EU safety data sheet

Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name
Armaflex 520
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Adhesive for processing all flexible Armaflex insulation materials
For industrial and professional use only
Uses advised against
No data available.

1.3 Details of the supplier of the safety data sheet

Address
Armacell GmbH
Robert-Bosch-Straße 10
48153 Münster
Telephone no. +49 (0) 251 - 7603-200
Fax no. +49 (0) 251 - 7603-561
e-mail [email protected]
Information provided by / telephone
Dr. Heribert Quante, Tel.: +49 (0) 251 - 7603-227
Advice on Safety Data Sheet
[email protected]
Address
Armacell UK Ltd
Mars Street
OL9 6LY Oldham
United Kingdom

email: [email protected]

1.4 Emergency telephone number

For medical advice (in German and English):
+49 (0)551 192 40 (Giftinformationszentrum Nord)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification in accordance with Regulation (EC) No 1272/2008 (CLP)
Aquatic Chronic 2; H411
Eye Irrit. 2; H319
Flam. Liq. 2; H225
STOT SE 3; H336
Classification information
This product is assessed and classified using the methods and criteria below referred to in Article 9 of Regulation (EC) n° 1272/2008:
Physical hazards: determined through assessment data based on the methods or standards referred to in part 2 of Annex I to CLP
Health hazards and environmental hazards: determined through toxicological and ecotoxicological assessment data based on the
methods or standards referred to in Part 3, 4 and 5 of Annex I to CLP.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP Regulation)

Hazard pictograms

GHS02 GHS07 GHS09

Signal word
Danger
Hazardous component(s) to be indicated on label:
Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane
ethyl-acetate

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

acetone
butanone
Hazard statement(s)
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
Hazard statements (EU)
EUH066 Repeated exposure may cause skin dryness or cracking.
EUH208 Contains Rosin; colophony. May produce an allergic reaction.
Precautionary statement(s)
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P391 Collect spillage.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to a facility in accordance with local and national regulations.

2.3 Other hazards

Vapours can form an explosive mixture with air.
PBT assessment
The components of this product are not considered to be a PBT.
vPvB assessment
The components of this product are not considered to be a vPvB.

SECTION 3: Composition/information on ingredients

3.1 Substances
Not applicable. The product is not a substance.

3.2 Mixtures
Hazardous ingredients
No Substance name Additional information
CAS / EC / Index / Classification (EC) 1272/2008 (CLP) Concentration %
REACH no
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane
64742-49-0 Aquatic Chronic 2; H411 > 25.00 - < 40.00 wt%
926-605-8 Asp. Tox. 1; H304
- Flam. Liq. 2; H225
01-2119486291-36 STOT SE 3; H336
EUH066
2 ethyl-acetate
141-78-6 EUH066 20.00 - < 25.00 wt%
205-500-4 Eye Irrit. 2; H319
607-022-00-5 Flam. Liq. 2; H225
01-2119475103-46 STOT SE 3; H336
3 acetone
67-64-1 Flam. Liq. 2; H225 10.00 - < 20.00 wt%
200-662-2 Eye Irrit. 2; H319
606-001-00-8 STOT SE 3; H336
01-2119471330-49 EUH066
4 butanone
78-93-3 Flam. Liq. 2; H225 1.00 - < 5.00 wt%
201-159-0 Eye Irrit. 2; H319
606-002-00-3 STOT SE 3; H336
01-2119457290-43 EUH066
5 propan-2-ol
67-63-0 Eye Irrit. 2; H319 1.00 - < 2.50 wt%
200-661-7 Flam. Liq. 2; H225
603-117-00-0 STOT SE 3; H336
01-2119457558-25
6 Rosin; colophony
8050-09-7 Skin Sens. 1; H317 0.10 - < 1.00 wt%
232-475-7

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

650-015-00-7
01-2119480418-32
Full Text for all H-phrases and EUH-phrases: pls. see section 16

