ACETIC ACID GLACIAL AR MSDS

CAS-No.: 64-19-7 MSDS

MATERIAL SAFETY DATA SHEET (MSDS)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Substance
Trade name : Acetic Acid Glacial AR
EC Index-No. : 607-002-00-6
EC-No. : 200-580-7
CAS-No. : 64-19-7
Product code : 00005
Formula : C2H4O2
Chemical structure :

Synonyms : Ethanoic Acid

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

LOBA CHEMIE PVT.LTD.
107 Wode House Road, Jehangir Villa, Colaba
400005 Mumbai - INDIA
T +91 22 6663 6663 - F +91 22 6663 6699
[email protected] - www.lobachemie.com

1.4. Emergency telephone number

Emergency number : + 91 22 6663 6663 (9:00am - 6:00 pm)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable liquids, H226
Category 3
Acute toxicity (inhal.), H332
Category 4
Skin corrosion/irritation, H314
Category 1A
Serious eye damage/eye H318
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irritation, Category 1

Full text of H statements : see section 16

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

C; R35
R10
Full text of R-phrases: see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS02 GHS05
Signal word (CLP) : Danger
Hazard statements (CLP) : H226 - Flammable liquid and vapour.
H314 - Causes severe skin burns and eye damage.
Precautionary statements (CLP) : P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER/doctor

2.3. Other hazards

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substances
Name : ACETIC ACID GLACIAL AR
CAS-No. : 64-19-7
EC-No. : 200-580-7
EC Index-No. : 607-002-00-6

Full text of R- and H-statements: see section 16

3.2. Mixtures
Not applicable
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SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek
medical advice (show the label where possible).
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
First-aid measures after skin contact : Take off immediately all contaminated clothing. Rinse skin with water/shower.
Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after eye contact : Causes serious eye damage.

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture

Fire hazard : Flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.

5.3. Advice for firefighters

Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when
fighting any chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible. Collect spillage. Store away from other materials.

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

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SECTION 7: Handling and storage

7.1. Precautions for safe handling

Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating,
drinking or smoking and when leaving work. Provide good ventilation in process area
to prevent formation of vapour. No open flames. No smoking. Take precautionary
measures against static discharge. Use only non-sparking tools. Do not breathe
dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing.
Hygiene measures : Wash hands, forearms and face thoroughly after handling.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Comply with applicable regulations.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep
container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.

7.3. Specific end use(s)

No additional information available
SECTION 8: Exposure controls/personal protection

8.1. Control parameters

No additional information available

8.2. Exposure controls

Personal protective equipment : Avoid all unnecessary exposure.
Hand protection : protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear appropriate mask
Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Colour : Clear Colorless.

Odour : strong, vinegar-like.

Odour threshold : No data available

pH : 2.4

Relative evaporation rate (butylacetate=1) : 0.97

Melting point : 16.2 °C

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Freezing point : No data available

Boiling point : 117 - 118

Flash point : 40 °C

Auto-ignition temperature : 485 °C

Decomposition temperature : No data available

Flammability (solid, gas) : Flammable liquid and vapour.

Vapour pressure : 15.2 hPa at 20°C

Relative vapour density at 20 °C : 2.1

Relative density : No data available

Density : 1.049 g/cm³

Solubility : Water: Complete

Log Pow : 0.17

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : No data available

Explosive limits : 0.04 - 0.199 vol %

9.2. Other information

No additional information available
SECTION 10: Stability and reactivity

10.1. Reactivity
Thermal decomposition generates : Corrosive vapours.

10.2. Chemical stability

Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.

10.3. Possibility of hazardous reactions

Not established.

10.4. Conditions to avoid

Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.

10.5. Incompatible materials

Strong acids. Strong bases.

10.6. Hazardous decomposition products

fume. Carbon monoxide. Carbon dioxide. May release flammable gases. Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Inhalation: Harmful if inhaled.

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Skin corrosion/irritation : Causes severe skin burns and eye damage.

pH: 2.4
Serious eye damage/irritation : Causes serious eye damage.
pH: 2.4
Respiratory or skin sensitisation : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : Not classified
Based on available data, the classification criteria are not met
Carcinogenicity : Not classified
Additional information : Based on available data, the classification criteria are not met

Reproductive toxicity : Not classified

Additional information : Based on available data, the classification criteria are not met
STOT-single exposure : Not classified
Additional information : Based on available data, the classification criteria are not met

STOT-repeated exposure : Not classified

Additional information : Based on available data, the classification criteria are not met

Aspiration hazard : Not classified

Additional information : Based on available data, the classification criteria are not met

Potential adverse human health effects : Based on available data, the classification criteria are not met.
and symptoms

SECTION 12: Ecological information

12.1. Toxicity
No additional information available

12.2. Persistence and degradability

Acetic Acid Glacial AR (64-19-7)
Persistence and degradability Not established.

