SAFETY DATA SHEET

Date of issue/Date of revision 15 June 2022

Version 7

Section 1. Identification
Product code : 40048-C1199/20L
Product identifier : SIGMARINE 48 BLUE 1199

Recommended use and restrictions

Use of the substance/ : Coating.
mixture
Uses advised against : Not applicable.

Supplier's details : PPG Industries Australia Pty Limited

(ABN 82 055 500 939)
14-20 McNaughton Rd
CLAYTON Victoria 3168
Tel: (03) 9263 6000 Fax: (03) 9263 6970

Emergency telephone : Australia 1800 883 254 / New Zealand 0800 000 096
number For international shipping emergencies: 1-412-391-1618

Section 2. Hazard(s) identification

Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture SKIN SENSITISATION - Category 1
CARCINOGENICITY - Category 1

GHS label elements

Hazard pictograms :

Signal word : DANGER

Hazard statements : Flammable liquid and vapour.
May cause an allergic skin reaction.
May cause cancer.
Precautionary statements
Prevention : Do not handle until all safety precautions have been read and understood. Wear
protective gloves, protective clothing and eye or face protection. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking
tools. Take action to prevent static discharges. Avoid breathing vapour.
Response : IF exposed or concerned: Get medical advice or attention. Take off contaminated
clothing and wash it before reuse. IF ON SKIN: Wash with plenty of water. If skin
irritation or rash occurs: Get medical advice or attention.
Storage : Not applicable.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Supplemental label : Not applicable.
elements

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Section 2. Hazard(s) identification

Other hazards which do not : Prolonged or repeated contact may dry skin and cause irritation.
result in classification

Section 3. Composition and ingredient information

Substance/mixture : Mixture

CAS number/other identifiers

CAS number : Not applicable.
EC number : Mixture.
Ingredient name CAS number % (w/w)
cobalt bis(2-ethylhexanoate) 136-52-7 <1

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment or have an OEL and hence
require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
SUB codes represent substances without registered CAS Numbers.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the
eyelids apart for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do NOT induce vomiting.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.

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Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
See toxicological information (Section 11)

Section 5. Firefighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media
Specific hazards arising : Flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon oxides
metal oxide/oxides
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Hazchem code : •3Y

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.

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Section 6. Accidental release measures

Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Avoid exposure - obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Do not
get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapour or mist.
Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Materials such as cleaning rags, paper wipes and protective clothing, which are
contaminated with the product may spontaneously self-ignite some hours later. To
avoid the risks of fires, all contaminated materials should be stored in purpose-built
containers or in metal containers with tight-fitting, self-closing lids. Contaminated
materials should be removed from the workplace at the end of each working day
and be stored outside.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

Conditions for safe storage, : Store between the following temperatures: 0 to 35°C (32 to 95°F). Store in
including any accordance with local regulations. Store in a segregated and approved area. Store
incompatibilities in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not
store in unlabelled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

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Section 8. Exposure controls and personal protection

Control parameters
Occupational exposure limits
None.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapour or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
For products that are sprayed, where practicable use a spray booth designed and maintained in accordance with AS/
NZS 4114.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety glasses with side shields.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Gloves : butyl rubber
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If
workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed
respirator complying with an approved standard if a risk assessment indicates this is
necessary.
Restrictions on use : Not applicable.
References: Eye protectors should conform to AS/NZS 1336 and AS/NZS 1337. Chemical-resistant gloves should
conform to AS/NZS 2161.1. Respiratory protection should conform to AS/NZS 1715 and AS/NZS 1716. Occupational
footwear should conform to AS/NZS 2210.

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Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Colour : Blue.
Odour : Aromatic.
Odour threshold : Not available.
pH : Not applicable.
Melting point : Not available.
Boiling point : >37.78°C (>100°F)
Flash point : Closed cup: 38.5°C (101.3°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapour pressure : Not available.
Vapour density : Not available.
Relative density : 0.98
Bulk Density (g/cm³) : 1.086
Solubility : Insoluble in the following materials: cold water.
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not Applicable

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Stable under recommended storage and handling conditions (see Section 7). When
exposed to high temperatures may produce hazardous decomposition products.

Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.

Hazardous decomposition : Depending on conditions, decomposition products may include the following
products materials: carbon oxides metal oxide/oxides

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Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
cobalt bis(2-ethylhexanoate) LD50 Dermal Rabbit >5 g/kg -
LD50 Oral Rat 3129 mg/kg -
Conclusion/Summary : There are no data available on the mixture itself.
Irritation/Corrosion
Not available.

Conclusion/Summary
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Sensitisation
Not available.
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Not available.

Conclusion/Summary : There are no data available on the mixture itself.

Carcinogenicity
Not available.
Conclusion/Summary : There are no data available on the mixture itself.
Reproductive toxicity
Not available.