SECTION 4: First aid measures

4.1 Description of first aid measures
General information
In case of persisting adverse effects, consult a physician. Remove contaminated clothing and shoes immediately, and launder thoroughly
before reusing.
After inhalation
When inhaled remove to fresh air and seek medical aid.
After skin contact
When in contact with the skin, clean with soap and water. Consult a doctor if skin irritation persists.
After eye contact
Remove contact lenses. Rinse eye thoroughly under running water keeping eyelids wide open and protecting the unaffected eye (at least
10 to 15 minutes). Get immediate ophthalmic treatment.
After ingestion
Do not induce vomiting. Rinse the mouth thoroughly with water. Never give anything by mouth to an unconscious person. Call a doctor
immediately.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms
Headache; Dizziness; Drowsiness; Nausea; Vomiting; redness

4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media
Carbon dioxide; Dry chemical extinguisher; Foam; Water spray jet
Unsuitable extinguishing media
High power water jet

5.2 Special hazards arising from the substance or mixture

In the event of fire, the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO); Nitrogen oxides (NOx); Hydrogen
chloride (HCl); halogenated compounds

5.3 Advice for firefighters

Use self-contained breathing apparatus. Wear full protective suit. Fire residues and contaminated firefighting water must be disposed of in
accordance with the local regulations. Containers close to fire should be transferred to a safe place.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Refer to protective measures listed in sections 7 and 8. Exclude sources of ignition and ventilate the area. Do not inhale vapours. Remove
persons to safety. Ensure adequate ventilation.
For emergency responders
No data available. Personal protective equipment (PPE) - see Section 8.

6.2 Environmental precautions

Do not discharge into the drains/surface waters/groundwater. Do not discharge into the subsoil/soil. In case of entry into waterways, soil
or drains, inform the responsible authorities.

6.3 Methods and material for containment and cleaning up

Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in
container for disposal according to local regulations (see section 13).

6.4 Reference to other sections

Information regarding safe handling, see section 7. Information regarding personal protective measures, see section 8. Information
regarding waste disposal, see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

Advice on safe handling

Provide good ventilation at the work area (local exhaust ventilation, if necessary). Risks inherent to handling the product must be
minimised by applying the appropriate protective and preventive measures. Working processes should - so far as possible, according to
the state of the art - be designed to rule out bodily contact or the release of hazardous substances. If workplace exposure limits are
exceeded, respiratory protection approved for this particular job must be worn. For personal protection see section 8.
General protective and hygiene measures
Do not eat, drink or smoke during work time. Keep away from foodstuffs and beverages. Wash hands before breaks and after work.
Remove soiled or soaked clothing immediately. Avoid contact with eyes and skin. Do not inhale vapours. Provide eye wash fountain in
work area. Have emergency shower available.
Advice on protection against fire and explosion
Keep away from sources of ignition - refrain from smoking. No sparking tools should be used. Vapours can form an explosive mixture with
air. Take precautionary measures against electrostatic loading (earthing necessary during loading operations).

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and storage conditions
Keep container tightly closed in a cool, well-ventilated place. Protect from heat and direct sunlight.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Always keep in containers of same material
as the original.
Incompatible products
Substances to be avoided, see section 10.

7.3 Specific end use(s)

No data available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limit values
No Substance name CAS no. EC no.
1 ethyl-acetate 141-78-6 205-500-4
2017/164/EU
Ethyl acetate
WEL short-term (15 min reference period) 1468 mg/m³ 400 ppm
WEL long-term (8-hr TWA reference period) 734 mg/m³ 200 ppm
List of approved workplace exposure limits (WELs) / EH40
Ethyl acetate
WEL short-term (15 min reference period) 400 ppm
WEL long-term (8-hr TWA reference period) 200 ppm
2 acetone 67-64-1 200-662-2
2000/39/EC
Acetone
WEL long-term (8-hr TWA reference period) 1210 mg/m³ 500 ppm
List of approved workplace exposure limits (WELs) / EH40
Acetone
WEL short-term (15 min reference period) 3620 mg/m³ 1500 ppm
WEL long-term (8-hr TWA reference period) 1210 mg/m³ 500 ppm
3 butanone 78-93-3 201-159-0
2000/39/EC
Butanone
WEL short-term (15 min reference period) 900 mg/m³ 300 ppm
WEL long-term (8-hr TWA reference period) 600 mg/m³ 200 ppm
List of approved workplace exposure limits (WELs) / EH40
Butan-2-one
WEL short-term (15 min reference period) 899 mg/m³ 300 ppm
WEL long-term (8-hr TWA reference period) 600 mg/m³ 200 ppm
Comments Sk, BMGV
4 propan-2-ol 67-63-0 200-661-7
List of approved workplace exposure limits (WELs) / EH40
Propan-2-ol
WEL short-term (15 min reference period) 1250 mg/m³ 500 ppm
t r ue
WEL long-term (8-hr TWA reference period) 999 mg/m³ 400 ppm

