A Simulation Model For Thickness Profile of The Film Deposited Using Planar Circular Type Magnetron Sputtering Sources
A Simulation Model For Thickness Profile of The Film Deposited Using Planar Circular Type Magnetron Sputtering Sources
A Simulation Model For Thickness Profile of The Film Deposited Using Planar Circular Type Magnetron Sputtering Sources
net/publication/224448807
A simulation model for thickness profile of the film deposited using planar
circular type magnetron sputtering sources
Article in Journal of Vacuum Science & Technology A Vacuum Surfaces and Films · October 1996
DOI: 10.1116/1.580193 · Source: IEEE Xplore
CITATIONS READS
12 168
7 authors, including:
Byeong-Soo Bae KS No
Korea Advanced Institute of Science and Technology Korea Advanced Institute of Science and Technology
272 PUBLICATIONS 4,868 CITATIONS 303 PUBLICATIONS 4,221 CITATIONS
Some of the authors of this publication are also working on these related projects:
Workforce Development Program by MKE & KIAT and Basic Science Reserch Program by NRF View project
All content following this page was uploaded by Seungbum Hong on 29 May 2014.
I. INTRODUCTION gime that occurs after thermalization. Fan et al.3 and Swann
et al.4 assumed no gas scattering, cosine emitting source, and
Recently, magnetron sputtering has been widely used in calculated the erosion rate from the erosion depth profile.
thin film fabrication since it offers high deposition rate and Most of the authors have calculated the target erosion rate
operates at lower pressure than the conventional one without from the target erosion depth profile. Though it has been
magnetron. The manifestation of the relationship between mentioned by many authors that the target erosion rate is
the main film quality ~mechanical, electrical, optical proper- dependent on the magnetic field profile, there is almost no
ties, etc.! and the deposition parameters ~total chamber pres- quantitative work on their relationship. Therefore, in this
sure, gas flow rate, target-substrate distance, etc.! is required study the role of the magnetic field profile and its relation-
to control the process more efficiently. Especially, among the ship with the erosion rate has been considered in simulating
main film quality, the thickness uniformity of the film is a the thickness profile of the film deposited by the planar
critical factor in optical applications because it is directly circular-type magnetron sputtering system. Then, the validity
relevant to the optical properties of the film such as transmit- of the model was confirmed by the measurement of the Cr
tance, absorption, and refractive index, etc. film thickness profiles after sputter deposition.
Much theoretical and experimental research has been per-
formed to investigate the film thickness distribution.1–4 He- II. MODEL DEVELOPMENT
berlein et al.1 used the Monte-Carlo method to simulate the In this study, several assumptions have been taken to sim-
film thickness, as well as angular and energy distributions. plify the model. These are ~1! no gas phase collisions, ~2!
They divided the magnetron sputtering process into three unit sticking coefficient, ~3! cosine-emitting source,5 and ~4!
parts; particle emission from target, gas scattering, and film linear proportionality between loop current density and etch
growth. Furthermore, they took the cosine distribution func- rate.
tion for emission characteristics, Thompson’s relation for
emission probability, erosion depth profile for erosion rate, A. Cosine-emitting source and plane parallel receiver
elastic gas scattering between sputtered particles and back- (Ref. 6)
ground gas particles, and particle losses by chamber wall Let F 0 denote the flux of the sputtered atoms from the
deposition or thermalization. Fursenko et al.2 also used the source per steradian in the direction perpendicular to the
Monte-Carlo method, but they added some hydrodynamic source plane. It is assumed that Knudsen’s cosine law of
concept into their simulation. They took the emission char- evaporation is valid for each elemental area, DA S , of a pla-
acteristics to be a cosine-emitting distribution function and nar emitting surface and that the source is planar, circular,
assumed the background gas to be a continuum media with and uniform. Then the flux of sputtered atoms from the area
hyposonic flow, focusing on the transport of gases at low of the source element, DA S , to the area of the receiver ele-
pressure and at medium pressure. In the low-pressure region, ment, DA R , should be
the linear Boltzmann equation and the Poisson distribution
F 0 DA R d 2
were used to describe the transport process of the particles dDH5 3rd f dr ~ mol/s! ,
and the collision between the Monte Carlo test particles and ~ r 2 22rx cos f 1x 2 1d 2 ! 2
background gases. In the medium pressure region, the test ~1!
particle Monte Carlo method was utilized for the kinetic re- where DH is the total flux from the source to the area of the
gime and convective diffusion equation for the diffusion re- receiver element DA R , r is the radial distance of the source
element from the origin on its plane, x is the projected length
a!
