Scribd Logo
Upload

Welcome to Scribd!

  • 56 views

    Material Safety Data Sheet: 1. Identification of The Substance/Preparation and Company

    Uploaded by

    Ahmed Khameis

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Material Safety Data Sheet: 1. Identification of The Substance/Preparation and Company

    Uploaded by

    Ahmed Khameis
    56 views3 pages

    Original Title

    Alcolin SDS

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    56 views3 pages

    Material Safety Data Sheet: 1. Identification of The Substance/Preparation and Company

    Uploaded by

    Ahmed Khameis

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    ®

    MATERIAL SAFETY DATA SHEET


    _________________________________________________________________________________________________________

    1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY

    PERMOSEAL (PTY) LTD Tel. +27 (0)21 555-7400


    Beverley Close Fax +27 (0)21 552-1848
    Montague Gardens, 7441 Toll-free No. 0800 222 400
    Cape Town Website www.alcolin.com

    TRADE NAME ALCOLIN WATERPROOF GLUE Chemical abstract no. Mixture


    Chemical family Isocyanate hardener NIOSH no. Unknown
    Chemical name None Hazchem code None
    Synonyms None UN no. None

    2. COMPOSITION / INFORMATION OF INGREDIENTS

    Ingredient CAS No. Approx Hazard Classification & Risk Phrases EEC No

    4,4’-methylenediphenyldiisocyanate;
    101-68-8 75-90% Xn, R20, R36/37/38, R42/43 202-966-0
    diphenylmethane-4,4’-diisocyanate

    3. HAZARDS IDENTIFICATION

    Main hazard: Irritant, Harmful by Inhalation


    Health effects: Eyes Moderate irritant to eyes
    Health effects: Skin Mild irritant on skin
    Health effects: Ingestion Harmful if swallowed. May be fatal
    Health effects: Inhalation Mist/vapours at elevated temperatures may cause irritation in respiratory system.

    4. FIRST- AID MEASURES

    Product in eyes Remove any contact lenses from the eyes before rinsing thoroughly with plenty of water (lift eye lids).
    Rinse for at least 15 minutes. Seek medical attention if any discomfort continues
    Product on skin Wash skin with soap and water – do not use solvents! Seek medical attention if irritation persists
    Product ingested Never make an unconscious person vomit or drink fluids. Get the affected person to drink a lot of
    water in small gulps. Do not induce vomiting. Seek medical attention if discomfort continues
    Product inhaled Move to fresh air in case of accidental inhalation of vapours or decomposition products

    5. FIRE-FIGHTING MEASURES

    Extinguishing media Water, dry chemical powder, foam, carbon dioxide or sand
    Special hazards In case of fire, hazardous combustion-gases are formed – CO. Toxic vapours are also released.
    Under certain conditions of combustion traces of other toxic substances cannot be excluded
    Protective clothing In case of fire, wear respiratory protection

    6. ACCIDENTAL RELEASE MEASURES

    Personal precautions Surface may be slippery


    Environmental precautions Avoid contamination of ground and water surfaces
    Small spills If recovery is not feasible, absorb with dry sand, soil or non-reactive absorbent material or coagulate
    by sprinkling sodium chloride over the spill. Place in a container suitable for disposal
    Large spills Stop leak if without risk. Ventilate area. Prevent entry into drains or sewers. Clean as per small spills

    MC/D182/Issue 02/July 2010 1 of 3 Uncontrolled copy: 30/11/2010


    7. HANDLING AND STORAGE

    Suitable material Steel container lined with polyethylene or polypropylene, polyethylene, PVC containers
    Storage precautions Keep product in a sealed container at temperatures between 5 and 30°C. Minimize c ontact with
    atmosphere to prevent contamination with micro-organisms

    8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

    Occupational exposure limits None


    Engineering controls Provide good ventilation when handling large quantities. No special measures are required if stored
    and handled as above
    Respiratory Protection Not required under normal conditions of use in a well-ventilated space
    Hand Protection Rubber gloves should be used if there is a risk of direct contact onto skin
    Eye Protection Safety glasses
    Skin Protection Observe the usual precautions when handling chemicals. Remove soiled or soaked clothing
    immediately
    Other Protection Wash hands at the end of each work shift and before eating

    9. PHYSICAL PROPERTIES

    • Appearance Honey coloured viscous liquid


    • Odour Mild aromatic odour
    • Flash point Approx >200°C
    • 3
    Density (g/cm @ 20°C) Approx 1.15
    • Solubility water Soluble

    10. STABILITY AND REACTIVITY

    Conditions to avoid Exposed air will form dry polymer skins. Avoid temperature extremes: < 5°C and above 30°C
    Incompatible materials Organic solvents, strong acids, strong alkalis, salts, oxidising agents, amines
    Hazardous decomposition products In case of fire, dense black smoke is formed. Carbon Monoxide, Nitrogen oxides, vapours of
    isocyanate and traces of cyanic acid may be formed

    11. TOXICOLOGICAL INFORMATION

    Acute Toxicity LD50 Oral Rat 15000mg/kg


    4,4’-methylenediphenyldiisocyanate
    LD50 Oral Rat 4700mg/kg

    12. ECOLOGICAL INFORMATION

    This product has not been tested for environmental effects. Based on its components, this product is unlikely to result in any
    detrimental ecological effects

    13. DISPOSIBLE CONSIDERATIONS

    Disposal methods Whatever cannot be saved for recovery/recycling should be handled according to current local waste
    disposal legislation. Do not allow to enter drains or sewers. Do not allow to enter any body of water
    Disposal of packaging Contaminated packaging should be emptied as far as possible and after appropriate cleaning may be
    taken for reuse or disposed of in approved facility in accordance with current local legislation

    MC/D182/Issue 02/July 2010 2 of 3 Uncontrolled copy: 30/11/2010


    14. TRANSPORT REGULATIONS

    UN no Not regulated
    Substance identity no. Not regulated
    Road / rail transport ADR / RID Not regulated
    Marine Transport IMDG Not regulated
    Inland waterways ADNR Not regulated
    Air transport IATA Not regulated

    15. REGULATORY INFORMATION

    EEC hazard classification 202-966-0


    Risk phrases R20, R36/37/38, R42/43
    Safety phrases S23, S26, S36/37, S45, S51
    National legislation Not regulated

    16. OTHER INFORMATION

    For intended use and applications see the Technical Date Sheet for the product. The information provided in this Material Safety
    Data Sheet is based on the present state of our knowledge. This data is intended to enable safety assessments to be made and
    should not be construed as guaranteeing specific properties. Recipients of our product must take responsibility for observing existing
    laws and regulations

    Risk Phrases R20/21 Harmful by inhalation and in contact with skin


    R36 Irritating to eyes
    R38 Irritating to skin

    Safety Phrases S24 Avoid contact with skin


    S29/56 Do not empty into drains, dispose of this material and it’s container at hazardous or special
    waste collection point
    S46 If swallowed, seek medical advice immediately and show this container or label
    S36/37/39 Wear suitable protective clothing, gloves and eye/face protection
    S51 Use only in well-ventilated areas

    MC/D182/Issue 02/July 2010 3 of 3 Uncontrolled copy: 30/11/2010

    You might also like