SAFETY DATA SHEET

Date of issue/Date of revision 23 July 2017

Version 5

Section 1. Identification
Product name : 01BK041F BASE COMPONENT
Product code : 01BK041F X04
Other means of : Not available.
identification
Product type : Liquid.

Relevant identified uses of the substance or mixture and uses advised against
Product use : Industrial applications.
Use of the substance/ : Coating.
mixture
Uses advised against : Not applicable.

Manufacturer : PPG Aerospace PRC-DeSoto

12780 San Fernando Road
Sylmar, CA 91342
Phone: 818 362 6711
Emergency telephone : (412) 434-4515 (U.S.)
number (514) 645-1320 (Canada)
01-800-00-21-400 (Mexico)

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 2
substance or mixture SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (liver, lymphatic
system, spleen) - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 37.5% (Oral),
45.4% (Dermal), 66.8% (Inhalation)

GHS label elements

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Section 2. Hazards identification

Hazard pictograms :

Signal word : Danger

Hazard statements : Highly flammable liquid and vapor.
Causes serious eye damage.
Causes skin irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.
May cause drowsiness or dizziness.
Causes damage to organs through prolonged or repeated exposure. (liver, lymphatic
system, spleen)
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Keep container tightly closed. Use only outdoors or
in a well-ventilated area. Do not breathe vapor. Do not eat, drink or smoke when using
this product. Wash hands thoroughly after handling. Contaminated work clothing must
not be allowed out of the workplace.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin
irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. Immediately call a POISON CENTER or physician.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label : Repeated exposure to high vapor concentrations may cause irritation of the respiratory
elements system and permanent brain and nervous system damage. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness and nausea and may lead to unconsciousness or death. Avoid contact with
skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.
Hazards not otherwise : Prolonged or repeated contact may dry skin and cause irritation.
classified

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Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Product name : 01BK041F BASE COMPONENT

Ingredient name % CAS number

reaction product: bisphenol-A-(epichlorhydrin); epoxy resin ≥10 - ≤20 25068-38-6
acetone ≥10 - ≤20 67-64-1
cyclohexanone ≥5.0 - ≤10 108-94-1
Phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-[(1-methylethylidene) ≥5.0 - ≤10 25036-25-3
bis(4,1-phenyleneoxymethylene)]bis[oxirane]
tert-butyl acetate ≥5.0 - ≤10 540-88-5
n-butyl acetate ≥5.0 - ≤10 123-86-4
Oxirane, 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, ≥1.0 - ≤5.0 25085-99-8
homopolymer
carbon black, respirable powder ≥1.0 - ≤5.0 1333-86-4
bis(1,2,2,6,6-pentamethyl-4-piperidyl) [[3,5-bis(1,1-dimethylethyl) ≥1.0 - ≤5.0 63843-89-0
-4-hydroxyphenyl]methyl]butylmalonate

SUB codes represent substances without registered CAS Numbers.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Description of necessary first aid measures
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression.

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Section 4. First aid measures

Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
from the chemical and the container may burst, with the risk of a subsequent explosion. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard. This
material is toxic to aquatic life with long lasting effects. Fire water contaminated with
this material must be contained and prevented from being discharged to any waterway,
sewer or drain.

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Section 5. Fire-fighting measures

Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides
nitrogen oxides
halogenated compounds
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

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Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Special precautions : Vapors may accumulate in low or confined areas or travel a considerable distance to a
source of ignition and flash back. Vapors are heavier than air and may spread along
floors. If this material is part of a multiple component system, read the Safety Data
Sheet(s) for the other component or components before blending as the resulting
mixture may have the hazards of all of its parts.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Do not store above the following temperature: 50°C (122°F). Store in accordance with
including any local regulations. Store in a segregated and approved area. Store in original container
incompatibilities protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
reaction product: bisphenol-A-(epichlorhydrin); epoxy resin None.
acetone ACGIH TLV (United States, 3/2016).
STEL: 500 ppm 15 minutes.
TWA: 250 ppm 8 hours.
OSHA PEL (United States, 6/2016).
TWA: 2400 mg/m³ 8 hours.
TWA: 1000 ppm 8 hours.
cyclohexanone ACGIH TLV (United States, 3/2016).
Absorbed through skin.
STEL: 50 ppm 15 minutes.
TWA: 20 ppm 8 hours.
OSHA PEL (United States, 6/2016).
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Section 8. Exposure controls/personal protection

