sds-2016

Download as pdf or txt
Download as pdf or txt
You are on page 1of 7

1.

IDENTIFICATION OF THE MATERIAL AND SUPPLIER


1.1 Product identifier
Product name CO CONTACT CLEANER (AEROSOL) (PRE JUNE 2010)
Synonyms 2015 - MANUFACTURER'S CODE ● 2016 - MANUFACTURER'S CODE ● CRC 2015 ● CRC 2015, 2016 CO
CONTACT CLEANER (AEROSOL) (FORMERLY) ● CRC 2016

1.2 Uses and uses advised against


Uses CLEANING AGENT ● ELECTRICAL CLEANER

1.3 Details of the supplier of the product


Supplier name CRC INDUSTRIES (AUST) PTY LIMITED
Address 9 Gladstone Road, Castle Hill, NSW, 2154, AUSTRALIA
Telephone (02) 9849 6700
Fax (02) 9680 4914
Email [email protected]
Website www.crcindustries.com.au

1.4 Emergency telephone numbers


Emergency 13 11 26 (PIC)

2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA
GHS classifications Aerosols - Flammable: Category 1
Aerosols - Pressurised: Category 1
Specific Target Organ Systemic Toxicity (Single Exposure): Category 3

2.2 GHS Label elements


Signal word DANGER
Pictograms

Hazard statements
H222 Extremely flammable aerosol.
H229 Pressurized container: may burst if heated.
H336 May cause drowsiness or dizziness.
Prevention statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after use.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
Response statements
P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.

SDS Date: 14 Feb 2018


Page 1 of 7
Version No: 2.1
PRODUCT NAME CO CONTACT CLEANER (AEROSOL) (PRE JUNE 2010)

Storage statements
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C.
Disposal statements
P501 Dispose of contents/container in accordance with relevant regulations.

2.3 Other hazards


No information provided.

3. COMPOSITION/ INFORMATION ON INGREDIENTS


3.1 Substances / Mixtures
Ingredient CAS Number EC Number Content
ISOHEXANE (MIXTURE OF ISOMERIC BRANCHED CHAIN 73513-42-5 - >60%
HEXANES)
N-HEXANE 110-54-3 203-777-6 <2%
CARBON DIOXIDE (PROPELLANT) 124-38-9 204-696-9 1 to 10%

4. FIRST AID MEASURES


4.1 Description of first aid measures
Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to
stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.
Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator or
an Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.
Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.
Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.
Ingestion For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If
swallowed, do not induce vomiting. Ingestion is considered unlikely due to product form.
First aid facilities None allocated.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.

4.3 Immediate medical attention and special treatment needed


Treat symptomatically.

5. FIRE FIGHTING MEASURES


5.1 Extinguishing media
Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.

5.2 Special hazards arising from the substance or mixture


Highly flammable aerosol. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Aerosol may
explode at temperatures exceeding 50°C. Eliminate all ignition sources, including cigarettes, open flames, spark producing
switches/tools, heaters, pilot lights, mobile phones, etc when handling. Aerosol cans may explode above 50°C.

5.3 Advice for firefighters


Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those
downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use
waterfog to cool intact containers and nearby storage areas.

5.4 Hazchem code


2Y
2 Fine Water Spray.
Y Risk of violent reaction or explosion. Wear full fire kit and breathing apparatus. Contain spill and run-off.

6. ACCIDENTAL RELEASE MEASURES

SDS Date: 14 Feb 2018


Page 2 of 7
Version No: 2.1
PRODUCT NAME CO CONTACT CLEANER (AEROSOL) (PRE JUNE 2010)

6.1 Personal precautions, protective equipment and emergency procedures


Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilate
area where possible.

6.2 Environmental precautions


Prevent product from entering drains and waterways.

6.3 Methods of cleaning up


Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place in
suitable containers for disposal.

6.4 Reference to other sections


See Sections 8 and 13 for exposure controls and disposal.

7. HANDLING AND STORAGE


7.1 Precautions for safe handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.
Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

7.2 Conditions for safe storage, including any incompatibilities


Store in a cool (< 50°C), dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs.
Ensure aerosol containers/ cans are adequately labelled, protected from physical damage and sealed when not in use. Check
regularly for damaged/ leaking containers. Large storage areas should have appropriate fire protection systems.

