VTT R 05984 12
VTT R 05984 12
VTT R 05984 12
RESEARCH REPORT
Confidentiality: Public
RESEARCH REPORT VTT-R-05984-12
3 (72)
Preface
This report is a part of the project NeReMa (Advanced Solutions for Recycling
Complex and New Materials, 2010 - 2012). The aim of the project was to analyse
current situation of selected waste value chains as well as the demands of the
current and future operational environment. An analysis of challenges and
development needs in these value chains was made and future development
opportunities identified. This report is a part of the value waste chains analysis
made dealing with recycling and utilisation of construction and demolition (C&D)
waste.
The project was funded by Tekes (Finnish Funding Agency for Technology and
Innovation) a group of companies and participating research institutes. The
research partners and their main duties in the project were:
VTT Technical Research Centre of Finland: Coordinator and the project
and main responsibility for the analysis of MSW and C&D value chains
Aalto University School of Science and Technology Lahti Center
(AALTO): Main responsibility for the WEEE, C&I and ELV value Chains
The Finnish Environment Institute (SYKE): Responsible for the analysis
of strategies and legislation, Life cycle analysis (LCA and LCC) and BAT
analysis
Lappeenranta University of Technology (LUT): Responsible for the Waste
to Energy opportunities in the value chains mentioned above.
The Steering Group of the project consisted of the following persons: Antero
Vattulainen, Kuusakoski Oy; Toni Andersson, Ekokem Oy; Tuomo Joutsenoja,
Rudus Oy; Ilkka Kojo, Outotec Oy; Markku Lehtokari, Turun Seudun Jätehuolto;
Marko Mäkikyrö, Ruukki Metals Oy; Pekka Pouttu, Kiertokapula Oy; Arto
Ryhänen, Jätekukko Oy; Jukka Ylijoki, Metso Automation Oy; Asko Vesanto,
Tekes; Jatta Jussila, CLEEN Oy; Eva Häkkä-Rönnholm, VTT; Juha Kaila, Aalto
University; Tuuli Myllymaa, Finnish Environment Institute and Mika
Horttanainen, Lappeenranta University of Technology.
Espoo 5.11.2012
Hannele Kuosa
RESEARCH REPORT VTT-R-05984-12
4 (72)
Executive summary
Introduction
On the other hand in several countries the use of e.g. recycled aggregates (RAs) in
concrete is already at least to some degree common, and this use is also regulated
by national specifications. Many countries have also introduced legislation and
policy measures to encourage the use of recycled aggregates in concrete. The use
of recycled aggregates in earth and road construction is more common, though
also this use could be essentially wider based on the technical and sustainable
benefits it can offer. This report is concentrated on the use of recycled aggregates
in concrete and other cement based materials. The main emphasis is on the ways
to widen the use. Quality of the produced recycled aggregates, as well as specified
ways for the use are important factors deciding the potential for economical,
sustainable and technically acceptable use.
This report also includes some information on the reuse of other C&D waste than
mineral waste for the production of recycled aggregates. Besides the reuse options
of the main non-mineral C&D waste is covered shortly.
As RA can include all kind of inorganic materials from the C&D waste, i.e.
concrete, concrete masonry units, mortars, aerated concrete and also clay masonry
units (bricks and tiles), it is not as good a material for concrete production as
recycled concrete aggregate (RCA). RCA is made of solely crushed concrete.
Separation of concrete material already during the demolition phase is essential to
make it easier to produce good quality RCA.
RCA (also RA) is typically classified according to the grain size. Typically coarse
RCA (> 4 mm) is much easier to use in concrete production than fine RCA (< 4
mm). This is because after normal concrete crushing and sieving operations the
proportion of good natural aggregates is much higher in the coarce portion than in
the fine portion. After advanced RCA production methods, coarce RCA can
basically consist of solely natural aggregate. Instead fine RCA typically contains
more cement paste which absorbs water and makes the concrete production more
challenging. Cement paste may also include harmful substances for concrete such
RESEARCH REPORT VTT-R-05984-12
5 (72)
as chlorides and sulphates. Especially fine RCA quality is dependent on the C&D
waste quality, as also coarse graded RCA quality if the cement paste content that
is adhered on the aggregate surfaces after the crushing and other processing
operations remains high. By forceful C&D waste sorting and processing it is
possible to produce high quality recycled aggregates for concrete production.
RA classification
Typically there can be for instance limits for RA composition (amount of certain
harmful or unfavourable substances such as chlorides, sulphates, organic
materials, glass, gypsum, plastic, timber, paper and bituminous material),
minimum density and maximum water absorption. The minimum density allowed
for RCA is typically between 2000 to 2200 kg/m3 and the maximum water
absorption values fall between 7 % and 10 %. Composition and properties are
linked together and that is why the limits for both the composition and certain
properties are not always needed. The maximum content allowed for chlorides
and sulfates is usually stated in the normative documents. If no values are
stipulated a reference is normally made to the need to specify a value through a
case-by-case analysis. The maximum authorised content of sulfates varies from
0.8 % to 1.0 % of aggregates (in mass). For chlorides the range of values is much
wider, changing according to the demand level of the use, even within the same
standard. For structural concrete, values between 0.03% to 0.05% are common. It
must be noted, that the end use requirements, which are based also on climatic
exposure classes, must be different in different countries because of different
climatic circumstances, and also because of different national policies and adopted
safety levels.
The normative national specifications define also the allowable use of the
specified RA. This means defining the maximum replacement of natural with
recycled aggregates (mainly only coarse but in some cases also fine recycled
aggregates), conditions of the use conforming with the European Standard EN
206-1 for concrete (e.g. only non-structural concrete, only non-aggressive
environments and/or specified environmental conditions/classes, etc.), and the
highest allowable compressive strength class for each case. In the more
sophisticated specifications it is also possible to assume that there are, in fact,
RESEARCH REPORT VTT-R-05984-12
6 (72)
For instance the maximum replacement ratio of natural with coarse RCA can be
20 – 35 % in a structural concrete with 30 MPa compressive strength. In a non-
structural concrete with 15 MPa compressive strength it can be even 100 %. The
replacement ratio can also be 100 % in 40 MPa concrete if the use of this concrete
is in a non-aggressive environment. In relation to the environmental conditions,
all standards generally aim at applications subject only to non-aggressive
conditions, and they are especially careful in terms of chemical attacks. Pre-
stressed concrete is outside the scope of most standards.
RA-concrete in Finland
High demands for construction materials are one obvious barrier for the reuse of
RA. Especially in Finland the demands for e.g. concrete durability are high.
Anyway there are also possibilities to widen the use of RA. Research is needed to
find out the most practical and economical ways for this. Knowledge is needed
e.g. on the effect of crushing and processing methods on the quality of RA. One
option to widen the use of RA is to find novel and value-added ways to use also
fine RA, and besides also fine filler aggregates (<0,063 mm) and powders created
in the RA production. These fine graded materials could be added in some
concrete types, especially in self compacting concrete (SCC), and possibly also in
some other construction materials to provide certain desired properties. Research
and innovations are needed for this. It may even be possible to create new
commercial products based on certain fractions of demolished concrete.
Novel methods for RA quality enhancement, as well as novel mix design and
mixing approaches, are one way to improve RA and RA-concrete quality. RA
quality can be enhanced by e.g. established thermal or microwave treatment, pre-
soaking treatment and by washing and chloride removal. Thermal treatments
cause a considerable reduction in the amount of cement paste or mortar adhering
to both the fine and the coarse aggregate particles. In concrete mix design and
mixing there are several methods to compensate the possibly unfavourable effects
RESEARCH REPORT VTT-R-05984-12
7 (72)
The use of RA together with other recycled materials in traditional cement based
or innovative new products is one option. The use of RA with fly ash
(FA)/classified FA/micronized FA, silica fume (SF), slag (SLG), other (recycled)
powder/micronized materials, brick powder, glass powder, rock powders and even
e.g. lime production waste is a way to widen the use of demolished concrete. RA
can also be used to produce low strength materials, as filling materials, including
ecological materials also totally without or with a minimum amount of cement.
Material technological possibilities are in all boundless and can also include other
C&D waste reuse.
