Mcqs For Mock Test

MCQs for Mock test
Class: F. Y. M. Pharm Sem: Sem II CBSGS Branch: Quality Assurance

A. Y.: 2020-21 Subject: Spectroscopic Structural Elucidation
1. IR spectrum is a plot of:

A. % Transmittance versus time
B. % Transmittance versus wavenumber
C. Peak area versus time
D. Peak area versus wavenumber
2. Separation of ions in mass spectrometer take place on the basis of which of the
following?
A. Mass
B. Charge
C. Molecular weight
D. Mass to charge ratio
3. The increment for α alkyl substitution on α, β unsaturated ketone is?

A. 12
B. 18
C. 10
D. 5
4. Calculate the ƛmax for the following diene:
A. 234 nm
B. 273 nm
C. 232 nm
D. 241 nm
5. Which of the following spectroscopy techniques is associated with molecular
emission?
A. UV-Visible spectroscopy
B. IR spectroscopy
C. Fluorescence spectroscopy
D. X-ray diffraction
6. Which of hydrogens a-d in the following molecule gives a triplet signal in a normal 1H
NMR spectrum?
A. Hydrogen a
B. Hydrogen b
C. Hydrogen c
D. Hydrogen d
7. Which of the following statements regarding IR spectroscopy is correct?

A. IR radiation is higher in energy than UV radiation
B. IR spectra records the scattering of the radiation
C. IR spectra gives information about the ƛmax of the molecule
D. IR radiation is higher in wavelength than UV radiation
8. What will be the correct order of carbon chemical shifts in the 13C NMR of the
following compound?
A. CMe < C2 < C3 < C1

B. CMe < C3 < C2 < C1
C. CMe < C2 < C1 < C3
D. CMe < C1 < C2 < C3
9. The IR band for C≡ N group is observed in the range of __________
A. 3000 – 2800 cm-1
B. 3400 – 3300 cm-1
C. 2260 – 2200 cm-1
D. 1750 – 1650 cm-1
10. Identify the correct statement

A. NMR signals towards the left of the spectrum correspond to low chemical shift values
B. NMR signals towards the right of the spectrum correspond to high chemical shift values
C. Chemical shift values are larger when shielding effects are greater
D. Chemical shift values are larger when deshielding effects are greater
11. Signal splitting in NMR arises from?

A. Shielding
B. Spin-spin decoupling
C. Spin-spin coupling
D. Deshielding
12. The spectrum of a compound with molecular formula C5H602 is shown below.
IR spectrum shows medium intensity band at 3270 and 2180 cm-1.
Proton NMR data: 1.3 (3H, t); 2.8 (1H, s), 4.3 (2H, q). What will be the structure of
compound?
A.
B.
C.
D.
13. The base peak in mass spectrum is?
A. The lowest mass peak
B. The peak corresponding to the parent ion
C. The highest mass peak
D. The peak set to 100% relative intensity
14. The IR band for -NH2 group is observed in the range of __________
A. 3000 – 2800 cm-1
B. 3400 – 3300 cm-1
C. 2200 – 2100 cm-1
D. 1750 – 1650 cm-1
15. How many signals will be shown by the following compound in 1H NMR?
A. 1
B. 2
C. 3
D. 4
16. The splitting for -CH2 group in proton NMR of CH3-CH2-OH will be observed as:
A. Doublet
B. Singlet
C. Quartet
D. Triplet
17. The splitting for -CH2 group in 13C NMR of CH3-CH2-NH2 will be observed as:
A. Doublet
B. Singlet
C. Quartet
D. Triplet
18. The molecular ion peak of ethanol will be observed at m/z value of _______
A. 46
B. 32
C. 45
D. 30
19. The base value for the following compound is
A. 214
B. 253
C. 217
D. 202
20. In IR spectroscopy, the wavenumber for carbonyl group is observed in the range of
A.3500-3300 cm-1
B. 2200-2100 cm-1
C.1740-1650 cm-1
D.3000-2800 cm-1
21. How many signals will be shown by the following compound in 1H NMR?
A. 4
B. 3
C. 2
D. 1
22. Which of the following techniques would be most useful to identify as well as
quantify the presence of a known impurity in a drug substance?
A. NMR
B. MS
C. IR
D. HPLC
23. Mass spectrum is a plot of:

A. % Relative abundance versus time
B. % Relative intensity versus m/z
C. % Relative abundance versus time
D. % Relative intensity versus m/z
24. The increment for double bond extending conjugation on 1, 3 butadiene is?
A. 5
B. 10
C. 30
D. 15
25. The splitting for -NH2 group in proton NMR of CH3-CH2-NH2 will be observed as:
A. Doublet
B. Singlet
C. Quartet
D. Triplet
ANSWER KEY
1. B
2. D
3. C
4. C
5. A
6. C
7. D
8. B
9. C
10. D
11. C
12. B
13. D
14. B
15. D
16. D
17. A
18. A
19. C
20. C
21. A
22. D
23. C
24. C
25. B

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MCQs for Mock test

Class: F. Y. M. Pharm Sem: Sem II CBSGS Branch: Quality Assurance

1. IR spectrum is a plot of:

3. The increment for α alkyl substitution on α, β unsaturated ketone is?

4. Calculate the ƛmax for the following diene:

7. Which of the following statements regarding IR spectroscopy is correct?

A. CMe < C2 < C3 < C1

10. Identify the correct statement

11. Signal splitting in NMR arises from?

19. The base value for the following compound is

23. Mass spectrum is a plot of:

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