DNEL, DMEL and PNEC values

DNEL values (worker)

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

No Substance name CAS / EC no

Route of exposure Exposure time Effect Value
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane 64742-49-0
926-605-8
dermal Long term (chronic) systemic 13964 mg/kg/day
inhalative Long term (chronic) systemic 5306 mg/m³
2 ethyl-acetate 141-78-6
205-500-4
dermal Long term (chronic) systemic 63 mg/kg/day
inhalative Long term (chronic) systemic 734 mg/m³
inhalative Short term (acut) systemic 1468 mg/m³
inhalative Long term (chronic) local 734 mg/m³
inhalative Short term (acut) local 1468 mg/m³
3 acetone 67-64-1
200-662-2
dermal Long term (chronic) systemic 186 mg/kg/day
inhalative Short term (acut) local 2420 mg/m³
inhalative Short term (acut) systemic 1210 mg/m³
4 butanone 78-93-3
201-159-0
dermal Long term (chronic) systemic 1161 mg/kg/day
inhalative Long term (chronic) systemic 600.00 mg/m³
5 propan-2-ol 67-63-0
200-661-7
dermal Long term (chronic) systemic 888 mg/kg/day
0
inhalative Long term (chronic) systemic 500 mg/m³
DNEL value (consumer)
No Substance name CAS / EC no
Route of exposure Exposure time Effect Value
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane 64742-49-0
926-605-8
oral Long term (chronic) systemic 1301 mg/kg/day
dermal Long term (chronic) systemic 1377 mg/kg/day
inhalative Long term (chronic) systemic 1131 mg/m³
2 ethyl-acetate 141-78-6
205-500-4
oral Long term (chronic) systemic 4.5 mg/kg/day
dermal Long term (chronic) systemic 37 mg/kg/day
inhalative Long term (chronic) systemic 367 mg/m³
inhalative Short term (acut) systemic 734 mg/m³
inhalative Long term (chronic) local 367 mg/m³
inhalative Short term (acut) local 734 mg/m³
3 acetone 67-64-1
200-662-2
oral Long term (chronic) systemic 62 mg/kg/day
dermal Long term (chronic) systemic 62 mg/kg/day
inhalative Long term (chronic) systemic 200 mg/m³
4 butanone 78-93-3
201-159-0
oral Long term (chronic) systemic 31 mg/kg/day
dermal Long term (chronic) systemic 412 mg/kg/day
inhalative Long term (chronic) systemic 106 mg/m³
5 propan-2-ol 67-63-0
200-661-7
oral Long term (chronic) systemic 26 mg/kg/day
dermal Long term (chronic) systemic 319 mg/kg/day
0
inhalative Long term (chronic) systemic 89 mg/m³
PNEC values
No Substance name CAS / EC no
ecological compartment Type Value
1 ethyl-acetate 141-78-6
205-500-4
water fresh water 0.24 mg/L
water marine water 0.024 mg/L
water fresh water sediment 1.15 mg/kg dry weight
water marine water sediment 0.115 mg/kg dry weight
soil - 0.148 mg/kg dry weight

