PSy Formula
PSy Formula
PSy Formula
Lars Olander
Foreword
This publication has been compiled because I have missed such a publication. Naturally
this means that the selection has been influenced by my views. However, in most cases I
have included a formula rather than exclude it. To make the number of pages limited
the explanations are as short as possible. The result is that this formula compilation can
not be used as a text book but only as a reference book or as a guideline to the literature
in one specific field.
For this, the third edition (in English) dr. techn. Y. Jin has done a lot of work to check
and complete formulas and literature references. I have not had the opportunity to make
the formulas available in a form direct usable for computers. To make calculations it is
necessary to transfer actual formula to a suitable program. To facilitate using and
searching in this compilation a diskette with all the formulas is included. The formulas
are there written in WordPerfect 5.1 (DOS/Windows).
This revised version has been transferred to Word (Microsoft © Word 97), probably the
Equation Editor must be installed to read the formulas. Since the equation editors in
Word and WordPerfect do not agree on how to treat different symbols, there could be
some difficulties with differentiating some symbols.
ii
Contents
Page nr
Introduction 1
3 Flow generation 26
3.1 Theoretical total pressure change for fans 26
3.2 Flow variations for fans 27
3.3 Pressure variations for fans 27
3.4 Power dependence for fans 27
3.5 Efficiency for fans 27
3.6 Air flow rate through critical orifice 27
3.7 Temperature increase of air in fans and ducts 29
iii
4.2 Laminar flow (Re <2300), smooth pipes 32
4.3 Turbulent flow (Re <80000), smooth pipes 32
4.4 Turbulent flow, smooth pipes, Prandtl's universal velocity distribution 32
4.5 Turbulent flow, rough pipe 33
4.6 Turbulent flow, transition smooth - rough pipes after Colebrook 33
4.7 Velocity distribution, laminar flow 34
4.8 Velocity distribution, turbulent flow 34
4.9 Cirkular and rectangular ducts with identical properties 35
4.10 Boundary layer thickness for pipe flow 35
4.11 Heat transfer in pipes 36
4.12 Deposition of particles in ducts with turbulent flow 38
4.13 Leakage from flexible ducts 38
4.14 Leakage from ducts 38
4.15 Ducts not made of sheet metal 39
5 Measuring 40
5.1 Pitot tube use in circular ducts 41
5.2 Orifice plate 42
5.3 Correction for pressure drop when measuring flow rate through terminal device43
5.4 Rotameter 43
5.5 Bag method 44
5.6 Tracer gas measurements 45
5.7 Kata thermometer 46
5.8 Hot wire anemometer 47
5.9 Sampling of aerosols in ducts 47
5.10 Sampling of aerosols in calm air 48
5.11 Tests of laboratory fume hoods 49
6 Air jets 51
6.1 Circular, isothermal free jets' velocity distribution and flow rate - after Baturin52
6.2 Circular, isothermal free jets' velocity distribution and flow rate - after Nielsen52
6.3 Plane, isothermal free jets' velocity distribution and flow rate - after Baturin 53
6.4 Plane, isothermal free jets' velocity distribution and flow rate - after Nielsen 54
6.5 Circular (radial) isothermal jets' velocity distribution - after Nielsen 54
6.6 Flow rate in jets - after Eck 55
6.7 Velocity distribution across plane, isothermal free jet 56
6.8 Velocity distribution across circular and plane isothermal free jet 56
6.9 Temperature and concentration distribution along and across free jets 56
6.10 Temperature distribution along circular free jet - after Baturin 57
6.11 Temperature distribution along plane jet 58
6.12 Temperature change for cold, free jet 58
6.13 Velocity and temperature decrease for vertical rising jets and bouyant plumes 58
6.14 Vertical air jets' throw lengths in room and horisontal jets' change of height 60
7 Contaminant generation 62
7.1 Solubility of gases in liquids 66
7.2 Evaporation from horisontal surfaces 68
iv
7.3 Evaporation from liquid baths 71
7.4 Evaporation from water baths 71
7.5 Evaporation from water surfaces 72
7.6 Evaporation from surfaces 73
7.7 Evaporation from open vessels 74
7.8 Leakage from vessels and pipes under pressure 75