Electronic mail: [email protected] to the x axis of the line connecting the origin on the source
2721 J. Vac. Sci. Technol. A 14(5), Sep/Oct 1996 0734-2101/96/14(5)/2721/7/$10.00 ©1996 American Vacuum Society 2721
2722 Hong et al.: A simulation model for thickness profile 2722
J y 5n e e v y , ~2!
S D
plane and the central point of the receiver element, d is the
source to receiver distance, and f is the angular coordinate z
E z 52E 0 12 , ~3!
of the source element6 ~Fig. 1!. L
d 2z dy
me 2 52eE z 1eB x . ~6!
dt dt
e 2E 0B x
v y 52 ~ 12cos v t ! , ~7!
m 2e v 2
where
eE 0 e 2 B 2x
v 25 1 2 . ~8!
m eL me
e 2 B 2x
m 2e LeB 2 L 2 eB 2
ratio5 5 5
eE 0 m e E 0 m e ~ V1V p !
m eL
~ 0.37631023 ! 2 31.63102193 ~ 1.76531022 ! 2
5
9.113102313 ~ 500110!
50.0152.
Since the value of the second term is found to be about 1.5%
of that of the first term, the second term can be ignored in
Eq. ~8!. This makes v to be constant independent of the B
field. Therefore, the time-averaged mean velocity becomes
e 2E 0B x
v y 52 5aBx , ~9!
m 2e v 2
where a proportional constant, a52e 2 E 0 /m 2e v 2 .
Thus, the mean current density becomes
J y 5n e e v y 5n e e a B x 5 b B x , ~10! FIG. 3. Distribution profile of x axis component of the magnetic field.
where a proportional constant, b5n e e a .
According to the assumption that the etching rate of the
source plane is proportional to the loop current density, it is A combination of Eqs. ~13! and ~14! will yield the following
found that the etching rate of the source plane increases lin- equation:
early with the magnetic field component being parallel to the DH
source plane. In the case of the planar and circular magne- 522 p
x DA R d 2
tron sputtering system, it can be inferred that
J u5 b B r ~11! 3 E 22.5
0
1.3031024 ~ r 2 222.5r !~ r 2 1x 2 1d 2 ! rdr
@ r 4 22r 2 ~ x 2 2d 2 ! 1 ~ x 2 1d 2 ! 2 # 3/2
.
and the modified form of Eq. ~1! is given by
~15!
B r DA R d 2
dDH5 x 2 3rd f dr, ~12! This can be divided into two parts
~ r 22rx cos f 1x 2 1d 2 ! 2
where x is a proportional constant.
DH
x DA R d 2
522 p E 0
22.5 1.3031024 r 2 ~ r 2 1x 2 1d 2 ! rdr
@ r 4 22r 2 ~ x 2 2d 2 ! 1 ~ x 2 1d 2 ! 2 # 3/2
pE
C. Magnetic field measurement and polynomial 22.5 1.3031024 322.5r ~ r 2 1x 2 1d 2 ! rdr
approximation of the magnetic field 12 .
0 @ r 4 22r 2 ~ x 2 2d 2 ! 1 ~ x 2 1d 2 ! 2 # 3/2
In this study, magnetic field was measured using a Gauss-
~16!
meter ~Fig. 3!. We have adopted the polynomial approxima-
tion method to fit the radial component of the magnetic field Letting j5r , the first term can be integrated in two parts9 to
2
H
at the surface of the source. Thus, the approximated qua- give
j ~ j 2C ! 1
dratic function for the region of interest is 21.3031024 p 1/22
~ C2D ! R ~ C2D !