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

sewage treatment plant - 650 mg/L

secondary poisoning - 0.2 g/kg
with reference to: food
2 acetone 67-64-1
200-662-2
water fresh water 10.6 mg/L
water Aqua intermittent 21 mg/L
water marine water 1.06 mg/L
water fresh water sediment 30.4 mg/kg
water marine water sediment 3.04 mg/kg
soil - 29.5 mg/kg
sewage treatment plant - 100 mg/L
3 butanone 78-93-3
201-159-0
water fresh water 55.8 mg/L
water marine water 55.8 mg/L
water Aqua intermittent 55.8 mg/L
water fresh water sediment 284.74 mg/kg
with reference to: dry weight
water marine water sediment 284.7 mg/kg
with reference to: dry weight
soil - 22.5 mg/kg
with reference to: dry weight
sewage treatment plant - 709 mg/L
secondary poisoning - 1000 mg/kg
with reference to: food
4 propan-2-ol 67-63-0
200-661-7
water fresh water 140.9 mg/L
water Aqua intermittent 140.9 mg/L
water marine water 140.9 mg/L
water fresh water sediment 552 mg/L
water marine water sediment 552 mg/L
soil - 28 mg/kg
sewage treatment plant - 2251 mg/L
secondary poisoning - 160 mg/kg
0
with reference to: food

8.2 Exposure controls

Appropriate engineering controls
Ensure adequate ventilation, local exhaust at the work station if necessary.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of aerosol and
mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Respirator AX
Eye / face protection
Tightly fitting safety glasses (EN 166).
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with
the product. Before use, the protective gloves should be tested in any case for its specific work-station suitability (i.e. mechanical
resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use,
storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn.
Design operations thus to avoid permanent use of protective gloves.
Appropriate Material butyl rubber
Material thickness > 0.7 mm
Inappropriate material nitrile rubber
Inappropriate material PVC
Inappropriate material viton
Inappropriate material Natural rubber, NR
Other
Fire-resistant antistatic protective clothing.
Environmental exposure controls
No data available.

SECTION 9: Physical and chemical properties

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

9.1 Information on basic physical and chemical properties

State of aggregation
2038
liquid
Form/Colour
liquid
270
beige
390

Odour
Lk. 7002998
like solvents
pH value
No data available
Boiling point / boiling range
Value 55 °C
Source supplier 55

Melting point/freezing point

No data available
Decomposition temperature
No data available
Flash point
Value -15 °C
Source supplier - 15

Ignition temperature
No data available
Auto-ignition temperature
Value 235 °C
Source supplier 235

Flammability
Not applicable
Source supplier Lk. 7002758

Lower explosion limit

Value 1 % vol
Source 1
supplier 40

Upper explosion limit

Value 20 % vol
Source 20
supplier 40

Vapour pressure
No data available
Relative vapour density
No data available
Relative density
Value 0.85
Source supplier 0. 85

Density
No data available
Solubility in water
Source supplier
Comments immiscible
Solubility
No data available
Partition coefficient n-octanol/water (log value)
No Substance name CAS no. EC no.
1 ethyl-acetate 141-78-6 205-500-4
log Pow 0.68
Reference temperature 25 °C
Source ECHA
2 acetone 67-64-1 200-662-2
log Pow -0.23
Method QSAR
Source ECHA

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

3 butanone 78-93-3 201-159-0

log Pow 0.3
Reference temperature 40 °C
Method OECD 117
Source ECHA
4 propan-2-ol 67-63-0 200-661-7
log Pow 0.05
Reference temperature 25 °C
Source ECHA 0. 68

Viscosity
Value > 1000 mm²/s
Reference temperature 40 °C
Type kinematic
Source
20 3
supplier
Particle characteristics
No data available

9.2 Other information

Other information
VOC: 78 %
Lk. 44280

SECTION 10: Stability and reactivity

10.1 Reactivity
No data available.

10.2 Chemical stability

Stable under recommended storage and handling conditions (See section 7).

10.3 Possibility of hazardous reactions

None, when used as directed.

10.4 Conditions to avoid

Heat, naked flames and other ignition sources.

10.5 Incompatible materials

No data available.

10.6 Hazardous decomposition products

None if stored, handled and transported properly. In case of fire: see section 5.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Acute oral toxicity
No Substance name CAS no. EC no.
1 ethyl-acetate 141-78-6 205-500-4
LD50 > 5600 mg/kg bodyweight
Species rat
Source ECHA
2 acetone 67-64-1 200-662-2
LD50 5800 mg/kg bodyweight
Species rat
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
3 butanone 78-93-3 201-159-0
LD50 2054 mg/kg bodyweight
Species rat
Method OECD 423
Source ECHA / Read across
4 propan-2-ol 67-63-0 200-661-7
LD50 5840 mg/kg bodyweight
Species rat
Method OECD 401
Source ECHA
3
Evaluation/classification
5600
Based on available data, the classification criteria are not met. Lk. 8898

Acute dermal toxicity

No Substance name CAS no. EC no.