7.9 Heat generation from electrical motors to the surroundings 75
7.10 Fibre generation from new fibre filters 76
7.11 Ozon generation from electrostatic filters 76
7.12 Corrosion of ducts 77
7.13 Vaporization of additives from plastic folie (PVC) 77
7.14 Vaporization of F-11 from polyurethan plates 77
7.15 Grinding machines 77
7.16 Falling powders' dust generation 79
7.17 Air flow generated by falling powder 80
7.18 Dust generation from pressure vessels containing powder 80
7.19 Particle generation from gas shielded welding 81
7.20 Airborne droplets from release of liquids under pressure 81
7.21 Vaporization of oil spill 81
7.22 Vaporization of organic solvents from water surfaces 83
7.23 Evaporation of solvents 84
7.24 Evaporation of liquid spills 94
8 Heat and contaminants from man 95
8.1 Man's heat balance 96
8.2 Fanger's comfort equation 96
8.3 Perception of thermal climate 97
8.4 Perception of heat 98
8.5 Perception of draught 99
8.6 Particle generation from man 100
8.7 Contaminant generation from man 101
8.8 Heat losses at low temperatures 101
9 Contaminants 102
9.1 Contaminants in rooms 103
9.2 Particle deposition on surfaces 103
9.3 Ozone in rooms 104
9.4 Resuspension 104
9.5 Permeability of water vapor through color layers 104
9.6 Heights of welding plumes in stable conditions with temperature gradient 105
9.7 Life-times for water drops 106
9.8 Vaporization of drops in air 106
9.9 Diesel exhausts in mines 107
v
10.4 Time dependent total mixing with incoming concentration 110
10.5 Ozone in room with copying machines 110
10.6 Concentration in rooms of Radon (222) 111
10.7 Concentration in rooms of Thoron (Rn 220) 111
10.8 Radon concentration in room 112
10.9 Time dependent contaminant generation 112
10.10 Ideal mixing, separate recirculation system, separate local exhaust with outlet
outside the room and with capture efficiency α 113
10.11 Age of air 115
10.12 Tracer gas measurements 115
10.13 Ventilation efficiency, definition 116
10.14 Air exchange efficiency, definition 116
10.15 Transport efficiency for air cooling systems - ATF 116
vi
14 Convective flow rates and velocities 134
14.1 Criteria for draught (Rydberg) 135
14.2 Cold draught from windows 135
14.3 Air velocities from cold draught 136
14.4 Heat exchange between room air and surfaces I 137
14.5 Heat exchange between room air and surfaces II 138
14.6 Heat exchange between room air and vertical, plane surfaces 138
14.7 Heat transfer from different surfaces through bouyancy 138
14.8 Natural ventilation 140
14.9 Influence of wind velocity and temperature difference on natural ventilation 141
14.10 Air velocity in plume above point heat source 141
14.11 Air flow rate in plume above point heat source 141
14.12 Air flow rate in plumes above hot sources 142
14.13 Air flow rate at upper edge of vertical surface of hot body 142
14.14 Air flow rate into hood close above heat source 143
14.15 Air flow rate into hood above heat source 144
14.16 Air flow rate above horizontal surface 144
vii
17.2 Exhausts of hot gases from smoke stacks (Oak Ridge model) 168
17.3 Exhausts of cold gases from smoke stacks (Sutton's model) 168
17.4 Concentration from exhaust of cold gas from smoke stacks 168
17.5 Lowest exhaust height 169
17.6 Demands on dilution of exhausts from buildings 169
17.7 Exhausts from roof or on lee-side 170
17.8 Concentrations from exhausts 171
17.9 Velocity and concentration distribution for bouyant plumes in homogenous
surroundings 171
17.10 Particle transport in convection plumes 172
17.11 Dispersion of traffic contaminants 174
17.12 Road tunnel ventilation 175
18 Summary 176
viii
Introduction
The introduction has not been translated since it only dscribes the reason for the
compilation of these formulas. It also describes why certain areas are not covered in this
report. Since the introduction is included in the Swedish version, anyone interested
could look there.
Charlesworth PS: Air exchange rate and airtightness measurement techniques - An application
guide. International Energy Agency, Air Infiltration and Ventilation Centre, Coventry, 1988.
