2.3. Waves and Particle Nature of Life
2.3. Waves and Particle Nature of Life
2.3. Waves and Particle Nature of Life
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2.3 - Waves and Particle Nature of Light
2.3.33 - Definitions
Frequency (f) The number of complete oscillations passing through a point per second.
Speed (v) The distance travelled by the wave per unit time.
Wavelength (λ) The length of one whole oscillation (e.g. the distance between successive
peaks/troughs).
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2.3.36 - Transverse waves
In transverse waves, the oscillations of particles (or fields) is at right angles to the direction of
energy transfer
-1
● All electromagnetic (EM) waves are transverse and travel at 3 x 108 ms in a vacuum.
● Transverse waves can be demonstrated by shaking a slinky vertically or through the
waves seen on a string, when it's attached to a signal generator.
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➔ Displacement-time graphs - these show how the displacement of a particle varies with
time and can be used to measure the period of a wave.
Phase How much a particle/wave lags behind another particle/wave. This can be
difference measured in radians, degrees or fractions of a cycle.
Superposition Where the displacements of two waves are combined as they pass each
other, the resultant displacement is the vector sum of each wave’s
displacement.
Coherence A coherent light source has the same frequency and wavelength and a
fixed phase difference.
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Wavefront A wavefront is a surface which is used to represent the points of a wave
which have the same phase.
As an example of a wavefront, consider a rock being dropped into a pond, the peak of each
ripple formed can be considered as a wavefront. This is shown in the diagram below:
There are two types of interference that can occur during superposition and they are:
● Constructive interference - this occurs when two waves are in phase (explained
below) and so their displacements are added
● Destructive interference - this occurs when the waves are completely out of phase
(explained below) and so their displacements are subtracted
The image below shows the interference of two waves (which are pictured below the resultant
wave). On the left is constructive interference and on the right is destructive interference.
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Two waves are completely out of phase when they have the same frequency and
wavelength (are coherent) and their phase difference is an odd integer multiple of 180° (π
radians).
The phase difference (in radians) of two waves with the same frequency and their path
differences are related as shown below:
λ
Δx = 2π Δϕ
Where Δx is the path difference, λ is the wavelength of the waves and ΔΦ is their phase difference.
Below is an example question where you have to use the above relation.
Two waves have a path difference of 6m and both have a wavelength of 2m, what is the phase
difference of these two waves?
Firstly, rearrange the above relation so that the phase difference is the subject.
Δx
Δϕ = 2π × λ
And so, their phase difference is 6π. As 6π is a multiple of 2π, the waves must be in phase.
2.3.41 - Stationary waves
A stationary wave (also known as a standing wave) is formed from the superposition of 2
progressive waves, travelling in opposite directions in the same plane, with the same
frequency, wavelength and amplitude.
A string fixed at one end, and fixed to a driving oscillator at the other gives a good example of
the formation of a stationary wave:
● A wave travelling down the string from the oscillator will be reflected at the fixed end of
the string, and travel back along the string causing superposition of the two waves.
Because the waves have the same wavelength, frequency and amplitude, a stationary
wave is formed. (Labelled combined wave on the diagram below).
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The diagram below shows multiple possible standing waves on a displacement-distance graph.
The blue points indicate antinodes, while the red points indicate nodes.
Where v is the speed, T is the tension in the string, and μ is the mass per unit length of the string (which
is constant).
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2.3.45 - Refractive index and Snell’s law
A refractive index (n) is a property of a material which measures how much it slows down light
passing through it. It is calculated by dividing the speed of light in a vacuum (c) by the speed of
light in that substance (v).
c
n= v
A material with a higher refractive index can also be known as being more optically dense.
Refraction occurs when a wave enters a different medium, causing it to change direction, either
towards or away from the normal depending on the material’s refractive index.
Snell’s law is used for calculations involving the refraction of light:
n1 sinθ1 = n2 sinθ2
➔ n1 is the refractive index of material 1,
➔ n2 is the refractive index of material 2,
➔ θ1 is the angle of incidence of the ray in material 1
➔ θ2 is the angle of refraction of the ray in material 2
In the example above, n2 is more optically dense than n1, therefore the ray of light slows down
and bends towards the normal. However, in the case where n2 is less optically dense than
n1 the ray of light will bend away from the normal.