B r 521.3031024 3 ~ r 2 222.5r ! ~ Tesla! , ~13!
as shown in Fig. 3. 3 @ AR1 ~ D2C ! ln~ 2 AR12 j 22D !# J 22.52
0
, ~17!
D. Indefinite integral and finite elemental method where C is x 2 1d 2 , D is x 2 2d 2 , and R is j22 j D1C 2.
The circular symmetry of the source makes the evaluation The second term in Eq. ~16! is found to be not solved by an
along one projected source radius describing completely the analytical method. Therefore, we used a finite element
distribution over the receiver surface. Thus, Eq. ~12! is suit- method to evaluate the second term.
able for our purpose. The integration of Eq. ~12! over f from
0 to 2p, exclusive of the coefficient x DA R d 2 , gives9 III. EXPERIMENT
DH
x DA R d 2
52 p E B r ~ r 2 1x 2 1d 2 ! rdr
@ r 4 22r 2 ~ x 2 2d 2 ! 1 ~ x 2 1d 2 ! 2 # 3/2
.
Cr films were prepared using a planar circular type mag-
netron sputtering system with a ring-shaped 2 in. target. The
~14! outside diameter of the Cr target was 50.8 mm and the inside
FIG. 6. The absolute deviation of the predicted values from the measured
data vs. Knudsen number. R, the relative flux, d, the maximum absolute
deviation among sampling points, h, the average absolute deviation over
the sampling points.
2. Calculation of the background gas density for verification and application of our model. However, it
Before calculating the background gas density, the gas was very difficult either to lower the pressure below 1.3 Pa
rarefaction effect should be taken into account. While the or to reduce the substrate-target distance below 5 cm in our
magnetron discharge current of 0.1 A is not expected to con- system so that there was no method to perform experiments
tribute to a significant change in the background gas density, where the Knudsen number reaches far beyond 1. Recently,
it is found to reduce the background gas density to 83% of there have been developed many magnetron sputtering de-
the original value at 1.3 Pa for Cu sputtering in Ar.15 Con- vices which operate at very low pressure ~less than 0.1 Pa!17
sidering the average sputtered energy, momentum transfer and this model may be more suitable for such equipment.
cross section,14 and sputtering yield of Cr,16 we can evaluate Nonetheless, though not perfectly matched, the simulated
the reduction factor of the background gas density to be 0.90 profile was matched to the experimental results quite well, as
from the work of Rossnagel,15 which is a bit higher value shown in Fig. 5. It is found that as the target to substrate
than that of Cu at the condition of interest. It is equivalent to distance increases, the discrepancy between the experimental
say that the background gas density is reduced to and the simulated values increases. This trend is shown in
331014/cm3 from 3.331014/cm3 at 1.3 Pa. Fig. 6 in terms of the deviation versus the Knudsen number.
The deviations between the predicted values and the experi-
3. Verification and applicability of the model mental data showed a linear dependence with the Knudsen
number. Moreover, the points far from the center are found
It is found that the mean free path for 11.93 eV Cr atoms to have more deviated values from the simulated ones. These
in Ar at 1.3 Pa with 0.1 A of magnetron discharge current is may be attributed to the fact that the model is less valid as
about 5.6 cm from the above calculations. This value is com- the collision frequency increases. If we take 3% as a toler-
parable to 4.5 cm at 1.3 Pa ~inferred from the 1.5 cm at 4 Pa! able limit for maximum deviation in the film thickness pro-
for Cu atoms calculated by Rossnagel15 without considering file, it is found that the Knudsen number should be at least 1
the gas rarefaction effect ~it will increase up to 5.4 cm if the for application of this model as is expected from the above
gas rarefaction is taken into account!. Eventually, the Knud- discussion.
sen number will vary from 0.56 to 1.12 with target-substrate
distance variation from 10 to 5 cm at the above given depo-
B. Application for other magnetron geometry
sition condition.
