Chapter 5: Surface Area To Volume Ratios in Nanoscience: Table of
Chapter 5: Surface Area To Volume Ratios in Nanoscience: Table of
Chapter 5: Surface Area To Volume Ratios in Nanoscience: Table of
1 CHAPTER 5 – SURFACE AREA TO VOLUME RATIOS
TABLE OF
CONTENTS CHAPTER 5: SURFACE
Introduction
AREA TO VOLUME RATIOS
SA/V Goals
Optional Review:
IN NANOSCIENCE
Surface Area, Volume,
and Ratio Calculations
Advanced Extension:
Comparing Surface Area
to Volume as Radius
Changes
SA/V demonstrations
Reading ‐ Reaction Rates
Computer Simulation
Roughness Reading and
Physical vs. Chemical
Reactions Reading
Roughness in Fractals
and Nature
Mentos and Coke
Experiment
Applications
Evaluation/Assessment
SA/V Diagram
INTRODUCTION
T he main focus of this chapter is the interesting change in
properties of materials due to increased surface area to volume
ratio. Reactions take place at the surface of a chemical or
material; the greater the surface for the same volume, the greater
the reactivity. The link to nanotechnology is that as particles get
smaller; their surface area to volume ratio increases dramatically.
Imagine a cube of sugar, reacting with water as the water
dissolves the outside of the sugar. Now imagine the same cube of
2 CHAPTER 5 – SURFACE AREA TO VOLUME RATIOS
sugar cut into many little pieces. Each cut makes new outer surfaces for the water to
dissolve. For smaller particles of sugar, the same volume of sugar now has much more
surface area. A particle with a high surface area has a greater number of reaction sites
than a particle with low surface area, and thus, results in higher chemical reactivity.
Nanoparticles are special and interesting because their chemical and physical properties
are different from their macro counterparts. The sugar example is interesting if you
want to make tea sweet faster (use granules instead of cubes), but serves little real
application. One prime example of surface area to volume ratio at the nanoscale is gold
as a nanoparticle. At the macroscale, gold is an inert element, meaning it does not react
with many chemicals, whereas at the nanoscale, gold nanoparticles become extremely
reactive and can be used as catalysts to speed up reactions.
This increased reactivity for surface area to volume ratio is widely taken advantage of in
nature, one biological example being the body’s digestive system. Within the small
intestine, there are millions of folds and subfolds that increase the surface area of the
inner lining of the digestive tract. These folds allow more nutrients and chemicals to be
absorbed at the same time, greatly increasing our body’s efficiency and the rate at
which we digest food.
The main goal in the surface area to volume ratio chapter is to engage students in a
variety of activities to teach this surface area to volume ratio concept. Each type of
activity has a different purpose whether to teach, analyze, or review surface area to
volume ratio. After teaching the basics of the concept, students will analyze and apply
these basics to invoke critical thinking. Review of the material helps them retain and use
the information for future courses.
These activities use common day materials and examples that the students should be
familiar with. The ideas gained from these commonplace examples should be applied to
other applications to develop the student’s understanding about nanotechnology.
CHAPTER 5 – SURFACE AREA TO VOLUME RATIOS 3
SA/V GOALS
By the end of this chapter, students should be able to:
RECALL BASIC CONCEPTS OF SURFACE AREA, VOLUME AND RATIOS
Correctly calculate the surface area, volume, and SA/V of an object with given
dimensions.
Recognize that SA/V is not a constant value.
Recognize that the shape changing acts of “flattening” and “drawing out” increase the
SA/V of an object.
Recognize that as an object of a particular shape gets smaller (lower volume) without
changing shape, the SA/V increases.
UNDERSTAND THE RELATION OF SA/V RATIO TO CHEMICAL REACTIVITY
As particles get smaller, their surface area to volume ratio gets larger. With more
surface area for the same volume, these small particles react much faster because more
surface area provides more reaction sites for the same volume, leading to more
chemical reactivity. Students will come to learn several factors which dictate surface
area, such as roughness of the surface and the size of the object.
RELATE ROUGHNESS TO A HIGHER SA/V RATIO AND HOW NATURE USES THIS
One important application of SA/V ratio is roughness, as surfaces that are significantly
rougher at the microscale and nanoscale have more surface area while taking up the
same approximate volume. Students will also learn about how nature takes advantage
of this SA/V ratio increase in natural phenomena such as the small intestine, lungs, and
root hairs, in order to operate efficiently.