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

1 ethyl-acetate 141-78-6 205-500-4

LD50 > 20000 mg/kg bodyweight
Species rabbit
Source ECHA
2 acetone 67-64-1 200-662-2
LD50 > 15800 mg/kg bodyweight
Species rabbit
Source ECHA
Evaluation/classification
3 Lk. 6866
Based on available data, the classification criteria are not met.
Acute inhalational toxicity
No Substance name CAS no. EC no.
1 acetone 67-64-1 200-662-2
LC50 76 mg/l
Duration of exposure 4 h
State of aggregation Vapour
Species rat
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
2 propan-2-ol 67-63-0 200-661-7
LC50 > 10000 ppmV
Duration of exposure 6 h
State of aggregation Vapour
Species rat
Method OECD 403
Source ECHA
Evaluation/classification
Lk. 8903
Based on available data, the classification criteria are not met. Lk. 3661

Skin corrosion/irritation
No Substance name CAS no. EC no.
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane 64742-49-0 926-605-8
Species rabbit
Method OECD 404
Source ECHA
Evaluation non-irritant
2 ethyl-acetate 141-78-6 205-500-4
Species rabbit
Method OECD 404
Source ECHA
Evaluation low-irritant
Evaluation/classification Based on available data, the classification criteria are not met.
3 acetone 67-64-1 200-662-2
Species guinea pig
Source ECHA
Evaluation non-irritant
Evaluation/classification Based on available data, the classification criteria are not met.
4 butanone 78-93-3 201-159-0
Duration of exposure 4 h
Species rabbit
Method OECD 404
Source ECHA / Read across
Evaluation non-irritant
5 propan-2-ol 67-63-0 200-661-7
Species rabbit
Source ECHA
Evaluation non-irritant
Evaluation/classification
Lk. 8973 4
Based on available data, the classification criteria are not met. Lk. 9003

Serious eye damage/irritation

No Substance name CAS no. EC no.
1 ethyl-acetate 141-78-6 205-500-4
Species rabbit
Method OECD 405
Source ECHA
Evaluation low-irritant
2 acetone 67-64-1 200-662-2
Species rabbit
Method OECD 405
Source ECHA
Evaluation irritant
Evaluation/classification Based on available data, the classification criteria are met.

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

3 butanone 78-93-3 201-159-0

Species rabbit
Method OECD 405
Source ECHA
Evaluation irritant
4 propan-2-ol 67-63-0 200-661-7
Species rabbit
Method OECD 405
Source ECHA
Evaluation irritant
Evaluation/classification
Lk. 8975
Based on available data, the classification criteria are met.
Respiratory or skin sensitisation
No Substance name CAS no. EC no.
1 ethyl-acetate 141-78-6 205-500-4
Route of exposure Skin
Species guinea pig
Method OECD 406
Source ECHA
Evaluation non-sensitizing
2 acetone 67-64-1 200-662-2
Route of exposure Skin
Species guinea pig
Source ECHA
Evaluation non-sensitizing
Evaluation/classification Based on available data, the classification criteria are not met.
3 butanone 78-93-3 201-159-0
Route of exposure Skin
Species guinea pig
Method OECD 406
Source ECHA
Evaluation non-sensitizing
4 propan-2-ol 67-63-0 200-661-7
Route of exposure Skin
Species guinea pig
Method OECD 406
Source ECHA
Evaluation non-sensitizing
Evaluation/classification
Lk. 3647 Lk. 8983
Based on available data, the classification criteria are not met.
Germ cell mutagenicity
No Substance name CAS no. EC no.
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane 64742-49-0 926-605-8
Source ECHA / Read across
Evaluation/classification Based on available data, the classification criteria are not met.
2 acetone 67-64-1 200-662-2
Type of examination in vitro gene mutation study in bacteria
Species Salmonella typhimurium
Method OECD 471
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
Type of examination In vitro Mammalian Chromosomal Aberration Test
Species Chinese hamster Ovary (CHO)
Method OECD 473
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
Type of examination in vitro gene mutation study in mammalian cells
Species Mouse lymphoma cells
Method OECD 476
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
3 butanone 78-93-3 201-159-0
Type of examination in vitro gene mutation study in bacteria
Species Salmonella typhimurium
Method OECD 471
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
Type of examination In vitro Mammalian Chromosomal Aberration Test
Species rat
Method OECD 473

