MSDS 113 Soleng en 8.0

Safety Data Sheet
sulphur dioxide
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Reference number: 113
Revision date: 19/12/2022
Supersedes version of: 28/01/2019
Version: 8.0
Danger
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Trade name : sulphur dioxide
SDS no : 113
Other means of identification : sulphur dioxide
CAS-No. : 7446-09-5
EC-No. : 231-195-2
EC Index-No. : 016-011-00-9
REACH registration No : 01-2119485028-34
Chemical formula : SO2
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses : Industrial and professional uses. Perform risk assessment prior to use.
See the list of identified uses and exposure scenarios in the annex of the safety data sheet.
Contact supplier for more information on uses.
Uses advised against : Consumer use.
1.3. Details of the supplier of the safety data sheet

Company identification : SOL SpA
Via G. Borgazzi 27
20900 MONZA - Italia
T +39 039 23.96.1
http:\\www.sol.it
[email protected]
E-Mail address (competent person) : [email protected]
1.4. Emergency telephone number

Emergency telephone number : Linea verde SET - 800452661 (24h/24h, 365 giorni l'anno); Dall'estero +39 0283421263
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Physical hazards Gases under pressure : Liquefied gas H280
Health hazards Acute toxicity (inhalation:gas) Category 3 H331
Skin corrosion/irritation, Category 1, Sub-Category 1B H314
Serious eye damage/eye irritation, Category 1 H318
2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :
GHS04 GHS05 GHS06

Signal word (CLP) : Danger
SOL SpA EN (English) 1/24

Via G. Borgazzi 27 20900 MONZA Italia, +39 039 23.96.1
Safety Data Sheet
sulphur dioxide
Hazard statements (CLP) : H280 - Contains gas under pressure; may explode if heated.
H331 - Toxic if inhaled.
H314 - Causes severe skin burns and eye damage.
EUH071 - Corrosive to the respiratory tract.
Precautionary statements (CLP)
- Prevention : P260 - Do not breathe gas, vapours.
P280 - Wear protective gloves, protective clothing, eye protection, face protection.
- Response : P303+P361+P353+P315 - IF ON SKIN : (or hair) Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower. Get immediate medical advice /
attention.
P304+P340+P315 - IF INHALED : Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Get immediate medical advice / attention.
P305+P351+P338+P315 - IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical
advice / attention.
- Storage : P405 - Store locked up.
P403 - Store in a well-ventilated place.
2.3. Other hazards

None.
SECTION 3: Composition/information on ingredients
3.1. Substances
Name % Product identifier Classification according to Regulation

(EC) No. 1272/2008 [CLP]
sulphur dioxide 100 CAS-No.: 7446-09-5 Press. Gas (Liq.), H280

EC-No.: 231-195-2 Acute Tox. 3 (Inhalation:gas), H331
EC Index-No.: 016-011-00-9 Skin Corr. 1B, H314
REACH registration No: 01- Eye Dam. 1, H318
2119485028-34-0032
Name Product identifier Specific concentration limits
sulphur dioxide CAS-No.: 7446-09-5 ( 1 ≤C < 100) STOT SE 3, H335

EC-No.: 231-195-2
EC Index-No.: 016-011-00-9
REACH registration No: 01-2119485028-
34-0032
Contains no other components or impurities which will influence the classification of the product.
Not applicable
3.2. Mixtures
SECTION 4: First aid measures

4.1. Description of first aid measures
- Inhalation : Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep
victim warm and rested. Call a doctor. Perform cardiopulmonary resuscitation if breathing
stopped.
- Skin contact : Remove contaminated clothing. Drench affected area with water for at least 15 minutes.
In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing. Obtain
medical assistance.
- Eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes.
- Ingestion : Ingestion is not considered a potential route of exposure.

