This document provides a summary of questions that appeared on a chemical engineering licensure examination from May 18-20, 2016. The first day covered chemical and physical principles and included questions on topics like the Clausius-Clapeyron equation, paramagnetism, acid-base titration calculations, effects of different types of radiation, and gas laws. The questions ranged from very basic to more complex and some required looking up information in references like handbooks.
This document provides a summary of questions that appeared on a chemical engineering licensure examination from May 18-20, 2016. The first day covered chemical and physical principles and included questions on topics like the Clausius-Clapeyron equation, paramagnetism, acid-base titration calculations, effects of different types of radiation, and gas laws. The questions ranged from very basic to more complex and some required looking up information in references like handbooks.
This document provides a summary of questions that appeared on a chemical engineering licensure examination from May 18-20, 2016. The first day covered chemical and physical principles and included questions on topics like the Clausius-Clapeyron equation, paramagnetism, acid-base titration calculations, effects of different types of radiation, and gas laws. The questions ranged from very basic to more complex and some required looking up information in references like handbooks.
This document provides a summary of questions that appeared on a chemical engineering licensure examination from May 18-20, 2016. The first day covered chemical and physical principles and included questions on topics like the Clausius-Clapeyron equation, paramagnetism, acid-base titration calculations, effects of different types of radiation, and gas laws. The questions ranged from very basic to more complex and some required looking up information in references like handbooks.
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CHEMICAL ENGINEERING LICENSURE EXAMINATION
(MAY 18-20, 2016)
DAY 1 – Chemical and Physical Principles
1. *Given initial and final Pressure, initial and final
Temperature. What is enthalpy of vaporization? Hint: use Clausius-Clapeyron Equation sa Handbook or kung kabisado mo, may 2 questions na ganito, may 2pts ka agad 2. May kwento about sun energy. Tapos ang tanong, which ferric ions are paramagnetic? A. All except Fe+8 and Fe+14 B. All except Fe+3 and Fe+ C and D, combination nung mga ions. Hint: itanong kay google 3. What is the normality of KOH solution if ___grams of KH2C2O4 is dissolved and diluted to 40mL water, then it is neutralized with 20mL KOH solution? Note: mali ung choices or mali ung given, hindi ko nakuha ito.haha 4. Which statement is true, what effect of alpha, beta and gamma rays to the atomic number? A. 0, 1, 2 B. 0,0,1 Etc. Hint: so basic, very basic! 5. Given the concentration of Cu+2 __Molar, what is the volume of hydroxide will be added to the wastewater tank to reduce the CuSO4 to __grams? Note: hindi ko din nakuha ito, sisihin ung choices or given para hindi mukhang bobo.haha 6. ***Animals stored energy in glycogen, plants stored in starch. What is the difference of their structure? Choices: about sa branches, kung magkakadikit ba or may interval na 8 to 12 molecules. 7. (Stray Question) Momentum: Given initial velocity of first cart, then second cart with __kg has initial velocity of __m/s. In perfect elastic collision, the velocity of first cart is __m/s after collision. What is the mass of first cart? Hint: use coefficient of restitution and perform the Law of Conservation of Momentum Equation. 8. (Situational Question) You are an employee of a famous fastfood restaurant, and you discovered that they put nitrates to the bacon as preservative. According to your research, these nitrates are carcinogenic when heated. What will you do? I. Report to your employer. II. Spread the news. III. Remain silent. Choices: A. II only B. III only C. Both I and II D. Both I and III Hint: test of character.haha 9. Who discovered radioactivity? A. Becquerel B. Marie Curie C. Roentgen D. __ Note: nalito kami kay Becqs at Curie. Pero si Becqs ang nagwagi.haha 10. Who discovered vulcanization? Answer: Goodyear 11. Kuwento about kay Guy-Lussac at PVnRT. Lalabas daw ba ung liquid sa champagne kapag inalog mo ung bottle before buksan? A. No, with explanation B. No, again with explanation C. Yes, gas expand then create ng bubbles then displace niya ung liquid kaya aapaw. (Conyo mode) D. Yes, with explanation. 