TWA: 200 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
Phenol, 4,4'-(1-methylethylidene)bis-, polymer with 2,2'-[ None.
(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis[oxirane]
tert-butyl acetate OSHA PEL (United States, 6/2016).
TWA: 950 mg/m³ 8 hours.
TWA: 200 ppm 8 hours.
ACGIH TLV (United States, 3/2016).
STEL: 150 ppm 15 minutes.
TWA: 50 ppm 8 hours.
n-butyl acetate OSHA PEL (United States, 6/2016).
TWA: 710 mg/m³ 8 hours.
TWA: 150 ppm 8 hours.
ACGIH TLV (United States, 3/2016).
STEL: 150 ppm 15 minutes.
TWA: 50 ppm 8 hours.
Oxirane, 2,2'-[(1-methylethylidene)bis(4,1-phenyleneoxymethylene)]bis-, None.
homopolymer
carbon black, respirable powder ACGIH TLV (United States, 3/2016).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction
OSHA PEL (United States, 6/2016).
TWA: 3.5 mg/m³ 8 hours.
bis(1,2,2,6,6-pentamethyl-4-piperidyl) [[3,5-bis(1,1-dimethylethyl) None.
-4-hydroxyphenyl]methyl]butylmalonate
Key to abbreviations
A = Acceptable Maximum Peak S = Potential skin absorption
ACGIH = American Conference of Governmental Industrial Hygienists. SR = Respiratory sensitization
C = Ceiling Limit SS = Skin sensitization
F = Fume STEL = Short term Exposure limit values
IPEL = Internal Permissible Exposure Limit TD = Total dust
OSHA = Occupational Safety and Health Administration. TLV = Threshold Limit Value
R = Respirable TWA = Time Weighted Average
Z = OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances
Consult local authorities for acceptable exposure limits.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

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Section 8. Exposure controls/personal protection

Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Chemical splash goggles and face shield.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Gloves : butyl rubber
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Black.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : >37.78°C (>100°F)
Flash point : Closed cup: -20°C (-4°F)
Material supports : Yes.
combustion.
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Flammability (solid, gas) : Not available.

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Section 9. Physical and chemical properties

Lower and upper explosive : Not available.
(flammable) limits
Evaporation rate : Not available.
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 1.06
Density ( lbs / gal ) : 8.85
Solubility : Insoluble in the following materials: cold water.
Partition coefficient: n- : Not available.
octanol/water
Viscosity : Kinematic (40°C (104°F)): >0.21 cm2/s (>21 cSt)
VOC : 203 g/l
% Solid. (w/w) : 58.83

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition products.
Refer to protective measures listed in sections 7 and 8.

Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.

Hazardous decomposition : Decomposition products may include the following materials: carbon monoxide, carbon
products dioxide, smoke, oxides of nitrogen.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
reaction product: bisphenol-A- LD50 Dermal Rabbit >2 g/kg -
(epichlorhydrin); epoxy resin
LD50 Oral Rat 11.4 g/kg -
acetone LC50 Inhalation Vapor Rat 76000 mg/m³ 4 hours
LD50 Dermal Rabbit 15.8 g/kg -
LD50 Oral Rat 5800 mg/kg -
cyclohexanone LC50 Inhalation Gas. Rat 8000 ppm 4 hours
LC50 Inhalation Vapor Rat 11 mg/l 4 hours

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Section 11. Toxicological information

LD50 Dermal Rabbit 1100 mg/kg -
LD50 Oral Rat 1.54 g/kg -
tert-butyl acetate LD50 Oral Rat 4100 mg/kg -
n-butyl acetate LC50 Inhalation Vapor Rat >21.1 mg/l 4 hours
LC50 Inhalation Vapor Rat 2000 ppm 4 hours
LD50 Dermal Rabbit >17600 mg/kg -
LD50 Oral Rat 10.768 g/kg -
carbon black, respirable LD50 Dermal Rabbit >3 g/kg -
powder
LD50 Oral Rat >15400 mg/kg -
bis(1,2,2,6,6-pentamethyl- LD50 Oral Rat 1500 mg/kg -
4-piperidyl) [[3,5-bis(1,
1-dimethylethyl)
-4-hydroxyphenyl]methyl]
butylmalonate
Conclusion/Summary : There are no data available on the mixture itself.
Irritation/Corrosion
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Sensitization
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Conclusion/Summary : There are no data available on the mixture itself.
Carcinogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Classification
Product/ingredient name OSHA IARC NTP
cyclohexanone - 3 -
carbon black, respirable - 2B -
powder
Carcinogen Classification code:
IARC: 1, 2A, 2B, 3, 4
NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen
OSHA: +
Not listed/not regulated: -

