EYS F 730-2-1

Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

1. Identification of the substance/preparation and company

1.1. Identification of the substance/preparation:

Product name: Sel Straw Grade PU Foam – 779-B3 straw

1.2. Use of the substance/preparation:

Insulation product in construction applications.

1.3. Company Address:

SEL Dış Ticaret ve Kimya San. A.Ş.
Fevzi Paşa Mahallesi Kınıklı Kavşağı Cad.
E–5 Karayolu Üzeri, No:138 Sel Binası
Değirmenköy/Silivri/İstanbul
Tel: +90 212 735 34 00
Faks: +90 212 735 34 66
E-posta: [email protected]

1.4. Telephone Number for emergency:

+90 212 735 34 00

2. Hazard Identification

2.1. Classification of the Mixture

Classification according to Regulation (EC) No 1272/2008

This product is classified as dangerous according to EU Directives- (EC) No. 1272/2008.

Acute toxicity, Inhalative, Category 4 (H332)

Skin irritation, Category 2 (H315)
Eye irritation, Category 2 (H319)
Sensitization of the respiratory airways, Category 1 (H334)
Sensitization of the skin, Category 1 (H317)
Carcinogenicity, Category 2 (H351)
Specific target organ toxicity (single exposure), Category 3 (H335)
Specific target organ toxicity (repeated exposure), Category 2 (H373)
Lact. (H362)
Extremely flammable aerosol, Category 1 (H222)
Aquatic Chronic 3, (H412)

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 EYS F 730-2-1
Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

2.2. Label Elements

Labeling according to Regulation EC No 1272/2008 (CLP)

Contains polymethylene polyphenyl isocyanate, 4,4'-methylenediphenyl diisocyanate

Signal Word: Danger

Hazard Statements
H222: Extremely flammable aerosol.
H229: Pressurized container, may burst if heated.
H351: Suspected of causing cancer.
H362: May cause harm to breast-fed children.
H332: Harmful if inhaled.
H373: May cause damage to organs through prolonged or repeated exposure if inhaled.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H315: Causes skin irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H412: Harmful to aquatic life with long lasting effects

Precautinary Statements
P101: If medical advice is needed, have product container or label at hand.
P102: Keep out of reach of children.
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P251: Pressurized container: Do not pierce or burn, even after use.
P280: Wear protective gloves and eye protection/face protection.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P410 /412: Protect from sunlight. Do no expose to temperatures exceeding 50 °C/ 122°F.
P501: Dispose of contents/container to manufacturer/competent authority

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 EYS F 730-2-1
Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

3. Composition/Information on Ingredients

According to EU Directives- (EC) No. 1272/2008:

REACH Conc.
EINECS/ELINCS
Chemical Name CAS No. Registration Classification
No. (%w/w)
Number
Carc. 2; H351
Acute Tox. 4; H332
STOT RE 2; H373
Polymethylene Eye Irrit. 2; H319
9016–87–9 - >25
polyphenyl isocyanate STOT SE 3; H335
Skin Irrit. 2; H315
Resp. Sens. 1; H334
Skin Sens. 1; H317
Flam. Gas 1 H220
Propane 74–98–6 200–827–9 <10
Press. Gas H280
Flam. Gas 1 H220
I-butane 75-28-5 200-857-2 <10
Press. Gas H280
01-2119472128-37- Flam. Gas 1 H220
Dimethyl Ether 115–10–6 204–065–8 <10
0003 Press. Gas H280
17-2119406889-25- Aq. Chronic 1 ; H410
Chloroalkanes C14-17 85535-85-9 287-477-0 <2,5
0000 Lact.;H362
*For the full text of the H-Statements mentioned in this Section, see Section 16.

4. First Aid Measures

4.1. In case of eye contact:

Hold the eyes open and rinse with preferably lukewarm water for a sufficiently long period of time
(at least 10 minutes)
Seek medical advice.

4.2. In case of skin contact:

Wipe off. Wash affected areas with soap and plenty of water.
If irritation persists, seek medical advice.

4.3. If swallowed:
Do not induce the patient to vomit. Rinse mouth.
Give victim two glasses of water.
Never give anything by mouth to an unconscious person.
Seek medical advice.
4.4. If inhaled:
Take the person into the fresh air.
Seek medical advice.
5. Fire-fighting measures

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 EYS F 730-2-1
Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

5.1. Special protective equipment/procedures:

A self –contained respirator and protective clothing should be worn.
Mask and chemical resistant personal protective equipment should be used.
Determine the need to evacuate or isolate the area according to your local emergency plan.