12. **Methyl bromide was banned in developing on 2005. When will this be phase out? A. 2010 B. 2015 C. 2020 D. 2025 13. A gas with Kp of __ and having a reaction NO + Cl2 NOCl Given Partial pressure of NO and Cl2. What is the partial pressure of NOCl? Hint: so basic, very basic. Careful lang sa balancing kasi minsan NO2 ung lumabas. 14. *Naming: Given two structure, diethyl amine, ung isa nakalimutan ko. Hint: tignan mo sa Section 2 ng Handbook ung formula tapos icheck mo sa choices ung tutugma. 15. *Rank the stability of the Plumes, Choices: may time, may weather at may wind speed Example: sunny morning with a windspeed of __kph Hint: Check mo sa Fig 22-7 16. Rank the bond strength of acetic acid A. C-O > C=O and C-C < C-H B. C-C < C-O and C=O > C-C Etc. Hint: basic ng organic chemistry, pero kung zero knowledge ka sa orgchem katulad ko, pulsuhan mo na lang, pakiramdaman mo.haha 17. *What is common in the structure of malic acid and lactic acid? A. Pyruvate B. Enzymate(not sure) C. Hydroxyacid D. Glutamine Hint: check mo ung formula nung dalawa sa Section 2 ng handbook. Check mo din ung formula nung mga nasa choices. Tapos icompare mo kung ano common. 18. One million liters of waste water has a concentration of 1100 mg/L of TEC. Then it is transferred to a 2 million capacity tank. What percent will the TEC reduced? No comment! 19. Given the table of log Kow vs. solubility, rank according to higher bioconcentration. A. (high log Kow) is the highest B. (low log Kow) is the highest C. (high solubility) is the highest D. (low solubility) is the highest Note: Tanong ulit si google. 20. Caliraya Lake in Laguna is 4 hectares. Umulan ng 1 inch of rain with ph 4.9. The water has 45 moles of propiotic acid and depth of the lake is 3 meters. What is the pH of the lake after the rain? Note: wag pumunta sa Caliraya after board exam. Calculation ng pH lang ginawa ko. 4 point something ung sagot. Dalawa sa choices 4 point something kaya ung mas malapit pinili ko.haha 21. Rank the toxicity: 2-DDT, 4-Heptachlor, 3-Dieldrin, 1- Arsenic, 5-Chromium Note: 2015 ung list na pinagkunan ko. Hindi ko sure kung same lang ba ng year ung list na pinagkunan nila sa board exam. Baka panahon pa ng kopong kopong pa nila ginawa ung question na yan. 22. If the ratio of Neutron to proton is 1, it is stable. If the ratio is greater than 83, it is radioactive. Which of the following is/are radioactive? Choices: combination ng Pa, Sn, Mg, Zn Hint: Magic Numbers! 23. Molecular weight of Lindane Note: given naman ung Molecular formula kaya chill lang. mga 5 questions na puro ganito, tapos swerte mo pa kung nasa Handbook ung formula. 65pts na lang to pass.haha 24. Compute the solubility product of 1x10^-3M Zn+1 and 1x10^- 1M S-1 Note: very basic pero walang sagot sa choices. Sayang ung 1 pt, topnotcher na sana! Jk.haha 25. Given 3 reactions with values of Kp. What is the Kp of the final reaction? Hint: Hess’s Law Note: mali ung Cl, dapat Cl2. Check na lang ulit kung balance. 26. AMU is derived from A. 1/12 blah blah of Carbon 12 B. 1/13 blah blah of Carbon 13 C and D may trending. Answer: majority ng sagot is A. 27. An atom is considered radioactive if ratio of atomic number is, A. >75 B. >83 C. Between 80 to 100 Note: nagkataon ata na nabanggit sa previous question ung sagot.haha. 1pt agad! May 9 free points ka na agad.haha 28. Balance the redox reaction, oxidation of C6H12O6 to CO2 and reduction of NO-3 to N2. Hint: Keep calm, Redox lang yan 29. The process involve in refrigerator is, A. Gas to liquid blah blah B. Liquid to Gas blah blah C. Gas to liquid gives cooling effect blah blah D. Liquid to gas gives cooling effect blah blah 30. *What is more soluble ROH or RSH? Hint: Check agad sa Section 2 ng solubility. Kapag hindi alam kung ano compound, kuha ka ng model compound. E.g. EtOH and EtSH, tapos compare mo sila. 31. *Given dG, compute for the cell potential. Hint: May formula ng Faraday’s Law sa Section 7 and 24 ng Handbook. No need to memorize na. 32. BOD computation na given lahat, substitute mo na lang. 33. Given ka ng 50kg of product and __% in feed, then find the weight of waste ore. Note: kahit nakapikit kaya mo isolve ito. Isecure mo na ang 1 pt.haha 34. Reaction of acid and alcohol Answer: Esterification. Kaumay na! 35. Filtration problem given ang dimension ng filter, filtration rate, number of filter. Note: simpleng dimensional analysis lang ito promise! 