12.3. Bioaccumulative potential

Acetic Acid Glacial AR (64-19-7)
Log Pow 0.17
Bioaccumulative potential Not established.

12.4. Mobility in soil

No additional information available

12.5. Results of PBT and vPvB assessment

No additional information available

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12.6. Other adverse effects

Additional information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product/Packaging disposal : Dispose in a safe manner in accordance with local/national regulations. Dispose of
recommendations contents/container to hazardous or special waste collection point, in accordance with
local, regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN

14.1. UN number
UN-No. (ADR) : 2789
UN-No. (IMDG) : 2789
UN-No. (IATA) : 2789
UN-No. (ADN) : 2789
UN-No. (RID) : 2789

14.2. UN proper shipping name

Proper Shipping Name (ADR) : ACETIC ACID, GLACIAL
Proper Shipping Name (IMDG) : ACETIC ACID, GLACIAL
Proper Shipping Name (IATA) : Acetic acid, glacial
Proper Shipping Name (ADN) : ACETIC ACID, GLACIAL
Proper Shipping Name (RID) : ACETIC ACID, GLACIAL
Transport document description (ADR) : UN 2789 ACETIC ACID, GLACIAL, 8 (3), II, (D/E)
Transport document description (IMDG) : UN 2789 ACETIC ACID, GLACIAL, 8 (3), II
Transport document description (IATA) : UN 2789 Acetic acid, glacial, 8 (3), II
Transport document description (ADN) : UN 2789 ACETIC ACID, GLACIAL, 8 (3), II
Transport document description (RID) : UN 2789 ACETIC ACID, GLACIAL, 8 (3), II

14.3. Transport hazard class(es)

ADR
Transport hazard class(es) (ADR) : 8 (3)
Danger labels (ADR) : 8, 3

IMDG
Transport hazard class(es) (IMDG) : 8 (3)
Danger labels (IMDG) : 8, 3

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IATA
Transport hazard class(es) (IATA) : 8 (3)
Hazard labels (IATA) : 8, 3

ADN
Transport hazard class(es) (ADN) : 8 (3)
Danger labels (ADN) : 8, 3

RID
Transport hazard class(es) (RID) : 8 (3)
Danger labels (RID) : 8, 3

14.4. Packing group

Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II

14.5. Environmental hazards

Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available

14.6. Special precautions for user

- Overland transport
Classification code (ADR) : CF1
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP15
Portable tank and bulk container : T7
instructions (ADR)
Portable tank and bulk container special : TP2
provisions (ADR)
Tank code (ADR) : L4BN
Vehicle for tank carriage : FL

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Transport category (ADR) : 2
Special provisions for carriage - Operation : S2
(ADR)
Hazard identification number (Kemler No.) : 83
Orange plates :

Tunnel restriction code (ADR) : D/E

EAC code : •2P
APP code : A(fl)

- Transport by sea
Limited quantities (IMDG) : 1L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-C
Stowage category (IMDG) : A
MFAG-No : 132

- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y840
PCA limited quantity max net quantity : 0.5L
(IATA)
PCA packing instructions (IATA) : 851
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 855
CAO max net quantity (IATA) : 30L
ERG code (IATA) : 8F

- Inland waterway transport

Classification code (ADN) : CF1
Limited quantities (ADN) : 1L
Excepted quantities (ADN) : E2
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 1

- Rail transport
Classification code (RID) : CF1
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP15
Portable tank and bulk container : T7
instructions (RID)
Portable tank and bulk container special : TP2
provisions (RID)
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 2

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Colis express (express parcels) (RID) : CE6
Hazard identification number (RID) : 83

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

No REACH Annex XVII restrictions

Acetic Acid Glacial AR is not on the REACH Candidate List
Acetic Acid Glacial AR is not on the REACH Annex XIV List

15.1.2. National regulations

Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV;
ID No. 93)
12th Ordinance Implementing the Federal : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Immission Control Act - 12.BImSchV

Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de : The substance is not listed
voortplanting giftige stoffen – Borstvoeding
NIET-limitatieve lijst van voor de : The substance is not listed
voortplanting giftige stoffen –
Vruchtbaarheid
NIET-limitatieve lijst van voor de : The substance is not listed
voortplanting giftige stoffen – Ontwikkeling

Denmark
Class for fire hazard : Class II-1
Store unit : 5 liter
Classification remarks : R10 <H226;H314>; Emergency management guidelines for the storage of
flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product

15.2. Chemical safety assessment

No chemical safety assessment has been carried out

SECTION 16: Other information

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Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF

THE COUNCIL of 16 December 2008 on classification, labelling and packaging of
substances and mixtures, amending and repealing Directives 67/548/EEC and
1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.

Full text of R-, H- and EUH-statements:

Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Flam. Liq. 3 Flammable liquids, Category 3
Skin Corr. 1A Skin corrosion/irritation, Category 1A
H226 Flammable liquid and vapour.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H332 Harmful if inhaled.
R10 Flammable
R35 Causes severe burns
C Corrosive

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and
environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

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