Safety Data Sheet

MAPEFLEX PS SL COMP B
Safety Data Sheet dated: 15/04/2021 - version 1
Date of first edition: 15/04/2021

1: Identification
GHS Product Identifier
Mixture identification:
Trade name: MAPEFLEX PS SL COMP B
Trade code: 9019388
Recommended use of the chemical and restrictions on use
Recommended use: Sealant
Uses advised against: Data not available
Supplier's details
Company: MAPEI CONSTRUCTION CHEMICALS L.L.C
P.O. BOX 73869 DUBAI - United Arab Emirates
Responsible: [email protected]
Office: 00971 4 8156666
Factory : 00971 4 8858428
Emergency phone number
Office: 00971 4 8156666

2: Hazard identification
Classification of the substance or mixture

Acute Tox. 4 Harmful if swallowed.

Adverse physicochemical, human health and environmental effects:
No other hazards
GHS label elements, including precautionary statements
Pictograms and Signal Words

Warning

Hazard statements:
H302 Harmful if swallowed.

Precautionary statements:
P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/…if you feel unwell.
P330 Rinse mouth.
P501 Dispose of contents/container in accordance with applicable regulations.
Other hazards which do not result in a classification
No other hazards

3: Composition/information on ingredients
Substances
Not available
Mixtures

Hazardous components within the meaning of GHS and related classification:

Concentration Name Ident. Numb. Classification Registration Number
(% w/w)
≥25 - <50 % manganese dioxide CAS:1313-13-9 Acute Tox. 4, H302; Acute Tox. 4,
EC:215-202-6 H332
Index:025-001-
00-3

4: First-aid measures
Description of necessary first-aid measures
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Description of necessary first-aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately
with plenty of running water and possibly with soap.
Wash thoroughly the body (shower or bath).
Remove contaminated clothing immediately and dispose of safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
Wash immediately with water.
In case of Ingestion:
Give nothing to eat or drink.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
Most important symptoms/effects, acute and delayed
Not available
Indication of immediate medical attention and special treatment needed, if necessary
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
Treatment:
(see paragraph 4.1)

5: Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Unsuitable extinguishing media:
None in particular.
Special hazards arising from the chemical
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
Hazardous combustion products: Not available
Explosive properties: Not available
Oxidizing properties: Not available
Special protective actions for fire-fighters
Use suitable breathing apparatus.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

6: Accidental release measures

Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Limit leakages with earth or sand.
Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Retain contaminated washing water and dispose it.

7: Handling and storage

Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.
Contaminated clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
Conditions for safe storage, including any incompatibilities
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
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 None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.

8: Exposure controls/personal protection

Control parameters

No data available
Appropriate engineering controls: Not available
Individual protection measures, such as personal protective equipment (PPE)
Eye protection:
Not needed for normal use. Anyway, operate according good working practices.
Protection for skin:
No special precaution must be adopted for normal use.
Protection for hands:
Suitable materials for safety gloves; EN ISO 374:
Polychloroprene - CR: thickness >=0,5mm; breakthrough time >=480min.
Nitrile rubber - NBR: thickness >=0,35mm; breakthrough time >=480min.
Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min.
Fluorinated rubber - FKM: thickness >=0,4mm; breakthrough time >=480min.
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Personal Protective Equipment should comply with relevant CE standards (as EN ISO 374 for gloves and EN ISO 166 for goggles),
correctly maintained and stored. Consult the supplier to check the suitability of equipment against specific chemicals and for user
information.

9: Physical and chemical properties

Physical state Not available
Color: light brown
Appearance: paste
Odour: Characteristic
Odour threshold: Not available
pH: Not available
Melting point / freezing point: Not available
Initial boiling point and boiling range: Not available
Flash point: 150 °C (302 °F)
Evaporation rate: Not available
Solid/gas flammability: Not available
Upper/lower flammability or explosive limits: Not available
Vapour pressure: Not available
Vapour density: Not available
Relative density: Not available
Solubility in water: Insoluble
Solubility in oil: Not available
Partition coefficient (n-octanol/water): Not available
Auto-ignition temperature: Not available
Decomposition temperature: Not available
Viscosity: Not available

10: Stability and reactivity

Reactivity
Stable under normal conditions
Chemical stability
Data not available.
Possibility of hazardous reactions
None.
Conditions to avoid
Stable under normal conditions.
Incompatible materials
None in particular.
Hazardous decomposition products
None.
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 None.