Via G. Borgazzi 27 20900 MONZA Italia, +39 039
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4.2. Most important symptoms and effects, both acute and delayed
May cause severe chemical burns to skin and cornea. Suitable first-aid treatment should be
immediately available. Seek medical advice before using product.
Prolonged exposure to small concentrations may result in pulmonary oedema.
Material is destructive to tissue of the mucuous membranes and upper respiratory tract.
Cough, shortness of breath, headache, nausea.
See section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Obtain medical assistance.
Treat with corticosteroid spray as soon as possible after inhalation.
SECTION 5: Firefighting measures

5.1. Extinguishing media
- Suitable extinguishing media : Water spray or fog.
- Unsuitable extinguishing media : Do not use water jet to extinguish.
5.2. Special hazards arising from the substance or mixture

Specific hazards : Exposure to fire may cause containers to rupture/explode.
Hazardous combustion products : None that are more hazardous than the product itself.
5.3. Advice for firefighters

Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat
radiation may cause gas receptacles to rupture. Cool endangered receptacles with water
spray jet from a protected position. Prevent water used in emergency cases from entering
sewers and drainage systems.
If possible, stop flow of product.
Use water spray or fog to knock down fire fumes if possible.
Move containers away from the fire area if this can be done without risk.
Special protective equipment for fire fighters : Wear gas tight chemically protective clothing in combination with self contained breathing
apparatus.
Standard EN 943-2: Protective clothing against liquid and gaseous chemicals, aerosols and
solid particles. Gas-tight chemical protective suits for emergency teams.
Standard EN 137 - Self-contained open-circuit compressed air breathing apparatus with full
face mask.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Try to stop release.
Evacuate area.
Monitor concentration of released product.
Wear self-contained breathing apparatus when entering area unless atmosphere is proved
to be safe.
Use chemically protective clothing.
Ensure adequate air ventilation.
Prevent from entering sewers, basements and workpits, or any place where its
accumulation can be dangerous.
Act in accordance with local emergency plan.
Stay upwind.
6.2. Environmental precautions

Reduce vapour with fog or fine water spray.
Try to stop release.

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6.3. Methods and material for containment and cleaning up

Hose down area with water.
Keep area evacuated and free from ignition sources until any spilled liquid has evaporated
(ground free from frost).
Wash contaminated equipment or sites of leaks with copious quantities of water.
6.4. Reference to other sections

See also sections 8 and 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Safe use of the product : The product must be handled in accordance with good industrial hygiene and safety
procedures.
Only experienced and properly instructed persons should handle gases under pressure.
Consider pressure relief device(s) in gas installations.
Ensure the complete gas system was (or is regularily) checked for leaks before use.
Do not smoke while handling product.
Avoid exposure, obtain special instructions before use.
Use only properly specified equipment which is suitable for this product, its supply pressure
and temperature. Contact your gas supplier if in doubt.
Installation of a cross purge assembly between the container and the regulator is
recommended.
Purge system with dry inert gas (e.g. helium or nitrogen) before gas is introduced and when
system is placed out of service.
Avoid suck back of water, acid and alkalis.
Do not breathe gas.
Avoid release of product into work area.
Safe handling of the gas receptacle : Refer to supplier's container handling instructions.
Do not allow backfeed into the container.
Protect containers from physical damage; do not drag, roll, slide or drop.
When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.)
designed to transport cylinders.
Leave valve protection caps in place until the container has been secured against either a
wall or bench or placed in a container stand and is ready for use.
If user experiences any difficulty operating valve discontinue use and contact supplier.
Never attempt to repair or modify container valves or safety relief devices.
Damaged valves should be reported immediately to the supplier.
Keep container valve outlets clean and free from contaminants particularly oil and water.
Replace valve outlet caps or plugs and container caps where supplied as soon as container
is disconnected from equipment.
Close container valve after each use and when empty, even if still connected to equipment.
Never attempt to transfer gases from one cylinder/container to another.
Never use direct flame or electrical heating devices to raise the pressure of a container.
Do not remove or deface labels provided by the supplier for the identification of the content
of the container.
Suck back of water into the container must be prevented.
Open valve slowly to avoid pressure shock.
7.2. Conditions for safe storage, including any incompatibilities

Observe all regulations and local requirements regarding storage of containers.
Containers should not be stored in conditions likely to encourage corrosion.
Container valve guards or caps should be in place.
Containers should be stored in the vertical position and properly secured to prevent them
from falling over.
Stored containers should be periodically checked for general condition and leakage.
Keep container below 50°C in a well ventilated place.
Store containers in location free from fire risk and away from sources of heat and ignition.
Keep away from combustible materials.