Conclusion/Summary : There are no data available on the mixture itself.

Teratogenicity
Not available.
Conclusion/Summary : There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Not available.

Specific target organ toxicity (repeated exposure)

Name Category Route of Target organs
exposure
cobalt bis(2-ethylhexanoate) Category 2 inhalation -

Aspiration hazard
Not available.

Information on likely routes : Not available.

of exposure
Potential acute health effects

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Section 11. Toxicological information

Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Conclusion/Summary : There are no data available on the mixture itself. This product contains TiO2 which
has been classified as a GHS Carcinogen Category 2 based on its IARC 2B
classification. For many PPG products, TiO2 is utilized as a raw material in a liquid
coating formulation. In this case, the TiO2 particles are bound in a matrix with no
meaningful potential for human exposure to unbound particles of TiO2 when the
product is applied with a brush or roller. Sanding the coating surface or mist from
spray applications may be harmful depending on the duration and level of exposure
and require the use of appropriate personal protective equipment and/or
engineering controls (see Section 8). Exposure to component solvent vapour
concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation
and adverse effects on the kidneys, liver and central nervous system. Symptoms
and signs include headache, dizziness, fatigue, muscular weakness, drowsiness
and, in extreme cases, loss of consciousness. Solvents may cause some of the
above effects by absorption through the skin. There is some evidence that repeated
exposure to organic solvent vapors in combination with constant loud noise can
cause greater hearing loss than expected from exposure to noise alone. If splashed
in the eyes, the liquid may cause irritation and reversible damage. Ingestion may
cause nausea, diarrhea and vomiting. This takes into account, where known,
delayed and immediate effects and also chronic effects of components from short-
term and long-term exposure by oral, inhalation and dermal routes of exposure and
eye contact.
Short term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Long term exposure
Potential immediate : There are no data available on the mixture itself.
effects
Potential delayed effects : There are no data available on the mixture itself.
Potential chronic health effects
Not available.
General : Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : No known significant effects or critical hazards.

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Section 11. Toxicological information

Reproductive toxicity : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapours) (dusts
(ppm) (mg/l) and mists)
(mg/l)
cobalt bis(2-ethylhexanoate) 3129 N/A N/A N/A N/A

Section 12. Ecological information

Toxicity
Not available.

Persistence and degradability

Not available.

Bioaccumulative potential
Not available.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Care should be taken when handling
emptied containers that have not been cleaned or rinsed out. Empty containers or
liners may retain some product residues. Vapour from product residues may create
a highly flammable or explosive atmosphere inside the container. Do not cut, weld
or grind used containers unless they have been cleaned thoroughly internally. Avoid
dispersal of spilt material and runoff and contact with soil, waterways, drains and
sewers.

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Section 14. Transport information

ADG IMDG IATA
UN number UN1263 UN1263 UN1263

UN proper shipping name PAINT PAINT PAINT

Transport hazard class 3 3 3

(es)

Packing group III III III

Environmental hazards Yes. The environmentally Yes. Yes. The environmentally
hazardous substance mark hazardous substance mark
is not required. is not required.
Marine pollutant Not applicable. (Naphtha (petroleum), Not applicable.
substances hydrodesulfurized heavy)

Additional information
ADG : None identified.
Hazchem code : •3Y
IMDG : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
IATA : The environmentally hazardous substance mark may appear if required by other transportation
regulations.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

Transport in bulk according : Not applicable.

to IMO instruments

Section 15. Regulatory information

Standard for the Uniform Scheduling of Medicines and Poisons
SUSMP : Not scheduled
Model Work Health and Safety Regulations - Scheduled Substances
Ingredient name Schedule
cobalt bis(2-ethylhexanoate) Restricted hazardous chemical [For
abrasive blasting at a concentration of
greater than 0.1% as cobalt]
Australia inventory (AIIC) : All components are listed or exempted.
New Zealand (NZIoC) : All components are listed or exempted.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

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Section 15. Regulatory information

Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals

Not listed.

Section 16. Any other relevant information

History
Date of issue/Date of : 15 June 2022
revision
Date of previous issue : 10/8/2021
Prepared by : EHS
Key to abbreviations : ADG = Australian Dangerous Goods
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
NOHSC = National Occupational Health and Safety Commission
SUSMP = Standard Uniform Schedule of Medicine and Poisons
UN = United Nations
References : Not available.
Indicates information that has changed from previously issued version.
Notice to reader
The information contained in this data sheet is based on present scientific and technical knowledge. The
purpose of this information is to draw attention to the health and safety aspects concerning the products
supplied by PPG, and to recommend precautionary measures for the storage and handling of the products.
No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted
for any failure to observe the precautionary measures described in this data sheet or for any misuse of the
products.

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