Sustainability
Also materials other than mineral C&D waste can be reused. This report includes
limited information on that area. C&D wastes such as gypsum/plasterboard,
mineral wool, expanded polystyrene, polyurethane, lightweight aggregate
RESEARCH REPORT VTT-R-05984-12
8 (72)
Some non-mineral C&D wastes can also be reused in concrete or other cement
based products as grouts, mortars and lightweight products. For instance expanded
polystyrene (EPS) without or with preliminary heat treatment, polyurethane
(PUR) and also PVC can be used in lightweight cement based product. There is
also a possibility to reuse recycled aggregates made of lightweight concretes
(aerated concretes) in cement based products. Economical polymeric treatment of
concrete to increase the durability properties of concrete (PC, polymer concrete) is
possible by using melted recycled plastics. Recycled plastics can also be reused as
fibres in concrete. Application of glass in cement based products can be rewarding
since the high production volume of concrete materials can incorporate large
quantities of recycled glass, and the reuse of glass in cement based products has
been studied widely. In Finland the use of glass in cement based products is
minimal. However the use of micronized glass powders has been studied also in
Finland. Finely ground glass (< 45 µm, even < 10 µm) has pozzolanic properties
contributing to the cement based materials´ strength.
RESEARCH REPORT VTT-R-05984-12
9 (72)
Contents
Preface ........................................................................................................................ 3
1 Introduction ........................................................................................................... 10
6 Possibilities and ideas for the reuse of other C&D wastes ................................... 43
6.1 Gypsum/plasterboards .................................................................................. 43
6.2 Mineral wool .................................................................................................. 47
6.3 Expanded polystyrene (EPS) ........................................................................ 49
6.4 Polyurethane (PUR) ...................................................................................... 50
6.5 Lightweight aggregate concrete (LWAC) and Aerated concrete ................... 52
6.6 Wood ............................................................................................................ 52
6.7 Plastics (e.g. PVC) ........................................................................................ 53
6.8 Glass (window-, door-, etc.) .......................................................................... 62
7 Conclusion ............................................................................................................ 64
References ................................................................................................................ 65
RESEARCH REPORT VTT-R-05984-12
10 (72)
1 Introduction
Research has already been done already a long time, more than 30 years, to
exploit the use of recycled materials as construction and demolition waste (C&D
waste) in new construction materials as e.g. in concrete. C&D waste is
increasingly seen as a valuable source of engineering materials for the
construction industry. However the percentage use of these materials is not at a
desired or sustainable level. There is also far too little knowledge of technically
realistic ways to reuse C&D waste. For instance designers do not know what
proportion of recycled aggregate should be specified in different concrete grades.
Besides it is not clear how big the sustainable advantage can be in different cases.
By far the biggest share of natural resource use stems from construction minerals,
i.e. aggregates such as sand, gravel, crushed rock and other bulk materials used by
the construction industry. They represent 40% of the Direct Material Inputs into
the European economy - mineral fuels represent 25%. Aggregates are important:
not only because of their resource intensity, but also because of environmental
impacts (drawn from LCA analysis), economic importance and, finally, because
they are predominantly a domestic natural resource.
In Finland the reuse of C&D waste e.g. in concrete is minimal. However, the use
of recycled aggregate (RA) and recycled concrete aggregate (RCA) in earth
construction is already more common and there are codes of practise and also
processes for the reuse of especially good enough quality RCA. [Rudus 2008, SFS
5884]
Also in e.g. U.S.A, the use of RCA is most common in earth or road
constructions:
o aggregate base course (road base)
o soil stabilization
o pipe bedding
o asphalt pavements
o landscape materials.
The USA Ready Mix concrete market is in its infancy stage with few recyclers
attempting a re-use strategy although confidence is gaining through the Build
Green program in U.S.A. In 2005 California wrote legislation mandating and
accepting the use of recycled concrete into new concrete. Generally, the American
Society for Testing and Materials (ASTM) and the American Association of State
Highway and Transportation Officials (AASHTO) are national trendsetters. Their
specifications allowing for recycled aggregate use reinforces confidence in
recycled products.
This review deals mainly only technical issues, i.e. the effects of C&D waste, as
RA/RCA, on the technical properties of the products they are used in. The use of
RA/RCA in earth construction is not covered here, though being traditionally the
most feasible way to use it.
2.1 General
To some extent, the investigation on recycled waste concrete was initiated by
Glushge in Russia 1946 [Xiao et al. 2006]. In the following years, a large amount
of experimental works have been carried out worldwide to investigate the
recycling of waste concrete. Previous studies were mainly engaged in the
processing of demolished concrete, mix-proportion design, mechanical properties,
durability aspects and improvements. Recently, structural performances and
economic aspects of using recycled aggregate concrete are also analyzed.
There is today a lot of information and literature on the use of RA/RCA. Here
only some main conclusions are reviewed shortly. More comprehensive
information analysis with experimental and practical work is needed for the real
use of RA/RCA in actual concrete production. In less demanding and clearly
defined cases, the use of RCA may also be more straightforward – e.g. small
proportion of good quality RCA from a known source. (see References, e.g.:
[Kasai 2004, Ilker & Selim 2004, Levy & Helene 2004, Poon et al. 2004A &
2004B, Nagataki et al. 2004, Topcu & Sengel 2004, Shayan & Xu 2003, Katz
2003, Otzuki et al. 2003, Ajdukiewicz & Kliszczewicz 2002, Dhir and Paine
2004, Dhir et al. 1999, Sagoe-Crentsil et al. 2001, Topcu and Sengel 2004, Xiao et
al. 2006, Paine & Dhir 2010, Fathifazl et al. 2010]).
High demands for concrete have been one clear obstacle for the reuse of
RA/RCA. Especially in Finland the demands for concrete durability are high.
There are anyway also possibilities to widen the use of RA/RCA in concrete. The
main point is to find a suitable demolition structure and concrete for a suitable
reuse. Powerful standardisation on the reuse of RA/RCA can help in this, but also
other ways are needed. There are also concretes and products, where RA/RCA can
fully compensate for natural aggregate in a sustainable way. Of course much
research is needed to find out the most practical and economical ways to reuse
RC/RCA in concrete. Knowledge is needed e.g. on the effect of crushing and
processing methods on the quality of RA/RCA and on the properties of concretes
including RA/RCA. There usually is a limit to the amount of RA/RCA in a certain
concrete, but with a low enough amount the effects on e.g. concrete strength
properties can also be in practise none or minimal.
Information (year 2005) on e.g. the research results and information on some
specifications and on the reuse of crushed concrete in concrete can be found in the
Finnish publication “Betonin, betonilietteen ja veden kierrätys betoniteollisuu-
dessa” (2005, in Finnish).
Clean graded RCA may contain foreign materials that alter fresh and hardened
concrete performance together with chemical impurities. Fine aggregates are
generally more susceptible to contaminants than the coarse fraction. The typical
effect of contaminants on hardened concrete properties is volume instability.
[Sagoe-Crentsil & Brown 1998]
In general, harmful substances are not allowed and all aggregates should be
suitable for the intended use of concrete.
≥90 Rc90
≥80 Rc80
Rc ≥70 Rc70
≥50 Rc50
<50 RcDeclared
No requirement RcNR
≥90 Rcu90
≥95 Rcu95
Rc + Ru ≥70 Rcu70
≥50 Rcu50
<50 RcuDeclared
No requirement RcuNR
≤10 Rb10-
≤30 Rb30-
Rb ≤50 Rb50-
>50 RbDeclared
No requirement RbNR
≤1 Ra1-
Ra ≤5 Ra5-
≤10 Ra10-
≤0.5 XRg0.5-
X + Rg ≤1 XRg1-
≤2 XRg2-
3
Content [cm /kg]
a)
≤0.2 FL0.2-
FL ≤2 FL2-
≤5 FL5-
a) The ≤0.2 category is intended only for special applications
requiring high quality surface finish
Today there are separate EN-standards for each end use (see above) – concrete,
mortar, asphalt, etc. This is sensible as each end use faces its own particular
challenges and issues. E.g. drying shrinkage of aggregate is important for concrete
but meaningless for asphalt. However each end use also faces some very similar
issues. The committees responsible for aggregate Standards have been working
recently to establish if these differences are necessary, or if a more consistent
approach can be adopted. E.g. it is likely, that coarse/fine split will be
RESEARCH REPORT VTT-R-05984-12
17 (72)
In several countries there are already additional specifications for the use of RAC
(RA) in concrete. In these national specifications guidelines and quality assurance
systems for the use of recycled aggregate in concrete are given. In all, there is still
a lot to do, to get RAC efficiently in use. Especially the use of RA is today
limited. Practical guidelines are needed. Too elaborate systems will not enhance
the use of recycled aggregates. Especially for the most undemanding cases there
should be straightforward ways to use RA/RCA in concrete production.
The analysis of the limits stipulated for harmful substances shows that organic
materials are between 0.5 % and 1 %, with the exception of the Brazilian standard
(2%) - the explanation for this is that only non-structural recycled aggregate
concrete is allowed. [Gonçalves & Brito 2010]
When filler is mentioned, the maximum filler content is smaller the stricter the
requirements of the application for which the aggregates are proposed. Filler can
significantly impair the mechanical properties of concrete, because it tends to
include materials such as clay particles.