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7.3. Specific end use(s)

None.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
sulphur dioxide (7446-09-5)
EU - Indicative Occupational Exposure Limit (IOEL)
Local name Sulphur dioxide
IOEL TWA 1.3 mg/m³
IOEL TWA [ppm] 0.5 ppm
IOEL STEL 2.7 mg/m³
IOEL STEL [ppm] 1 ppm
Remark SCOEL Recommendations (2009)
Regulatory reference COMMISSION DIRECTIVE (EU) 2017/164
sulphur dioxide (7446-09-5)
DNEL: Derived no effect level (Workers)
Acute - local effects, inhalation 2.7 mg/m³
Long-term - local effects, inhalation 1.3 mg/m³
PNEC (Predicted No-Effect Concentration) : None established.
8.2. Exposure controls

8.2.1. Appropriate engineering controls
Provide adequate general and local exhaust ventilation.
Product to be handled in a closed system.
Systems under pressure should be regularily checked for leakages.
Ensure exposure is below occupational exposure limits (where available).
Gas detectors should be used when toxic gases may be released.
Consider the use of a work permit system e.g. for maintenance activities.
8.2.2. Individual protection measures, e.g. personal protective equipment

A risk assessment should be conducted and documented in each work area to assess the
risks related to the use of the product and to select the PPE that matches the relevant risk.
The following recommendations should be considered:
PPE compliant to the recommended EN/ISO standards should be selected.
• Eye/face protection : Wear goggles and a face shield when transfilling or breaking transfer connections.
Standard EN 166 - Personal eye-protection - specifications.
Provide readily accessible eye wash stations and safety showers.
• Skin protection
- Hand protection : Wear working gloves when handling gas containers.
Wear chemically resistant protective gloves.
Standard EN 388 - Protective gloves against mechanical risk, performance level 1 or higher.
Wear cold insulating gloves when transfilling or breaking transfer connections.
Standard EN 511 - Cold insulating gloves.
Standard EN 374 - Protective gloves against chemicals.
Chloroprene rubber (CR).

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- Other : Keep suitable chemically resistant protective clothing readily available for emergency use.
Standard EN943-1 - Full protective suits against liquid, solid and gaseous chemicals.
Wear safety shoes while handling containers.
Standard EN ISO 20345 - Personal protective equipment - Safety footwear.
• Respiratory protection : Gas filters may be used if all surrounding conditions e.g. type and concentration of the
contaminant(s) and duration of use are known.
Use gas filters with full face mask, where exposure limits may be exceeded for a short-term
period, e.g. connecting or disconnecting containers.
Standard EN 137 - Self-contained open-circuit compressed air breathing apparatus with full
face mask.
Recommended: Filter E (yellow).
Gas filters do not protect against oxygen deficiency.
Standard EN 14387 - Gas filter(s), combined filter(s) and standard EN136, full face masks .
Keep self contained breathing apparatus readily available for emergency use.
Self contained breathing apparatus is recommended, where unknown exposure may be
expected, e.g. during maintenance activities on installation systems.
• Thermal hazards : None in addition to the above sections.
8.2.3. Environmental exposure controls

Refer to local regulations for restriction of emissions to the atmosphere. See section 13 for
specific methods for waste gas treatment.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance
- Physical state at 20°C / 101.3kPa : Gas.
- Colour : Colourless.
Odour : Pungent.
Odour threshold is subjective and inadequate to warn of overexposure.
Melting point / Freezing point : -75.5 °C
-75.5 °C
Boiling point : -10 °C
Flammability : Non flammable.
Lower explosion limit : Not available
Upper explosion limit : Not available
Flash point : Not applicable for gases and gas mixtures.
Auto-ignition temperature : Non flammable.
Decomposition temperature : Not applicable.
pH : If dissolved in water pH-value will be affected.
Viscosity, kinematic : No reliable data available.
Water solubility [20°C] : Not available
Partition coefficient n-octanol/water (Log Kow) : Not applicable for gas mixtures.
Vapour pressure [20°C] : 3.3 bar(a)
Vapour pressure [50°C] : 8.4 bar(a)
Density and/or relative density : Not applicable.
Relative vapour density (air=1) : 2.3
Particle characteristics : Not applicable.
9.2. Other information

9.2.1. Information with regard to physical hazard classes
Explosive properties : Not applicable.
Explosion limits : Non flammable.
Oxidising properties : Not applicable.
Critical temperature [°C] : 158 °C
9.2.2. Other safety characteristics

Molar mass : 64 g/mol
Evaporation rate : Not applicable for gases and gas mixtures.