1 pt agad.haha 36. ***How many hydrogen bonding meron sa Uracil and Adenine? Note: hindi kami prepared para sa ganitong question.haha. Use Psychic powers! 37. May binigay na coal tapos i-subject sa CO2 and O2. Kailan daw namatay yung apoy. Note: May iba pang given nakalimutan ko lang. Basta mahirap siya kaya use Psychic Powers and Prayer.haha Hint: Nuclear Chemistry 38. ***What is sigmatropic rearrangement? Note: medyo mahahalata mo sa choices ung sagot kaya wag kabahan. 39. What number of moles of the gas with given pressure of 2490.2mL and 0.8391 moles taken the volume expanded to 6220.4mL? Note: nagulat ka sa problem noh, pressure tas mL ang unit. Copy paste yang tanong na yan, pati values exact. Diskartehan mo lang ang pagsolve para may lumabas sa choices.haha 40. ***What is the function of EDTA in meat industry? Note: Magaganda ung mga explanation sa choices, kaw na bahala kung saan ka makukumbinse para piliin sila. 41. Given ka ng half-life ng Uranium, hanapin ung time kapag naging 0.26 grams ung mass nia. Hint: Exponential Decay Note: may 2 question ulit about decay, pero mahirap. Kaya hindi sure ang 2pts mo.haha 42. Given %C,%H,%O and %N, what is empirical weight, empirical formula and molar mass. Note: Don’t worry, nasa choices ang susi sa sagot. No need to solve na yang empirical na yan kase obvious sa choices.haha 43. Nuclear Chemistry: may given na disintegration/sec ang meron sa radiation ng isang element. May iba pang given, nakalimutan ko lang. What mass ng element ang kailangan to supply ung power 1500MW in one day? Note: Elite na Nuclear Chemistry ito. Wag pagaksayahan ng time. 44. *What is the volume of 1mol of pure ethanol? Hint: Dimensional analysis, Properties from section 2 of Handbook Note: kahit nakapikit ka masosolve mo ito.haha 45. *Given density ng benzene and melting point at 1 atm. What is the melting point at 1000 atm? Hint: Use clapeyron Equation. Get the latent heat of fusion of Benzene in Section 2. Answer: nasa 7.something ang sagot. Ung ibang sagot, 1.something, -0.something tas 10.something. pag nakita mo ung “7”,shade na agad,wag na isolve.haha 46. Balance the complete combustion of methanol that is used in formula one racing. Note: Originally, Ethanol ung nakalagay sa problem kaya kahit anong balance na ginawa ko wala sa choices ung sagot. Typoerror ung letter “m”. Badtrip diba? Nagmukha akong tanga sa problem na ito. Madali lang sa unang tingin, un pla methanol ung given. Paasa! 47. Given capsules A and B having KMnO4 and MnO2 inside respectively. Which capsule will attract to the magnet? Hint: Depende sa Charge Note: hindi din ako prepared sa ganitong question, ask na lang si Magneto ng X-men.haha 48. What is the subatomic particles of nucleus? A. Electron and Neutron B. Neutron and Protons C and D, combination. Note: May 1pt ka na ulit.haha 49. What is the molecular weight of 1,1-tetradecenyl acetate? Hint: Hindi mo kailangan i-drawing, ang kailangan mo Section 2 ng Handbook. Since walang 1,1-tetradecenyl acetate sa handbook, hatiin mo sa dalawa ung compound. Sa handbook may Tetradecane pero walang acetate, kunin mo agad ung molar mass ng tetradecane tska mo iplus sa molar mass ng acetate. Kung hindi mo pa rin alam ang molar mass ng acetate, kunin mo ang molar mass ng Acetic acid/Ethanoic acid/ Vinegar sa Handbook. I-minus mo na lang ung mass ng hydrogen dahil sa acid. Ung pinakamalapit sa choices,un ang piliin mo para may instant 1 pt ka na.haha 50. Given Table ng Concentration vs. Time, find the order of reaction and k. Hint: Basic kinetics. Use regression to check the linearization of the equation (rhyme) 51. Which number gives the identity of an element? A. Electron B. Positron C. Proton D. Neutron Answer: Proton Note: Tricky ang question na ito. 52. With presence of