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Image source: Rice university,CC BY 4.0
In the case that one of the materials (n2) is air (which has a refractive index of approximately 1),
you can use the following formula to find the critical angle (C):
sin C = n1 w
here n > 1
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3. Using a protractor, draw lines leaving the point you have marked at 10° intervals from
10° - 70°, where the angle is measured from the normal line to the line you are drawing.
These will be the incident rays.
4. Put the material block back, making sure that it fits the outline as well as possible.
5. Using a ray box, shine a ray of line along the 10° line and mark the point at which the
light ray leaves the material block.
6. Join the point you have just marked down to the point on the normal line, at which the
light ray enters the block. Using a protractor, measure the angle between this line and
the normal. This is the angle of refraction.
7. Repeat the above two steps for all of the incident angles.
8. Repeat the above method two more times and find the average value of the angle of
refraction for each incident angle.
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9. Plot a graph of sine of the incident angles (sin i) against sine of the refracted angles (sin
r). Plot a line of best fit and find the gradient - this is the refractive index of the material
used.
Our initial material is air, which has a refractive index of 1, so the snell’s law equation above can
be simplified to:
sinθ1 = n2 sinθ2
If you replace θ1 (the angle of incidence) with i, θ2 (the angle of refraction) with r, and n2 with n to
represent the refractive index of our material, you get:
sin i = n sin r
Y = mx
This is simply the equation of the straight line in a graph of sin i against sin r, meaning that its
gradient must be n.
Below is a diagram which shows the effect of vertically polarised and horizontally polarised
waves passing through a block with vertical slits, which acts as a vertically polarising filter.
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Image source: Rice University,CC BY 4.0
(a) The vertically polarised wave passes through the filter without a problem.
(b) The horizontally polarised wave cannot pass through the filter as it blocks waves which
are not in the vertical plane.
Polarised sunglasses are an application of polarisation. They reduce glare by blocking
partially polarised light reflected from water and tarmac, as they only allow oscillations in the
plane of the filter to pass through, making it easier to see.
Huygens’ construction states that every point on a wavefront is a point source to secondary
wavelets, which spread out to form the next wavefront, as shown in the diagram below:
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Huygens’ construction can be used to explain the diffraction of light when it meets an obstacle
or passes through a gap.
For example, consider a sound wave travelling through a doorway. From experience, you know
that the sound will (probably) be heard throughout the entire room, this is because, as the sound
wave travels through the doorway, it diffracts, spreading through the entire room. Diffraction
occurs here because each point on the wavefront passing through the doorway (labelled 1 - 5),
is a source of wavelets, which spread out from the gap of the doorway forming further circular
wavefronts.
In contrast to this, consider light travelling through a doorway. The light passes through the
doorway without diffracting much at all, which is why you get straight-edged shadows (as
shown in the diagram below).
The reason the light waves barely diffract, while the sound waves diffract a lot, is because their
wavelength is much smaller in comparison to the size of the doorway. Whereas, the wavelength
of the sound wave is much closer to that of the doorway, and the greatest amount of diffraction
occurs when the gap is the same size as the wavelength.
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Image source: Rice University,CC BY 4.0
The interference pattern created by the type of experiment described above, looks like a set of
concentric rings as shown below:
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If electrons only had a particle nature, you would expect the pattern to look like a single point,
where the electron beam has passed through the lattice. However, this is not the case as the
electrons undergo diffraction, which is something only waves can experience. This is why
electron diffraction provides evidence for the wave nature of electrons.
Image source: Rice University,CC BY 4.0 Image source: Rice University,CC BY 4.0
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difference in densities of the materials; the greater this difference, the greater the
reflection.
3. The reflected waves are detected as they leave the target.
4. The intensities of the reflected waves are used to determine the structure of the target
and the time taken for these reflected waves to return is used to determine the position
of objects in the target (using s = vt).
Also, as the wavelength of the waves used increases, the less fine details can be resolved,
meaning that amount of information you obtain will decrease.
On the other hand, in terms of the wave model, EM radiation can be described as a transverse
wave.