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Gas group : Press. Gas (Liq.).

Other data : Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below
ground level.
SECTION 10: Stability and reactivity

10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability

Stable under normal conditions.
10.3. Possibility of hazardous reactions

None.
10.4. Conditions to avoid

Avoid moisture in installation systems.
10.5. Incompatible materials

Reacts with water to form corrosive acids.
May react violently with alkalis.
Reacts with most metals in the presence of moisture, liberating hydrogen, an extremely
flammable gas.
With water causes rapid corrosion of some metals.
Moisture.
For additional information on compatibility refer to ISO 11114.
10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not
be produced.
SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute toxicity : Toxic if inhaled.

Delayed fatal pulmonary oedema possible.
LC50 Inhalation - Rat [ppm] 1260 ppm/4h
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Causes serious eye damage.
Respiratory or skin sensitisation : No known effects from this product.
Germ cell mutagenicity : No known effects from this product.
Carcinogenicity : No known effects from this product.
Toxic for reproduction : Fertility : No known effects from this product.

Toxic for reproduction : unborn child : No known effects from this product.
STOT-single exposure : Severe corrosion to the respiratory tract at high concentrations.
STOT-repeated exposure : No known effects from this product.
Aspiration hazard : Not applicable for gases and gas mixtures.
11.2. Information on other hazards

No additional information available
SECTION 12: Ecological information

12.1. Toxicity
Assessment : Classification criteria are not met.

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EC50 48h - Daphnia magna [mg/l] : 89 mg/l

EC50 72h - Algae [mg/l] : 48.1 mg/l
LC50 96 h - Fish [mg/l] : No data available.
12.2. Persistence and degradability

Assessment : Not applicable for inorganic products.
12.3. Bioaccumulative potential

Assessment : Product is an inorganic gas with a low potential to bioaccumulate in aquatic species.
12.4. Mobility in soil

Assessment : Because of its high volatility, the product is unlikely to cause ground or water pollution.
Partition into soil is unlikely.
12.5. Results of PBT and vPvB assessment

Assessment : Not classified as PBT or vPvB.
12.6. Endocrine disrupting properties

Assessment :
12.7. Other adverse effects

Other adverse effects : May cause pH changes in aqueous ecological systems.
Effect on the ozone layer : None.
Effect on global warming : No known effects from this product.
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Contact supplier if guidance is required.
Must not be discharged to atmosphere.
Gas may be scrubbed in alkaline solution under controlled conditions to avoid violent
reaction.
Ensure that the emission levels from local regulations or operating permits are not
exceeded.
Refer to the EIGA code of practice Doc.30 "Disposal of Gases", downloadable at
http://www.eiga.org for more guidance on suitable disposal methods.
Return unused product in original container to supplier.
List of hazardous waste codes (from Commission : 16 05 04 *: Gases in pressure containers (including halons) containing hazardous
Decision 2000/532/EC as amended) substances.
13.2. Additional information

External treatment and disposal of waste should comply with applicable local and/or
national regulations.
SECTION 14: Transport information

14.1. UN number or ID number
In accordance with ADR / RID / IMDG / IATA / ADN
UN-No. : 1079

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14.2. UN proper shipping name
Transport by road/rail (ADR/RID) : SULPHUR DIOXIDE

Transport by air (ICAO-TI / IATA-DGR) : Sulphur dioxide
Transport by sea (IMDG) : SULPHUR DIOXIDE
14.3. Transport hazard class(es)
Labelling :
2.3 : Toxic gases.