H+ and heat, which of the following is the reactant to produce alkene? Hint: Reaction mechanism sa Orgchem A. Structure ng Alkane B. Structure ng halide C. Structure ng aldehyde D. Structure ng Carboxylic acid 53. Given the reaction and Q, find the heat accompanying 3.51 kg of Ca. Note: nakalimutan ko ung ibang given Hint: Heat Balance 54. Ung Barista daw ng Starbucks accidentally nalagyan ng milk ung coffee mo. Given initial amount in mass ng coffee and milk. Assume the density and specific heat of milk and coffee is the same with water. Given din ung initial temperature nung coffee. What is the heat absorbed? Note: kulang ng temperature ng milk, inassume na room temperature. Nabura nanaman ng nagtatype. Haist! Wala sa choices pa din. 55. Given ka ng combination ng solution, Ag2CO3 and CaCl2, NaNO3 and PbSO4, tas nakalimutan ko na ung isa. Which of the following will form precipitate? A. P/NP/P B. NP/NP/NP C. NP/P/P D. P/P/P Note: Be ready sa mga ganitong klaseng problem or else manghuhula ka.haha 56. Acetylation of histone Choices: Equation Reaction with Structure. Note: hindi ko maintindihan ung drawing. May lone pair ung Hydrogen. Tapos putol putol pa ung structure. Tapos hindi pa aligned ung mga bonds. May naliligaw pang carbon. Kahit ung examiner hindi kayang sagutan un.(reklamador spotted) 57. *Given ung molecular weight ng Cumene, what is the molecular formula? Hint: Nasa Section 2 ng Handbook. Pero kung tinatamad ka magbuhat at buksan ang Handbook, pede mong iconsider ung nasa choices na sagot. Calculate mo ung molecular weight ng mga nasa choices,tapos kung sino lumapit sa given siya ang panalo.haha 58. ***What is radioactivity? Note: kung saang explanation ng mga choices ka macoconvince, un ung isagot mo.haha 59. ***What is nuclear fission? Note: wag mailto sa fission at fusion. 60. What is the degrees of freedom of water at triple point? Answer: Zero Hint: may formula ng pagkuha ng Degrees of freedom sa Section 4 ng Handbook. 61. ***Three beakers with CCl4, water and dry ice. Which beaker will absorbed heat? Hint: Dipole moments 62. Analysis ng Horse manure. Given %N sa manure for fertilizer, given din ung mass ng P2O5 para sa % ng P. Note: Mahaba pa ung problem, madami ding values tska madami ding hinahanap. Next question agad.
Legend: *can be solved using ChE Handbook **nadiscuss sa MRII ***GMG (Google Mo Girl) __ nakalimutan ung value DAY 2 – Chemical Engineering Principles
Disclaimer: Konti lang natandaan namin kase lahat kami gusto
nang kalimutan ang bangungot ng Day 2.
1. What chemical used in pesticides derive from a type of
Chrysanthemum? A. Pyrethoid B. Pyrethrin C. Carbophox D. Nalimutan Answer: Pyrethrin For 2 and 3, given ka ng density ng solution. 2. What is molality of the solution. 3. If the melting point of pure substance is __, what is the melting point of the solution? 4. Definition ng Joule Thompson effect 5. Definition ng Corresponding states Hint: see Section 2 of Handbook 6. Which equipment is non proprietary? A. Distillation Column B. Centrifuge C. Pumps D. Compressors For 7 to 9, RS+T Calculate the following, 7. rate constant 8. volume of reactor and 9. Time 10. Definition of P.I.O.N.A. 11. Definition of M.W.C.O. 12. Definition of S.C.A.D.A 13. Parts of Perfume is called? A. Aromatics B. Constituents C. Essence D. Nakalimutan Answer: Essence 14. Drying and Humidification: May volatile compound na nasa soil. Then, ung air pumasok sa soil, paglabas may kasama nang volatile compound. May mga given values na humidity, moles ng volatile compound etc. Three items ito. May air, water at volatile compound na involve sa problem kaya dugo ang utak sa problem na ito. Kapit sa Reverse Engineering! 15. Formula equation sa pagkuha ng diameter ng v-notch weir 16. Reason ng multiple shell and tube. 17. Most important role ng boltzmann constant sa physics at ideal gas? Answer: Bridge 18. Difference ng integral sa differential control? 