Reproductive toxicity
Conclusion/Summary : There are no data available on the mixture itself.
Teratogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)

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Section 11. Toxicological information

Name Category
acetone Category 3
n-butyl acetate Category 3
Specific target organ toxicity (repeated exposure)
Name Category
bis(1,2,2,6,6-pentamethyl-4-piperidyl) [[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl] Category 1
butylmalonate
Target organs : Contains material which causes damage to the following organs: blood, brain.
Contains material which may cause damage to the following organs: kidneys, lungs,
liver, lymphatic system, gastrointestinal tract, upper respiratory tract, immune system,
skin, bones, central nervous system (CNS), eye, lens or cornea.

Aspiration hazard
Not available.

Information on the likely routes of exposure

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
Delayed and immediate effects and also chronic effects from short and long term exposure

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Section 11. Toxicological information

Conclusion/Summary : There are no data available on the mixture itself. Exposure to component solvent vapor
concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases,
loss of consciousness. Solvents may cause some of the above effects by absorption
through the skin. There is some evidence that repeated exposure to organic solvent
vapors in combination with constant loud noise can cause greater hearing loss than
expected from exposure to noise alone. If splashed in the eyes, the liquid may cause
irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic
effects of components from short-term and long-term exposure by oral, inhalation and
dermal routes of exposure and eye contact.
Short term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
General : Causes damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Route ATE value
Oral 7531 mg/kg
Dermal 6810 mg/kg
Inhalation (gases) 30116.2 ppm
Inhalation (vapors) 41.41 mg/l

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Section 12. Ecological information

Toxicity
Not available.

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
acetone - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
acetone -0.24 3 low
cyclohexanone 0.81 - low
tert-butyl acetate 1.76 - low
n-butyl acetate 1.78 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures

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14. Transport information

DOT IMDG IATA
UN number UN1263 UN1263 UN1263
UN proper shipping PAINT PAINT PAINT
name
Transport hazard class 3 3 3
(es)
Packing group II II II
Environmental hazards No. Yes. Yes. The environmentally
hazardous substance mark is
not required.
Marine pollutant Not applicable. (reaction product: bisphenol-A- Not applicable.
substances (epichlorhydrin); epoxy resin,
Phenol, 4,4'-
(1-methylethylidene)bis-,
polymer with 2,2'-[
(1-methylethylidene)bis(4,
1-phenyleneoxymethylene)]bis
[oxirane])
Product RQ (lbs) 30767.2 Not applicable. Not applicable.
RQ substances (acetone) Not applicable. Not applicable.

Additional information
DOT : Package sizes shipped in quantities less than the product reportable quantity are not subject to the
RQ (reportable quantity) transportation requirements.
IMDG : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
IATA : The environmentally hazardous substance mark may appear if required by other transportation
regulations.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Section 15. Regulatory information

United States
United States inventory (TSCA 8b) : All components are listed or exempted.
SARA 302/304
SARA 304 RQ : Not applicable.
Composition/information on ingredients
No products were found.

SARA 311/312

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Product code 01BK041F X04 Date of issue 23 July 2017 Version 5
Product name 01BK041F BASE COMPONENT