Lide DR (Ed.): CRC Handbook of Chemistry and Physics. 73th edition. 1993.
Perry RH, Green DW and Maloney JO (Eds): Perry's Chemical Engineer's Handbook. 6th
edition. McGraw Hill, New York 1984.
Rohsenow WM and Hartnett JP (Ed.): Handbook of Heat Transfer, McGraw Hill, New York
1973.
Text books
1
Basic theory and measurements
Beckwiht TG, Marangoni RD, and Lienhard JH: Mechanical Measurements (5th edition),
Addison-Wesley, New York 1993.
Bird RB, Steward WE and Lightfood EN: Transport Phenomena, Wiley & Sons, New York
1960.
Doebelin EO: Measurement systems - Application and design. McGraw-Hill, New York,
1966.
Schlichting H: Boundary-Layer Therory (7th editon), McGraw Hill, New York 1979.
Alden L, Kane JM: Design of Industrial Ventilation Systems. 5th edition. Industrial Press,
New York 1982.
Burgess WA, Ellenbecker MJ, Treitman RD: Ventilation for control of the work environment.
John Wiley & Sons, New York 1989.
Dorman RG: Dust Control and Air Cleaning. Pergamon Press, Oxford 1974.
Goodfellow, H.D. (Ed.): Ventilation '85. Proceedings of the 1st International Symposium on
Ventilation for Contaminant Control, October 1-3 1985, Toronto, Canada. Elsevier,
Amsterdam 1986
Heinsohn RJ: Industrial Ventilation. John Wiley & Sons, New York 1991.
Hemeon WCL: Plant and process ventilation. The Industrial Press, New York 1963.
Hughes, R.T., Goodfellow, H.D., Rajhans, G.S. (Eds): Ventilation '91. Proceedings of the 3rd
International Symposium on Ventilation for Contaminant Control, September 16-20, 1991,
2
Cincinnati, Ohio, USA. American Conference of Governmental Industrial Hygienists,
Cincinnati, Ohio USA 1993.
Jansson, A., Olander, L. (Eds): Ventilation '94. Proceedings of the 4th International
Symposium on Ventilation for Contaminant Control, held in Stockholm, September 5-9,
1994. Arbete och HΣlsa 1994:18 (2 vols). National Institute of Occupational Health, Solna,
Sweden 1994.
Licht W: Air Pollution Control Engineering. 2nd Ed. Marcel Dekker, New York 1988.
McDermott HJ: Handbook of Ventilation for Contaminant Control. Ann Arbor Science 1976.
McQuiston FC and Parker JD: Heating, Ventilating and Air Conditioning - Analysis and
Design (3rd edition), John Wiley & Sons, News York 1988.
Mⁿrmann H: Lufttechnische Anlagen für gewerbliche Betriebe. Carl Marhold, Berlin 1980.
Aerosols
A bibliography of Aerosol Science and Technology. Aerosol Science and Technology, vol.14,
sid 1-4, 1991.
Calvert S, Englund HM (Eds): Handbook of Air Pollution Technology, John Wiley & Son,
New York 1984.
Friedlander SK: Smoke, Dust and Haze Fundamentals of Aerosol Behavior. Wiley-
Interscience, New York 1977.
Fuchs NA: The Mechanics of Aerosols. Pergamon Press 1964. (Reprint Dover 1989)
Heskett HE: Fine Particles in Gaseous Media. 2nd Ed. Lewis Publishers, Michigan 1986
3
Liu BYH (Ed.): Fine particles. Aerosol Generation, Measurement, Sampling and Analysis.
Academic Press, New York 1976.
Liu BYH, Pui DYH, Fissan HJ (Eds): Aerosols. Science, Technology and Industrial
Applications of Airborne Particles. First International Conference, Elsevier 1984.
Marple VA, Liu BYH (Eds): Aerosols in the Mining and Industrial Work Environments. 3
Vol. Ann Arbor Science 1983.
Willeke K, Baron PA (Eds): Aerosol Measurement. Van Nostrand Reinhold, New York 1993.