19. Commonly used control? A. PID B. PI Etc. 20. Definition ng Autensitic metal 21. Describes local equilibrium A. Explosion B. Steam boiler C. Shockwave 22. Definition about galvanic corrosion 23. Which theory is under membrane separation, A. solute precipitation B. flux paradox C. Two film Theory D. nakalimutan 24. Fluids: Velocity gradient is equal to zero when, A. Viscous sublayer B. Turbulent core C. Boundary Layer D. Nakalimutan 25. Hardness of lime A. More Calcium B. Hydraulic hydrated C. Dolomine For 26 to 28,Feed with sulfur content and negligible amount of inert. The scrubbing water was reacted with caustic soda to produce bisulfate. 26. Ilan ang S content? 27. Ilan ang NaOH? 28. Ilan ang SO3? For 29 to 31, Waste gas containing CO2, tas sa ilalim ng scrubber nagpasok ng pure CO2. Then inanalyze ung lumabas, 8% CO2, 29. Ilan ang mole fraction 30. Ilan ung feed na waste gas? 31. Ilan ung lumabas? 32. Determine the approximate cost of the project prior to the preparation of flowsheets to set a rapid estimate of the investment that is likely to be required. A. ROI B. EBITDA C. Six-tenths rule D. Payback period 33. What motion is parallel to the gravitational force that push the particle to other angle? A. Stokes motion B. Two dimensional motion For 34 to 36, Given 20 ft long and 0.62 diameter, Cp is 0.65 Btu/lb-F, thermal coefficient is 0.085 english units, viscosity at 122 F is 4 Btu/hr.ft, viscosity at 212 F is 1.95. bulk temperature is 212 F. 34. Find Reynolds number using G is 2000lb/hr A. 22,575 B. 25225 C. 27,522 35. Find the heat transfer coefficient at 2000lb/hr A. 201.3 B. 203.1 36. If the rate is reduced by 100lb/hr, what is the heat transfer coefficient? A. 9.01 B. 10.11 C. 11.03 D. 12.03 37. What is the section at the top of feed plate? A. Condenser B. Stripping C. Reboiler D. Rectifying For 38 to 40, given helium atoms, T is 300K, molar volume is 24.63L/mol 38. Convert L.atm to J 39. What is the enthalpy rate? 40. Given molar rate at same temperature, what is heat rate? For 41 to 43, Given steam at 10 bar with degree of superheat of 190 deg C, mass flowrate of 2000kg/hr, outlet steam at 1 bar. 41. What is inlet saturated enthalpy? 42. What is outlet enthalpy? 43. Nakalimutan 44. A tube 60mm(2.36in) OD is insulated with 50mm(1.97in) layer of silica foam, for which the conductivity is 0.055W/m.C(0.032Btu/ft-h-F), followed with a 40mm(1.57in) layer of cork with conductivity of 0.05W/m.C(0.03Btu/ft-h- f). If the temperature of the outer surface of the pipe is 150 C(302 F) and the temperature of the surface of the cork is 30 C(86 F), Calculate the heat loss in watts per meter of pipe. 45. Given propane gas at __pressure and __temperature. Given Tr, Pr and acentric factor. Compute enthalpy residual. For 46 to 48, Given carnot cycle, the inlet conditions before isothermal expansion P is 300 psia, V is 1ft3, T is 540 F, expansion ratio of 2, compression ratio of 5. 46. What is the temperature of heat sink? A. 55 B. 65 47. Heat? 48. Nakalimutan 49. Closed system that produce maximum work? A. Cyclic B. Equilibrium C. irreversible 50. Limitation of UNIFAC For 51 to 53, Given a solution with 5g of solute in 100g of water at 1 atm. The solution boils at 100.421 C. 51. What is the molecular weight of the compound if the mole fraction of the solute in the solution is 0.421/28.5 A. 65.1 g/gmol B. 61.0 C. 60.1 D. 62.1 52. What is the effective vapor pressure of the solvent at 25 C? A. 25.3mmHg B. 26.0 C. 23.4 D. 24.3 53. What is the freezing point of the solution at 1 atm? A. -3.15 C B. -1.53 C. -3.53 D. -1.35 For 54 to 56, Given a relative volatility of 4,600 mols of A and 400 mols of B are fed in a kettle for distillation. A is more volatile than B. 54. What is the amount of the overhead product if the remaining mixture in the kettle is 80%B?(725 mols) 55. How much A is in the overhead product?(545 mols) 56. If 50% of the feed evaporated, how much A remains in the kettle? For 57 to 59, A single effect evaporator is to concentrate 20,000 lb/h (9070kg/h) of a 20 % solution of NaOH to 50% solids. The gauge pressure of the steam is to be 20 lb/in2(1.37atm); the absolute pressure in the vapor space is to be 100mmHg(1.93 lb/in2).The overall coefficient is estimated to be 250 Btu/ft2- h-F(1400W/m2-C). The feed temperature is 100F(37.8C). Calculate the, 57. Amount of steam consumed 58. Economy 59. Heating surface required 60. What is used in ultrasonic flow meters? Answer: Doppler DAY 3 – General Engineering, Codes and Ethics
Note: Study Grade 7 to 12 Mathematics and Science. Un lang ang