This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous

Chemicals - Code of Practice” (Feb 2016).

SAFETY DATA SHEET

1. Identification of the material and supplier
Names
Product name : Vanish Napisan Plus Powder
SDS no. : D8341587 v.2
Formulation # : 8308982 v1.0
Supplier : AUSTRALIA
Reckitt Benckiser (Australia) Pty Limited
ABN: 17 003 274 655
680 George Street, Sydney NSW 2000
Tel: +61 (0)2 9857 2000

NEW ZEALAND
Reckitt Benckiser (New Zealand) Limited
2 Fred Thomas Drive, Takapuna,
Auckland, New Zealand 0622
Tel: +64 9 484 1400

Poison Information contact: : Australia - 13 11 26

New Zealand - 0800 764 766 or 0800 POISON

Material uses : Fabric Treatment

Product use : Consumer

Section 2. Hazard(s) identification

Classification of the : SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A
substance or mixture
HSNO Classification : 6.4A

GHS label elements

Hazard pictograms :

Signal word : WARNING

Hazard statements : Causes serious eye irritation.
Precautionary statements
General : Keep out of reach of children. If medical advice is needed, have product container or
label at hand.
Prevention : Wash hands thoroughly after handling.
Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Wash hands thoroughly after handling.
IF SWALLOWED: Call a POISON CENTER/doctor/[***]/if you feel unwell.
Storage : Not applicable.

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Section 2. Hazard(s) identification

Disposal : Not applicable.
Supplemental label : Not applicable.
elements
Additional information : Keep container dry.

Other hazards which do not : None known.

result in classification

Section 3. Composition and ingredient information

Substance/mixture : Mixture

Ingredient name % (w/w) CAS number

disodium carbonate, compound with hydrogen peroxide (2:3) ≥10 - ≤30 15630-89-4
Reaction product of Benzenesulfonic acid, 4-C10-13-sec-alkyl derivs. and ≤5 -
Benzenesulfonic acid, 4-methyl- and sodium hydroxide
Other Non-hazardous ingredients to 100%
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if
adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Get medical attention if symptoms occur. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms

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Section 4. First aid measures

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Firefighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : No specific fire or explosion hazard.

from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
sulfur oxides
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Hazchem code

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

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Section 6. Accidental release measures

Methods and material for containment and cleaning up
Small spill : Move containers from spill area. Avoid dust generation. Using a vacuum with
HEPA filter will reduce dust dispersal. Place spilled material in a designated,
labeled waste container. Dispose of via a licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach the release from upwind. Prevent entry
into sewers, water courses, basements or confined areas. Avoid dust generation.
Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place
in a closed, labeled waste container. Dispose of via a licensed waste disposal
contractor. Note: see Section 1 for emergency contact information and Section 13
for waste disposal.

See Section 1 for emergency contact information.

See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not
in use. Empty containers retain product residue and can be hazardous. Do not
reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved
including any area. Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and
drink. Eliminate all ignition sources. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabelled containers. Use
appropriate containment to avoid environmental contamination. Storage
temperature: daily average 30°C.

Section 8. Exposure controls and personal protection

Control parameters
Australia
Occupational exposure limits
None.
New Zealand
Occupational exposure limits : No exposure standard allocated.

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

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Section 8. Exposure controls and personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Skin protection
Hand protection : Use chemical resistant gloves classified under Standard EN374 - Protective gloves
against chemicals and micro-organisms.

Examples of preferred glove barrier materials include: Nitrile/butadiene rubber

("nitrile" or "NBR"); Chlorinated polyethylene; Butyl rubber; Polyethylene.

Examples of acceptable glove barrier materials include: Natural rubber ("latex");

Neoprene; Viton; Ethyl vinyl alcohol laminate ("EVAL").

A glove with a protection class of 4 or higher (breakthrough time greater than 120
minutes according to EN 374) is recommended. When only brief contact is expected,
a glove with a protection class of 1 or higher (breakthrough time greater than 10
minutes according to EN 374) is recommended.

Gloves should be replaced regularly and if there is any sign of damage to the glove
material. Always ensure that gloves are free from defects and that they are stored
and used correctly. The performance or effectiveness of the glove may be reduced
by physical/ chemical damage and poor maintenance.

