Liquid Solution Board Booster Worksheet-2

Liquid Solution Mittal Sir
90. Calculate the amount of CaCl2 (molar mass = 111 g mol-1) which must be added to 500 g of
water to lower its freezing point by 2 K assuming CaCl2 to be completely dissociated (K for
water =1.86 K kg mol-1)
[Ans: 19.89 g]
91. Solution A contains 6 g of urea in 100 mL of it at 27C while solution B has 6 g of acetic acid
in 100 mL of the solution at the same temperature. Are the two solutions equimolar as well as
isotonic?
[Ans: not isotonic]
92. The freezing point of a solution containing 0.3 g of acetic acid in 30 g of benzene is lowered by
0.45. Calculate Van’t Hoff factor. (K for benzene = 5.12 K kg mol-1)
[Ans: 0.53]
93. A solution contains 0.8960 g of K2SO4 in 500 mL. Its osmotic pressure is found to be 0.69 atm
at 27C. Calculate the value of Van’t Hoff factor. [Ans: 2.72]
94. 0.6 mL acetic acid (CH3COOH), having density 1.06 g mL-1 , was dissolved in 1 litre of water.
The depression in freezing point observed for this strength of acid was 0.0205C. Calculate the
van’t Hoff factor and the dissociation constant of acid. (K for water = 1.86 K kg mol-1)
[Ans: 1.78  10-5]
95. An aqueous solution containing 1.248 g of barium chloride (molar mass = 208.34 g mol-1) in
100 g of water boils at 100.0832C. Calculate degree of dissociation of barium chloride (Kb of
water = 0.52 K kg mol-1).
[Ans: 83.5%]
96. Calculate the boiling point of one molar aqueous solution (density = 1.04 g mL-1) of potassium
chloride (Kb = 0.52 K kg mol-1).
[Ans: 374.078 K]
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97. 75.2 g of phenol (C6H5OH) is dissolved in solvent of K = 14 K kg mol-1. If depression in

freezing point is 7 K, find the percentage of phenol that dimerises.
[Ans : 75%]
98. 17.4% K2SO4 solution at 27C is isotonic with 4% NaOH solution at the same temperature. If
NaOH is 100% ionised, what is the degree of ionization of K2SO4 in aqueous solution?
[Ans: 50%]
99. 2.0 g of benzoic acid dissolved in 25.0 g of benzene shows a depression in freezing point equal
to 1.62 K. Molal depression constant (K) for benzene is 4.9 K kg mol-1 . What is the percentage
association of the acid?
[Ans: 99.2%]
100. Three particle of a solute ‘A’ associate in benzene to form species (A)3 .Calculate the freezing
point of 0.25 molal solution. The degree of association of solute ‘A’ is found to be 0.80. The
freezing point of benzene is 5.5C and its cryoscopic constant is 5.12 K m-1.
[Ans: 4.9C]
101. 0.5 g KCl was dissolved in 100 g of water and the solution originally at 0C froze at – 0.24C.
Calculate percentage ionization of the salt (K per 1000 g of water = 1.86 K kg mol-1).
[Ans: 92.3 %]
102. Benzoic acid completely dimerises in benzene. What will be the vapour pressure of a solution
containing 61 g of benzoic acid per 500 g benzene when the vapour pressure of pure benzene at
this temperature of experiment is 66.6 torr ? What would be vapour pressure in the absence of
dimerisation ? [Ans: 61.78 torr]

103. Calculate freezing point depression expected for 0.0711 m aqueous solution of Na2SO4. If this
solution actually freezes at-0.320C, what will be the value of Van’t Hoff factor? (K for water
= 1.86C mol-1) [Ans : 242]
104. What mass of sodium chloride (molar mass = 58.5 g mol-1) must be dissolved in 65 g of water
to lower the freezing point by 7.5C ? The freezing point depression constant K for water is
1.86 K kg mol-1 .Assume Van’t Hoff factor for NaCl is 1.87.
[Ans:8.2 g]
105. Calculate the freezing point of an aqueous solution containing 10.50 g of MgBr2 in 200 g of
water (molar mass of MgBr2 = 184 g mol-1; K for water = 1.86 K kg mol-1).
[Ans: 271.41 K]
106. What is the freezing point of 0.4 molal solution of acetic acid in benzene in which it dimerises
to the extent of 85%. Freezing point of benzene is 278.4 K and its molar heat of fusion is 10.042
kJ mol-1.
[Ans: 277.25 K]
107. Calculate the boiling point of a solution containing 0.61 g of benzoic acid in 5 g of CS2
assuming 84% dimerisation of acid. The boiling point and Kb of CS2 are 46.2C and 2.3 K kg
mol-1 respectively.
[Ans: 46.3334C]


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Liquid Solution Mittal Sir

BMC CLASSES PVT. LTD. Page No -64

97. 75.2 g of phenol (C6H5OH) is dissolved in solvent of K = 14 K kg mol-1. If depression in

BMC CLASSES PVT. LTD. Page No -65

BMC CLASSES PVT. LTD. Page No -66

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