The minimum density allowed for RCA is typically between 2000 to 2200 kg/m3.
The maximum content allowed for chlorides and sulfates is usually stated in the
normative documents. If no values are stipulated a reference is normally made to
the need to specify a value through a case-by-case analysis.
The maximum authorised content of sulfates varies from 0.8% and 1.0%
of aggregates (in mass).
For chlorides the range of values is much wider, changing according to the
demand level of the use, even within the same standard. For structural
concrete, values between 0.03% and 0.05% are common, usually
associated with RCA because they are the most suitable recycled
aggregates for this type of application. The Brazilian standard allows
much higher amounts of chlorides because it does not envisage the use of
recycled aggregates in structural concrete.
The normative documents define also the allowable use of the specified RA/RCA.
This includes:
the maximum replacement of natural with recycled aggregates (mainly
only coarse but in some cases also fine recycled aggregates),
conditions of the use (conforming with EN 206-1, e.g. only non-structural
concrete, only non-aggressive environments and/or specified
environmental conditions/classes, etc.), and
the highest strength class for each case.
For instance the maximum replacement ratio of natural with coarse RCA can be
20 – 35 % in a 30 MPa structural concrete, and as much as 100% in a 15 MPa
non-structural concrete. The replacement ratio can also be e.g. 100 % in a 40 MPa
concrete if the use is in a non-aggressive environment. In relation to
environmental conditions, all standards generally aim at applications subject only
RESEARCH REPORT VTT-R-05984-12
19 (72)
Finland
There is a need for a specification for the use of RA/RCA in Finland. Without this
kind of more or less comprehensive national instructions the use of recycled
aggregates in concrete will be unsound and very limited also in the future.
National specifications should be based on local climatic conditions, and all the
other local circumstances. The aim should be value-added sustainable application
of recycled aggregates. Also the use of RA in wider applications should be studied
and promoted. Considerable attention is required to the control of construction
and demolition waste processing and subsequent sorting, crushing, separation and
grading of aggregates for use in concrete, and possibly also in other materials,
especially cement based materials.
RILEM
Japan
In [Kasai 2004] there is information on the Japanese guideline ”TR A006 2000 –
Concrete using recycled aggregate”. The main principle is that the mortar
component will decrease quality and this becomes evident as higher water
absorption when the mortar content is increased.
In [Kasai 2004] a technical regulation “TR A006 (2000) Concrete using recycled
aggregate” is reviewed. Classification is based on the amount of mortar. The
mortar phase increases water absorption. With a higher mortar amount, the quality
of recycled aggregate is lowered. The amount of absorption should be less than
7 % for coarce aggregate and less than 10 % for fine aggregate. This regulation
includes also the methods for quality control.
In Japan the use of recycled aggregate is recommended only for concrete without
frost attack. The amount of RA is determined by each case. It can be 100 % of
coarce aggregate, or 50 % of both coarce and fine aggregate can be recycled.
When the amount of recycled aggregate is less than 30 %, the effects on concrete
strength and other properties are normally considered small [Kasai 2004].
United Kingdom
In some concretes any amount of RCA is possible in UK. For instance low grade
flooring (small garages) with no reinforcement and some pavement curbs can
include high amounts of RCA. In other allowable cases the amount of RCA is
usually limited to 20 % of total aggregate, though also 30 % has often only minor
effects on especially the critical concrete properties in low exposure classes.
Australia (1998)
The project report [Sagoe-Crentsil & Brown 1998] presents draft guidelines for
specifying commercially produced RCA for pre-mix concrete production based on
product variability trials. A quality assurance systems was also created on the
supply and utilisation of RCA in relation to existing product standards in
Australia.
This outlined technical information only applies to coarse RCA produced from
clean uncontaminated crushed concrete (particle density >2100 kg/m3, including
< 2 % of brick, stony material or other forms of contaminants). Physical
contaminant levels typically less than 2% were achievable under existing
manufacturing practices. The need for assessing chemical contaminant levels was
recommended. Such contaminants have the potential to alter concrete rheology,
setting characteristics and concrete durability.
Class 1 RCA was deemed to be suitable for production of plain unreinforced and
reinforced concrete up to and including 40 MPa concrete, with no mandatory
limits on RCA substitution levels. Extra care must be taken to ensure satisfactory
RESEARCH REPORT VTT-R-05984-12
21 (72)
Switzerland
Recycled Aggregate (RA) that does not meet the requirements for RCA may have
a wide range of composition, for example:
a mixture of 94 % crushed concrete and 6 % crushed brick, and
100 % crushed brick, are both considered to be RA.
In [Paine & Dhir 2010] an alternative route for specifying RA for use in concrete
is studied and presented. It overcomes concerns regarding potential variability
through reference to the properties of the aggregate, as opposed to the
composition.
Although the use of crushed concrete (Rc) and/or crushed brick (Rb) in concrete
led usually to lower concrete performance than concrete mixes prepared with
natural aggregates, the loss in performance could be correlated to appropriate
properties of the aggregate:
LA coefficient – determination of the resistance to fragmentation
[EN 1097-2:1998]
aggregate water absorption,
density and
drying shrinkage.
respectively). The relevant limits for these corrections are also shown in Table 3,
and the three limits given could be proposed as three classes of RA: A, B and C.
This classification of RA should permit a wider use of RAs in higher-value
applications than the current compositional limits in UK and in BS 8500.
Based on the results in [Paine & Dhir 2010], Table 4 provides a tentative list of
environments in which it can be assumed that these three classes of RA could be
used. For example, it can be suggested that RA meeting class A is suitable for a
range of exposure conditions, including use in concrete exposed to carbonation
(up to XC-4), sulfate conditions (up to D-2) and other aggressive agents. In
addition, it is tentatively suggested that due to the low water absorption value, RA
meeting class A will be suitable for use in the least aggressive chloride (XD and
XS) environments because performance is similar to that of natural aggregate.
Recycled aggregate meeting class B would be suitable for use in fewer exposure
conditions, but could be used in concrete exposed to e.g. carbonation (XC-4).
Recycled aggregate meeting class C has very low requirements and therefore
would only be suitable for use in concrete exposed to e.g. moderate levels of
carbonation (XC-2).
RESEARCH REPORT VTT-R-05984-12
24 (72)
It was also possible to separate the combinations of aggregate into classes that
would perform to a given requirement if suitable practical considerations were
taken into account, for example slight adjustments to the water-cement ratio, as
recommended elsewhere [Dhir et al. 1999]. This in turn should encourage the
development of sustainable use of all C&D waste. It is recommended that further
works should be done so that e.g. the proposed classification for the RA can be
strengthened for its adoption in practice.
Many researches have recorded reduction in strength for concrete made with RA.
As a result, the use of RA is mainly confined to low-grade applications. In
research by [Xiao et al. 2006] an experimental database was developed with
regard to the main mechanical properties of RAC. It is based on a large number of
RESEARCH REPORT VTT-R-05984-12
25 (72)
Although it may be sustainable to use RA, the current legislation and experience,
however, are not sufficient to support and encourage recycling of demolished
concrete waste.
Fine RCA
In [Evangelista & de Brito 2007 & 2010] results on an experimental study are
presented on the use of fine recycled concrete aggregates as partial or global
replacements of natural fine aggregates in the production of structural concrete.
The experimental results indicate that it is possible to produce concrete made with
fine recycled concrete aggregates suitable for structural concrete, considering that:
o < 30% replacement ratios can give good results in favourable cases,
o both tensile splitting and modulus of elasticity are reduced with the
increase of the replacement ratio; however, the values were still
acceptable, especially for reasonable levels of the replacement ratio (30%),
o the abrasion resistance seems to increase with the replacement of fine
natural with fine recycled concrete aggregates,
o considering the acceptable mechanical behaviour and the fact that some
structures are not affected by durability issues (e.g. concrete elements
protected from natural aggressive agents), concrete fine RCA can be a
useful source of material and could potentially replace fine natural
aggregate in some concrete mixes [Evangelista & de Brito 2010].
It should be noted that fine RCA used in [Evangelista & de Brito 2007] was
obtained from concrete mixes especially produced in laboratory, which led to
controlled crushing and sieving of RCA. Also the concrete used to produce the
fine RCA was made with normal hydration speed cement (CEMtype II), that takes
longer to fully hydrate, and therefore affected also compressive strength
development of RCA-concrete it was used in. It is expected that fine RCA
obtained from old field structures would behave differently, i.e. with smaller
effect on strength development. Also RCA obtained from field structures likely
have particles from debris that might reduce their performance. Nevertheless, the
careful extraction of fine RCA from precast concrete elements would avoid such
problems.