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
Type of examination In vitro mammalian cell gene mutation test
Species Mouse lymphoma cells
Method OECD 476
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
Type of examination In vivo mammalian somatic cell study: cytogenicity / erythrocyte micronucleus
Species mouse
Method OECD 474
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
4 propan-2-ol 67-63-0 200-661-7
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met. Lk. 3661

Reproduction toxicity
No Substance name CAS no. EC no.
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane 64742-49-0 926-605-8
Source ECHA / Read across
Evaluation/classification Based on available data, the classification criteria are not met.
2 acetone 67-64-1 200-662-2
Route of exposure inhalational
NOAEC 2200 ppm
Type of examination Prenatal Developmental Toxicity Study
Species rat
Method OECD 414
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
3 butanone 78-93-3 201-159-0
Route of exposure inhalational
Type of examination Prenatal Developmental Toxicity Study
Species rat
Method OECD 414
Source ECHA
Evaluation/classification
Lk. 9006
Based on available data, the classification criteria are not met. Lk. 3661

Carcinogenicity
No Substance name CAS no. EC no.
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane 64742-49-0 926-605-8
Source ECHA / Read across
Evaluation/classification Based on available data, the classification criteria are not met.
2 acetone 67-64-1 200-662-2
Route of exposure dermal
Type of examination Toxicity study
Species mouse
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
3 butanone 78-93-3 201-159-0
Source ECHA
Evaluation/classification
Lk. 3661
Based on available data, the classification criteria are not met.
STOT - single exposure
No data available
STOT - repeated exposure
No Substance name CAS no. EC no.
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane 64742-49-0 926-605-8
Source ECHA / Read across
Evaluation/classification Based on available data, the classification criteria are not met.
2 acetone 67-64-1 200-662-2
Route of exposure oral
NOAEL 10000 ppm
Species rat
Method OECD 408
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
Route of exposure inhalational
NOAEC 19000 ppm
Species rat
Source ECHA

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

Evaluation/classification Based on available data, the classification criteria are not met.
3 butanone 78-93-3 201-159-0
Route of exposure inhalational
Species rat
Method OECD 413
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
4 propan-2-ol 67-63-0 200-661-7
Route of exposure inhalational
Source ECHA
Evaluation/classification
Lk. 8997
Based on available data, the classification criteria are not met. Lk. 3661

Aspiration hazard
Based on available data, the classification criteria are not met.
Lk. 16155

11.2 Information on other hazards

Endocrine disrupting properties
No data available.
Other information
No data available.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity to fish (acute)
No Substance name CAS no. EC no.
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane 64742-49-0 926-605-8
LL50 12 mg/l
Duration of exposure 96 h
Species Oncorhynchus mykiss
Method OECD 203
Source ECHA
2 ethyl-acetate 141-78-6 205-500-4
LC50 220 mg/l
Duration of exposure 96 h
Species Pimephales promelas
Source ECHA
3 acetone 67-64-1 200-662-2
LC50 5540 mg/l
Duration of exposure 96 h
Species Oncorhynchus mykiss
Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
4 butanone 78-93-3 201-159-0
LC50 2993 mg/l
Duration of exposure 96 h
Species Pimephales promelas
Method OECD 203
Source ECHA
5 propan-2-ol 67-63-0 200-661-7
LC50 9640 mg/l
Duration of exposure 96 h
Species Pimephales promelas
Method OECD 203
Source
Lk. 10988
ECHA Lk. 3661

Toxicity to fish (chronic)