5.2. Hazards during fire fighting

On burning may emit t0xic fumes.

5.3. Suitable extinguishing media:

Water fog ( if unavailable fine water spray), foam, dry chemical or carbon dioxide can be used.

5.4. Unsuitable extinguishing media:

None known.

6. Accidental Release Measures

6.1. Spill / Leak:

Avoid contact with.
Ventilate the area with fresh air.
Stop the leak if there is no risk.

6.2. Personal precautions:

Use personal protective equipment (protective gloves, work clothes and glasses)
Provide adequate ventilation.
Keep away from sources of ignition.
Smoking is prohibited.

6.3. Methods for cleaning up:

Allow product to solidify and remove it by mechanical means. Take collected spill to
manufacturer/competent authority. Clean (treat) contaminated surfaces with acetone. Further disposal
by incineration in accordance with local laws in force.

6.4. Environment related measures:

Collect the resulting residue containing solution.
Place in a closed container approved for transportation by appropriate authorities.
Dispose of collected material as soon as possible.

Prevent the spilled material to leak and contact with garbage, canals and sewage
If the product has caused environmental pollution (sewers, waterways, soil or air),
inform the relevant authorities.
7. Handling and Storage

7.1. Usage:

ADVICE ON SAFE HANDLING:

Provide good room ventilation even at ground level (vaporous are heavier than air )
Handle with care-avoid shock, friction and impact.

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 EYS F 730-2-1
Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:

Emergency cooling must be provided for the eventuality of a fire in the viomity.
Keep away from sources of ignition-refrain from smoking.

7.2. Storage:

REQUIREMENTS FOR STORAGE ROOMS AND VESSELS:

Store in a cool and dry place
Storage Temperature: <50°C
Keep out of direct sunlight.

ADVICE ON STORAGE COMPALIBILITY:

Do not store together with oxidizing agents.
Do not store with combustible materials.
Keep away from acids and bases.

FURTHER INFORMATION ON STORAGE CONDITIONS:

Protect from heat / overheating.
Heat causes increase in pressure and risk of bursting.

8. Exposure Controls/Personal Protection

8.1. Control Parameters

Exposure limits of substances in the mixture.

Time Weighted Time Weighted

Short Time Short Time
Substance Ca No: Basis / Country Average Average
Value Value
Exposure Limit Exposure Limit
ppm-
mg/m3 mg/m3-8 h ppm-Calculated
Calculated

Diphenyl methane
9016-87-9 / 101-
diisocyanate, isomers Germany/ TRGS 900 0,05
68-8
and homologues (1)

Chloroalkanes C14-17 85535-85-9 Germany/ TRGS 900 0,3 6 2,4 48

Denmark 500 1200 1000 2400
N-butane 106-97-8 United Kingdom 600 1450 75 1810
Germany/ TRGS 900 1000 2400
Belgium 1000
Iso-Bütan 75-28-5
Germany/ TRGS 900 1000 2400
Belgium 1000
Propane 74-98-6
Germany/ TRGS 900 1000 1800
Germany/ TRGS 900 1000 1900
Dimethyl ether 115-10-6
European Union 1000 1920
"Polymeric MDI" (PMDI) is a technical grade MDI, containing 30 % - 80 % w/w 4,4'-methylene diphenyl isocyanate
1
(MDI); the remainder consists of MDI oligomers and MDI homologues

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 EYS F 730-2-1
Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

8.2. Engineering Controls:

Contains Polymethylene polyphenyl isocyanate and propane/I-butane and DME gases.
Use general dilution ventilation and/or local exhaust ventilation.
If ventilation is not adequate, use respiratory protection equipment.

8.3. Personal Protection Equipment

Eyes: Avoid eye contact. Safety goggles should be worn.
Skin: Avoid skin contact.
Chemical resistant gloves should be worn.
(Recommended: Suitable materials for safety gloves; EN 374-3)
Respiratory: Avoid breathing of vapors.
Respiratory protection should be used.
In case of long-term interactions, fresh air mask should be used.
8.4 Hygiene Measures:
Avoid contact with eyes.
Especially in confined places, make sure you have proper ventilation.
Follow good industrial hygiene and safety practice.
Especially before eating, drinking or smoking, wash hands.
While using the product, do not drink, eat or smoke.