RCA powder
Self-compacting concrete (SCC) must show both high fluidity and good
cohesiveness at the same time. Fine powder materials are very useful in SCCs. In
[Corinaldesi & Moriconi 2011 A] several SCC mixes were prepared by using
either powder from recycled concrete or limestone powder, and also different kind
of fibres. In [Corinaldesi & Moriconi 2011 B] either recycled aggregate powder,
limestone powder or fly ash was used.
A powder obtained from the recycling process of old concrete was employed.
This process mainly consists of crushing concrete waste from building demolition
RESEARCH REPORT VTT-R-05984-12
27 (72)
and collecting the material passing through a suitable sieve. In this case 0.150 mm
sieve was used. This recycled concrete powder had a Blaine fineness of 0.73 m2/g
and specific gravity of 2150 kg/m3. Its chemical composition is presented in
Table 5. SEM images of rubble powder and limestone powder are presented in
Figure 3.
On the basis of the rheological tests on cement pastes, the rubble powder proved
to be the most effective mineral addition. All concretes, which were prepared for
manufacturing thin pre-cast elements with fibres, met both the self compaction
requirements while fresh, and the mechanical requirement of 45 MPa when
hardened. Excellent performances were generally obtained, particularly for the
self compacting concretes prepared with powder from recycled concrete and steel
fibres. The use of recycled concrete powder instead of limestone powder seemed
to be promising, particularly in terms of fresh concrete flowability, even if a
higher tendency to shrink was detected when recycled concrete powder was used
with polymeric fibres.
Table 5. Chemical composition and fineness of materials passing the sieve 0.150
mm (sieve ASTM No. 100) [Corinaldesi & Moriconi 2011 A].
Figure 3. SEM images of rubble powder and limestone powder [Corinaldesi &
Moriconi 2011 A].
RESEARCH REPORT VTT-R-05984-12
28 (72)
Contaminating materials (crushed clay brick, crushed ceramic tile, crushed waste
glass, wood chips, etc.)
In Hong Kong, the use of recycled concrete aggregates for preparing concrete
products has been successfully implemented and gaining wider acceptance.
However, the allowable level of contaminating materials (e.g., crushed clay brick,
crushed ceramic tile, crushed waste glass, wood chips, etc.) in the recycled
concrete aggregate, in the current specifications, is very low (<1%) due to
stringent quality control standards that are usually adopted from specifications for
raw materials. This significantly increases the sorting efforts at construction sites
and recycling plants and limits the types of construction waste that can be
considered recyclable. [Poon & Chan 2007]
In [Poon & Chan 2007] it was investigated (Hong Kong Polytechnic University)
how paving plock properties were affected, if they were made with RCA
contaminated by other waste materials. Four types of materials were used as
contaminants: (1) crushed clay brick, (2) crushed tile, (3) crushed waste glass, and
(4) wood chips. These materials were blended together to replace a maximum of
10% of the recycled concrete aggregate in the production of the paving blocks.
The used RCA was obtained from a C&D waste recycling facility in Hong Kong.
Only the recycled fine (<5 mm) aggregate was used (oven-dry density 2093
kg/m3). The results of this study reveal a possible increase in the allowable
contamination level in recycled concrete aggregate in the production of paving
blocks. The requirements for paving blocks are somewhat different in different
countries, but it may be possible to meet the standards by adjusting the aggregate-
cement ratio or with the use of additional cementitious materials such as fly ash in
the mixes. The high water absorption value of the contaminated paving blocks is a
problem for countries where freezing and thawing do occur. Also, more research
efforts are required to determine the influence of the variability of the
contaminations on the properties and durability of the concrete products.
The effects for the two-stage mixing approach (TSMA) can be attributed to the
porous nature of recycled aggregate, and hence pores and cracks can be
successfully filled up during the pre-mixing process, yielding denser concrete,
improved interfacial zones around recycled aggregate and thus a higher strength in
comparison with concrete using traditional mixing approaches. The two-stage
mixing approach is thus intended to improve recycled aggregate concrete quality
and to lower its strength variability.
RESEARCH REPORT VTT-R-05984-12
29 (72)
Quality enhancement with the use of additional materials, e.g. fly ash and silica
fume, is discussed in Chapter 3 below.
The shear behaviour and strength of concrete beams made with coarse RCA was
studied experimentally in [Fathifazl et al. 2010]. The distinguishing feature of the
beams is the manner in which their concrete mixture is proportioned. A new
method of concrete mixture proportioning is used: Equivalent mortar volume
method (EMV). The results show that the shear performance of reinforced RCA-
concrete beams is comparable, or even superior, to that of beams made entirely
with natural aggregates at both the serviceability and ultimate limit states. The
current Canadian Standards Association, American Concrete Institute and
Eurocode provisions (Eurocode 2) for shear design can be used without any
modification to design recycled concrete aggregate-concrete beams, provided the
new mixture proportioning method is used.
Also earlier results by Fathifazl et al. (2009) have shown that using the proposed
EMV-method, unlike the conventional method, yields concrete mixes with
consistent, predictable, and comparable properties to those of similar mixes made
with natural aggregates. [Fathifazl et al. 2009]
RESEARCH REPORT VTT-R-05984-12
30 (72)
Heat treatment
Microwave decontamination
The results in [Akbarnezhad & Ong 2010] confirmed the capability of high-
frequency microwaves to remove the surface layer of a concrete block through
development of localised high thermal stresses. (Figure 4)
Pre-soaking treatmets
A concentration of about 0.1 mole chosen for the acidic solution can provide a
suitable acidic environment for the aggregate to remove the old cement mortar
and will not lower the aggregate quality. The behaviour of RA could be improved
with reduction in water absorption, without simultaneous exceeding the limits of
chloride and sulphate compositions after the treatment. [Tam et al. 2007]
Soaking in
Soaking Recycled
acidic Watering
with water aggregate
envirionment
According to [Debieb et al. 2009] recycled aggregates with chloride content are
leached if they are soaked in water (Figure 6). These chlorides are consequently
free chlorides because they can go out from concrete after adequate leaching.
After a good washing or total immersion into water during a minimum of 2
weeks, these aggregates can be reused in concrete and even in reinforced or
prestressed concrete. This is only one result and more information is needed on
the effect of RCA washing on contaminants such as chlorides.
RESEARCH REPORT VTT-R-05984-12
32 (72)
2.7 Sustainability
The concept of sustainable development includes the judicious use of natural
resources. The use of these non-renewable resources, such as virgin aggregates,
needs to be reduced by recycling rubble from demolished buildings, processed in
such a way that it can be used to replace virgin fine and coarse aggregate. This
replacement reduces natural resource consumption and allows for reduction in the
volume of materials disposed of in landfills. Recycled aggregate concrete, if
satisfactory concrete properties are achieved, can be an example of sustainable
construction materials. [Corinaldesi & Moriconi 2009]
The XRD and SEM analyses indicated that the following processes occurred
during the hydration and hardening of the original compositions:
Complete transformation of lime (CaO) and partial transformation of
Portlandite Ca(OH)2 into various carbonates forms, e.g., Calcite, Dolomite
and Ancerite.
Synthesis and enhancement of crystalline structures – Tobermorite,
Afwillite and Calcium hydrosilicates.
Growth of a significant number of new amorphous formations, which were
clearly visible with SEM, especially under high magnification.
The synthesis of these three groups of new formations likely explains the
substantial increase in the strength of the concrete and lime waste composites.
Table 6. Compositions of the mixtures under study. [Mymrin & Correa 2007]
RESEARCH REPORT VTT-R-05984-12
34 (72)
Table 7. Compressive strength of the new materials. [Mymrin & Correa 2007]
Hansen (1990) has demonstrated that it is possible to produce new concrete from
concrete waste, without requiring new cement, by adding fly ash, with the novel
concrete containing 79 % of concrete waste, 11 % of fly ash and 10 % of water.
The recycled concrete gains strength very slowly probably due to the pozzolanic
reaction between fly ash and calcium hydroxide from the cement paste in the old
concrete. It is suggested that the process may be used to upgrade the quality of
demolished and crushed concrete for fill or road base purposes. [Hansen 1990]
Fine and coarse recycled concrete aggregate (RCA) and slag/fly ash for
Controlled Low-Strength Materials - no added cement
In an experimental study the feasibility of using fine and coarse RCA (Figure 7)
with slag or fly ash to produce Controlled Low-Strength Materials (CLSM) was
studied [Achtemichuk et al. 2009]. CLSMs are construction materials that
consolidate under their own weight making them ideal substitutes for compacted
soil. Unlike soil, CLSMs do not settle once they are hardened. CLSMs can be
used in a variety of applications including backfills, structural fills, pavement
bases, conduit beddings and void fillings.
