An Investigation of Heat Transfer in A Mechanically Agitated Vessel
An Investigation of Heat Transfer in A Mechanically Agitated Vessel
An Investigation of Heat Transfer in A Mechanically Agitated Vessel
Agitated Vessel
A. Debab 1, N. Chergui 1and J. Bertrand2
1
Université des Sciences et de la Technologie d’Oran, Département de Chimie Industrielle,
BP1505 Oran El-Mnouar (Algérie)
2
Laboratoire de Génie Chimique, INP-ENSIACET
5, Rue Paulin Talabot, B.P1301-31106 Toulouse cedex 1(France)
Email: [email protected]
ABSTRACT
The objective of this study is to optimize experimental conditions of agitating a non-Newtonian liquid using
experimental design methodology. The measurements of the temperatures have been carried out in a jacketed
vessel equipped with Turbine impellers. The rheological properties of aqueous solutions of carboxymethyl
cellulose sodium salt had been studied using shear stress/shear rate data. The results of the experimental studies,
concerning the effect of the diameter of the impeller, the impeller speed and baffled or unbaffled vessel on the
overall heat transfer coefficient have been approximated in the form of equations. Based on the optimization
criterion, an agitated vessel equipped with Flat Blade Disc Turbine (FBDT) of diameter ratio d/D = 0.6 and
baffles is proposed as the most advantageous for heat transfer processes.
KEYWORDS: Stirred vessel, non-Newtonian liquid, experimental design, heat transfer coefficient, Wilson plot.
NOMENCLATURE
2
A Heat transfer surface area (m )
Cp Specific heat (J kg-1K-1) μ Dynamic viscosity (kg m-1 s-1)
d Diameter of the agitator (m) ηa Apparent viscosity (kg m-1 s-1)
D Inner diameter of the agitated vessel (m) ρ Fluid density (kg m-3)
dt Time step (s) τ Shear stress (Pa)
h Film heat transfer coefficient (Wm-2K-1) γ& Shear rate (s-1)
k Fluid consistency (Pa s-n)
n Fluid index (-)
Dimensionless numbers
N Speed of agitation (rpm)
Np Power number (Np=P. ρ-1.N-3.d-5)
P Power consumption (W)
q Volumetric flow rate (m3s-1) Nu Nusselt number (Nu =h0.D.λ-1)
T Temperature (°C) Pr Prandtl number (Pr =μ.Cp. λ-1)
t Time (s) Re Reynolds number (Re =ρN.d2.μ-1)
U overall heat transfer coefficient (Wm-2K-1) Vi Viscosity ratio (Vi=μbulk/μwall )
V Volume of fluid (m3)
Subscripts
Greek symbols 0 at the surface internal side
λ Thermal conductivity of agitated liquid i inlet
(W m-1 K-1) j jacket
r vessel
Table 1 Exponent for different impellers and Re
1. INTRODUCTION regimes
Mixing has found wide application in chemical and Type of agitator Re range θ10
biochemical processing. Many stirred tank
bioreactors and chemical reactors require precise Flat blade disc turbine
control of both mixing and heat transfer to achieve
optimum productivity (J.Y.Oldshue 1983; N. Harnby 9 Unbaffled vessel Re<400 0.54
et al. 1983; S. Nagata 1975). Heat transfer in agitated 9 Baffled vessel Re>400 0.74
vessels is one of the most significant factors for
controlling the outcome of biochemical processes. Propeller with three 5500 to 0.64
The temperature of fermentation generally must be blades and baffled vessel 37000
maintained within very narrow limits (T.J.S. Brian et
al. 1989; S.Yüce et al. 1999). Usually, agitated The typical values for θ20, θ30 and θ40 are respectively
vessels have a heat transfer surface, in the form of a 2/3, 1/3 and 0.14 (Chapman et al. 1965; Strek et al.
jacket or internal coils, for addition or removal of the 1967; Fletcher P. 1987). The constant θ10 which is
heat. used to multiply the whole equation have been
The intensity of heat transfer during mixing of fluids reported to range from 0.33 to 1.0, mainly varying
depends on the type of the agitator, the design of the due to system geometry and type of impeller.