Section 15. Regulatory information

Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
Name Fire Sudden Reactive Immediate Delayed
hazard release of (acute) (chronic)
pressure health health
hazard hazard
reaction product: bisphenol-A- No. No. No. Yes. No. -
(epichlorhydrin); epoxy resin
acetone Yes. No. No. Yes. No. -
cyclohexanone Yes. No. No. Yes. No. -
Phenol, 4,4'-(1-methylethylidene)bis-, Yes. No. No. Yes. No. -
polymer with 2,2'-[(1-methylethylidene)
bis(4,1-phenyleneoxymethylene)]bis
[oxirane]
tert-butyl acetate Yes. No. No. Yes. No. -
n-butyl acetate Yes. No. No. Yes. No. -
Oxirane, 2,2'-[(1-methylethylidene)bis Yes. No. No. Yes. No. -
(4,1-phenyleneoxymethylene)]bis-,
homopolymer
carbon black, respirable powder Yes. No. No. No. Yes. -
bis(1,2,2,6,6-pentamethyl-4-piperidyl) [ Yes. No. No. Yes. Yes. -
[3,5-bis(1,1-dimethylethyl)
-4-hydroxyphenyl]methyl]butylmalonate
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health : 3 * Flammability : 3 Physical hazards : 0
( * ) - Chronic effects
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the
preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark
and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)
Health : 3 Flammability : 3 Instability : 0
Date of previous issue : 5/20/2017
Organization that prepared : EHS
the MSDS

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Product code 01BK041F X04 Date of issue 23 July 2017 Version 5
Product name 01BK041F BASE COMPONENT

Section 16. Other information

Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Indicates information that has changed from previously issued version.
Disclaimer
The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.

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 SAFETY DATA SHEET
Date of issue/Date of revision 15 March 2017
Version 2.03

Section 1. Identification
Product name : 80X109 CURING SOLUTION COMPONENT
Product code : 80X109 CURING SOLUTION COMPONENT
Other means of : Not available.
identification
Product type : Liquid.

Relevant identified uses of the substance or mixture and uses advised against
Product use : Industrial applications.
Use of the substance/ : Coating.
mixture
Uses advised against : Not applicable.

Manufacturer : PPG Aerospace PRC-DeSoto

12780 San Fernando Road
Sylmar, CA 91342
Phone: 818 362 6711
Emergency telephone : (412) 434-4515 (U.S.)
number (514) 645-1320 (Canada)
01-800-00-21-400 (Mexico)

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 2
substance or mixture ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION - Category 1A
SERIOUS EYE DAMAGE - Category 1
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 24.9%

GHS label elements

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COMPONENT
Product name 80X109 CURING SOLUTION COMPONENT

Section 2. Hazards identification

Hazard pictograms :

Signal word : Danger

Hazard statements : Highly flammable liquid and vapor.
Harmful if swallowed or if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention : Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep
away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment. Use only non-sparking tools. Take precautionary measures against static
discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area.
Do not breathe vapor. Do not eat, drink or smoke when using this product. Wash
hands thoroughly after handling. Contaminated work clothing must not be allowed out
of the workplace.
Response : Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Immediately call a POISON CENTER or physician. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do
NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse.
Immediately call a POISON CENTER or physician. IF ON SKIN: Wash with plenty of
soap and water. Wash contaminated clothing before reuse. If skin irritation or rash
occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or physician.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label : Do not taste or swallow. Repeated exposure to high vapor concentrations may cause
elements irritation of the respiratory system and permanent brain and nervous system damage.
Inhalation of vapor/aerosol concentrations above the recommended exposure limits
causes headaches, drowsiness and nausea and may lead to unconsciousness or death.
Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes
when heated.
Hazards not otherwise : Causes digestive tract burns. Prolonged or repeated contact may dry skin and cause
classified irritation.

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COMPONENT
Product name 80X109 CURING SOLUTION COMPONENT

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Product name : 80X109 CURING SOLUTION COMPONENT

Ingredient name % CAS number

butan-2-ol ≥20 - ≤50 78-92-2
benzyl alcohol ≥20 - ≤41 100-51-6
4,4'-methylenebis(cyclohexylamine) ≥5.0 - ≤10 1761-71-3
Cyclohexanamine, 4,4'-methylenebis-, reaction products with bisphenol A ≥5.0 - ≤10 129733-57-9
diglycidyl ether homopolymer
3,6-diazaoctanethylenediamin ≥0.10 - ≤2.2 112-24-3

SUB codes represent substances without registered CAS Numbers.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of
this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have
Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.
Description of necessary first aid measures
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep
person warm and at rest. Do NOT induce vomiting.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness or dizziness. May cause respiratory irritation.
Skin contact : Causes severe burns. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : Harmful if swallowed. Corrosive to the digestive tract. Causes burns. Can cause
central nervous system (CNS) depression.
Over-exposure signs/symptoms

