TheraCem Base

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 6/8/2023 Supersedes: 7/14/2022 Version: 6.0

SECTION 1: Identification

1.1. Identification
Product form : Mixture
Product name : TheraCem Base

1.2. Recommended use and restrictions on use

Use of the substance/mixture : For Rx Only

1.3. Supplier

Manufacturer
BISCO, Inc.
1100 W. Irving Park Rd.
Schaumburg, IL , 60193
U.S.A.
T 1-800-247-3368 or 1-847-534-6000
[email protected] - www.bisco.com

1.4. Emergency telephone number

Emergency number : CHEMTREC - 24-Hour Hazmat Emergency Communications Center
Domestic: 1-800-424-9300 Outside the U.S.: 1-703-527-3887, collect calls accepted

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture

GHS US classification
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation
Skin sensitization, Category 1 H317 May cause an allergic skin reaction
Specific target organ toxicity - Single exposure, Category 3, H335 May cause respiratory irritation
Respiratory tract irritation
Full text of H statements : see section 16

2.2. GHS Label elements, including precautionary statements

GHS US labeling
Hazard pictograms (GHS US) :

Signal word (GHS US) : Warning

Hazard statements (GHS US) : H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
Precautionary statements (GHS US) : P261 - Avoid breathing dust, fume, vapors.
P264 - Wash hands thoroughly after handling
P272 - Contaminated work clothing must not be allowed out of the workplace.
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P302+P352 - If on skin: Wash with plenty of water and soap
P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing.

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P312 - Call a poison center/a doctor if you feel unwell
P321 - Specific treatment (see First aid measures on this label)
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.
P501 - Dispose in a safe manner in accordance with local/national regulations

2.3. Other hazards which do not result in classification

No additional information available

2.4. Unknown acute toxicity (GHS US)

Not applicable

SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable

3.2. Mixtures

Name Product identifier % GHS US classification

Ytterbium w/ Barium Glass CAS-No.: NA 30 - 50 Eye Irrit. 2, H319
STOT SE 3, H335

Ethoxylated Bis A Dimethacrylate CAS-No.: 41637-38-1 10 - 30 Aquatic Chronic 4, H413

Portland Cement CAS-No.: 65997-15-1 10 - 30 Skin Irrit. 2, H315

Eye Irrit. 2, H319
Skin Sens. 1, H317
STOT SE 3, H335

Ytterbium Fluoride CAS-No.: 13760-80-0 1-5 Skin Irrit. 2, H315

Eye Irrit. 2, H319

Brombenzenesulfinic Acid, Sodium Dihydrate CAS-No.: 175278-64-5 1-5 Skin Irrit. 2, H315
Eye Irrit. 2, H319
STOT SE 3, H335

BisGMA CAS-No.: 1565-94-2 1-5 Skin Irrit. 2, H315

Eye Irrit. 2, H319
Skin Sens. 1, H317
STOT SE 3, H335

Titanium Dioxide CAS-No.: 13463-67-7 <1 Carc. 2, H351

Acetyl-2-Thiourea CAS-No.: 591-08-2 <1 Acute Tox. 2 (Oral), H300

Full text of hazard classes and H-statements : see section 16

SECTION 4: First-aid measures

4.1. Description of first aid measures

First-aid measures general : Call a poison center/doctor/physician if you feel unwell.

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison
center/doctor/physician if you feel unwell.
First-aid measures after skin contact : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs:
Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Call a poison center/doctor/physician if you feel unwell.

4.2. Most important symptoms and effects (acute and delayed)

Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact : May cause eye irritation.

4.3. Immediate medical attention and special treatment, if necessary

Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media

Suitable extinguishing media : Water spray. Dry powder. Foam.

5.2. Specific hazards arising from the chemical

Hazardous decomposition products in case of fire : Toxic fumes may be released.

5.3. Special protective equipment and precautions for fire-fighters

Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel
Emergency procedures : Ventilate spillage area. Avoid breathing dust, fume, vapors. Avoid contact with skin and eyes.

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer
to section 8: "Exposure controls/personal protection".

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Mechanically recover the product.
Other information : Dispose of materials or solid residues at an authorized site.

6.4. Reference to other sections

For further information refer to section 13.