vessel and conditions of the process. When designing Attempts were made to study batch heat transfer in an
an agitated vessel, the impeller, vessel geometry and agitated jacketed vessel, with a view to developing a
baffles should give the degree of mixing the process design equation to determine film heat transfer
demands, but it is impractical to specify the agitator coefficient, h0, in such vessels. But as the variables
to give a specific heat transfer coefficient. The main influencing the heat transfer coefficient are quite
factor when selecting an agitator is the nature of the large in number, complete study covering all the
fluid. Large diameter agitators operating at low variables could not be made. It is essential to have
speeds normally give excellent blending and heat complete information on the effects of possible
transfer characteristics with high viscosity fluids. variables on the rate of heat transfer and also a
Small impellers operating at high speed are more general correlation valid over wide ranges of
suited for low viscosity fluids. Turbine impellers are operating conditions for heat transfer coefficients for
normally used for high speed, low viscosity design and efficient working of the process. The aim
applications. of the present work was to study the effect of the
The normal design of turbine impeller has either four impeller speed N, impeller diameter d and vessel with
or six flat blades on a central disc. The ratio of or without baffles on heat transfer coefficient using
turbine diameter to vessel diameter d/D is usually in an experimental method in which the measurements
the range from 1/3 to 2/3. Baffles are essential in are mathematically planned.
stirred batch vessels to provide good mixing patterns
throughout the vessel. They act to reduce tangential
flow and promote axial motion. As baffling increases 1.1 Vessel modeling
turbulence, it affects the heat transfer rates.
Because heat transfer in agitated vessels is complex, Figure 1 shows the configuration for the agitated
an empirical approach based on dimensionless vessel used in the experiments.
analysis has been used to predict the average heat M
transfer coefficients at the jacketed wall. Hence, the
results of many heat transfer studies are frequently
correlated using a dimensionless equation. Tjo, ρj, Vj,
C
(1) Tj
Where θ10, θ20, θ30 and θ40 are found by fitting Eq. (1) Tr
to experimental data. A review of many such Tji
correlations has been presented by Pankaj Mohan et
al. (1992). Fig. 1: A typical arrangement of a jacketed vessel
Extensive characterization work has been carried out with labels.
by authors for different agitator types. The values of
the constant θ10 reported are given in Table 1.
An energy balance in the vessel, considering the UiAi
vessel volume and the heat capacity of the vessel
βj =
(ρ jCp jVj ) and ⁄
contents to be constant, reads: φ j = q j Vj
(2)
Where and are the power terms associated with 1.2 The determination of the overall heat
the energy transfer from the stirrer and the heat of transfer coefficient
reaction, respectively.
On the other hand the energy balance in the jacket Overall inside heat transfer coefficient Ui is obtained
can be expressed as: from Eq. (2), it can therefore be rewritten to give:
· 5
(3)
A plot of time versus temperature such as shown in
It is assumed that the heat loss of the usually Fig.2 can be used to evaluate Ui with sufficient
insulated jacket is negligible. accuracy for design purposes.
When the test begins, the temperatures in the vessel
and in the jacket are respectively Tr(0) and Tj(0).
Then, the vessel temperature is forced to go up or
down when the jacket temperature is changed, Trf
suddenly or slowly, to a new set point. The jacket
inlet temperature Tji(t) is recorded, and so is the time
to go from Tr(0) to Tr(t). Tr
With known jacketed surfaces area, flow rates, heat
capacities and densities, the time-temperature
response is applied to the pertinent mathematical Tri
model. ti tf
The initial conditions are Tj(t) = Tj(0) and Tr(t) =
Tr(0). In Eq. (2), since there is no reaction the heat of Fig. 2: Temperature plot for unsteady-state heat
reaction and kinetic energy transferred from the transfer.
