SAFETY DATA SHEET

Product name: Corium 123 Page: 1/10

Supersedes date: 2015-10-20 Last revised date: 2016-05-01
Product No.: SDS-ID: GB-EN/2.1

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
1.1. Product identifier
Product name: Corium 123
1.2. Relevant identified uses of the substance or mixture and uses advised against
Application: Degreasing agent
1.3. Details of the supplier of the safety data sheet
Supplier: EU importer:

.
.
Manufacturer ITW PP & F Korea Limited.
13th Fl., Unit B, PAX Tower
609 Eonju-ro, Gangnam-gu
Seoul, Korea 06108
Tel:+82-2-2088-3560
Fax:+82-2-513-3567
www.magnagroup.com
Further information can be [email protected]
obtained from:
1.4. Emergency telephone number
Emergency telephone: Call a Poison Center, emergency number or doctor/physician.
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Supersedes date: 2015-10-20 Last revised date: 2016-05-01
Product No.: SDS-ID: GB-EN/2.1

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture
CLP: Aerosol 2;H223,H229
Skin Irrit. 2;H315
Eye Irrit. 2;H319
STOT SE 3;H335
STOT SE 3;H336
Repr. 1B;H360
STOT RE 2;H373
2.2. Label elements

Danger
Contains: 1-Bromopropane
H223 Flammable aerosol.
H229 Pressurised container: May burst if heated.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H360FD May damage fertility. May damage the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.

P201 Obtain special instructions before use.

P308 + P313 IF exposed or concerned: Get medical advice/attention.
P260 Do not breathe vapour/spray.
P280 Wear protective gloves, eye and face protection.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P251 Do not pierce or burn, even after use.
P410/412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F.
P102 Keep out of reach of children.
Restricted to professional users.
2.3. Other hazards
Other: The product is highly flammable, and explosive vapours/air mixtures may be
formed even at normal room temperatures. Aerosol containers can explode when
heated, due to excessive pressure build-up. When sprayed on a naked flame or
any incandescent material the aerosol vapours can be ignited.
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Supersedes date: 2015-10-20 Last revised date: 2016-05-01
Product No.: SDS-ID: GB-EN/2.1

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures
The product contains: 1-Bromopropane, propellant and Stabiliser.
CLP:

%: CAS-No.: EC No.: REACH Reg. No: Chemical name: Hazard classification: Notes:
60-100 106-94-5 203-445-0 - 1-Bromopropane Flam. Liq. 2;H225
Repr. 1B;H360FD
STOT RE 2;H373
Eye Irrit. 2;H319
STOT SE 3;H335
Skin Irrit. 2;H315
STOT SE 3;H336
3-7 124-38-9 204-696-9 - Carbon dioxide -

<1 106-88-7 203-438-2 - 1,2-Epoxybutane Flam. Liq. 2;H225

Carc. 2;H351
Acute Tox. 4;H302
Acute Tox. 4;H312
Acute Tox. 4;H332
STOT SE 3;H335
Skin Irrit. 2;H315
Eye Irrit. 2;H319
<1 75-52-5 200-876-6 - Nitromethane Flam. Liq. 3;H226
Acute Tox. 4;H302

References: The full text for all hazard statements is displayed in section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures
Burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call
an ambulance. Continue flushing during transport to hospital.
Inhalation: Move injured person into fresh air and keep person calm under observation. If
uncomfortable: Seek hospital and bring these instructions.
Skin contact: Remove contaminated clothing. Wash skin thoroughly with soap and water for
several minutes. If irritation persists: Seek medical attention and bring along
these instructions.
Eye contact: Immediately flush with plenty of water for up to 15 minutes. Remove any contact
lenses and open eyelids widely. If irritation persists: Seek medical attention and
bring along these instructions.
Ingestion: Immediately rinse mouth and drink plenty of water or milk. Keep person under
observation. Do not induce vomiting. If vomiting occurs, keep head low. Transport
immediately to hospital and bring along these instructions.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects: See section 11 for more detailed information on health effects and symptoms.
4.3. Indication of any immediate medical attention and special treatment needed
Medical attention/treatments: Treat symptomatically.
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Supersedes date: 2015-10-20 Last revised date: 2016-05-01
Product No.: SDS-ID: GB-EN/2.1

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media
Extinguishing media: Extinguish with foam, carbon dioxide, dry powder or water fog. Do not use water
jet as an extinguisher, as this will spread the fire.
Cool containers exposed to heat with water spray and remove container, if no
risk is involved.
5.2. Special hazards arising from the substance or mixture
Specific hazards: When heated and in case of fire, toxic and corrosive vapours/gases may be
formed. Aerosol containers can explode when heated, due to excessive pressure
build-up.
5.3. Advice for firefighters
Protective equipment for fire- Use air-supplied respirator during fire fighting. Wear full protective clothing.
fighters:

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions: Avoid inhalation of aerosols and contact with skin and eyes. Do not smoke or use
open fire, or other sources of ignition. Follow precautions for safe handling
described in this safety data sheet.
6.2. Environmental precautions
Environmental Aerosol containers should not be dumped in nature.
precautions:
6.3. Methods and material for containment and cleaning up
Methods for cleaning up: Remove sources of ignition. Beware of the explosion danger. Collect with
absorbent, non-combustible material into suitable containers.
Do not allow to enter drains, sewers or watercourses.
6.4. Reference to other sections
References: For personal protection, see section 8.
For waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling
Safe handling advice: Avoid exposure! Obtain special instructions before use.
Technical measures: Do not smoke or use open fire or other sources of ignition.
Technical precautions: Provide adequate ventilation.
Provide easy access to water supply or an emergency shower.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures for safe Follow rules for flammable liquids.
storage:
Storage conditions: Store in tightly closed original container in a dry, cool and well-ventilated place.
Do not store near heat sources or expose to high temperatures.
7.3. Specific end use(s)
Specific use(s): Degreasing agent
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Supersedes date: 2015-10-20 Last revised date: 2016-05-01
Product No.: SDS-ID: GB-EN/2.1

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Occupational exposure limits:

CAS-No.: Chemical name: As: Exposure limits: Type: Notes: References:

124-38-9 Carbon dioxide - 5000 ppm 9150 mg/m3 TWA - EH40

- 15000 ppm 27400 mg/m3 STEL 15min
75-52-5 Nitromethane - 100 ppm 254 mg/m3 TWA - EH40
- 150 ppm 381 mg/m3 STEL 15min
8.2. Exposure controls
Engineering measures: Provide adequate ventilation. Observe Occupational Exposure Limits and
minimise the risk of inhalation of vapours and aerosols.
Personal protection: Personal protection equipment should be chosen according to the CEN
standards and in discussion with the supplier of the personal protective
equipment.
Respiratory equipment: High-efficiency particulate respirator with full facepiece.

Hand protection: Wear protective gloves. It is recommended to use protective gloves of viton.
Be aware that the liquid may penetrate the gloves. Frequent change is
advisable. The most suitable glove must be chosen in consultation with the
gloves supplier, who can inform about the breakthrough time of the glove
material.
Eye protection: Wear goggles/face shield.

Skin protection: Wear appropriate clothing to prevent any possibility of liquid contact and
repeated or prolonged vapour contact.
Hygiene measures: Wash hands after handling.
When using do not eat, drink or smoke.
Environmental Exposure Not available.
Controls:

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties
Appearance: Aerosol.
Form: Clear liquid.
Colour: Colourless.
Odour: Not available.
Boiling point: 68-71°C
Flash point: 25°C (1-Bromopropane)
Vapour pressure: 143 mmHg
Relative density: ~1,33 (25°C)
Solubility: Water.: ~0,24 g/100 ml (25°C)
Partition coefficient (n- Koc 330
octanol/water):
9.2. Other information
Other data: Volatile Organic Compound (VOC): 1.314 g/l
log Kow 2,1
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Supersedes date: 2015-10-20 Last revised date: 2016-05-01
Product No.: SDS-ID: GB-EN/2.1

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity
Reactivity: None known.
10.2. Chemical stability
Stability: Stable under normal temperature conditions.
10.3. Possibility of hazardous reactions
Hazardous Reactions: In use, may form flammable/explosive vapour-air mixture.
10.4. Conditions to avoid
Conditions to avoid Keep away from heat, sparks and open flame.
10.5. Incompatible materials
Incompatible materials: Water, moisture.
Strong alkalis. Strong acids and strong oxidizers.
May react with lithium, titanium, zirconium and other reactive metals.
10.6. Hazardous decomposition products
Hazardous decomposition When heated and in case of fire, toxic and corrosive vapours/gases may be
products: formed.
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Supersedes date: 2015-10-20 Last revised date: 2016-05-01
Product No.: SDS-ID: GB-EN/2.1

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects
Acute Toxicity (Oral): Based on available data, the classification criteria are not met.
Acute Toxicity (Dermal): Based on available data, the classification criteria are not met.
Acute Toxicity (Inhalation): Based on available data, the classification criteria are not met.
Skin Corrosion/Irritation: Based on available data, the classification criteria are not met.
Serious eye damage/irritation: Based on available data, the classification criteria are not met.
Respiratory or skin Based on available data, the classification criteria are not met.
sensitisation:
Germ cell mutagenicity: Based on available data, the classification criteria are not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
Reproductive Toxicity: Based on available data, the classification criteria are not met.
STOT - Single exposure: Based on available data, the classification criteria are not met.
STOT - Repeated exposure: Based on available data, the classification criteria are not met.
Aspiration hazard: Based on available data, the classification criteria are not met.