8.5. Environmental exposure controls:

Refer to section 6 and 12.

9. Physical and Chemical Properties:

9.1. Physical Form: Aerosol

9.2. Important Health, Safety and Environmental Information:

Flash Point: no data available (based on propellant)
Decomposition Temperature: no data available
Viscosity: no data available
Explosion Limits: no data available
Water Solubility: Not compatible.
Density: 20+/-2 kg/m3
Vapor Pressure: no data available
Vapor Density: no data available
Evaporation Rate: no data available
Melting Point: no data available
Boiling Point: no data available
Partition Coefficient
(n-octanol/water): no data available

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 EYS F 730-2-1
Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

Autoignition Temperature: no data available

The above information is not intended for use in preparing product spesifications.

10. Stability and Reactivity

10.1. Chemical Stability:

Stable under normal usage conditions.
Unstable on exposure to heat.

10.2. Incompatible Substances:

Unknown.

10.3. Dangerous Reactions:

The risk of explosion.

10.4. Conditions to Avoid:

Keep away from ignition sources, acids and bases.
Containers may explode at temperatures above 50 ° C
11. Toxicological Information

11.1. Information about Toxicological Effects:

No data available for the mixture.

11.1.1. Acute Toxicity

Acute Toxicity
Exposure Exposure Value
Substance Cas No Parameter Method Value Species
Type Time Determination
Toxicological
studies of a
Diphenylmethane- Oral LD50 >2000 mg/kg rat
comparable
diisocyanate, isomers 9016–87–9 product.
and homologues
Inhalation Literature/
LD50 490 mg/m3 4h
(aerosol) Supplier
Literature/
Chloro alkenes C14-17 85535-85-9 Oral LD50 >4000 mg/kg rat
Supplier
Literature/
Isobutane 75-28-5 Inhalation LC50 658 mg/lt 4h rat
Supplier
Literature/
Propane 74–98–6 Inhalation LC50 658 mg/lt 4h rat
Supplier
Test- Haskell
Dimethyl Ether 115–10–6 Inhalation LC50 309018 mg/l rat
Laboratories

May cause allergic respiratory response.

MDI concentrations above the exposure guidelines may cause allergic respiratory reactions in individuals
already sensitized.

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 EYS F 730-2-1
Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest.
Occasionally, breathing difficulties may be life threatening.

11.1.2. Corrosion/ Irritation

Corrosion / Irritation

Exposure Exposure Value

Substance Cas No Result Method Species
Type Time Determination

Toxicological
Diphenylmethane-
OECD studies of a
diisocyanate, isomers 9016–87–9 Skin irritating rabbit
/404 comparable
and homologues
product.
slightly
Chloro alkenes C14-17 85535-85-9 Eye Supplier
irritating

May cause eye and skin irritation.

11.1.3. Sensitization
Sensitization

Exposure Exposure Value

Substance Cas No Result Method Species
Type Time Determination

Toxicological
Diphenylmethane-
skin / OECD studies of a
diisocyanate, isomers 9016–87–9 sensitizing rabbit
inhalation /404 comparable
and homologues
product.
Not- Guinea
Chloro alkenes C14-17 85535-85-9 Supplier
Sensitizing Pigs

Repeated contact can cause allergic reactions.

11.1.4. Genotoxicity (in vivo)

Genotoxicity (in vivo)
Exposure Value
Substance Cas No Result Method Species Organ
Time Determination
not
Chloro alkenes C14-17 85535-85-9 Ames Test
mutagenic

Contains no known mutagenetic chemicals

11.5. Other Information:

Chronic Toxicity:

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 EYS F 730-2-1
Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

Over-exposure entails the risk of concentration-dependent irritating effects on eyes, nose throat, and
respiratory tract. Delayed appearance of the complaints and development of hypersensitivity (difficult
breathing, coughing, asthma) are possible. Hypersensitive persons may suffer from these effects even at
low isocyanate concentrations, including concentrations below the UK Workplace Exposure Limit (WEL).
Prolonged contact with the skin may cause tanning and irritant effects.
Reproductive Toxicity:
This product does not contain any known or suspected reproductive hazards.
Target Organ Effects:
Contains component(s) that have been reported to have specific target organ effects.