impeller to the vessel fluid are neglected. Equations
(2) and (3) can be rewritten in terms of dimensional If the time increment dt is evaluated as a specific
groups, as described below. Tr(t) is isolated in Eq. (3) constant time interval ∆t, and Trf and Tri are the final
as a function of dTj/dt, Tj0(t) and Tji(t). The outcome and initial temperatures respectively of the liquid
is introduced into Eq. (2) to obtain dTr/dt as a being heated, then we can write Eq. (5) as:
function of the same variables. Then, the obtained
equations are differentiated with respect to time and · 6
∆
solved by Laplace transform to yield the expression
for Tr(t):
Where
Tr (t) =
1
βj
{(β +φ +λ ).C e −(β
j j 1 1
λ1t
j +φ j + λ2 ).C2eλ2t } (4) ∆
~
2.2 Wilson
n plot meth
hod
Digital Coomputer
Trbb
Trh
The commonnly used methhod to determ mine the heatt
M Tjo
Data Acquisition transfer coeffficient is the W
Wilson plot meethod (Wilsonn
1 1915). The in nput data for thhis method arre the physicall
Coolingg parameters deefining the dimensions of the t equipmentt
Water
8
(the heat trannsfer surface),, the fluids floowing in eachh
8 circuit, the mass flow rates, and the averagee
5
temperatures in the inlet aand outlet con nnector pipes.
The heat trannsfer coefficieent on each side of the heatt
M
2 Tj transfer surfaace depends onn the flow reggime. In orderr
3 to experimenntally determinne this param meter in givenn
6 equipment, varied
v is the mass
m flow rate in one side,
and the masss flow rate in the other side is keptt
7 4
constant. Tem mperature annd mass flow w rate are thee
Figg. 3: Schemattic representattion of the laaboratory input parametters varying dduring the experiment.
equuipment: 1-Veessel, 2-Agitattor, 3-Flow meter, The original Wilson plot method was modified in a
4-PPump, 5-Tempperature contrroller, 6-Therrmostatic variety of ways. The modiffication mainlly consisted inn
batth, 7-Electric hheater, 8-Bafffles. changing the number of ddetermined parameters. Thee
original versiion required kknowledge off the exponentt
at the Reyn nolds numbeer. Briggs et e al. (1969))
proposed an iterative methhod to determ mine both heatt
transfer coeffficients withouut knowing off the exponentt
at the Reynnolds numbeer. Further modificationss
allowed for determining
d off up to five parameters cann
be found in Joosé Fernandezz-Seara et al. (2007).
(
The overall heat
h transfer rresistance throough the walll
of the agitateed vessel is ddescribed by the followingg
approximatioon formula:
The agitated vesseel is equippedd with a straigght jacket, Where: Rw is the wall resisstance. It shou uld be noticedd
whicch has a circuulating liquid in a closed looop. Heat that every liqquid can prodduce a layer or deposit off
is prrovided from this fluid byy means of ann electric extraneous materials
m on the heat tran nsfer surface,
heat exchanger annd a thermosttatic bath, as indicated which will prrovoke a timee-modificationn of both film m
in Fig.
F 3. It iis instrumentted by four PT-100 heat transfer coefficients.. In these caases, the heatt
tempperature sensoors; one is positioned in the high part transfer resistance increases considerab bly due to thee
of thhe agitated fluid (Trh) and thhe other in thee low part fact that this type of mateerials normally y has a lowerr
(Trb).
) Water circulate in the jacket and his thermal condductivity. Thiss effect is refeerred to as thee
tempperature is meeasured with two t sensors positioned
p fouling or dirrt factor, and sshould be avoided or, if thiss
at thhe inlet (Tji) annd the outlet side
s (Tjo) of th
he jacket. is not possiible, taken innto account as a furtherr
Fourr equally-spacced, flat wall baffles
b were used
u each resistance to heat
h transfer.
withh a width equaal to 1/10 of thhe inner diameeter of the Substituting to Eq. (1) deefinitions of the similarityy
vessel. numbers, thee heat transffer coefficiennt hi can bee
The Temperaturee controller controls thhe jacket expressed in the
t form:
tempperature and allows
a trackingg a desired seet point of
the vessel
v temperaature.
h i = α 0 . N θ 20 (8)
The jacket-side
j heeat transfer cooefficient hj deepends on
the flow
f of the cirrculating heatt transfer fluidd through Where, α0 is a constant.
the jacket;
j it wass calculated foor the maxim mum mass
flow
w rate, which was kept coonstant during all the According too Eq. (8), oonly the stirrer speed cann
modify the value
v of the internal film heat transferr
coefficient for a given vessel, with the same liquid The slope of the straight line is the reciprocal of α0.
and temperature conditions inside it. The value of α0 When the stirrer speed has no effects on the value of
is described by Eq. (9). hi (N → ∞), 1/U gives the parameter b.
