CYCLOHEXANOL FOR SYNTHESIS MSDS

CAS-No.: 108-93-0 MSDS

MATERIAL SAFETY DATA SHEET (MSDS)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Substance
:
EC Index-No. : 603-009-00-3
EC-No. : 203-630-6
CAS-No. : 108-93-0
Product code : 00085

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : Laboratory chemicals

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

LOBA CHEMIE PVT.LTD.
107 Wode House Road, Jehangir Villa, Colaba
400005 Mumbai - INDIA
T +91 22 6663 6663 - F +91 22 6663 6699
[email protected] - www.lobachemie.com

1.4. Emergency telephone number

Emergency number : + 91 22 6663 6663 (9:00am - 6:00 pm)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (inhal.), H332
Category 4
Acute toxicity (oral), H302
Category 4
Skin corrosion/irritation, H315
Category 2
Specific target organ H335
toxicity — Single
exposure, Category 3,
Respiratory tract irritation

Full text of H statements : see section 16

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Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Xn; R20/22
Xi; R37/38
Full text of R-phrases: see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS07
Signal word (CLP) : Warning
Hazard statements (CLP) : H302+H332 - Harmful if swallowed or if inhaled
H315 - Causes skin irritation.
H335 - May cause respiratory irritation.
Precautionary statements (CLP) : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substances
Name : CYCLOHEXANOL For Synthesis
CAS-No. : 108-93-0
EC-No. : 203-630-6
EC Index-No. : 603-009-00-3

Full text of R- and H-statements: see section 16

3.2. Mixtures
Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.

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First-aid measures after skin contact : Wash with plenty of water/…. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical advice/attention. Specific treatment (see supplemental
first aid instruction on this label).
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER/doctor if you feel unwell.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause respiratory irritation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after ingestion : Harmful if swallowed.

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use extinguishing media containing water.

5.2. Special hazards arising from the substance or mixture

No additional information available

5.3. Advice for firefighters

Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel
Emergency procedures : Avoid contact with skin and eyes.

6.1.2. For emergency responders

Protective equipment : Use personal protective equipment as required.
Emergency procedures : Stop release.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Clean up immediately by sweeping or vacuum. Clean contaminated surfaces with an
excess of water.

6.4. Reference to other sections

No additional information available
SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-
ventilated area.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands, forearms and face
thoroughly after handling.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store in a
dry place.

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7.3. Specific end use(s)

No additional information available
SECTION 8: Exposure controls/personal protection

8.1. Control parameters

No additional information available

8.2. Exposure controls

Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Molecular mass : 100.16 g/mol

Colour : Clear Colorless.

Odour : camphor / menthol odor.

Odour threshold : No data available

pH : 6.5 at 40 g/l at 20 °C

Relative evaporation rate (butylacetate=1) : 0.08

Melting point : 20 - 22

Freezing point : No data available

Boiling point : 160 - 161

Flash point : 68 °C

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapour pressure : 1.31 mm Hg at 25 °C

Relative vapour density at 20 °C : 4.01

Relative density : No data available

Density : 0.948 g/cm³

Solubility : Water: 4 g/100ml @ 200C

Log Pow : 1.25 at 25 °C

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Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : No data available

Explosive limits : 0.0125 - 0.1225 vol %

9.2. Other information

No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
No additional information available

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No additional information available

10.4. Conditions to avoid

Direct sunlight. Heat. Open flame. Overheating.

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

No additional information available

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Inhalation: Harmful if inhaled. Oral: Harmful if swallowed.

Skin corrosion/irritation : Causes skin irritation.

pH: 6.5 at 40 g/l at 20 °C
Serious eye damage/irritation : Not classified
pH: 6.5 at 40 g/l at 20 °C
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : May cause respiratory irritation.

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

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Potential adverse human health effects : Harmful if swallowed.

and symptoms

SECTION 12: Ecological information

12.1. Toxicity
No additional information available

12.2. Persistence and degradability

No additional information available

12.3. Bioaccumulative potential

CYCLOHEXANOL For Synthesis (108-93-0)
Log Pow 1.25 at 25 °C

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

12.6. Other adverse effects

No additional information available
SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product/Packaging disposal : Dispose of contents/container to hazardous or special waste collection point, in
recommendations accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

14.1. UN number
UN-No. (ADR) : Not applicable
UN-No. (IMDG) : Not applicable
UN-No. (IATA) : Not applicable
UN-No. (ADN) : Not applicable
UN-No. (RID) : Not applicable

14.2. UN proper shipping name

Proper Shipping Name (ADR) : Not applicable
Proper Shipping Name (IMDG) : Not applicable
Proper Shipping Name (IATA) : Not applicable
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable

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14.3. Transport hazard class(es)

ADR
Transport hazard class(es) (ADR) : Not applicable

IMDG
Transport hazard class(es) (IMDG) : Not applicable

IATA
Transport hazard class(es) (IATA) : Not applicable

ADN
Transport hazard class(es) (ADN) : Not applicable

RID
Transport hazard class(es) (RID) : Not applicable

14.4. Packing group

Packing group (ADR) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable

14.5. Environmental hazards

Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport
No data available

- Transport by sea
No data available

- Air transport
No data available

- Inland waterway transport

No data available

- Rail transport
No data available

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

No REACH Annex XVII restrictions

CYCLOHEXANOL For Synthesis is not on the REACH Candidate List
CYCLOHEXANOL For Synthesis is not on the REACH Annex XIV List
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15.1.2. National regulations

Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV;
ID No. 240)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV

Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de : The substance is not listed
voortplanting giftige stoffen – Borstvoeding
NIET-limitatieve lijst van voor de : CYCLOHEXANOL For Synthesis is listed
voortplanting giftige stoffen –
Vruchtbaarheid
NIET-limitatieve lijst van voor de : The substance is not listed
voortplanting giftige stoffen – Ontwikkeling

Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product

15.2. Chemical safety assessment

No additional information available

SECTION 16: Other information

Full text of R-, H- and EUH-statements:

Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Skin Irrit. 2 Skin corrosion/irritation, Category 2
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H302 Harmful if swallowed.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
R20/22 Harmful by inhalation and if swallowed
R37/38 Irritating to respiratory system and skin
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Xi Irritant
Xn Harmful

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and
environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

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