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Avoid breathing dust, fume, vapors. Avoid contact with skin and eyes. Wear personal protective
equipment.
Hygiene measures : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed
out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands
after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in a well-ventilated place. Keep container tightly closed. Keep cool.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

No additional information available

8.2. Appropriate engineering controls

Appropriate engineering controls : Ensure good ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.

8.3. Individual protection measures/Personal protective equipment

Hand protection:

Protective gloves

Eye protection:

Safety glasses

Skin and body protection:

Wear suitable protective clothing

Respiratory protection:

In case of insufficient ventilation, wear suitable respiratory equipment

Personal protective equipment symbol(s):

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Solid
Appearance : Paste.
Color : Straw
Odor : Acrylic
Odor threshold : No data available
pH : No data available
Melting point : No data available

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Freezing point : Not applicable

Boiling point : No data available
Flash point : Not applicable
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Non flammable.
Vapor pressure : No data available
Relative vapor density at 20°C : No data available
Relative density : Not applicable
Solubility : No data available
Partition coefficient n-octanol/water (Log Pow) : No data available
Auto-ignition temperature : Not applicable
Decomposition temperature : No data available
Viscosity, kinematic : Not applicable
Viscosity, dynamic : No data available
Explosion limits : Not applicable
Explosive properties : No data available
Oxidizing properties : No data available

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

Ethoxylated Bis A Dimethacrylate (41637-38-1)

LD50 oral rat > 2000 mg/kg Source: ECHA

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Ethoxylated Bis A Dimethacrylate (41637-38-1)

LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female, Read-
across, Dermal, 15 day(s))

Acetyl-2-Thiourea (591-08-2)
LD50 oral rat 50 mg/kg Source: National Library of Medicine/Hazardous Substances Data Bank

ATE US (oral) 50 mg/kg body weight

Ytterbium Fluoride (13760-80-0)

LD50 oral rat > 2000 mg/kg body weight Animal: rat, Animal sex: female, Guideline: OECD Guideline 420
(Acute Oral Toxicity - Fixed Dose Method), Guideline: EU Method B.1 bis (Acute Oral Toxicity -
Fixed Dose Procedure)

Titanium Dioxide (13463-67-7)

LD50 oral rat > 2000 mg/kg body weight (OECD 401: Acute Oral Toxicity, Rat, Male / female, Experimental
value, Oral, 14 day(s))

LC50 Inhalation - Rat > 5.09 mg/l (OECD 403: Acute Inhalation Toxicity, 4 h, Rat, Male, Experimental value,
Inhalation (dust), 14 day(s))

LC50 Inhalation - Rat (Dust/Mist) > 6.82 mg/l Source: ECHA

Skin corrosion/irritation : Causes skin irritation.

Portland Cement (65997-15-1)

pH 11 - 13.5 (20 °C)

Ethoxylated Bis A Dimethacrylate (41637-38-1)

pH 4.7 (< 0.01 %, 20 °C, OECD 105: Water Solubility)

Acetyl-2-Thiourea (591-08-2)
pH 6 (17.3 %)

Ytterbium Fluoride (13760-80-0)

pH 4.53 Temp.: 20 °C

Titanium Dioxide (13463-67-7)

pH 7 Source: ECHA
Serious eye damage/irritation : Causes serious eye irritation.

Portland Cement (65997-15-1)

pH 11 - 13.5 (20 °C)

Ethoxylated Bis A Dimethacrylate (41637-38-1)

pH 4.7 (< 0.01 %, 20 °C, OECD 105: Water Solubility)

Acetyl-2-Thiourea (591-08-2)
pH 6 (17.3 %)

Ytterbium Fluoride (13760-80-0)

pH 4.53 Temp.: 20 °C

Titanium Dioxide (13463-67-7)

pH 7 Source: ECHA
Respiratory or skin sensitization : May cause an allergic skin reaction.

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Brombenzenesulfinic Acid, Sodium Dihydrate (175278-64-5)

IARC group 4 - Probably not carcinogenic to humans

Ytterbium Fluoride (13760-80-0)

IARC group 4 - Probably not carcinogenic to humans

Titanium Dioxide (13463-67-7)

IARC group 2B - Possibly carcinogenic to humans
Reproductive toxicity : Not classified
STOT-single exposure : May cause respiratory irritation.