No data available
Toxicity to Daphnia (acute)
No Substance name CAS no. EC no.
1 ethyl-acetate 141-78-6 205-500-4
EC50 1350 mg/l
Duration of exposure 48 h
Species Daphnia magna
Source ECHA
2 acetone 67-64-1 200-662-2
EC50 8800 mg/l
Duration of exposure 48 h
Species Daphnia pulex

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

Source ECHA
Evaluation/classification Based on available data, the classification criteria are not met.
3 butanone 78-93-3 201-159-0
EC50 308 mg/l
Duration of exposure 48 h
Species Daphnia magna
Method OECD 202
Source ECHA
4 propan-2-ol 67-63-0 200-661-7
EC50 > 10000 mg/l
Duration of exposure 24 h
Species Daphnia magna
Method OECD 202
Source
Lk. 9025
ECHA Lk. 3661

Toxicity to Daphnia (chronic)

No data available
Toxicity to algae (acute)
No Substance name CAS no. EC no.
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane 64742-49-0 926-605-8
EL50 26 mg/l
Duration of exposure 72 h
Species Pseudokirchneriella subcapitata
Method OECD 201
Source ECHA
2 butanone 78-93-3 201-159-0
EC50 2029 mg/l
Duration of exposure 96 h
Species Pseudokirchneriella subcapitata
Method OECD 201
Source
Lk. 11032
ECHA
Toxicity to algae (chronic)
No data available
Bacteria toxicity
No data available

12.2 Persistence and degradability

Biodegradability
No Substance name CAS no. EC no.
1 Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane 64742-49-0 926-605-8
Type aerobic biodegradation
Value 98 %
Duration 28 day(s)
Method OECD 301 F
Source ECHA
Evaluation readily degradable
2 ethyl-acetate 141-78-6 205-500-4
Type COD
Value 1.69 g O2/g
Source ECHA
Evaluation readily biodegradable
3 acetone 67-64-1 200-662-2
Type aerobic biodegradation
Value 90.9 %
Duration 28 day(s)
Method OECD 301 B
Source ECHA
Evaluation readily biodegradable
4 butanone 78-93-3 201-159-0
Type aerobic biodegradation
Value 98 %
Duration 28 day(s)
Method OECD 301 D
Source ECHA
Evaluation readily biodegradable
5 propan-2-ol 67-63-0 200-661-7
Type BOD/COD
Value 53 %

Page 13 of 16
 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

Duration 5 day(s)
Source ECHA
Evaluation readily biodegradable
U_906

12.3 Bioaccumulative potential

Partition coefficient n-octanol/water (log value)
No Substance name CAS no. EC no.
1 ethyl-acetate 141-78-6 205-500-4
log Pow 0.68
Reference temperature 25 °C
Source ECHA
2 acetone 67-64-1 200-662-2
log Pow -0.23
Method QSAR
Source ECHA
3 butanone 78-93-3 201-159-0
log Pow 0.3
Reference temperature 40 °C
Method OECD 117
Source ECHA
4 propan-2-ol 67-63-0 200-661-7
log Pow 0.05
Reference temperature 25 °C
Source ECHA 0. 68

12.4 Mobility in soil

No data available.

12.5 Results of PBT and vPvB assessment

Results of PBT and vPvB assessment
PBT assessment The components of this product are not considered to be a PBT.
Lk. 2045
vPvB assessment
Lk. 2046
The components of this product are not considered to be a vPvB.

12.6 Endocrine disrupting properties

No data available.

12.7 Other adverse effects

No data available.

12.8 Other information

Other information
U_9000
Do not discharge into drains or waters and do not dispose of in public landfills.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Waste code 08 04 09* waste adhesives and sealants containing organic solvents or other hazardous
substances
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional
waste disposal company.
dispose of in accordance with local regulation.
Packaging
Waste code 15 01 10* packaging containing residues of or contaminated by hazardous substances
Residues must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste
removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.