7.3 Specific end uses


No information provided.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


8.1 Control parameters
Exposure standards
TWA STEL
Ingredient Reference
ppm mg/m³ ppm mg/m³
Carbon dioxide SWA (AUS) 5000 9000 30000 54000
Carbon dioxide in coal mines SWA (AUS) 12500 22500 30000 54000
Hexane, other isomers SWA (AUS) 500 1760 1000 3500
n-Hexane SWA (AUS) 20 72 -- --

Biological limits

Ingredient Determinant Sampling Time BEI


N-HEXANE 2,5-Hexanedione in urine (without hydrolysis) End of shift at 0.4 mg/L
end of workweek
Reference: ACGIH Biological Exposure Indices

8.2 Exposure controls


Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical explosion proof
extraction ventilation is recommended. Flammable vapours may accumulate in poorly ventilated or confined
areas. Vapours are heavier than air and may travel some distance to an ignition source and flash back.
Maintain vapour levels below the recommended exposure standard.

SDS Date: 14 Feb 2018


Page 3 of 7
Version No: 2.1
PRODUCT NAME CO CONTACT CLEANER (AEROSOL) (PRE JUNE 2010)

PPE
Eye / Face Wear splash-proof goggles.
Hands Wear nitrile or neoprene gloves.
Body When using large quantities or where heavy contamination is likely, wear coveralls.
Respiratory At high vapour levels, wear a Type A-Class P1 (Organic gases/vapours and Particulate) respirator. Where
the boiling point is < 65°C, use an AX filter type.

9. PHYSICAL AND CHEMICAL PROPERTIES


9.1 Information on basic physical and chemical properties
Appearance COLOURLESS LIQUID (AEROSOL DISPENSED)
Odour ETHEREAL ODOUR
Flammability HIGHLY FLAMMABLE
Flash point < 0°C
Boiling point 51°C
Melting point NOT AVAILABLE
Evaporation rate NOT AVAILABLE
pH NOT AVAILABLE
Vapour density NOT AVAILABLE
Specific gravity 0.69
Solubility (water) INSOLUBLE
Vapour pressure NOT AVAILABLE
Upper explosion limit 7.0 %
Lower explosion limit 1.0 %
Partition coefficient NOT AVAILABLE
Autoignition temperature NOT AVAILABLE
Decomposition temperature NOT AVAILABLE
Viscosity NOT AVAILABLE
Explosive properties NOT AVAILABLE
Oxidising properties NOT AVAILABLE
Odour threshold NOT AVAILABLE

10. STABILITY AND REACTIVITY


10.1 Reactivity
Carefully review all information provided in sections 10.2 to 10.6.

10.2 Chemical stability


Stable under recommended conditions of storage.

10.3 Possibility of hazardous reactions


Polymerization is not expected to occur.

10.4 Conditions to avoid


Avoid heat, sparks, open flames and other ignition sources.

10.5 Incompatible materials


Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), alkalis (e.g. sodium hydroxide), heat and ignition
sources.

10.6 Hazardous decomposition products


May evolve carbon oxides and hydrocarbons when heated to decomposition.

11. TOXICOLOGICAL INFORMATION

SDS Date: 14 Feb 2018


Page 4 of 7
Version No: 2.1
PRODUCT NAME CO CONTACT CLEANER (AEROSOL) (PRE JUNE 2010)

11.1 Information on toxicological effects


Acute toxicity Based on available data, the classification criteria are not met. This product may have the potential to cause
adverse health effects if intentionally misused (e.g. deliberately inhaling contents).
Information available for the ingredients:

Oral LD50 Dermal LD50 Inhalation LC50


Ingredient

N-HEXANE 25 g/kg (rat) 3000 mg/kg (rabbit) 48000 ppm/4 hours (rat)
Skin Not classified as an irritant. Contact may result in mild irritation, drying and defatting of the skin, rash and
dermatitis.
Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.
Sensitisation Not classified as causing skin or respiratory sensitisation.
Mutagenicity Not classified as a mutagen.
Carcinogenicity Not classified as a carcinogen.
Reproductive Not classified as a reproductive toxin.
STOT - single Over exposure may result in irritation of the nose and throat, coughing and headache. High level exposure
exposure may result in nausea, dizziness and drowsiness.
STOT - repeated Not classified as causing organ damage from repeated exposure.
exposure
Aspiration Not classified as causing aspiration.

12. ECOLOGICAL INFORMATION


12.1 Toxicity
No information provided.

12.2 Persistence and degradability


No information provided.

12.3 Bioaccumulative potential


No information provided.

12.4 Mobility in soil


No information provided.

12.5 Other adverse effects


No information provided.