Inhalation: Harmful: danger of serious damage to health by prolonged exposure through

inhalation. Vapours irritate the respiratory system, and may cause coughing and
difficulties in breathing. In high concentrations, vapours and spray mists are
narcotic and may cause headache, fatigue, dizziness and nausea.
Skin contact: Irritating to skin. Repeated or prolonged contact may cause defatting of the skin
resulting in dryness, cracking and dermatitis.
Eye contact: Irritating and may cause redness and pain.
Ingestion: May cause nausea, headache, dizziness and intoxication.
Specific effects: Frequent inhalation of even small concentrations may cause irritability, fatigue
and memory failure and eventually permanent damage to the nervous system,
including the brain.
May damage fertility or the unborn child.
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Supersedes date: 2015-10-20 Last revised date: 2016-05-01
Product No.: SDS-ID: GB-EN/2.1

SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity
Ecotoxicity: 1-Bromopropane: LC50 (Fathead minnow, 96h): 67 mg/l
Not classified as dangerous to the environment. However, the product should not
be allowed to enter drains or water courses or be deposited where it can affect
ground or surface waters.
12.2. Persistence and degradability
Degradability: There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential: Bioaccumulation: Is not expected to be bioaccumulable.
BCF 23
12.4. Mobility in soil
Mobility: No data available.
12.5. Results of PBT and vPvB assessment
PBT/vPvB: Not relevant.
12.6. Other adverse effects
Other adverse effects: The product contains volatile, organic compounds which have a photochemical
ozone creation potential.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
Dispose of waste and residues in accordance with local authority requirements. Waste is classified as
hazardous waste. Do not puncture or incinerate even when empty. Rags and the like, moistened with flammable
liquids, must be discarded into designated fireproof bucket.
Waste from residues: Used cloths, etc. EWC-code: 15 02 02
Contaminated packaging: EWC-code:15 01 10
Empty aerosol containers before disposal.
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Supersedes date: 2015-10-20 Last revised date: 2016-05-01
Product No.: SDS-ID: GB-EN/2.1

SECTION 14: TRANSPORT INFORMATION

14.1. UN number
UN-No: 1950
14.2. UN proper shipping name
Proper Shipping Name: AEROSOLS, FLAMMABLE.
14.3. Transport hazard class(es)
Class: 2.1
14.4. Packing group
PG: -
14.5. Environmental hazards
Marine pollutant: No.
Environmentally Hazardous No.
substance:
14.6. Special precautions for user
Special precautions: None known.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk: Not relevant.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Special provisions: Substance of very high concern (SVHC):1-Bromopropane

Restricted to professional users.

As a general rule, persons under 18 years of age are not allowed to work with
this product. Users must be carefully instructed in the proper work procedure,
the dangerous properties of the product and the necessary safety instructions.
National regulation: Regulation (EC) No 1907/2006 of the European Parliament and of the Council of
18 December 2006 concerning the Registration, Evaluation, Authorisation and
Restriction of Chemicals (REACH), establishing a European Chemicals Agency,
amending Directive 1999/45/EC and repealing Council Regulation (EEC) No
793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and
2000/21/EC, with amendments.
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of
16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and
amending Regulation (EC) No 1907/2006 with amendments.
The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No.
2677) with amendments.
EH40/2005, Workplace exposure limits 2005, with amendments.
The Aerosol Dispensers Regulations 2009 (SI 2824), with amendments.
The Management of Health and Safety at Work Regulations 1999 (SI 1999 No.
3242), with amendments.
The List of Wastes (England) (Amendment) Regulations 2005. (SI 2005 No. 895).

15.2. Chemical Safety Assessment

CSA status: No information available.
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Supersedes date: 2015-10-20 Last revised date: 2016-05-01
Product No.: SDS-ID: GB-EN/2.1

SECTION 16: OTHER INFORMATION

For restrictions on use see section 15.

The following sections contain revisions or new statements: 1, 11, 16

Corium Industrial Chemicals

13th Fl., Unit B, PAX Tower,
609, Eonju-Ro, Gangnam-Gu, Korea 06108
Tel : +82-2-2088-3560
Fax : +82-2-513-3567
Web site : www.magnagroup.com

The Corium Trade Mark is the property of ITW Inc., and is used under license by ITW PP & F Korea Limited.

Additional information: Classification according to Regulation (EC) No. 1272/2008: Calculation method.
Wording of H-statements:
H223 Flammable aerosol.
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H229 Pressurised container: May burst if heated.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H360FD May damage fertility. May damage the unborn child.
H360Fd May damage fertility. Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.

The information on this data sheet represents our current data and is reliable provided that the product is used
under the prescribed conditions and in accordance with the application specified on the packaging and/or in the
technical guidance literature. Any other use of the product which involves using the product in combination with
any other product or any other process is the responsibility of the user.
Made by DHI - Environment and Toxicology, Agern Allé 5, DK-2970 Hørsholm, Denmark.
www.dhigroup.com.