SECTION 14: Transport information

14.1 Transport ADR/RID/ADN
Class 3
Classification code F1
Packing group II
Hazard identification no. 33
UN number UN1133
Proper shipping name ADHESIVES
Special Provision 640 640D
Tunnel restriction code D/E
Label 3
Environmentally hazardous Symbol "fish and tree"

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 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

substance mark

14.2 Transport IMDG

Class 3
Packing group II
UN number UN1133
Proper shipping name ADHESIVES
Technical name Hydrocarbons, C6-C7, isoalkanes, cyclics, <5% n-hexane
EmS F-E, S-D
Label 3
Marine pollutant mark Symbol "fish and tree"

14.3 Transport ICAO-TI / IATA

Class 3
Packing group II
UN number UN1133
Proper shipping name Adhesives
Label 3

14.4 Other information

No data available.

14.5 Environmental hazards

Information on environmental hazards, if relevant, please see 14.1 - 14.3.

14.6 Special precautions for user

To be transported always in closed, upright and safe containers. Make sure that persons handling these containers are aware of the rules
of conduct in case of incident or spillage.

14.7 Maritime transport in bulk according to IMO instruments

Not relevant

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations

Regulation (EC) No 1907/2006 (REACH) Annex XIV (List of substances subject to authorisation)
According to the data available and/or specifications supplied by upstream suppliers, this product does not contain any substances
considered as substances requiring authorisation as listed on Annex XIV of the REACH regulation (EC) 1907/2006.
REACH candidate list of substances of very high concern (SVHC) for authorisation
According to available data and the information provided by preliminary suppliers, the product does not contain substances that are
considered substances meeting the criteria for inclusion in annex XIV (List of Substances Subject to Authorisation) as laid down in Article
57 and article 59 of REACH (EC) 1907/2006.
Regulation (EC) No 1907/2006 (REACH) Annex XVII: RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET
AND USE OF CERTAIN DANGEROUS SUBSTANCES, MIXTURES AND ARTICLES
The product is considered being subject to REACH regulation (EC) 1907/2006 annex XVII. No 3, 40
The product contains following substance(s) that are considered being subject to REACH regulation (EC) 1907/2006 annex XVII.
No Substance name CAS no. EC no. No
1 acetone 67-64-1 200-662-2 75
2 butanone 78-93-3 201-159-0 75
3 ethyl-acetate 141-78-6 205-500-4 75
4 propan-2-ol 67-63-0 200-661-7 75
5 Rosin; colophony 8050-09-7 232-475-7 75
6 Talc 14807-96-6 238-877-9 75
Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances
This product is subject to Part I of Annex I, risk category: E2, P5b
If the properties of the substance/product give rise to more than one classification, for the purposes of 2012/18/UE, the lowest qualifying
quantities set out in Part 1 and Part 2 of Annex I shall apply.
Directive 2010/75/EU on industrial emissions (integrated pollution prevention and control)
VOC content 78 %

15.2 Chemical safety assessment

A chemical safety assessment has not been carried out for this mixture.

SECTION 16: Other information

Further information

Page 15 of 16
 EU safety data sheet
Trade name: Armaflex 520

Current version : 13.0.0, issued: 31.03.2022 Replaced version: 12.0.0, issued: 27.01.2022 Region: GB

Authors responsible for the compilation of the material safety data sheet: UMCO GmbH - D-21107 Hamburg, Georg-Wilhelm-Strasse 187,
Tel.: +49(40)555 546 300, Fax: +49(40)555 546 357, e-mail: [email protected].
The information is based on our current knowledge however it does not represent a guarantee of product properties nor does it create any
legal obligation.
Sources of key data used to compile the data sheet:
Regulation (EC) No 1907/2006 (REACH), 1272/2008 (CLP) as amended in each case.
Directives 2000/39/EC, 2006/15/EC, 2009/161/EU, (EU) 2017/164.
National Threshold Limit Values of the corresponding countries as amended in each case.
Transport regulations according to ADR, RID, IMDG, IATA as amended in each case.
The data sources used to determine physical, toxic and ecotoxic data, are indicated directly in the corresponding section.
Full text of the H- and EUH- phrases drawn up in sections 2 and 3 (provided not already drawn up in these sections)
H304 May be fatal if swallowed and enters airways.
H317 May cause an allergic skin reaction.
Alterations/supplements:
Alterations to the previous edition are marked in the left-hand margin.
Document protected by copyright. Alterations or reproductions require the express written permission of UMCO GmbH.
.
Prod-ID 636618

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