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    Samuel Chigozie
    The document provides data and calculations to determine the specific volume of a gas mixture at different pressures using three equations of state. At 1 atm, the specific volumes from the three equations are close, indicating ideal gas behavior. However, at 200 atm the values diverge, showing non-ideal behavior as pressure increases. The Redlich-Kwong-Soave equation gives results closest to the ideal gas value.

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    From Previous Problem

    Uploaded by

    Samuel Chigozie
    161 views12 pages
    The document provides data and calculations to determine the specific volume of a gas mixture at different pressures using three equations of state. At 1 atm, the specific volumes from the three equations are close, indicating ideal gas behavior. However, at 200 atm the values diverge, showing non-ideal behavior as pressure increases. The Redlich-Kwong-Soave equation gives results closest to the ideal gas value.

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    Calculations in chemical engineering using excel

    Original Title

    COMPUTERAPP.xlsx

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    The document provides data and calculations to determine the specific volume of a gas mixture at different pressures using three equations of state. At 1 atm, the specific volumes from the three equations are close, indicating ideal gas behavior. However, at 200 atm the values diverge, showing non-ideal behavior as pressure increases. The Redlich-Kwong-Soave equation gives results closest to the ideal gas value.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    161 views12 pages

    From Previous Problem

    Uploaded by

    Samuel Chigozie
    The document provides data and calculations to determine the specific volume of a gas mixture at different pressures using three equations of state. At 1 atm, the specific volumes from the three equations are close, indicating ideal gas behavior. However, at 200 atm the values diverge, showing non-ideal behavior as pressure increases. The Redlich-Kwong-Soave equation gives results closest to the ideal gas value.

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    of 12

    UNIVERSITY: NNAMDI AZIKIWE UNIVERSITY, AWKA

    FACULTY: ENGINEERING
    DEPARTMENT: CHEMICAL ENGINEERING
    COURSE TITLE: COMPUTER APPLICATION IN CHEMICAL ENGINEERING
    COURSE CODE: CHE463
    SEMESTER: 1ST SEMESTER 2020/20201 SESSION
    LECTURER: ENGR DR UZOH CHIGOZIE FRANCOLLINS
    NAME: NZEKWE SAMUEL CHIGOZIE
    REG NUMBER: 2017214013

    QUESTIONS 2.32:
    Find the compressibility factor of ammonia gas at conditions from 50 to 250atm and 400k
    using the Redlich-kwong Soave equation of state in Excel. ( Hint: before begining your
    spreadsheet, think about how you can organize it so that you can copy formulas from cell to
    cell easily.)
    Experimental data is available that gives a volume of 0.459l/g.mol at 66.8atm and 446K

    From Previous Problem


    Parameters - Ammonia Data
    Tc 405.5 K T 400
    Pc 111.3 atm P 200
    R 0.08206 Liter-atm/g mol K
    a 4.2527 gmol-1 Tr 0.986436
    -1
    b 0.0259 gmol α 1.006852
    Molar Volume 0.56211270548739 L/gmol Pr 1.796945
    Formula Result
    A 5/2
    0.42747(Pr/Tr ) 0.794818
    B 0.08664(Pr/Tr) 0.157828
    r AB 0.125445
    q 2
    B +B-A -0.61208
    z -3.672324284E-07 0.317174
    ERING

    m 50 to 250atm and 400k


    before begining your
    copy formulas from cell to

    l at 66.8atm and 446K

    K
    atm
    UNIVERSITY: NNAMDI AZIKIWE UNIVERSITY, AWKA
    FACULTY: ENGINEERING
    DEPARTMENT: CHEMICAL ENGINEERING
    COURSE TITLE: COMPUTER APPLICATION IN CHEMICAL ENGINEERING
    COURSE CODE: CHE463
    SEMESTER: 1ST SEMESTER 2020/20201 SESSION
    LECTURER: ENGR DR UZOH CHIGOZIE FRANCOLLINS
    NAME: NZEKWE SAMUEL CHIGOZIE
    REG NUMBER: 2017214013

    QUESTIONS 2.42:
    Consider the following mixture going into a water-gas shift reactor to make hydrogen for the hydrog
    CO, 630; H₂O, 1130; CO2, 189; H₂, 63 kmol/h. The gas is at 1 atm and 500 K. Use Excel (or MATLAB) t
    the specific volume using(a) ideal gas law(b) Redlich-Kwong equation of state(c) Redlich-Kwong-Soa
    of state.The acentric factors for the RK-Soave method are: CO, 0.049; water, 0.344; CO₂2.0.225; Hyd
    -0.22.Where did you get the other data you needed? How do the three answers compare? Is the gas
    not? Comment. Then redo the calculations for a pressure of 200 atm and comment on the results.