11: Toxicological information

Information on toxicological effects

Toxicological information of the mixture:

There is no toxicological data available on the mixture. Consider the individual concentration of
each component to assess toxicological effects resulting from exposure to the mixture.

Toxicological information on main components of the mixture:

manganese dioxide a) acute toxicity LD50 Oral Rat = 9000 mg/kg
LC50 Inhalation Rat > 1500 mg/m3 4h

If not differently specified, the information required in the regulation and listed below must be considered as N.A.
a) acute toxicity
b) skin corrosion/irritation
c) serious eye damage/irritation
d) respiratory or skin sensitisation
e) germ cell mutagenicity
f) carcinogenicity
g) reproductive toxicity
h) STOT-single exposure
Toxicological kinetics, metabolism
and distribution information

i) STOT-repeated exposure
j) aspiration hazard

12: Ecological information

Ecotoxicity
Adopt good working practices, so that the product is not released into the environment.
Eco-Toxicological Information:

List of Eco-Toxicological properties of the product

No data available
Persistence and degradability

Not available
Bioaccumulative potential

Not available
Mobility in soil

Not available
Other adverse effects

No Components with evironmental hazard properties found.

13: Disposal considerations

Disposal methods
The generation of waste should be avoided or minimized wherever possible. Recover if possible.
Methods of disposal:
Disposal of this product, solutions, packaging and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements.
Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor.
Do not dispose of waste into sewers.
Disposal considerations:
Do not allow to enter drains or watercourses.
Dispose of product according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no longer apply and the appropriate code should be
assigned.
Dispose of containers contaminated by the product in accordance with local or national legal provisions. For further information,
contact your local waste authority.
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 Dispose of containers contaminated by the product in accordance with local or national legal provisions. For further information,
contact your local waste authority.
Special precautions:
This material and its container must be disposed of in a safe way. Care should be taken when handling untreated empty containers.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Empty containers or liners may retain some product residues. Do not re-use empty containers.

14: Transport information

UN number
3077
UN proper shipping name
ADR-Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
IATA-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
IMDG-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport hazard class(es)
ADR-Class: 9
IATA-Class: 9
IMDG-Class: 9
Packing group, if applicable
Road and Rail ( ADR-RID ) :
ADR-Label: 9
ADR-Packing Group: III
ADR-Hazard identification number: 90
ADR-Transport category (Tunnel restriction code): 3 (-)
Air ( IATA ) :
IATA-Passenger Aircraft: 956
IATA-Cargo Aircraft: 956
IATA-Label: 9
IATA-Packing group: III
IATA-Subsidiary hazards: -

IATA-Erg: 9L
IATA-Special Provisioning: A97 A158 A179 A197
Sea ( IMDG ) :
IMDG-Packing group: III
IMDG-Stowage Code: Category A SW23
IMDG-Stowage Note: -

IMDG-Subsidiary hazards: -

IMDG-Special Provisioning: 274 335 966 967 969

IMDG-EMS: F-A, S-F
Environmental hazards
Marine pollutant: No
Environmental Pollutant: Not available
Special precautions for user
Not available
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not available
These substances, when carried in single or combination packagings containing a net quantity per single or inner packaging of 5 l or less for
liquids, or having a net mass per single or inner packaging of 5 kg or less for solids, are not subject to provisions of ADR, IMDG and IATA
DGR.

15: Regulatory information

Safety, health and environmental regulations specific for the product in question
This Safety Data Sheet has been prepared according to the Globally Harmonized System of Classification and Labelling of Chemicals (GHS),
Fifth revised edition.
SCAQMD Rule 1113 : N.A.
SCAQMD Rule 1168: N.A.

16: Other information

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Code Description
H302 Harmful if swallowed.
H332 Harmful if inhaled.

This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European
Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
Insert here further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This SDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
IMDG: International Maritime Code for Dangerous Goods.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
CLP: Classification, Labeling, Packaging.
EINECS: European Inventory of Existing Commercial Chemical Substances.
INCI: International Nomenclature of Cosmetic Ingredients.
CAS: Chemical Abstracts Service (division of the American Chemical Society).
GefStoffVO: Ordinance on Hazardous Substances, Germany.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
DNEL: Derived No Effect Level.
PNEC: Predicted No Effect Concentration.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
WGK: German Water Hazard Class.
KSt: Explosion coefficient.

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