NOTICE: The selection of a specific glove for a particular application and duration of
use in a workplace should also take into account all relevant workplace factors such
as, but not limited to: Other chemicals which may be handled, physical requirements
(cut/puncture protection, dexterity, thermal protection), potential body reactions to
glove materials, as well as the instructions/specifications provided by the glove
supplier. Considering the parameters specified by the glove manufacturer, checks
during use should be carried out to ensure the gloves are still retaining their
protective properties.

Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties

Appearance
Physical state : Solid.
Colour : White.
Odour : Chemical.
Odour threshold : Not available.
pH : 10.3 to 11.3
Melting point : Not available.
Boiling point : Not available.

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Section 9. Physical and chemical properties

Flash point : Not available.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not applicable, considering single substances properties.
(flammable) limits
Vapour pressure : Not available.
Vapour density : Not available.
Relative density : Not available.
Solubility : Easily soluble in the following materials: cold water and hot water.
Solubility in water : Easily soluble in the following materials: Cold water and hot water.
Partition coefficient: n- : Not applicable, complex mixture including surfactants.
octanol/water See section 12.3 for single substances values.
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not applicable
Flow time (ISO 2431) : Not available.

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid the creation of dust when handling and avoid all possible sources of ignition
(spark or flame). Take precautionary measures against electrostatic discharges.
To avoid fire or explosion, dissipate static electricity during transfer by earthing and
bonding containers and equipment before transferring material. Prevent dust
accumulation.
Do not mix with acids reducing agents chlorine-based bleaching agents
Keep away from direct sunlight or strong incandescent light. Protect from moisture.

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Note: Above reported LD50 values have been used to derive the classification for
acute toxicity.
Irritation/Corrosion
Not available.

Conclusion/Summary
Skin : Expert judgment. Causes skin irritation.
Eyes : Based on Calculation method: Causes serious eye damage.
Respiratory : Based on available data, the classification criteria are not met.

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Section 11. Toxicological information

Sensitisation
Not available.
Conclusion/Summary
Skin : Based on available data, the classification criteria are not met.
Respiratory : Based on available data, the classification criteria are not met.
Mutagenicity
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Carcinogenicity
Not available.

Conclusion/Summary : Based on available data, the classification criteria are not met.
Reproductive toxicity
Not available.

Conclusion/Summary : Based on available data, the classification criteria are not met.
Teratogenicity
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Information on likely routes : Not available.

of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure

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Section 11. Toxicological information

Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Not available.
Conclusion/Summary : Based on available data, the classification criteria are not met.

Persistence and degradability

Conclusion/Summary : The surfactants contained in this mixture comply with the biodegradability criteria as
laid down in Regulation (EC) No. 648/2004 on detergents.Data to support this
assertion are held at the disposal of the competent authorities of the Member States
and will be made available to them, at their direct request or at the request of a
detergent manufacturer.

Bioaccumulative potential
Not available.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty

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Section 13. Disposal considerations

containers or liners may retain some product residues. Avoid dispersal of spilt
material and runoff and contact with soil, waterways, drains and sewers.

14. Transport information

Regulation UN number Proper shipping name Classes PG* Label Additional information
ADG Not Not applicable. Not - -
Regulated applicable.
IMDG Not Not applicable. Not - -
Regulated applicable.

IATA Not Not applicable. Not - -

Regulated applicable.

PG* : Packing group

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Section 15. Regulatory information

Standard Uniform Schedule of Medicine and Poisons
SChedule: S5 CAUTION
Model Work Health and Safety Regulations - Scheduled Substances
Sodium Percarbonate
Australia inventory (AICS) : All components are listed or exempted.
New Zealand Inventory of : All components are listed or exempted.
Chemicals (NZIoC)
HSNO Group Standard : Cleaning products (Subsidiary hazard).
HASNO Approval Number : HSR002530.

Approved handler requirement : No omponents are listed or exempted

Tracking requirement : No mponents are listed or exempted.

Section 16. Any other relevant information

Key to abbreviations : ADG = Australian Dangerous Goods
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
NOHSC = National Occupational Health and Safety Commission
SUSMP = Standard Uniform Schedule of Medicine and Poisons
UN = United Nations
Date of issue / Date of : 2/15/2019
revision
Version : 2

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Section 16. Any other relevant information

Procedure used to derive the classification
Classification Justification
SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A Calculation method
References : Not available.
Indicates information that has changed from previously issued version.

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.

Please read all labels carefully before using product.

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