    GIVEN DATA
    T(K) P(atm) R(liter-atm/g.mol.k) Total Moles(kmol/hr) Total Moles(mol/s)
    500 1 0.08206 2012 558.88
    20

    FINDING VALUES FOR (CO)

    PARAMETERS FORMULA

    Tc (k) Critical Temperature


    Pc (bar) Critical Pressure
    Tr B29/J36
    a (RK) 0.42748*((D29^2 * J36^2)/J37)*J42
    a(SRK) 0.42748*J43*((D29^2 * J36^2)/J37)
    b 0.08664*((D29*J36)/J37)
    α (RK) 1 / J38^0.5
    α (SRK) (1 + J45*(1 - J38^0.5))^2
    ω Pitzer acentric factor
    m 0.48508 + 1.55171*J44 - 0.1561*J44^2
    Number of moles(n) mass / molecularmass
    Mole fraction(Y) J46 / E29
    FINDING VALUES FOR (H2O)

    PARAMETERS FORMULA

    Tc (k) Critical Temperature


    Pc (bar) Critical Pressure
    Tr B29/J54
    a (RK) 0.42748*((D29^2 * J54^2)/J55)*J60
    a(SRK) 0.42748*((D29^2 * J54^2)/J55)*J61
    b 0.08664*((D29*J54)/J55)
    α (RK) 1 / J56^0.5
    α (SRK) (1 + J63*(1 - J56^0.5))^2
    ω Pitzer acentric factor
    m 0.48508 + 1.55171*J62 - 0.1561*J62^2
    Number of moles(n) mass / molecularmass
    Mole fraction(Y) J64 /E29

    FINDING VALUES FOR (CO2)

    PARAMETERS FORMULA

    Tc (k) Critical Temperature


    Pc (bar) Critical Pressure
    Tr B29/J72
    a (RK) 0.42748*((D29^2 * J72^2)/J73)*J78
    a(SRK) 0.42748*((D29^2 * J72^2)/J73)*J79
    b 0.08664*((D29*J72)/J73)
    α (RK) 1 / J74^0.5
    α (SRK) (1 + J81*(1 - J74^0.5))^2
    ω Pitzer acentric factor
    m 0.48508 + 1.55171*J80 - 0.1561*J80^2
    Number of moles(n) mass / molecularmass
    Mole fraction(Y) J82 / E29

    FINDING VALUES FOR (H2)

    PARAMETERS FORMULA

    Tc (k) Critical Temperature


    Pc (bar) Critical Pressure
    Tr B29/J90
    a (RK) 0.42748*((D29^2 * J90^2)/J91)*J96
    a(SRK) 0.42748*((D29^2 * J90^2)/J91)*J97
    b 0.08664*((D29*J90)/J91)
    α (RK) 1/J92^0.5
    α (SRK) (1 + J99*(1 - J92^0.5))^2
    ω Pitzer acentric factor
    m 0.48508 + 1.55171*J98 - 0.1561*J98^2
    Number of moles(n) mass / molecularmass
    Mole fraction(Y) J100 / E29

    SUMMATION OF a and b VALUES

    SUMMATION FORMULA
    ∑a (RK) (J47*J39^0.5 + J65*J57^0.5 + J83*J75^0.5 + J101*J93^0.5)^2
    ∑a (SRK) (J47*J40^0.5 + J65*J58^0.5 + J83*J76^0.5 + J101*J94^0.5)^2

    ∑b J47*J41 + J65*J59 + J83*J77 + J101*J95

    A) Calculation of specific volume using the ideal


    gas law

    PARAMETER FORMULA

    AT 1 atm V D29*B29/C29
    AT 200 atm v D29*B29/C30

    B) Calculation of specific volume using REDLICH KWONG EQUATION OF STATE


    (RK)
    PARAMETER
    FORMULA

    F(v)