The main objective in [Achtemichuk et al. 2009] was to produce CLSM using
only recycled and by-product materials without the need to add Portland cement.
In addition to the hydraulic activity of slag and high-calcium fly ash, their
pozzolanic reaction was activated by the alkalis and calcium hydroxide present in
the residual paste of the RCA. Preliminary tests showed mixtures with slag to
have 7-day compressive strengths 70% higher than mixtures with fly ash (Figure
7). Two types of CLSM with slag were investigated in further detail: one with fine
and the other with fine/coarse RCA. The results showed that the developed
CLSMs are suitable for a wide range of applications particularly those requiring
structural support and fast hardening.
RESEARCH REPORT VTT-R-05984-12
35 (72)
A B
Figure 7. A) Grain size distribution of the fine and fine/coarse RCA.
B) Compressive strength of mortars containing fine RCA and slag or fly ash
(SCM = Supplementary cementing materials). [Achtemichuk et al. 2009]
In [Buranasing et al. 2010] high fineness fly ash was used as a cement
replacement to improve recycled aggregate concrete properties. The mixture
proportions of RA-concretes were first prepared using 100% recycled coarse
aggregate, and then river sand was replaced with recycled fine aggregate at 0, 50,
RESEARCH REPORT VTT-R-05984-12
36 (72)
and 100% by weight of the fine aggregate (river sand plus recycled fine
aggregate). The results indicated that use of 35-50% fly ash (with respect to total
cementitious content) of high fineness could improve slump loss behaviour in
recycled aggregate concretes. Use of high fineness fly ash in RA-concrete could
produce greater compressive strength than that of the recycled aggregate concrete
alone. The results suggest that high fineness fly ash can be used to improve
various properties of recycled aggregate concrete.
An alternative use of both masonry rubble and surplus fine recycled material
could be in mortars. The alternative use of undesirable fractions of recycled
aggregate for the production of mortar has the added effect of improving the
quality of the recycled aggregate for the production of concrete.
Figure 8. Mix design of the mortars and maximum bond strength values.
[Moriconi et al. 2003]
The investigation in [Lin et al. 2010] showed the pozzolic characteristics of pastes
that contain waste brick from C&D wastes. Waste brick had a pozzolanic strength
activity index of 107 % after 28 days. It can be regarded as a strong pozzolanic
material when used as partial replacement of cement. The compressive strengths
of waste brick blended cement that contained 10% waste brick increased from
71.2 MPa at 28 days to 75.1 MPa at 60 days.
Figure 10. Distinct treatment of four different C&D waste streams. [Mulder et al.
2007]
For concrete and masonry, the new concept implies that the material cycle will be
completely closed, and the original constituents (clay bricks, gravel, sand, cement
stone) are recovered in thermal processes. The mixed C&D waste streams are
separated and decontaminated. For this purpose several dry separation techniques
are being developed.
To be able to close the material cycle for concrete completely, high quality raw
materials must be produced from concrete rubble. These raw materials need to
fulfil the criteria that are set for primary raw materials. A thermal process has
been developed for the treatment of concrete rubble (Figure 11). This technology
RESEARCH REPORT VTT-R-05984-12
39 (72)
Figure 11. Flow scheme of thermal treatment of concrete rubble. [Mulder et al.
2007]
Masonry debris
Figure 12. Process scheme of the treatment and recycling of masonry debris.
[Mulder et al. 2007]
Mixed C&D waste streams will have to be separated and extensively cleaned up,
in order to gain enough quality to reuse the different fractions. In the Closed
Cycle Construction project the aim was to end up with a decontaminated mineral
aggregate fraction that could be reused in concrete and a decontaminated
combustible fraction that could be used as a fuel in the thermal processes. The
challenge in this respect was to find the right combination of an inexpensive bulk
separation technique and one or more automated sorting techniques for the further
clean-up of the pre-concentrated fractions. Several dry density separation
techniques were investigated experimentally, on a pilot scale. All investigated
separators showed variable but satisfactory efficiency (see [Mulder et al. 2007]).
Figure 13. Three requirements facilitating reuse (Kawano, 1995). [Tam et al.
2007]
To find novel ways for the use of RA/RCA there should be more research to find:
o new ideas for the use of fine RA/RCA and RA/RCA powders in
concrete or other cement based materials (specific grouts and mortars,
self compacting concrete (SCC), etc.),
o methods for RA/RCA quality enhancement
different crushing and rubbing methods, sieving methods and
heat-, washing-, pre-soaking-, acid-, microwave- etc.
treatments) [Nagai 2011 A & B], RA/RCA surface
quality/impregnation/etc. methods,
o methods to improve RA/RCA-concrete quality
novel mix design methods, new mixing methods, use of
additional materials/admixtures,
o use of RA/RCA with other (recycled) materials to produce traditional,
novel or low strength materials, such as filling materials, including
ecological materials without or with minimum amount of cement, use
of RA/RCA with
RESEARCH REPORT VTT-R-05984-12
42 (72)
It must be noticed that the end use requirements, which are based also on
exposure classes, must be different in different countries because of different
climatic circumstances and also because of different national policies and adopted
safety levels. Also, structural concrete must always meet the demands presented
for concrete in prevailing mandatory standards (for concrete EN 206-1 + national
Annex).
6.1 Gypsum/plasterboards
General - landfill and composting
Plasterboard recycling is becoming a key source of raw materials for more and
more plasterboard plants. Plasterboard recycling means that waste that would
RESEARCH REPORT VTT-R-05984-12
44 (72)
otherwise be disposed in landfills now is being recycled and turned into a gypsum
powder that the plasterboard manufacturers can use when making new boards.
A literature review [Brown & Allock 2008] prepared for the Ministry for the
Environment, New Zealand, provides a comprehensive summary of available
information on the viability of composting waste plasterboard generated from
construction sites. Alternative uses for waste plasterboard are also reviewed.
Composting waste plasterboard is assessed to be a viable, low cost option. In the
short term there appears to be no great drawback in developing the composting
option until remanufacturing systems are initiated. Composting waste plasterboard
would be problematic if it is done using an anaerobic process as it would generate
hydrogen sulphide.
The main issue for many recyclers is the problem of contamination in loads. Items
such as metal, bricks, glass and plastic can often be found in supposedly
‘plasterboard only´ loads. This can slow down and even prevent the recycling
process for such material. By taking extra steps to keep loads clean, waste
producers can assist recycling. This applies especially to material produced from
the demolition sector. Anyways, it is also possible to recycle demolition
plasterboards. Contaminants like nails, screws, paper, wall coverings etc. are
removed from the gypsum core, which is crushed into a fine gypsum powder. The
recycled gypsum powder makes up 94% of the plasterboard waste recycled and
can substitute virgin gypsum raw materials at the gypsum consuming industries.
[Plasterboard recycling 2011, Gypsum recycling International 2011, Roy Hatfield
Plasterboard Recycling 2011]
Traditionally the routes for gypsum recycled from plasterboard waste includes:
use in plasterboard manufacture,
cement manufacture and
agriculture
amongst other smaller niche outlets.
Under the existing and future legal provisions for recycling and disposal of waste,
the disposal of gypsum-containing waste is made extremely expensive for the
user. For this reason, the European gypsum industry must demonstrate to its
customers viable alternative and cost-saving disposal routes. The German
Confederation of the Gypsum Industry is currently developing for Germany a
concept for the construction of strategically sited recycling facilities for
plasterboard waste. The plasterboard waste processed in these recycling plants
will be returned to the gypsum industry's production cycles. The Confederation is
also drafting quality specifications for acceptance of recycled gypsum. [Hamm et
al. 2007]
New West Gypsum Recycling developed and patented a process that takes both
wet and dry plasterboard waste from:
Construction and renovation sites;
Gypsum moulds from the manufacture of aeroplane parts, ceramic sanitary
ware and prosthetics
Production waste from plasterboard manufacturers.
This material is delivered to the New West Gypsum recycling facilities, where the
recycling process removes contaminants and the facing paper from the
plasterboard to produce a quality recycled gypsum product.
One of the key requirements for use by plasterboard manufacturers is a low paper
content. Once a low enough content could be demonstrated, the local plasterboard
manufacturers became interested in the product. The paper content within the
recycled gypsum powder product was between 0.5% and 1%, which is considered
non-detrimental for re-use in plasterboard manufacturing. (Figure 16).