8 : Corrosive substances.
Transport by road/rail (ADR/RID)
Class : 2
Classification code : 2TC
Hazard identification number : 268
Tunnel Restriction : C/D - Tank carriage : Passage forbidden through tunnels of category C, D and E. Other
carriage : Passage forbidden through tunnels of category D and E
Transport by sea (IMDG)
Class / Div. (Sub. risk(s)) : 2.3 (8)
Emergency Schedule (EmS) - Fire : F-C
Emergency Schedule (EmS) - Spillage : S-U
14.4. Packing group

Transport by road/rail (ADR/RID) : Not applicable.
Transport by air (ICAO-TI / IATA-DGR) : Not applicable.
Transport by sea (IMDG) : Not applicable.
14.5. Environmental hazards

Transport by road/rail (ADR/RID) : None.
Transport by air (ICAO-TI / IATA-DGR) : None.
Transport by sea (IMDG) : None.
14.6. Special precautions for user
Packing Instruction(s)
Transport by road/rail (ADR/RID) : P200.
Transport by air (ICAO-TI / IATA-DGR)
Passenger and Cargo Aircraft : Forbidden.
Cargo Aircraft only : Forbidden.
Transport by sea (IMDG) : P200.
Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's
compartment.
Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in
the event of an accident or an emergency.
Before transporting product containers:
- Ensure there is adequate ventilation.
- Ensure that containers are firmly secured.
- Ensure valve is closed and not leaking.
- Ensure valve outlet cap nut or plug (where provided) is correctly fitted.
- Ensure valve protection device (where provided) is correctly fitted.
14.7. Maritime transport in bulk according to IMO instruments

Not applicable.

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SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU-Regulations
Restrictions on use : None.
Other information, restriction and prohibition : Ensure all national/local regulations are observed.
regulations Not listed on the PIC list (Regulation EU 649/2012).
Seveso Directive : 2012/18/EU (Seveso III) : Covered.
National regulations
No additional information available
15.2. Chemical safety assessment

A CSA has been carried out.
SECTION 16: Other information

Indication of changes : Revised safety data sheet in accordance with commission regulation (EU) No 2015/830.
Abbreviations and acronyms : ATE - Acute Toxicity Estimate.

CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008.
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
(EC) No 1907/2006.
EINECS - European Inventory of Existing Commercial Chemical Substances.
CAS# - Chemical Abstract Service number.
PPE - Personal Protection Equipment.
LC50 - Lethal Concentration to 50 % of a test population.
RMM - Risk Management Measures.
PBT - Persistent, Bioaccumulative and Toxic.
vPvB - Very Persistent and Very Bioaccumulative.
STOT- SE : Specific Target Organ Toxicity - Single Exposure.
CSA - Chemical Safety Assessment.
EN - European Standard.
UN - United Nations.
ADR - European Agreement concerning the International Carriage of Dangerous Goods by
Road.
IATA - International Air Transport Association.
IMDG code - International Maritime Dangerous Goods.
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail.
WGK - Water Hazard Class.
STOT - RE : Specific Target Organ Toxicity - Repeated Exposure.
Training advice : Users of breathing apparatus must be trained.
Ensure operators understand the toxicity hazard.
Full text of H- and EUH-statements
Acute Tox. 3 (Inhalation:gas) Acute toxicity (inhalation:gas) Category 3
EUH071 Corrosive to the respiratory tract.
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
H280 Contains gas under pressure; may explode if heated.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
Press. Gas (Liq.) Gases under pressure : Liquefied gas

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Skin Corr. 1B Skin corrosion/irritation, Category 1, Sub-Category 1B
STOT SE 3 Specific target organ toxicity – Single exposure, Category 3, Respiratory tract irritation
DISCLAIMER OF LIABILITY : Before using this product in any new process or experiment, a thorough material
compatibility and safety study should be carried out.
Details given in this document are believed to be correct at the time of going to press.
Whilst proper care has been taken in the preparation of this document, no liability for injury
or damage resulting from its use can be accepted.