12. Ecological Information

12.1. Toxicity
No test data is available on the mixture.
Substance Cas No: Method Parameter Result Duration Species Value Source
mg/l h
Activated Literature/
OECD/209 EC50 >100 3
Diphenyl Sludge/bacterial Supplier
methane
Daphnia Magna /Water Literature/
diisocyanate, 9016-87-9 / 101- OECD/202 EC50 >1000 24
Flea Supplier
isomers and 68-8
homologues Danio Rerio / Zebra Literature/
(1) OECD /203 LC50 >1000 96
Fish Supplier

Activated Literature/
EC50 >2000 3
Chlorinated Sludge/bacterial Supplier
85535-85-9
Paraffin
Literature/
LC50 >5000 96 Alburnus
Supplier
Literature/
LC50 >4000 96 Fish
Dimethyl Supplier
115-10-6
ether Literature/
EC 50 >4000 48 Dapnia Magna
Supplier

12.2. Persistence and Degradability

Persistence and Degradability

Substance Cas No: Method Result Duration Value Source
% Day
Diphenyl methane
9016-87-9 / Literature/
diisocyanate, isomers OECD/302C 0 28
101-68-8 Supplier
and homologues (1)

Contains no biodegradable products

12.3. Bioaccumulation
Bioaccumulation
Substance Ca No: Parameter Result Duration Species Value Source

Chlorinated Literature/
85535-85-9 BCF 1000
Paraffin Supplier

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 EYS F 730-2-1
Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

Contains no bio-accumulative substances

12.4. Movement and Partitioning:

In the aquatic environment, movement is expected to be limited by its reaction with water forming
predominantly insoluble polyureas.
13. Disposal Considerations:

13.1. Product Disposal:

Dispose of in accordance with local regulations.

13.2. Packing Disposal:

Dispose of in accordance with local regulations.

14. Transport Information:

Road /Rail Sea Transport Air Transport

(ADR/RID) (IMDG) (IATA)
UN No 1950 1950 1950
UN Proper AEROSOLS AEROSOLS Aerosols,
Shipping Name flammable
Class 2.1 2.1 2.1
EMS Number - F-D,S-U -
Classification Code 5F
Package Group - - -
Limited quantity E0-1 lt See SP277
Environmental No No No
Hazards

15. Regulatory Information:

15.1. National Legislation/Regulations:

COMMISSION REGULATION (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of
the European Parliament and of the Council on the Registration, Evaluation, Authorization and
Restriction of Chemicals (REACH)

16. Other Information

16.1. Information Sources:

This SDS is prepared based on the information received from the suppliers.

16.2. Full text of H phrases referred to under sections 2 and 3

H220: Extremely flammable gas.
H222: Extremely flammable aerosol.
H229: Pressurized container, may burst if heated.
H351: Suspected of causing cancer.
H362: May cause harm to breast-fed children.

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 EYS F 730-2-1
Edition Date: 2013 Rev No: 05 Rev. Date:29.05.2017

Safety Data Sheet

According to Regulation EC No: 1907/2006 (REACH) (amended -2015/830)

H332: Harmful if inhaled.

H373: May cause damage to organs through prolonged or repeated exposure if inhaled.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H315: Causes skin irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction
H302: Harmful if swallowed
H280: Contains gas under pressure; may explode if heated.
H410: Very toxic to aquatic life with long lasting effects.

16.3. Additional Information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication.
The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used
in combination with any other materials or in any process, unless specified in the text.

It is the responsibility of persons in receipt of this Product Safety Data Sheet to ensure that the
information contained herein is properly read and understood by all people who may use, handle,
dispose or in any way come in contact with the product. If the recipient subsequently produces a
formulation containing the product, it is the recipient’s sole responsibility to ensure the transfer of all
relevant information from the Product Safety Data Sheet to their own Product Safety Data Sheet.

All information and instructions provided in this Safety Data Sheet (SDS) are based on the current state
of scientific and technical knowledge at the date indicated on the present SDS.
As stated above, this Safety Data Sheet has been prepared in compliance with applicable European law.
If you purchase this material outside Europe, where compliance laws may differ, you should receive
from your local supplier a SDS applicable to the country in which the product is sold and intended to be
used. Please note that the appearance and content of the SDS may vary –even for the same product –
between different countries, reflecting the different compliance requirements.

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