RESEARCH REPORT VTT-R-05984-12
46 (72)
UK example protocol
The Quality Protocol applies to the use of recycled gypsum in the following
market applications:
o as a raw material in the manufacturing of new gypsum-based products, e.g.
plasterboard and coving,
o as a soil treatment agent for agricultural benefit, and
o as a raw material in the manufacture of cement. [Quality Protocol 2010]
The contents of the above two documents [Gypsum 2008, Quality Protocol 2010]
are not reviewed here more closely - they are available on the internet (see
References).
Recycled gypsum, which is derived from gypsum waste plasterboard, is one of the
wastes that has recently been used in Japan for ground improvement in different
projects such as embankments and highways [Ahmed & Ugai 2011].
According to the laboratory testing results in [Ahmed & Ugai 2011] the durability
of stabilized soil improved with the increase of both contents of recycled gypsum
and cement. It was concluded that more than 2.5 % of cement content is adequate
to achieve a degree of rigidity for stabilized soil-gypsum specimens to resist the
effect of freeze–thaw and wet–dry actions, as well to prevent the solubility.
[Ahmed & Ugai 2011]
The recycling process accepts mineral wool composite panels from site
demolition or renovation waste, site waste from new build and waste from
manufacturing processes. Scrap steel and mineral wool raw materials are
RESEARCH REPORT VTT-R-05984-12
48 (72)
produced which are suitable for a range of products including, potentially, new
composite panels.
Figure 17. Flow chart illustrating the segregation and recycling process
(Eurobond) [WRAP 2008].
RESEARCH REPORT VTT-R-05984-12
49 (72)
A B
Figure 18. A) Composite panel being fed into a composite panel recycling
machine (Eurobond). B) Separation of mineral wool from steel fraction
(Eurobond) [WRAP 2008].
Lightweight concretes
It has been found that for instance by replacing 10%, 20%, 30% of the coarse
aggregate by solid volume with polystyrene beads, the density of normal
structural concrete reduces from 2455 kg/m3 to 2330, 2210 and 2080 kg/m3,
respectively (Ravindrayah 1999). [Laukaitis et al. 2005]
Recycled polystyrene waste (EPS) as well as blown polystyrene granules can also
be used as the filler for lightweight thermo-insulating foam cement composites. In
a study by Laukaitis et al. (2005) the density of a foam cement composite was 150
–170 kg/m3, while compressive strength was 0.25–0.28 MPa. The highest
composite compressive strength of 0.75 MPa was reached when fine EPS granules
with a density of 275 kg/m3 were used. Thermal conductivity of the composite
depended on its density, the EPS-filler, its sort and amount used. [Laukaitis et al.
2005]
RESEARCH REPORT VTT-R-05984-12
50 (72)
A new recycling process has been developed from the waste EPS foams by using
heat treatment. This technique reduces the volume of waste EPS about 20 times of
the original. Before the heat treatment, the average density, thermal conductivity
and compressive strength of waste EPS foams were 10 kg/m3, 0.0368 W/mK, and
0.12 MPa, respectively. The best result of modification was determined at 130 oC
and 15 min. After the modification, density, thermal conductivity and
compressive strength of waste EPS, increased to 217 kg/m3, 0.0555 W/mK and
8.29 MPa, respectively. This new material, which is obtained after the heat
treatment, is called modified waste EPS (MEPS). MEPS aggregate was used as a
replacement of natural aggregate, at the levels of 0%, 25%, 50%, 75%, and 100%
by volume. The density of MEPS is much less than that of natural aggregate;
MEPS concrete becomes a lightweight concrete with a density of about 900 -
1700 kg/m3. The 28 d compressive strengths of MEPS concrete range from
12.6 MPa to 23.3 MPa, which satisfies the strength requirement of semi-structural
lightweight concrete. [Kan & Demirboga 2009A&B].
Figure 19. PUR foam wastes (left: ‘‘coarse” aggregates, right: ‘‘fine”
aggregates). [Mounanga et al. 2008, Fraj et al. 2010]
These results in [Gadea et al. 2010] confirm that mortar produced with recycled
PUR (Figure 20) is comparable to lightweight mortar made with traditional
materials. It was conclude that it is technically possible to use polymeric foams
from industrial waste materials in the manufacturing of cement-based mortars and
that these could be of use in the building industry. At the same time, these are
environmentally friendly materials that will contribute to sustainable
development.
A B
C
Figure 20. A) Polyurethane foam wastes used, B) basic chemical composition
and C) particle size distribution of sand and PUR foam waste. [Gadea et al. 2010]
RESEARCH REPORT VTT-R-05984-12
52 (72)
The objective of one part of Brite EuRam III project was to determine if crushed
lightweight aggregate concrete (LWAC) can be used as an aggregate in concrete
(recycled LWAC-aggregates) [EuroLightCon 2000].
Aerated concrete can be crushed and used in earth construction. It can also be
used as other lightweight aggregates. Aerated concrete boards can be reused as
recycled products e.g. in single-family houses.
6.6 Wood
Clean, untreated wood can be used to make e.g.
engineered particle board,
re-milled into flooring,
mulch (cover of soil),
compost,
animal bedding and
fuel.
These re-use options are not discussed here in detail.
For all markets, wood contaminated with lead-based paint or wood preservatives
should be removed and managed according to local regulations. [Construction
Business Owner 2007]
RESEARCH REPORT VTT-R-05984-12
53 (72)
As part of the Life project "APPRICOD" (Assessing the Potential for Plastic
Recycling in the Construction and Demolition Activities), funded by e.g. the
European Commission, a workshop was held to address issues such as:
How to optimise the selective collection of plastics from C&D waste?
What are the different plastics involved and how can they be recognized?
What are the requirements for plastic recycling, which plastic fractions can
be collected together?
What are the recycling opportunities and constraints?
What costs and benefits are associated with a selective collection system
for plastic C&D waste ? Is it worth it?
What are the opinions and perspectives from the main stakeholders: C&D
sector, Plastic industry, Recyclers, Local and Regional Authorities, etc.?
What conclusions and recommendations can be made for the future ?
What are the legal, technical and financial needs?
How can the plastic C&D waste issue be integrated into a broader
resource-product-waste approach? [Association of Cities and Regions for
Recycling and sustainable Resource management 2011]
Figure 21. Plastic waste management process by Rebeiz & Craft (1995) [Siddique
et al. 2008].
RESEARCH REPORT VTT-R-05984-12
55 (72)
PVC
PVC waste quantities are projected to increase significantly in the next years. A
major part of PVC is used for long-life products in the construction sector (e.g.
pipes, window frames, floor coverings) which are still in use. Since the large-scale
consumption of PVC started in the 1970s and taking into account the expected
lifetime of 30 years and more, the ”big push” of PVC waste quantities can be
expected to start around 2010. [Plinke et al. 2000]
It is obvious that all the PVC that is being produced will become waste some day.
The European Association of Plastics Converters (EuPC) has estimated the
amount of PVC waste for the periods between 2010 and 2020. Post-consumer
PVC waste (accounting for 88% of all PVC waste) is expected to increase from
3.6 to 6.4 million t per year across the EU. The existing recycling rate for this
waste is very low, at only 3%. This low percentage reflects the high separation
and processing costs required. Figure 22 shows the sources of PVC post-consumer
waste arising now, and in the future. Building products are the biggest source -
pipes and fittings, window profiles, other profiles and cable insulations are the
most important applications here.
It has been often suggested that PVC can be successfully recycled into a variety of
products such as bottles, various pipes, pipe fittings and other profiles with good
appearance and properties. [Sadat-Shojai & Bakhshandeh 2011] Also recycling
rates of PVC have increased steadily in the United States and European countries
since the mid-1980s, as many new recycling programs were developed, for
example Vinyl 2010. [Vinyl 2010]
Several studies have indicated that instability of PVC results in the worse
performance and lower applicability of the recycled material. A number of
solutions to this problem have been proposed as e.g. blending of the recycled PVC
with virgin PVC and/or with other thermoplastics. For example, it is suggested
that at least 40 % and 20 % virgin PVC must be incorporated into the recycled
PVC pipes and recycled window frames, respectively, to produce a high quality
RESEARCH REPORT VTT-R-05984-12
57 (72)
product. However, in practice even this is not happening to any significant degree
(in Germany) [PVC Plastic: a looming Waste Crisis 2011].
Another obstacle for PVC recycling is that old material can contain relatively high
levels of additives, such as lead and cadmium stabilisers and PCBs, which would
contaminate new products in which those additives have been reduced or
eliminated. For this reason, PVC recycling of cables and old windows may be
restricted in countries where these additives are regulated, banned or restricted. A
prime example is Austria, that does not use post consumer PVC windows re-
granulate because of the lead and cadmium content of old windows. More
additives are likely to be classified as hazardous, such as chlorinated paraffins
(OSPAR) and phthalates (Denmark), and this may further restrict the potential for
PVC recycling in future.