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Annex to the safety data sheet

This Annex documents the Exposure Scenarios (ESs) related to the identified uses of the registered substance. The ESs detail protective measures
for workers and the environment in addition to those described in sections 7, 8, 11, 12 and 13 of the SDS that are required to ensure that the
potential exposure to workers and the environment remains within acceptable levels for each of the identified uses.
Table of contents of the Annex
Identified Uses Es N° Short title Page
Formulation of mixtures in pressure receptacles EIGA113- Industrial uses, closed contained conditions 13
1
Calibration of analysis equipment EIGA113- Industrial uses, closed contained conditions 13

1
Transfilling in pressure receptacles EIGA113- Industrial uses, closed contained conditions 13

1
Metal treatment EIGA113- Industrial uses, closed and open conditions 17

2
Feedstock in chemical processes EIGA113- Industrial uses, closed and open conditions 17
2
Glass coating EIGA113- Industrial uses, closed and open conditions 17

2
Water treatment EIGA113- Industrial uses, closed and open conditions 17

2
Lubrication of rollers in glass manufacture EIGA113- Industrial uses, closed and open conditions 17
2
Resin curing EIGA113- Industrial uses, closed and open conditions 17

2
Refilling of refrigeration equipment EIGA113- Professional uses 21

3
Wine making EIGA113- Professional uses 21

3

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CAS-No.: 7446-09-5 Product form: Substance Physical state: Gas
1. EIGA113-1: Industrial uses, closed contained conditions
1.1. Title section
Industrial uses, closed contained conditions

ES Ref.: EIGA113-1
Processes, tasks, activities covered Industrial uses, including product transfers and associated laboratory activities within
different closed or contained systems
Environment Use descriptors
CS01
Worker Use descriptors
CS02
CS03
Assessment method MEASE
1.2. Conditions of use affecting exposure
1.2.1. Control of environmental exposure:
Product (article) characteristics
Physical form of product See section 9 of the SDS, No additional information
Concentration of substance in product ≤ 100 %
Amount used, frequency and duration of use (or from service life)
Regional use tonnage: ≤ 80000 t/yr
Emission Days (days/year) 365
Technical and organisational conditions and measures
Use appropriate abatement systems to ensure that the emission levels defined by local
regulations are not exceeded.
No emissions to water. In case of emissions to water, pH impact on the receiving water should
be avoided, e.g. by neutralizing the effluent
Ensure operatives are trained to minimise releases
Conditions and measures related to sewage treatment plant
Not applicable as there is no release to wastewater

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Conditions and measures related to treatment of waste (including article waste)
See section 13 of the SDS
Other conditions affecting environmental exposure
Closed systems are used in order to prevent

unintended emissions
1.2.2. Control of worker exposure:
Amount used (or contained in articles), frequency and duration of use/exposure
The actual tonnage handled per shift is not considered

to influence the exposure as such for this scenario.
Instead, the combination of the scale of operation and
level of containment/automation (as reflected in the
technical conditions) is the main determinant of the
process-intrinsic emission potential.
Exposure duration ≤ 8 h/day
Covers frequency up to: 5 days/week
Handle product within a closed system
Ensure operatives are trained to minimise exposure
Ensure supervision is in place to check that the RMMs are in place and are being used
correctly and that the OCs are being followed
Conditions and measures related to personal protection, hygiene and health evaluation
See section 8 of the SDS.
Other conditions affecting workers exposure
Indoor or outdoor use

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During indoor processes or in cases where natural ventilation is not sufficient, LEV should be
in place at points were emissions could occur. Outdoor, LEV is not generally required.
Fill containers at dedicated fill points supplied with local extract ventilation.
Drain down and flush system prior to equipment break-in or maintenance.
Apply a good standard of general or controlled ventilation when maintenance activities are
carried out.
1.3. Exposure estimation and reference to its source
1.3.1. Environmental release and exposure:
1.3.2. Worker exposure:
Route of exposure and type of effects Exposure estimate Assessment conditions RCR
Dermal - Long-term - systemic effects Since the product has corrosive

properties, dermal exposure has
to be minimised as far as
technically feasible. A DNEL for
dermal effects has not been
derived. Thus, dermal exposure is
not assessed in this exposure
scenario

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Dermal - Acute - systemic effects Since the product has corrosive

scenario
Acute - Local - Inhalation 0.648 mg/m³ Indoor or outdoor use 0.24

scenario

scenario
Acute - Local - Inhalation 1.08 mg/m³ Indoor or outdoor use 0.4
1.4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the ES
1.4.1. Environment
Guidance - Environment Guidance is based on assumed operating conditions which may not be applicable to all
sites; thus, scaling may be necessary to define appropriate site-specific risk management
measures. For scaling see : www.ebrc.de/mease.html
1.4.2. Health
Guidance - Health Guidance is based on assumed operating conditions which may not be applicable to all