4
1 Properties of air and water vapor
This chapter includes some properties dependence of pressure, temperature, humidity etc and
data for the most important properties for air and water vapor. First is the ideal-gas law (1),
which is usable for air at normal temperatures. For extreme pressures or temperatures an
equation of state (2) can be used. For ideal gases there exist a number of connections (3),
which can be used for air. Some properties variation with temperature are presented in 4. In 5
are given figures for air and in 6 for water and water vapor. For water vapor can the ideal-gas
law be used for approximative calculations (1). If more accurate values are needed an equation
of state is used (7,8). Mixtures of air and water vapor are frequent and formulas are presented
in 9. In 11 and 12 are formulas to be used when measuring water vapor in air. In 10 are some
formulas for the variation of heat content with temperature and humidity. Air pressure
variation with height are given in 13. Some equations for connection between contaminant
concentration and sight length end this chapter (14).
If the pressure is not given or if it is not a part of the formulas, normal pressure i.e. 1.013 bar
(=101.3 kPa) is presumed.
5
1.1 The Ideal-Gas Law
m
p • v = R • T or p • V = n • R • T or p • V = •R • T
M
p = pressure
v = molecular volume
R = gas constant (8,31441 J/mol,K = 1,9872 cal/K,mol =
0,08205 lit,atm/K,mol = 62,4 lit,mm Hg/K,mol)
T = absolute temperature
V = volume
n = number of mols
m = mass
M = molecular weight.
(Normally used for air, also when some water vapor or contaminants are present.)
p = pressure, atm
v = molecular volume, lit/mol
R = gas constant 0,08205 lit╖atm/mol╖K
T = temperature, K.
(To be used at extreme pressures or temperaturs, or when more accurate values than
from (1) are needed).
a = κ •p / ρ = κ •R•T
6
κ = isentrop exponent = Cp/Cv
ρ = density
R, T, p see 1.2.
b)
T
η = 150,3 • 108 •
123,6
1+
T
c) Another expression is
3/ 2
η = 1.45 • 106 • T
T + 110
η = viscosity, kg/m,s
T = temperature, K.
d)
3
η T 2 + 110
= ( ) • T0
η 0 T0 T + 110
η = viskosity at temperature T
η0 = viskosity at temperature T0.
e) In small intervals this can be simplified to
7
ω
η T
=( )
η 0 T0
f)
1.80
805 T
D (H 2 O in air) = •( )
p T0
1.80
T
D = 0.216 • ( ) (cm2 /s)
273
2.5
0.926 T
D=( )•( )
p T + 245
8
1.5 Air properties (at 100 kPa)
Molecular weight M = 28.962458 g/mol
Density at 0°C (dry air) ρ = 1.2929 kg/m3
at 15°C, 0% R.H, 105 Pa 1.2094 kg/m3
at 15°C, 50% R.H, 105 Pa 1.2055 kg/m3
at 15°C, 100% R.H, 105 Pa 1.2017 kg/m3
at 20°C, 0% R.H, 105 Pa 1.1887 kg/m3
at 20°C, 50% R.H, 105 Pa 1.1834 kg/m3
at 20°C, 100% R.H, 105 Pa 1.1783 kg/m3
Heat conductivity at 18°C λ = 0.025 W/m╖°C
Specific heat capacity at 0°C Cp = 1.00 kJ/kg,°C
Cp = 29.0 kJ/kmol,K
Viscosity at 0°C η = 17.0 ⋅ 10-6 kg/s,m
Viscosity at 20°C η = 18.192 ⋅ 10-6 kg/s,m
Critical temperature Tc = 132.5 K
Critical pressure Pc = 36 bar
Melting point Ts = 60.1 K
Boiling point Tk = 80.2 K
Density at boiling point ρ = 880 kg/m3
N2 78.084 vol %
O2 20.946 "
Ar 0.934 "
CO2 0.033 " (variabel)
Ne 18.18 ppm
He 5.24 "
Kr 1.14 "
H2 0.5 "
Xe 0.087 "
CH4 2 "
N2O 0.5 "
O3 0.01 " (variabel)
Rn 6 ⋅10-14 " (variabel)
η π
l= •
I 8• ρ • P
9
I = constant = 0.4987445.