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Section 4. First aid measures

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

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Section 5. Fire-fighting measures

Specific hazards arising : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
from the chemical and the container may burst, with the risk of a subsequent explosion. Vapors may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard. This
material is harmful to aquatic life with long lasting effects. Fire water contaminated with
this material must be contained and prevented from being discharged to any waterway,
sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides
nitrogen oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
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Section 6. Accidental release measures

information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Special precautions : Vapors may accumulate in low or confined areas or travel a considerable distance to a
source of ignition and flash back. Vapors are heavier than air and may spread along
floors. If this material is part of a multiple component system, read the Safety Data
Sheet(s) for the other component or components before blending as the resulting
mixture may have the hazards of all of its parts.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Do not store above the following temperature: 35°C (95°F). Store in accordance with
including any local regulations. Store in a segregated and approved area. Store in original container
incompatibilities protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits

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Section 8. Exposure controls/personal protection

Ingredient name Exposure limits
butan-2-ol ACGIH TLV (United States, 3/2016).
TWA: 303 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
OSHA PEL (United States, 6/2016).
TWA: 450 mg/m³ 8 hours.
TWA: 150 ppm 8 hours.
benzyl alcohol IPEL (PPG).
TWA: 10 ppm
STEL: 50 ppm
4,4'-methylenebis(cyclohexylamine) None.
Cyclohexanamine, 4,4'-methylenebis-, reaction products with bisphenol None.
A diglycidyl ether homopolymer
3,6-diazaoctanethylenediamin IPEL (PPG). Absorbed through skin.
TWA: 1 ppm
Key to abbreviations
A = Acceptable Maximum Peak S = Potential skin absorption
ACGIH = American Conference of Governmental Industrial Hygienists. SR = Respiratory sensitization
C = Ceiling Limit SS = Skin sensitization
F = Fume STEL = Short term Exposure limit values
IPEL = Internal Permissible Exposure Limit TD = Total dust
OSHA = Occupational Safety and Health Administration. TLV = Threshold Limit Value
R = Respirable TWA = Time Weighted Average
Z = OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances
Consult local authorities for acceptable exposure limits.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Chemical splash goggles and face shield.

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Section 8. Exposure controls/personal protection

Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Gloves : nitrile neoprene
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Amber.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : >37.78°C (>100°F)
Flash point : Closed cup: 22.22°C (72°F)
Material supports : Yes.
combustion.
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Evaporation rate : Not available.
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 0.93
Density ( lbs / gal ) : 7.76

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Section 9. Physical and chemical properties

Solubility : Insoluble in the following materials: cold water.
Partition coefficient: n- : Not available.
octanol/water
Viscosity : Kinematic (40°C (104°F)): >0.21 cm2/s (>21 cSt)
VOC : 589 g/l
% Solid. (w/w) : 36.63

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition products.
Refer to protective measures listed in sections 7 and 8.

Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents, strong alkalis, strong acids.

Hazardous decomposition : Decomposition products may include the following materials: carbon monoxide, carbon
products dioxide, smoke, oxides of nitrogen.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
butan-2-ol LC50 Inhalation Vapor Rat 48500 mg/m³ 4 hours
LD50 Oral Rat 2054 mg/kg -
benzyl alcohol LD50 Dermal Rabbit 2000 mg/kg -
LD50 Oral Rat 1.23 g/kg -
4,4'-methylenebis LD50 Dermal Rabbit 2.11 g/kg -
(cyclohexylamine)
LD50 Oral Rat 0.625 g/kg -
3,6-diazaoctanethylenediamin LD50 Dermal Rabbit 805 mg/kg -
LD50 Oral Rat 2500 mg/kg -
Conclusion/Summary : There are no data available on the mixture itself.
Irritation/Corrosion
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.

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Section 11. Toxicological information

Respiratory : There are no data available on the mixture itself.
Sensitization
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Conclusion/Summary : There are no data available on the mixture itself.
Carcinogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Reproductive toxicity
Conclusion/Summary : There are no data available on the mixture itself.
Teratogenicity
Conclusion/Summary : There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Name Category
butan-2-ol Category 3

Specific target organ toxicity (repeated exposure)

Name Category
4,4'-methylenebis(cyclohexylamine) Category 2

Target organs : Contains material which causes damage to the following organs: blood, kidneys, liver,
heart, brain, central nervous system (CNS).
Contains material which may cause damage to the following organs: gastrointestinal
tract, upper respiratory tract, skin, eyes.