Portland Cement (65997-15-1)

STOT-single exposure May cause respiratory irritation.

Brombenzenesulfinic Acid, Sodium Dihydrate (175278-64-5)

STOT-single exposure May cause respiratory irritation.

BisGMA (1565-94-2)
STOT-single exposure May cause respiratory irritation.

Ytterbium w/ Barium Glass (NA)

STOT-single exposure May cause respiratory irritation.
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Viscosity, kinematic : Not applicable

Portland Cement (65997-15-1)

Viscosity, kinematic Not applicable (solid)

Ethoxylated Bis A Dimethacrylate (41637-38-1)

Viscosity, kinematic No data available in the literature

Titanium Dioxide (13463-67-7)

Viscosity, kinematic Not applicable (solid)
Symptoms/effects after inhalation : May cause respiratory irritation.
Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction.
Symptoms/effects after eye contact : May cause eye irritation.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.

Portland Cement (65997-15-1)

LC50 - Fish [1] > 1000 mg/l (96 h, Pisces)

Ethoxylated Bis A Dimethacrylate (41637-38-1)

LC50 - Fish [1] > 100 mg/l Source: ECAH

EC50 72h - Algae [1] > 100 mg/l Source: ECAH

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Acetyl-2-Thiourea (591-08-2)
LC50 - Fish [1] 3417 mg/l Source: Ecological Structure Activity Relationships

Ytterbium Fluoride (13760-80-0)

EC50 - Crustacea [1] > 0.52 mg/l Test organisms (species): Daphnia magna

BisGMA (1565-94-2)
LC50 - Fish [1] 0.537 mg/l Source: ECOSAR

Titanium Dioxide (13463-67-7)

LC50 - Fish [1] > 100 mg/l

EC50 - Crustacea [1] > 1000 mg/l (Invertebrata, Fresh water)

EC50 72h - Algae [1] > 50 mg/l Source: ECHA

12.2. Persistence and degradability

Portland Cement (65997-15-1)

Persistence and degradability Biodegradability: not applicable.

Chemical oxygen demand (COD) Not applicable (inorganic)

ThOD Not applicable (inorganic)

BOD (% of ThOD) Not applicable

Ethoxylated Bis A Dimethacrylate (41637-38-1)

Persistence and degradability Not readily biodegradable in water.

Acetyl-2-Thiourea (591-08-2)
Persistence and degradability Biodegradability in water: no data available.

BisGMA (1565-94-2)
Persistence and degradability Biodegradability in water: no data available.

Titanium Dioxide (13463-67-7)

Persistence and degradability Biodegradability: not applicable.

Chemical oxygen demand (COD) Not applicable (inorganic)

ThOD Not applicable (inorganic)

12.3. Bioaccumulative potential

Portland Cement (65997-15-1)

Bioaccumulative potential No bioaccumulation data available.

Ethoxylated Bis A Dimethacrylate (41637-38-1)

Partition coefficient n-octanol/water (Log Pow) 5.62 (Practical experience/observation, OECD 117: Partition Coefficient (n-octanol/water),
HPLC method)

Bioaccumulative potential High potential for bioaccumulation (Log Kow > 5).

Acetyl-2-Thiourea (591-08-2)
Partition coefficient n-octanol/water (Log Pow) -0.27 Source: National Library of Medicine

Bioaccumulative potential Not bioaccumulative.

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Ytterbium Fluoride (13760-80-0)

Partition coefficient n-octanol/water (Log Pow) 0.22 Source: EPISUITE

BisGMA (1565-94-2)
Partition coefficient n-octanol/water (Log Pow) 4.94 Source: ChemIDplus

Bioaccumulative potential No bioaccumulation data available.

Titanium Dioxide (13463-67-7)

Bioaccumulative potential Not bioaccumulative.

12.4. Mobility in soil

Portland Cement (65997-15-1)

Surface tension No data available in the literature

Ecology - soil No (test)data on mobility of the substance available.

Ethoxylated Bis A Dimethacrylate (41637-38-1)

Surface tension No data available in the literature

Organic Carbon Normalized Adsorption Coefficient 2.56 - 3.88 (log Koc, Calculated value)
(Log Koc)

Ecology - soil Low potential for mobility in soil.