    AT 1 atm RESULTS 2.90285396442602E-07


    AT 200 atm 2.92489830117093E-06

    C) Calculation of specific volume using REDLICH


    KWONG SOAVE EQUATION OF STATE (SRK)
    C) Calculation of specific volume using REDLICH
    KWONG SOAVE EQUATION OF STATE (SRK)

    PARAMETER FORMULA

    F(v)

    AT 1 atm RESULTS 1.77377983902327E-05


    AT 200 atm 1.88832752115453E-06

    DISCUSSION
    I obtained the other data needed for the calculation from the ChemSep software, versi
    The three answers obtained appear to be fairly close together, as they can be easily
    approximated to 41 l/g mol. Therefore, it can be concluded that the gas behaves ideally
    on which value tends to approach the ideal gas value, the Redlich-Kwong-Soave EOS ap
    to be more accurate than the Redlich-Kwong EOS.
    Unlike at 1 atm, the specific volume values here are not quite close together. Thus, as th
    pressure is increased, the gas begins to deviate from ideal conditions. Consequently, th
    Redlich-Kwong EOS appears to show greater deviation from the ideal gas value than the
    Redlich-Kwong-Soave EOS.   Also, the specific volume decreases as the pressure is incre
    from 1 atm to 200 atm.              
    ydrogen for the hydrogen economy.
    se Excel (or MATLAB) to compute
    (c) Redlich-Kwong-Soave equation
    .344; CO₂2.0.225; Hydrogen,
    ers compare? Is the gas ideal or
    ment on the results.

    MOLE CONVERSIONS
    1mol/s = 3.6Kmol/hr

    RESULTS

    132.7
    34.532
    3.7678975131877
    0.7562221585157
    0.3294288803167
    0.0273211607691
    0.5151698748957
    0.224420605967
    0.048
    0.5592024256
    630
    0.3131212723658
    RESULTS

    647
    220.5
    0.7727975270479
    6.2164999097474
    6.8647193939542
    0.0208615053279
    1.1375412080448
    1.2561572115593
    0.343
    0.9989515211
    1130
    0.5616302186879

    RESULTS

    304.21
    73.8
    1.6436014595181
    2.8156014307636
    2.1256037580091
    0.0293067109223
    0.7800128204075
    0.5888611094731
    0.224
    0.8248305664
    189
    0.0939363817097

    RESULTS

    33.19
    13
    15.064778547755
    0.0628446920603
    0.0832982633145
    0.0181515558535
    0.2576431640855
    0.3414962731073
    -0.215
    0.1442466275
    63
    0.0313121272366

    RESULTS

    3.378514495038

    3.2299831083625

    0.0235926186323

    LA RESULTS

    C29 41.03
    C30 2.0515

    40.97123
    1.992287
    RESULTS

    40.97485
    1.996075

    emSep software, version 8.


    they can be easily
    he gas behaves ideally. Based
    h-Kwong-Soave EOS appears

    se together. Thus, as the


    ons. Consequently, the
    deal gas value than the
    s the pressure is increased
    UNIVERSITY: NNAMDI AZIKIWE UNIVERSITY, AWKA
    FACULTY: ENGINEERING
    DEPARTMENT: CHEMICAL ENGINEERING
    COURSE TITLE: COMPUTER APPLICATION IN CHEMICAL ENGINEERING
    COURSE CODE: CHE463
    SEMESTER: 1ST SEMESTER 2020/20201 SESSION
    LECTURER: ENGR DR UZOH CHIGOZIE FRANCOLLINS
    NAME: NZEKWE SAMUEL CHIGOZIE
    REG NUMBER: 2017214013

    QUESTIONS 2.51:
    Consider a mixture of 25% ammonia, the rest nitrogen and hydrogen in a 1:3 ratio. The gas
    is at 270 atm and 550 K. Use Excel (or MATLAB) to compute the specific volume using(a)
    ideal gas law(b) Redlich-Kwong equation of state(c) Redlich-Kwong-Soave equation of
    state.Where did you get the data you needed? How do the three answers compare? Is the
    gas ideal or not? Comment on the reasons the RKS equation might be expected to be better.
    3 ratio. The gas
    me using(a)
    quation of
    ompare? Is the
    ted to be better.

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