Y = b0 + b1 X1 + b2 X 2 + b3 X 3 + b12 X1 X 2 +
y b13 X1 X 3 + b23 X 2 X 3 + b123X1 X 2 X 3 (16)
80 T=30°C
µa(Pa.s)
τ(Pa)
T=40°C
70
T=50°C
60 T=60°C
50 T=30°C
0,1
40 T=40°C
30 T=50°C
20 T=60°C
10
0,01
0
1 10 100 γ˙(1/s) 1000
0 200 400 600 800
γ˙ (s-1) Fig. 7: The dependence of apparent viscosity
Fig. 6: The dependence of shear stress on the shear on the shear rate.
rate.
The apparent viscosity is computed from the estimation of an averaged Overall heat transfer
following equation: coefficient Ui from Eq. (6) and the experimental time-
temperature results presented in Fig.8
η a = kγ& n −1 (19) The values calculated from Eq. (6) are presented in
table 4.
Table 4 Values of N, Re and Ui
3.2 Influence of non-Newtonian flow FBDT(d=81mm) FBDT(d=45mm)
behavior on mixing process
characteristics N,rpm Re Ui Re Ui
In an agitated vessel, the rheological properties of the 260 142.80 129.30 140.78 83.95
material to be processed are of main importance
regarding the parameters which have to be considered 450 241.95 188.68 265.07 116.22
for the configuration. The viscosity influences the
formation of the flow field inside the tank and, 650 353.75 240.82 373.49 146.68
therefore, the mixing and power behavior.
Thus, the viscosity is the most important 850 430.91 276.19 573.08 189.72
characteristic value. While Newtonian fluids are
characterized by a constant viscosity, the processing
of non-Newtonian materials demands the From table 4, it can be seen that the heat transfer
consideration of a changing viscosity through a coefficient is calculated in the transition regime.
viscosity function.
For the configuration of agitators for the processing In the second part of the steady, the time response of
of non-Newtonian materials, the changing viscosity the theoretical vessel temperature Tv(t) using Eq. (4)
is presented in Fig. 8. From these plots it could be
needs to be considered, where the Reynolds number
is the decisive characteristic value. The main problem clearly seen that the agreement between the
is the determination of the correct viscosity at a set experimental data and the theoretical values
calculated using Eq. (4) is satisfactory. Similar plots
rotation rate; as a consequence the Reynolds number
cannot be calculated. This means that also the mixing prepared for the agitator of 45mm diameter also
indicated satisfactory agreement.
time and power characteristics only can be included
as approximations in the configuration stage. For this 335
Tr(K)
rotation rate of the stirrer and mean shear rate γ& in the Tr-exp
315
agitated vessel can be described by a linear
correlation according to the method of Metzner and 310
Otto (1957).
305
295
Where the constant Ks in pseudo-plastic fluids has the 0 500 1000 1500 2000 2500 3000
value 11.5, when a flat blade disc turbine is used; for time (s)
the pitched blade turbine (θ=45°) the value is 13 and
for the propeller it is 10 (Reinhold P. et al. 1980). Fig. 8: Time-Temperature Plots for FBDT
d= 81mm and N=850 rpm.
3.3 Heat transfer calculation
3.3.1 Experimental determination of heat The third step deals with the determination of the
transfer coefficients by Wilson Plot partial heat transfer coefficient hi using Wilson plot
method.
A computer programme was used to analyze the data
taken from the experiments in this heat transfer study. The calculated values of the local heat transfer
The first step of the calculation deals with the coefficient hi from the Wilson graphs have been
plottted against the speed of th he impeller for each of
the impellers. From m this plots itt has been ded
ducted the
correelations givenn in table 5.
Table 5 Valu
ues of hi
FBDT(d=81mm) F
FBDT(d=45mmm)
Y = 428
4 ,37 + 113,533 X 1 + 21,29 X 2 + 90,45 X 3 +
(21)
17,055 X 1 X 2 + 23,844 X 1 X 3 + 15,1X 2 X 3 +
9,23 X 1 X 2 X 3
407.06 96
6.48 75.3
35
61
14.6 (23)