ME 525 Example Problem: Mixture Fraction Relations For A Nonpremixed N-Hexane/air Flame

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ME 525 Example Problem: Mixture Fraction Relations for a Nonpremixed n-Hexane/air

Flame

A nonpremixed n-hexane (C6H14) jet flame is stabilized with an annular co-flow of dry air.
Laser diagnostics are used to make point measurements of temperature and the mole fractions of
the following species: C6H14, CO2, CO, H2O, H2, OH, O, H, O2, N2, and CH3. Calculate the
value of the stoichiometric mixture fraction and develop an expression for the value of the
mixture fraction at a particular measurement point as a function of the measured mole fractions.

For stoichiometric n - hexane / air combustion :


C6 H14  9.5 O2  35.72 N 2  6 CO2  7 H 2O  35.72 N 2

mass originating from fuel stream


f 
mass of mixture
 YC  YH ( for HC fuels, no air or diluent in fuel stream)

f is the same on the product and reactant sides for the mixture
g g
MWH  1.008 MWC  12.011
gmol gmol
g g
MWO  16.00 MWN  14.007
gmol gmol
Consider reactant side :
6 MWC
YC 
6 MWC  14 MWH  19 MWO  71.44 MWN
6 12.011
YC 
6 12.011  14 1.008   19 16.00   71.44 14.007 
72.060
YC   0.05181
1390.8

14 MWH
YH 
6 MWC  14 MWH  19MWO  71.44 MWN
14 1.008 
YH   0.01015
1390.8

f stoich  YC  YH  0.06196
At the measurement locations,
1
 6 MWC 14 MWH  MWC MWC 2 MWH
f  YC6 H14     YCO2  YCO  YH 2O
 MWC H MWC6 H14  MWCO2 MWCO MWH 2O
 6 14 
1
2MWH
1
MWH MWH
1
 MWC  3MWH 
YH 2  YOH  YH  YCH3  
MWH 2 MWOH MWH  MWCH3 

MWC MWC 2 MWH MWH


f  YC6 H14  YCO 2  YCO  YH 2O  YH 2  YOH  YH  YCH3
MWCO2 MWCO MWH 2O MWOH

In terms of mole fractions :


xi MWi
Yi  MWmix   xi MWi
MWmix i

f   xC6 H14  6 MWC  14 MWH   xCO2 MWC  xCO MWCO  xH 2O 2 MWH  xH 2 2 MWH  xOH MWH
 xH MWH  xCH3  MWC  3MWH   MWmix

f 
  
MWC 6 xC6 H14  xCO2  xCO  xCH3  MWH 14 xC6 H14  2 xH 2O  2 xH 2  xOH  xH  3 xCH3 
MWmix

MWmix  xC6 H14 MWC6 H14  xCO2 MWCO2  xCO MWCO  xCH3 MWCH3  xH 2O MWH 2O
 xH 2 MWH 2  xOH MWOH  xH MWH  xO MWO  xN 2 MWN 2  xO2 MWO2

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