Initially, light (which is a type of EM wave) was believed to be composed of tiny particles as this
could explain the reflection and refraction of light. However, light was later proved to act as a
wave through diffraction experiments, so people believed it was instead formed of waves.
Before long, due to the discovery of photoelectricity (explained in 2.392) , the attitude towards
the composition of light (and EM waves) changed once again. Light had now been proven to act
as both a particle and a wave, which led to development of the photon model of light and
wave-particle duality.
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2.3.59 - Photoelectricity
The photoelectric effect is where photoelectrons are emitted from the surface of a metal after
light above a certain frequency is shone on it. This certain frequency is different for different
types of metals and is called the threshold frequency.
Photoelectrons are emitted because electrons near the surface of the metal absorb a photon
and gain enough energy to leave the surface.
The photoelectric equation shows the relationship between the work function, the frequency of
light (shone onto the metal) and the maximum kinetic energy of the emitted photoelectrons.
E = hf = Φ + E k (max)
Where E is the photon energy, Φ is the work function and Ek(max) is the maximum kinetic energy.
2.3.61 - Electronvolt
The electronvolt (eV) is a unit of energy, usually used to express small energies. 1 eV is equal
to the kinetic energy of an electron accelerated across a potential difference of 1 V or 1.6 x 10-19
J.
You can convert between joules and electron volts quite easily:
● Joules to electron volts - divide by 1.6 x 10-19
● Electron volts to joules - multiply by 1.6 x 10-19
2.3.62 - The photoelectric effect as evidence for the particle nature of EM radiation
The photoelectric effect also couldn’t be explained by wave theory as:
1. Wave theory suggests that any frequency of light should be able to cause
photoelectric emission as the energy absorbed by each electron will gradually
increase with each incoming wave, and so can’t explain the existence of a threshold
frequency.
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2. The photoelectric effect is immediate, which contradicts wave theory which suggests
time is needed for the energy supplied to the electrons to reach the work function
(minimum energy required for electrons to be emitted from the surface of a metal).
3. Increasing the intensity of the light does not increase the speed of photoelectric
emission as would be suggested by wave theory, but instead it increases the number
of photoelectrons released per second.
4. Photoelectrons are released with a range of kinetic energies.
The photon model of EM radiation, which suggests that EM waves are released in discrete
packets called photons, which have particle-like interactions, could be used to explain all the
points above which wave theory couldn’t:
1. When a photon interacts with an electron, all of its energy is transferred to it, and an
electron can only interact with a single photon. If this energy is above the work
function, a photoelectron is emitted, if this energy is below the work function, the electron
remains in place. As the energy of a photon is directly proportional to frequency ( E = hf ),
the threshold frequency is the frequency at which the photon energy is equal to
the work function of the metal.
2. The photon energy is transferred to the electron immediately when they interact, leading
to photoelectrons being emitted immediately.
3. Intensity is equal to the number of photons released per second, if this is increased
the number of photoelectrons emitted is increased because more photons interact
with electrons per second.
4. All electrons will receive the same amount of energy from a photon of light, however
electrons which are deeper in the metal will lose energy through collisions when
leaving the metal, and will therefore have a lower kinetic energy.
Inside a fluorescent tube, electrons are accelerated, causing gas atoms to become excited and
then de-excite, releasing photons. By passing the light from a fluorescent tube through a
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diffraction grating or prism, you get a line spectrum. Each line in the spectrum represents a
different wavelength of light emitted by the tube. As this spectrum is not continuous but rather
contains only discrete values of wavelength, the photon energies emitted will correspond to
these wavelengths. This is evidence to show that the electrons in atoms can only transition
between discrete energy levels.
The difference between two energy levels is equal to a specific photon energy emitted by a
fluorescent tube, or absorbed in a line absorption spectrum.
Therefore, you can calculate the energy of an emitted photon by using the following formula:
ΔE = E 1 − E 2
Where ΔE is the photon energy and E1/E2, represent energy levels.
Using the photon energy equation ( E = hf ), you can see that you can find the photon
frequency by using the following equation:
ΔE = hf = E 1 − E 2
E 1 −E 2
f= h
Where f is the photon frequency and h is the Planck constant.
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