13. DISPOSAL CONSIDERATIONS


13.1 Waste treatment methods
Waste disposal For small amounts, absorb contents with sand or similar and dispose of to an approved landfill site. Do not
puncture or incinerate aerosol cans. Contact the manufacturer/supplier for additional information (if required).
Legislation Dispose of in accordance with relevant local legislation.

14. TRANSPORT INFORMATION


CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

SDS Date: 14 Feb 2018


Page 5 of 7
Version No: 2.1
PRODUCT NAME CO CONTACT CLEANER (AEROSOL) (PRE JUNE 2010)

LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)

14.1 UN Number 1950 1950 1950


14.2 Proper AEROSOLS AEROSOLS AEROSOLS
Shipping Name

14.3 Transport 2.1 2.1 2.1


hazard class
14.4 Packing Group None allocated. None allocated. None allocated.
14.5 Environmental hazards
Not a Marine Pollutant
14.6 Special precautions for user
Hazchem code 2Y
GTEPG 2D1
EMS F-D, S-U

15. REGULATORY INFORMATION


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Poison schedule Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).
Classifications Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and
Labelling of Chemicals.
The classifications and phrases listed below are based on the Approved Criteria for Classifying Hazardous
Substances [NOHSC: 1008(2004)].
Hazard codes F+ Extremely flammable
Xn Harmful
Risk phrases R12 Extremely Flammable.
R67 Vapours may cause drowsiness and dizziness.
Safety phrases S45 In case of accident or if you feel unwell seek medical advice immediately (show the label
where possible).
S53 Avoid exposure - obtain special instructions before use.
Inventory listings AUSTRALIA: AICS (Australian Inventory of Chemical Substances)
All components are listed on AICS, or are exempt.

16. OTHER INFORMATION


Additional information AEROSOL CANS may explode at temperatures approaching 50°C.

RESPIRATORS: In general the use of respirators should be limited and engineering controls
employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator
selection and training is undertaken. Remember that some respirators may be extremely
uncomfortable when used for long periods. The use of air powered or air supplied respirators should
be considered where prolonged or repeated use is necessary.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:


The recommendation for protective equipment contained within this report is provided as a guide
only. Factors such as form of product, method of application, working environment, quantity used,
product concentration and the availability of engineering controls should be considered before final
selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:


It should be noted that the effects from exposure to this product will depend on several factors
including: form of product; frequency and duration of use; quantity used; effectiveness of control
measures; protective equipment used and method of application. Given that it is impractical to
prepare a report which would encompass all possible scenarios, it is anticipated that users will
assess the risks and apply control methods where appropriate.

SDS Date: 14 Feb 2018


Page 6 of 7
Version No: 2.1
PRODUCT NAME CO CONTACT CLEANER (AEROSOL) (PRE JUNE 2010)

Abbreviations ACGIH American Conference of Governmental Industrial Hygienists


CAS # Chemical Abstract Service number - used to uniquely identify chemical compounds
CNS Central Nervous System
EC No. EC No - European Community Number
EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous
Goods)
GHS Globally Harmonized System
GTEPG Group Text Emergency Procedure Guide
IARC International Agency for Research on Cancer
LC50 Lethal Concentration, 50% / Median Lethal Concentration
LD50 Lethal Dose, 50% / Median Lethal Dose
mg/m³ Milligrams per Cubic Metre
OEL Occupational Exposure Limit
pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly
alkaline).
ppm Parts Per Million
STEL Short-Term Exposure Limit
STOT-RE Specific target organ toxicity (repeated exposure)
STOT-SE Specific target organ toxicity (single exposure)
SUSMP Standard for the Uniform Scheduling of Medicines and Poisons
SWA Safe Work Australia
TLV Threshold Limit Value
TWA Time Weighted Average

Report status This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the
product and serves as their Safety Data Sheet ('SDS').
It is based on information concerning the product which has been provided to RMT by the
manufacturer, importer or supplier or obtained from third party sources and is believed to represent
the current state of knowledge as to the appropriate safety and handling precautions for the product
at the time of issue. Further clarification regarding any aspect of the product should be obtained
directly from the manufacturer, importer or supplier.
While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does
not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts
no liability for any loss, injury or damage (including consequential loss) which may be suffered or
incurred by any person as a consequence of their reliance on the information contained in this SDS.

Prepared by Risk Management Technologies


5 Ventnor Ave, West Perth
Western Australia 6005
Phone: +61 8 9322 1711
Fax: +61 8 9322 1794
Email: [email protected]
Web: www.rmt.com.au

[ End of SDS ]

SDS Date: 14 Feb 2018


Page 7 of 7
Version No: 2.1

You might also like