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2. EIGA113-2: Industrial uses, closed and open conditions
2.1. Title section
Industrial uses, closed and open conditions

ES Ref.: EIGA113-2
Processes, tasks, activities covered Industrial uses, including product transfers and associated laboratory activities within
closed or partially closed conditions
CS01
CS02
CS03

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23.96.1
Exposure scenario
sulphur dioxide
Local exhaust ventilation - efficiency of at least [%]: 90
carried out.
Wear suitable gloves tested to EN374 Mandatory since the product is corrosive
Wear suitable working clothes Personal protection measures have to be applied

in case of potential exposure only.
Use suitable eye protection. Wear suitable face shield Personal protection measures have to be applied
Face mask with an ABEK1 filter offering an assigned protection factor of 30 Personal protection measures have to be applied

scenario

scenario

23.96.1
Exposure scenario
sulphur dioxide
Acute - Local - Inhalation 1.08 mg/m³ Indoor or outdoor use, With 0.4
LEV90%
2.4.1. Environment
2.4.2. Health

23.96.1
Exposure scenario
sulphur dioxide
3. EIGA113-3: Professional uses
3.1. Title section
Professional uses
ES Ref.: EIGA113-3
Processes, tasks, activities covered Professional uses, including transfer of product in non-industrial settings
CS01
CS02
CS03
Use appropriate abatement systems to ensure that the emission levels defined by local
regulations are not exceeded.

23.96.1
Exposure scenario
sulphur dioxide


carried out.
Wear suitable working clothes. Chemical resistant safety shoes Personal protection measures have to be applied

23.96.1
Exposure scenario
sulphur dioxide

Exposure duration ≤ 15 min/day
Wear suitable working clothes. Chemical resistant safety shoes Personal protection measures have to be applied
Face mask with an ABEK1 filter offering an assigned protection factor of 30

scenario

23.96.1
Exposure scenario
sulphur dioxide

scenario
LEV90%, With RPE95%

scenario

scenario
LEV90%, With RPE95%
3.4.1. Environment
3.4.2. Health
End of document

23.96.1

MSDS 113 Soleng en 8.0

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Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.2. Label elements

GHS04 GHS05 GHS06

SOL SpA EN (English) 1/24

2.3. Other hazards

SECTION 3: Composition/information on ingredients

Name % Product identifier Classification according to Regulation

sulphur dioxide 100 CAS-No.: 7446-09-5 Press. Gas (Liq.), H280

Name Product identifier Specific concentration limits

sulphur dioxide CAS-No.: 7446-09-5 ( 1 ≤C < 100) STOT SE 3, H335

SECTION 4: First aid measures

SOL SpA EN (English) 2/24

SECTION 5: Firefighting measures

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.2. Environmental precautions

SOL SpA EN (English) 3/24

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.2. Conditions for safe storage, including any incompatibilities

SOL SpA EN (English) 4/24

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

sulphur dioxide (7446-09-5)

EU - Indicative Occupational Exposure Limit (IOEL)

Local name Sulphur dioxide

IOEL TWA 1.3 mg/m³

IOEL TWA [ppm] 0.5 ppm

IOEL STEL 2.7 mg/m³

IOEL STEL [ppm] 1 ppm

Remark SCOEL Recommendations (2009)

Regulatory reference COMMISSION DIRECTIVE (EU) 2017/164

sulphur dioxide (7446-09-5)

DNEL: Derived no effect level (Workers)

Acute - local effects, inhalation 2.7 mg/m³

Long-term - local effects, inhalation 1.3 mg/m³

PNEC (Predicted No-Effect Concentration) : None established.

8.2. Exposure controls

8.2.2. Individual protection measures, e.g. personal protective equipment

SOL SpA EN (English) 5/24

8.2.3. Environmental exposure controls

SECTION 9: Physical and chemical properties

9.2. Other information

9.2.2. Other safety characteristics

SOL SpA EN (English) 6/24

Gas group : Press. Gas (Liq.).

SECTION 10: Stability and reactivity

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

SECTION 11: Toxicological information