Several strategies by which the PVC pipes can economically be recycled to the
products having defined characteristics have been proposed. The most favoured
approach is to assess the possibility of incorporating the recycled PVC pipes into
the virgin pipe grade PVC powder to make a new pipe product. There are good
results on this closed loop recycling of pipes.
Window frames
PVC plastics are also used in the production of window frames. The term “post-
consumer windows” arises from unplasticised window frames of PVC which were
installed in houses about 20- 40 years ago (in Germany) to replace the older
timberframed windows. Although these products, as the first generation of
unplasticised PVC windows, were not absolutely ideal, PVC windows have still
achieved a substantial percentage in the marketplace because of their durability
and low maintenance requirements. For example, annual installation of PVC
windows in Germany is about 10 000 000 units with a market share of 45%.
Currently, the old unplasticised windows frames are being replaced with up-to-
date products known as second-generation frames. The first-generation windows
could be reprocessed and reused in another or the same product. So far, several
technical facilities for fully automatic and clean recycling of post-consumer
windows have been used. Moreover, up to now many commercial projects have
been conducted on this issue. [Sadat-Shojai & Bakhshandeh 2011]
Floorings (PVC)
PVC flooring and roofing materials are also currently being considered in
recycling schemes.
PVC floorings can change during their service life owing to ageing processes.
This can influence recycling methods, such as mechanical recycling and energy
recovery. For example, Yarahmadi et al. (2003) investigated old PVC flooring
materials obtained from three apartment blocks built in 1964, 1971, and 1974.
They studied how the important properties of PVC floorings change during their
service life owing to the ageing processes, and how these can influence their
suitability as post-consumer products for recycling processes such as mechanical
recycling and energy recovery. Their results showed that PVC floorings can be
mechanically recycled in the form in which they were recovered without addition
of any new plasticizer. [Yarahmadi et al. 2003]
RESEARCH REPORT VTT-R-05984-12
58 (72)
It is also shown that the high alkalinity of moist concrete can lead to the
decomposition of the plasticizer when PVC flooring is glued onto it. However, the
degree of decomposition of plasticizer is very small relative to the mass loss by
evaporation, and consequently should not cause any problems for mechanical
recycling. Nevertheless, decomposition products such as butanol and octanol can
cause indoor environmental problems sometimes designated as “sickbuilding
syndrome”. For this reason, gluing directly onto fresh concrete should be avoided.
Gluing also makes mechanical recycling less favourable owing to troublesome
dismantling, and the high degree of contamination from the glue. [Yarahmadi et
al. 2003]
Some of the floor sheets (for example, for using in interior material for railway
vehicle) were layered by vulcanized surface for instance to improve the
appearance. These floor sheets which turn to a thermosetting resin may be
considered as inappropriate material for recycling. In recent years reusing and
recycling of such floor sheets have also been requested. In this long-term stability
has been found to be a necessary factor for practical applications. [Sadat-Shojai &
Bakhshandeh 2011]
Research published on the effect of recycled and waste plastic on the fresh and
hardened properties of concrete is also presented widely in [Siddique et al. 2008].
Plastic wastes:
may be used with some effectiveness as a partial replacement of inorganic
aggregates in concrete applications to decrease the dead weight of
structures – lightweight concretes. The main desired properties are low dry
density and at the same time acceptable compressive strength. Competent
and advanced mix designs are needed.
Recycled plastics can also be used as fibres in concrete. These increase
resistance of concrete to impact and shrinkage cracking, and can also
somewhat enhance the impermeability and de-icer salt scaling resistance.
Discrete reinforcement for concrete can be derived from
o shredded mixed plastic,
o milled mixed plastic particles and
o melt-processed plastic fibres.
The purpose of a study by Jo et al. (2008) was to solve some of the solid waste
problems posed by plastics and concrete demolition. Mechanical properties of
polymer concrete, in particular, polymer concrete made of unsaturated polyester
resins from recycled polyethylene terephthalate (PET) plastic waste and recycled
concrete aggregates, were evaluated. The strength and the resistances to acid and
alkali compounds of the polymer concrete were measured by varying the coarse
and fine aggregate ratio and resin content. [Jo et al. 2008]
[Kou et al. 2009] investigated the effect of replacing river sand by recycled PVC
originated from scraped PVC pipes on the fresh and hardened properties of
lightweight aggregate concretes. Their results showed that the as-produced
concrete in which sand is optimally replaced by recycled PVC (15% by volume)
had lower density, higher ductility, lower drying shrinkage, and higher resistance
to chloride ion penetration. However, according to their results, such concretes
also had some negative side effects such as lower workability, lower compressive
strength and lower tensile splitting strength. [Sadat-Shojai & Bakhshandeh 2011]
PVC composites
PVC applications which contain another material to fulfil their function, but
cannot be separated into pure PVC (so called ´composites´) are only suitable for
such applications where the mixed composition can be tolerated. PVC recycling
operations, covering such products, have also been initiated. [PVC/Sustainability
2011]
RESEARCH REPORT VTT-R-05984-12
60 (72)
Mixed plastics
When homogenous plastics streams are not available, recycling schemes suitable
for mixed plastics, including PVC, may be used. Mixed plastic waste containing
up to 15 percent PVC is not considered to pose technical problems, although the
quality of the recyclate is suitable for a limited number of applications.
PlasticsEurope has studied this subject in depth. The technical report on `The
mechanical recycling of mixed plastics waste', published October 1994, is
available on request. [PVC/Sustainability 2011]
Research projects
There have been many research projects on plastics recycling and reuse. These are
not reviewed here closely. Some scattered information is presented below.
In Finland
Many problems prevent the development of post consumer PVC waste recycling
in Finland (2006). There is no functioning commercial recyclate market for post
consumer PVC. Several reasons explain this situation:
Experiences in pipe collection scheme and other plastics recycling projects
have not been successful. Transporting and gate fees to other European
PVC-recyclers mean high costs.
PVC is scarcely used for packaging as retailers have recommended their
suppliers to reduce its use as much as possible. So, the proportion of PVC
in household waste is low.
There is no use of plastic windows in Finland because of the competition
of wood (which can be found in abundance).
The electric cords removed from the WEEE before treatment are exported
to China for recycling.
Collection costs are high because the country produces only a small
amount of PVC waste on a large area.
RESEARCH REPORT VTT-R-05984-12
61 (72)
Transport costs (particularly for waste exports) are high for the same
reason as above and because distances to mainland Europe are big.
Sorting, treatment and recycling costs are high compared to those of the
Asian countries.
In conclusion, almost all post consumer PVC waste still goes in Finland to landfill
or is exported to China (2006). [Sevenster 2006]
Assorted plastics can be used for the production of granules for plastic industry.
[L&T Suomessa/Raaka-aineiden toimitukset 2011]
In Sweden the total post consumer PVC recycled (year 2004) was 2 675 tonnes
and the number of recycling companies identified was 3.
The availability of free incineration capacity at a lower gate fee (down to €50/t) in
the Northern countries has pushed waste collecting companies to sort less, and a
considerable fraction of mixed rigid plastics was sent to the Far East (year 2009).
In Germany total post consumer PVC recycled in the country (year 2004) was
17 879 tonnes and the number of recycling companies identified was 29. Post
consumer PVC waste collected through pipe, windows and floor-covering
collection systems (AgPR, Rewindo, etc. ) is recycled either on the own sites of
each system or in a small number of recyclers. Most profiles and windows
collected through Rewindo are recycled in a close-loop. The small proportion of
coloured windows (brown) goes generally to the manufacture of window profiles.
If there is no capacity available at converters level, it is used for pipe manufacture
(internal layer). In Germany, low incineration cost has decreased the sorting of
contaminated fractions (year 2009). More and more, only pre-sorted material is
processed. C-level material was exported to the Far East. Large window recyclers
have kept their market position in Germany (year 2009).
In the UK the total post consumer PVC recycled (year 2004) was 13 783 tonnes
and number of recycling companies identified was 20.
In the Netherlands total post consumer PVC recycled (year 2004) was 19 557
tonnes and number of the recycling companies identified was 6. Large tonnages of
windows and profiles are collected in the Netherlands, but they are recycled in
other countries.