1.6 Water properties (at 100 kPa)
Molecular weight M = 18.0152 g/mol
Density at 0°C ρ = 999.84 kg/m3
at 20°C = 998.205 kg/m3
Heat conductivity at 20°C λ = 0.598 W/m,°C
Specific heat capacity at 0°C Cp = 4.218 kJ/kg,K
at 20-100°C Cp = 4.18 kJ/kg,K
Viscosity at 0°C η = 1792⋅10-6 kg/s,m
at 20°C = 1002⋅10-6 kg/s,m
Melting point ts = + 0°C
Melting heat Qs = 334 kJ/kg
Boiling point tk = + 100°C
Vaporization enthalpy Qk = 2257 kJ/kg
Density at boiling point (1.013 bar) ρ = 958.35 kg/m3
Critical temperature Tc = 647.4 K
Critical pressure Pc = 221.3 bar
ν 0.616 (0° C)
Sc = ={
D 0.617 (20° C)
Sc
Le = = 0.866 (0 − 20° C)
Pr
5.454 • 106
(p + 2
) • (v 30.42) = R • T
v
p in atmospheres
v in cm3/mol
10
T in K
R = 82.054 atm,cm3/mol,K.
T
x =1 −
647 . 3
T = temperature, K
pvp = vapor pressure, bar.
1.9 Mixture of air and water vapor: Density and vapor pressure
a)
P p
ρ = 0.465 ( ) − 0.176 ( v )
T T
273.13 P − 0.3783 • pv
ρ = ρt • •
T 760
x
pv = 18 • 1013
1 x
+
29 18
11
(If 1013 is changed to 760 the partial pressure is expressed in mm Hg.)
c)
ρ = ρ t • (1 + x)
pv
x = 0 . 622 •
P − pv
d)
td
x = 4.8 • 10 3 • 10 38
The partial pressure of water vapor for a specific dew point can be calculated by using
dew point temperature instead of air temperature in e or f.
273.16 T
log ( pm ) = 10.79586 • 1 − − 5.02808 log
T 273.16
+ 1.50474 • 10− 4 • 1 − 10 −8.29692 • 273.16 − 1 +
T
+ 0.42873 • 10−3 • 104.76966 • 1 − T − 1 + 0.78613974
273.16
273 . 16 273 . 16
log ( pm ) = − 9. 096936 − 3. 56654 • log
T T
T
+ 0. 876817 • 1 − + 0. 78613974
273 . 16
12
g)
−2
pm = 0.62796 • e6.5557 • 10 •t
(0 − 26 ° C)
h)
−2
pm = 0 . 83721 • e5. 4169 • 10 •t
(26 − 50 ° C)
pf (b • ∆ t / 1510)
ϕ=
ps
h = t • Cp + t • x • Cp (H 2 O) + x • r
13
b)
h = t + (2500 + 1.9 • t) • x
2 Calculate absolute humidity for saturated state (xm with 1.9.c). (Put pσ = pm and xm is
the result.)
1.005 ( t v − t t ) + x m • (2 . 27 • t v − 2500)
x= for t x > 0 ° C
4 .19 • t v − 1 . 86 • t t − 2500
or from
1 , 005 ( t t − t v) + x m • (0 . 25 • t v − 2833)
x= for t t ≤ 0 ° C
2 .11 • t v − 1 . 86 • t t − 2833
Dew point, partial pressure and density is calculated by using equations 1.9.d and
1.9.b.
If the starting point is relative humidity instead of the wet temperature the following
calculations are done:
1 Calculate the saturation pressure for water vapor (pm) with 1.9.e.
14
ϕ • pm
pv =
100
3 Calculate absolute humidity for the saturated state (xm) with 1.9.c.
pv • x m
x=
pm
p v = pm − P • A • ( t t − t v )
−4
p = 101 . 86425 • e − 1. 24087 • 10 •h
(0 − 1524 m)
−4
p = 102 . 12563 • e − 1. 25184 • 10 •h
(1525 − 3048 m)
15
p = barometric pressure, kPa
h = height over sea level, m.
M = 3 . 8 • 105 • σ 0.55 µ m
1 .8 • 106
M=
L
L = sight length, m
M = contaminant concentration, µg/m3.
C = 0 . 20 • σ 0.55 µ m
16