Aspiration hazard
Not available.
Information on the likely routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness or dizziness. May cause respiratory irritation.
Skin contact : Causes severe burns. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : Harmful if swallowed. Corrosive to the digestive tract. Causes burns. Can cause
central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness

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Section 11. Toxicological information

Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
Delayed and immediate effects and also chronic effects from short and long term exposure
Conclusion/Summary : There are no data available on the mixture itself. Can form nitrosamines in the
presence of certain organic materials and if heated. Exposure to component solvent
vapor concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and
adverse effects on the kidneys, liver and central nervous system. Symptoms and signs
include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Solvents may cause some of the above effects by
absorption through the skin. There is some evidence that repeated exposure to organic
solvent vapors in combination with constant loud noise can cause greater hearing loss
than expected from exposure to noise alone. If splashed in the eyes, the liquid may
cause irritation and reversible damage. Ingestion may cause nausea, diarrhea and
vomiting. This takes into account, where known, delayed and immediate effects and
also chronic effects of components from short-term and long-term exposure by oral,
inhalation and dermal routes of exposure and eye contact.
Short term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
General : May cause damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.

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Section 11. Toxicological information

Fertility effects : No known significant effects or critical hazards.
Numerical measures of toxicity
Acute toxicity estimates
Route ATE value
Oral 1400.9 mg/kg
Dermal 4066 mg/kg
Inhalation (gases) 12288.7 ppm
Inhalation (vapors) 30.04 mg/l
Inhalation (dusts and mists) 4.096 mg/l

Section 12. Ecological information

Toxicity
Not available.

Persistence and degradability

Product/ingredient name Aquatic half-life Photolysis Biodegradability
benzyl alcohol - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
butan-2-ol 0.61 - low
benzyl alcohol 1.1 - low
3,6-diazaoctanethylenediamin -1.66 to -1.4 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere

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Section 13. Disposal considerations

inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees. Section 6. Accidental release measures

14. Transport information

DOT IMDG IATA
UN number UN3470 UN3470 UN3470
UN proper shipping PAINT, CORROSIVE, PAINT, CORROSIVE, PAINT, CORROSIVE,
name FLAMMABLE FLAMMABLE FLAMMABLE
Transport hazard class 8 (3) 8 (3) 8 (3)
(es)
Packing group II II II
Environmental hazards No. No. No.
Marine pollutant Not applicable. Not applicable. Not applicable.
substances

Additional information
DOT : None identified.
IMDG : None identified.
IATA : None identified.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Section 15. Regulatory information

United States
United States inventory (TSCA 8b) : All components are listed or exempted.
SARA 302/304
SARA 304 RQ : Not applicable.
Composition/information on ingredients
No products were found.

SARA 311/312
Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard

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Section 15. Regulatory information

Composition/information on ingredients
Name Fire Sudden Reactive Immediate Delayed
hazard release of (acute) (chronic)
pressure health health
hazard hazard
butan-2-ol Yes. No. No. Yes. No. -
benzyl alcohol No. No. No. Yes. No. -
4,4'-methylenebis(cyclohexylamine) No. No. No. Yes. Yes. -
Cyclohexanamine, 4,4'-methylenebis-, Yes. No. No. Yes. No. -
reaction products with bisphenol A
diglycidyl ether homopolymer
3,6-diazaoctanethylenediamin No. No. No. Yes. No. -
SARA 313
Chemical name CAS number Concentration
Supplier notification : butan-2-ol 78-92-2 15 - 40
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health : 3 * Flammability : 3 Physical hazards : 0
( * ) - Chronic effects
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or
risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are
to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®
materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
Health : 3 Flammability : 3 Instability : 0
Date of previous issue : 11/14/2016
Organization that prepared : EHS
the MSDS
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Indicates information that has changed from previously issued version.
Disclaimer

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Section 16. Other information

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures
described in this data sheet or for any misuse of the products.

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