Latent Heat Lab

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Latent Heat of Fusion

Introduction
When a solid has reached its melting point, additional heating melts the solid without a
temperature change. The temperature will remain constant at the melting point until all of the
solid has melted. The amount of heat needed to melt the solid depends only on the mass of the
solid. In this experiment the heat of fusion of ice will be determined by using the method of
mixtures. Using the method of mixtures, two substances of different temperatures are mixed
together. The warmer object will release heat that the cooler object will absorb until they reach
an equilibrium temperature. {Eq. 1}

Q​lost​ = - Q​gained {Eq. 1}


where Q is the amount of thermal energy absorbed or released. The amount of thermal energy
absorbed or gained can be determined by using the specific heat capacity {Eq. 2} for when the
temperature of state is changing.

Q = mcΔT {Eq. 2}

Where m is mass, c is the material’s specific heat capacity, and ΔT is the change in
temperature. The latent heat of fusion {Eq. 3} or latent heat of vaporization {Eq. 4} is used to
determine the amount of thermal energy lost or gained due to a change in state.

Q = mL​f {Eq. 3}

Q = mL​v {Eq. 3}

Where m is mass, L​f​ is the latent heat of fusion, and L​v​ is the latent heat of vapourization.
Ice will be added to a calorimeter containing warm water. The heat energy lost by the water and
calorimeter does two things:
1. It melts the ice;
2. It warms the water formed by the melting ice from zero to the final temperature.

{Eq 4}

Materials
● Ice
● Tap water
● Vernier LabQuest
● Temperature probe
● Calorimeter
● balance
Procedure:
1. Using the digital scale or the triple beam balance determine the mass of the empty
calorimeter, m​c​, and record the data.
2. Fill the calorimeter cup to about half full with warm water. The water temperature
3. should be between 5℃-10℃ above room temp. (around 20℃)
4. Determine the mass of the calorimeter cup and water, m​cw​ and record the data.
5. Measure and record the initial temperature of the water, T​wi
6. Dry several small pieces of ice with a paper towel to remove any adhering water. We
want to add ice and not the liquid water on the ice. Add the pieces of ice to the
calorimeter
7. Keep the mixture well stirred.
8. When all the ice has melted, (the temperature will remain constant), measure and
record the equilibrium temperature, T​f​.
9. Measure and record the combined mass of the calorimeter cup and water, m​cwi​, which
now includes water from the melted ice.

Results

Table 1. Mass & Temperature Data

Mass of cup, mass of the cup & initial temperature Equilibrium mass of the cup,
m​c​ (g) water, of the water, temperature, water, & ice
m​cw​ (g) T​wi​ (℃) T​f​ (℃) m​cwi​ (g)

​Analysis

Table 2. Calculated masses

Mass of water, m​w

Mass of ice, m​i

**Delete these “guidelines” in your report**


● Determine the latent heat of ice. Include full calculation (can be an inserted photo OR
use an equation editor. (you will need to look up the values for specific heat capacities)
● Compare value with actual latent heat of ice. (you will need to research this)
● Determine the percent error.

● Discuss reasons for the discrepancy between the two values

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