In Finland the use of glass in cement based products is minimal, but some
research has already been done (e.g. with micronized glass) also in Finland. More
knowledge, experience and applications are needed. [Shi & Zheng 2007]
The major drawback of glass has been that the alkalis in the cement can react with
the silica in the glass. This alkali-silica reaction (ASR) produces a gel which
swells and can cause the concrete to crack. For this reason the concrete industry
has avoided using glass as an aggregate or binding material, particularly as the
ASR reaction may take several years to manifest itself. However, recent work has
RESEARCH REPORT VTT-R-05984-12
63 (72)
demonstrated that the ASR reaction can be avoided by either using a fine sized
glass aggregate, less than 0.5 - 1 mm, or by suppressing the reaction with
admixtures or using a low alkali cement. [Rajabipour et al. 2010]
Foam glass
Production of foam class started in Finland in early 2011 by Uusioaines Oy. Foam
glass is a special product, that can be used:
in road construction as frost insulation,
as light weight material/fill,
as break for capillarity,
as insulating material (base floors and frost insulation, flat roof insulation).
There are instructions by Uusioaines Oy for flat glass and laminated glass sorting
for recycling (Figure 23) [Uusioaines Oy 2011B]. There can be a small amount
(< 1 cm) silicon or some organic putty beside flat glass. More information can be
found in [Uusioaines Oy 2011C, Suomen Tasolasiyhdistys ry 2011].
Laminated class:
Flat glass:
Figure 23. Instruction for laminated and flat glass sorting [Uusioaines Oy
2011B].
7 Conclusion
The main emphasis in this report is in the use of recycled aggregates/concrete
aggregates (RA/RCA) in concrete.
To find novel, value added and sustainable ways for the use of RA/RCA there
should be more research and innovations. This novel use could include also fine
RA and RA-powders. Methods for RA quality enhancement should also be found,
as well as novel mix design and mixing methods. Use of RA with other materials
to produce traditional, novel or low strength materials, including possibly also
other recycled materials, without or with minimum amount of cement could be a
possibility to widen the use of demolished concrete.
RESEARCH REPORT VTT-R-05984-12
65 (72)
References
Achtemichuk, S., Hubbard, J., Sluce, R. & Shehata, M. H. 2009. The utilization
of recycled concrete aggregate to produce controlled low-strength materials
without using Portland cement. Cement & Concrete Composites, Vol. p. 31, 564–
569.
Chen H.-Ji, Yen, T. & Chen K.-H. 2003. Use of building rubbles as recycled
aggregates. Cement and Concrete Research, Vol. 33, p. 125–132.
Dhir, R., Dyer, T. & Paine, K. 2006. Appropriate use of sustainable construction
materials. Concrete, p. 20 – 24.
EN 1367-4. 2008. Tests for thermal and weathering properties of aggregates. Part
4: Determination of drying shrinkage. 18 p.
EN 933-11. 2011. Tests for geometrical properties for aggregates. Part 11:
Classification test for the constituents of coarse recycled aggregate.
RESEARCH REPORT VTT-R-05984-12
67 (72)
Fathifazl, G., Abbas, A., Razaqpur, A. Isgor, O. B., Fournier, B. & Foo, S. 2009.
Mixture Proportioning Method for Concrete Made with Coarse Recycled
Concrete Aggregate. J. Mat. in Civ. Engineering. Volume 21, Issue 10, p. 601-
611.
Fathifazl, G., Razaqpur, A. G., Isgor, O. B., Abbas, A., Fournier, B. & Foo, S.
2010. Shear strength of reinforced recycled concrete beams with stirrups.
Magazine of Concrete Research, Vol. 62, No. 10, p. 685–699.
Gadea, J., Rodríguez, A., Campos, P. L., Garabito, J. & Calderón, V. 2010.
Lightweight mortar made with recycled polyurethane foam. Cement & Concrete
Composites , Vol. 32, p. 672–677.
Gypsum. 2008A. Technical report on the production and use of gypsum from
waste plasterboard. Waste & Resources Action Programme (WRAP) &
Environment Agency UK 28 p. < http://www.environment-
agency.gov.uk/static/documents/Business/Technical_report_for_gypsum_.pdf .>
Hamm, H., Huller, R., & Demmich, J. 2007. Recycling of plasterboard. ZKG
International ,Vol. 60 Iss. 5, p. 68 – 74.
Hansen C. 1990. Recycled concrete aggregate and fly ash produce concrete
without strength Cement. Cement and Concrete Research Vol. 20, No. 3, p. 355–
356.
Jo, B.-W., Park, S.-K. & Park, J.-C. 2008. Mechanical properties of polymer
concrete made with recycled PET and recycled concrete aggregates. Construction
and Building Materials, Vol. 22, p. 2281–2291.
Kasai, Y. 2004. Recent trends in recycling of concrete waste and use of recycled
aggregate concrete in Japan. Julkaisussa: ACI SP-219, Recycling concrete and
other materials for sustainable development, Ed. Liu, T. C. & Meyer, C. p. 11 –
34.
Katz, A. 2003. Properties of concrete made with recycled aggregate from partially
hydrated old concrete. Cement and Concrete Research, Vol. 33, p. 703-711
Kou, S.-C., Lee G., Poon, C. S. & Lai, W. L. 2009. Properties of lightweight
aggregate concrete prepared with PVC granules derived from scraped PVC pipes.
Waste Manage, Vol. 29, p. 621-628.
Lay, J. 2009. Current technical issues for aggregates. Concrete, July 2009, p. 14 –
16.
Lin, K. L., Wu, H. H., Shie, J. L., Hwang C. L. & Cheng, A. 2010. Recycling
waste brick from construction and demolition of buildings as pozzolanic
materials. Waste management & research, Vol. 28, Iss. 7, p. 653-659.
Meyer, C., Egosi & Andela, C. 2001. Concrete with waste glass as aggregate.
“Recycling and Re-use of Glass Cullet”, ed. Dhir, Dyer & Limbachiya.
Proceedings of the International Symposium Concrete Technology Unit of ASCE
and University of Dundee, March 19-20, 2001. <
http://www.seas.columbia.edu/earth/wtert/sofos/meyer_egosi_paper.pdf > Visited
15.8.2011
Mounanga P., Gbongbon W., Poullain P. & Turcry, P. 2008. Proportioning and
characterization of lightweight concrete mixtures made with rigid polyurethane
foam wastes. Cement & Concrete Composites, Vol. 30, p. 806–814.
Mulder, E., Tako P.R. de Jong & Feenstra, L. 2007. Closed Cycle Construction:
An integrated process for the separation and reuse of C&D waste. Waste
Management, Vol. 27, p. 1408–1415.
Nagai, H. 2011 A. Concrete recycling. Past, Present and Future. Slide series (not
published), 33 p.
Nagai, H. 2011 B. Recycling concrete and gypsum in Japan. Slide series (not
published), 36 p.
Poon, C. S., Shui, Z. H. & Lam, L. 2004 (B). Effect of microstructure of ITZ on
compressive strength of concrete prepared with recycled aggregates. Construction
and Building Materials, Vol. 18, p. 461-468.
Poon, C. S., Shui, Z. H., Lam, L., Fok, H. & Kou, S. C. 2004 (A) Influence of
moisture states of natural and recycled aggregates on the slump and compressive
strength of concrete. Construction and Building Materials, Vol. 34, p. 31-36.
Project LIFE APPRICOD. 2011. Plastic waste generated by the construction and
demolition activities. <
http://www20.gencat.cat/portal/site/arc/menuitem.60fb2478680e61fd624a1d25b0
c0e1a0/?vgnextoid=f43cb243f43b6210VgnVCM1000008d0c1e0aRCRD&vgnext
channel=f43cb243f43b6210VgnVCM1000008d0c1e0aRCRD&vgnextfmt=default
&newLang=en_GB > Visited 15.8.2011
Progress Report 2010. Reporting on the activities of the year 2009. The European
PVC Industry's Sustainable Development Programme. 44 p.
Quality Protocol. 2010. Recycled gypsum from waste plasterboard. End of waste
criteria for the production and use of recycled gypsum from waste plasterboard.
Waste & Resources Action Programme (WRAP) & Environment Agency UK,
15 p. http://www.environment-
agency.gov.uk/static/documents/Leisure/100119PM_W524GypsumFINAL.pdf
Shi, C. & Zheng, K. 2007. A review on the use of waste glasses in the production
of cement and concrete. Resources, Conservation and Recycling , Vol. 52, p. 234–
247.
Siddique, R., Khatib, J. & Kaur, J. 2008. Use of recycled plastic in concrete: A
review. Waste Management, Vol. 28, p. 1835–1852.
Uusioaines Oy. 2011B. Laminoidun lasin lajittelu & Tasolasin lajittelu. <
http://kotisivukone.fi/files/uusioainesoy.kotisivukone.com/tasolasinlajitteluohjeet
2011.pdf > Visited 15.8.2011
Xiao, J. Z., Li, J. B. & Zhang, C. 2006. On relationships between the mechanical
properties of recycled aggregate concrete: An overview. Materials and Structures,
Vol. 39, No.7, p. 655–664.