5 mg/m3 TWA
Respirable fraction.
2.4 MPPCF TWA
Respirable.
0.1 mg/m3 TWA
Respirable.
0.05 mg/m3 TWA
0.025 mg/m3 TWA (Respirable dust.)
Quartz (SiO2), <1% respirable None None
Respirable fraction. (Respirable dust.)
0.025 mg/m3
OSHA_ACT
(Respirable dust.)
0.05 mg/m3 PEL
Respirable dust.

Engineering controls: Local exhaust ventilation is recommended when general ventilation is not
sufficient to control airborne contamination below occupational exposure
limits.

Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed
established exposure limits exists. When workplace hazards warrant the use
of a respirator, appropriate respirators must be used, and a program that
follows 29 CFR 1910.134 must be followed.

Eye/face protection: Safety goggles or safety glasses with side shields.

Skin protection: Chemical resistant, impermeable gloves.

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive

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 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Beige
Odor: Acetone-like
Odor threshold: Not available.
pH: 7
Vapor pressure: Not available.
Boiling point/range: 56 - 57 °C (132.8 - 134.6 °F)
Melting point/ range: < 0 °C (< 32°F)
Specific gravity: 1.44
Vapor density: 2.0
Flash point: -17 °C (1.4 °F)
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Flammability: Not applicable
Evaporation rate: 14.4
Solubility in water: Slightly soluble
Partition coefficient (n-octanol/water): Not available.
VOC content: 0.22 %; 5.67 g/l (by weight, calculated using CARB method; g/L less water,
less exempts calculated using SCAQMD method)
Viscosity: 375,000 mPa.s
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions of storage and use.

Hazardous reactions: Will not occur.

Hazardous decomposition Carbon dioxide, carbon monoxide and irritating and/or toxic gases and particulate may be
products: generated by thermal decomposition or combustion.

Incompatible materials: Strong oxidizing agents.

Reactivity: Not available.

Conditions to avoid: Heat, flames, sparks and other sources of ignition.

11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Inhalation, Skin contact

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive

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 Potential Health Effects/Symptoms

Inhalation: Irritates the nose, throat and respiratory system. Exposure to high doses may cause central
nervous system depression. Such doses may also cause adverse effects in the liver, kidneys,
and lungs. Abrasion of cured material such as by sanding or grinding could release respirable
particles of silica quartz, a cancer hazard by inhalation. Normal use of this product causes no
such release. Reports have associated repeated and prolonged overexposure to solvents with
permanent brain and nervous system damage. Intentional misuse by deliberately concentrating
and inhaling the contents may be harmful or fatal.
Skin contact: Prolonged and/or repeated skin contact with this product may cause irritation/dermatitis.
Eye contact: Contact with eyes can cause eye irritation. Symptoms may include stinging, tearing, redness,
swelling, and blurred vision.
Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Limestone None Nuisance dust
Oral LD50 (Rat) = > 5,000 mg/kg
Kaolin Nuisance dust
Dermal LD50 (Rat) = > 5,000 mg/kg
Oral LD50 (Mouse) = 5.2 g/kg
Oral LD50 (Mouse) = 3,000 mg/kg
Oral LD50 (Rabbit) = 5,340 mg/kg
Acetone Oral LD50 (Rat) = 5,800 mg/kg Central nervous system, Irritant
Oral LD50 (Rat) = 9,800 mg/kg
Dermal LD50 (Rabbit) = 20,000 mg/kg
Inhalation LC50 (Rat, 4 h) = 76 mg/l
Resin acids and Rosin acids, esters with
None Irritant
pentaerythritol
Methyl acetate Oral LD50 (Rabbit) = 3.7 g/kg Blood, Central nervous system, Eyes, Irritant
Irritant, Respiratory, Some evidence of
Titanium dioxide None
carcinogenicity
Immune system, Lung, Some evidence of
Quartz (SiO2), <1% respirable None
carcinogenicity

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Limestone No No No
Kaolin No No No
Acetone No No No
Resin acids and Rosin acids, esters with
No No No
pentaerythritol
Methyl acetate No No No
Titanium dioxide No Group 2B No
Known To Be Human
Quartz (SiO2), <1% respirable Group 1 Yes
Carcinogen.

12. ECOLOGICAL INFORMATION

Ecological information: Not available.

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive

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 13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.

Hazardous waste number: It is the responsibility of the user to determine if an item is hazardous as
defined in the Resource Conservation and Recovery Act (RCRA) at the time of
disposal. Product uses, transformations, mixtures, processes, etc., may
render the resulting material hazardous, under the criteria of ignitability,
corrosivity, reactivity and toxicity characteristics of the Toxicity Characteristics
Leaching Procedure (TCLP) 40 CFR 261.20-24. If discarded, this product is
considered a RCRA ignitable waste, D001.

14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II

International Air Transportation (ICAO/IATA)

Proper shipping name: Adhesives
Hazard class or division: 3
Identification number: UN 1133
Packing group: II

Water Transportation (IMO/IMDG)

Proper shipping name: ADHESIVES
Hazard class or division: 3
Identification number: UN 1133
Packing group: II

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.

CERCLA/SARA Section 311/312: Fire, Immediate Health, Delayed Health
CERCLA/SARA Section 313: None above reporting de minimis.

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: This Safety Data Sheet contains changes
from the previous version in Section(s): 2, 3, 16

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive

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 Prepared by: Product Safety and Regulatory Affairs

Issue date: 05/22/2018

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 1652275 Product name: Loctite PL400 Subfloor Adhesive

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