Acetyl-2-Thiourea (591-08-2)
Mobility in soil 22 Source: HSDB

Titanium Dioxide (13463-67-7)

Surface tension No data available in the literature

Ecology - soil Low potential for mobility in soil.

12.5. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Disposal methods

Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.

SECTION 14: Transport information

In accordance with DOT / TDG / IMDG / IATA

14.1. UN number
Not regulated for transport

14.2. UN proper shipping name

Proper Shipping Name (DOT) : Not applicable
Proper Shipping Name (TDG) : Not applicable
Proper Shipping Name (IMDG) : Not applicable
Proper Shipping Name (IATA) : Not applicable

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

14.3. Transport hazard class(es)

DOT
Transport hazard class(es) (DOT) : Not applicable

TDG
Transport hazard class(es) (TDG) : Not applicable

IMDG
Transport hazard class(es) (IMDG) : Not applicable

IATA
Transport hazard class(es) (IATA) : Not applicable

14.4. Packing group

Packing group (DOT) : Not applicable
Packing group (TDG) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable

14.5. Environmental hazards

Other information : No supplementary information available.

14.6. Special precautions for user

DOT
No data available

TDG
No data available

IMDG
No data available

IATA
No data available

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. US Federal regulations

All components of this product are present and listed as Active on the United States Environmental Protection Agency Toxic Substances Control Act
(TSCA) inventory, except for:

Brombenzenesulfinic Acid, Sodium Dihydrate CAS-No. 175278-64-5 1 - 5%

Ytterbium w/ Barium Glass CAS-No. NA 30 - 50%

This product or mixture is not known to contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40
CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40
CFR Part 372.

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Acetyl-2-Thiourea (591-08-2)
CERCLA RQ 1000 lb

15.2. International regulations

CANADA

Portland Cement (65997-15-1)

Listed on the Canadian DSL (Domestic Substances List)

Ethoxylated Bis A Dimethacrylate (41637-38-1)

Listed on the Canadian DSL (Domestic Substances List)

Brombenzenesulfinic Acid, Sodium Dihydrate (175278-64-5)

Not listed on the Canadian DSL (Domestic Substances List)/NDSL (Non-Domestic Substances List)

Acetyl-2-Thiourea (591-08-2)
Listed on the Canadian NDSL (Non-Domestic Substances List)

Ytterbium Fluoride (13760-80-0)

Listed on the Canadian NDSL (Non-Domestic Substances List)

BisGMA (1565-94-2)
Listed on the Canadian DSL (Domestic Substances List)

Titanium Dioxide (13463-67-7)

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations
No additional information available

National regulations

Portland Cement (65997-15-1)

Listed on INSQ (Mexican National Inventory of Chemical Substances)

Acetyl-2-Thiourea (591-08-2)
Listed on INSQ (Mexican National Inventory of Chemical Substances)

Titanium Dioxide (13463-67-7)

Listed on IARC (International Agency for Research on Cancer)
Listed on INSQ (Mexican National Inventory of Chemical Substances)

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm

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TheraCem Base
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Component State or local regulations

Portland Cement(65997-15-1) U.S. - New Jersey - Right to Know Hazardous Substance List; U.S. - Pennsylvania - RTK
(Right to Know) List

Acetyl-2-Thiourea(591-08-2) U.S. - New Jersey - Right to Know Hazardous Substance List; U.S. - Pennsylvania - RTK
(Right to Know) List

Titanium Dioxide(13463-67-7) U.S. - New Jersey - Right to Know Hazardous Substance List; U.S. - Pennsylvania - RTK
(Right to Know) List

SECTION 16: Other information

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 06/08/2023

Full text of H-phrases

H300 Fatal if swallowed

H315 Causes skin irritation

H317 May cause an allergic skin reaction

H319 Causes serious eye irritation

H335 May cause respiratory irritation

H351 Suspected of causing cancer

H413 May cause long lasting harmful effects to aquatic life

Indication of changes:

Section Changed item Change Comments

Issue date Removed

Revision date Added

Precautionary statements (GHS US) Modified

Supersedes Added

2.1 GHS-US classification Modified

3 Composition/Information on ingredients Modified

7.1 Precautions for safe handling Modified

7.2 Storage conditions Modified

Safety Data Sheet (SDS), USA

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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