A large Knudsen number over 1 which ensures molecular As mentioned above, this model may be applied not only
flow of the background gas would be the primary condition to circular magnetron systems but also to noncircular mag-
netron systems such as rectangular ones. Rectangular mag- integration in the case of segments I and III. However, only
netron can be thought of as a combination of linear magne- the light gray triangle in Fig. 7~b! will be discussed in detail,
trons of parallel-type and perpendicular-type with respect to and then the total flux from segments I and III will be given
the sampling direction of the thickness profile ~Fig. 7!. The without further details. First of all, the upper limit for r in the
deposition profile can be obtained by summing the fluxes integration of Eq. ~12! is a function of f and is equal to
contributed by each segment divided, as shown in Fig. 7. b/cos f, hence the limits of the integration over r is 0 to
Segments I and III represent the areas where the magnetic b/cos f. Also, it can be easily shown that the limits for f in
field is a function of both x and y coordinates of the point of the integration is 0 to p/4 from Fig. 7~d!. Secondly, the x
interest, while segment II represents the area where it is an axis is shifted by a value of ‘‘a,’’ thus the ‘‘x’’ in Eq. ~12!
only function of its y coordinate. The dimension of each should be replaced by ‘‘x2a.’’ However, the x axis shift is
segment can be given, as shown in Fig. 7~a!, because the in the reverse direction for segment I and, accordingly, the
width of the open space @denoted by arrows in Fig. 7~a!# ‘‘x’’ should be replaced by ‘‘x1a.’’ Thirdly, assuming that
between magnetrons is usually the same. the maximum value of the B field, B max , in the r axis is
Since the magnetrons beneath the target have a mirror constant with a small variation of the distance between the
symmetry with respect to the x axis, the total flux from the ‘‘N’’ pole and ‘‘S’’ pole of the magnetrons, the equation for
target can be calculated by doubling the flux from the upper the B r will be
half part of the target @Fig. 7~b!#. The flux from each segment
will be treated in detail, and the equation for the total flux
will be given in the form of an integral which necessitates
the use of the finite elemental method. B r 52 ~ const! r r2 S b
cos f
. D ~18!
DH5 E E
p /4 b/cos f
x 2
r r2S
b
cos f
d2 D rdrd f . ~19!
0 0 @ r 22r ~ x2a ! cos f 1 ~ x2a ! 2 1d 2 # 2
If we denote the denominator of the integrand in Eq. ~12! as f (r,x,d, f ) then the total flux from segments I and III will be
0
b/cos f
0
S
r r2
b
cos f D
d2
f ~ r,x1a,d, f !
J rdrd f 1 E E
p /4
p /2 b/sin f
0
H S
r r2
b
sin f
d2
f ~ r,x1a,d, f !
D J rdrd f
1 E E
0
p /4
H Sb/cos f
0
r r2
b
cos fD d2
f ~ r,x2a,d, f !
J rdrd f 1 E E p /2
p /4
b/sin f
0
H S
r r2
b
sin f
d2
f ~ r,x2a,d, f !
D J G
rdrd f . ~20!
2. The sputtered flux from segment II in Fig. 7 Hence, the flux from the dark triangular region in Fig. 7 is
The derivation of the equation for the sputtered flux from
segment II in Fig. 7 will be done in the similar way to that of
Sec. IV B 1. In this section, only the dark gray triangular
region will be discussed in detail, and then the total flux will DH5 E tan21 ~ b/a !
0
E
0
a/cos f
x
r sin f ~ r sin f 2b ! d 2
~ r 2 22rx cos f 1x 2 1d 2 ! 2
be derived. First, the limits of the integration of Eq. ~12! over
r in this area are 0 to a/cos f, and those of integration over 3rdrd f . ~22!
f are 0 to tan21(b/a). Secondly, since the B field is an only
function of the y coordinate, the B r will be If we use the same notation for the denominator in Eq. ~22!
with Eq. ~20!, the total flux from segment II can be expressed
B r 52 ~ const! r sin f ~ r sin f 2b ! . ~21! as follows:
0
E
0
a/cos f r sin f 3 ~ r sin f 2b ! 3d 2
f ~ r,x,d, f !
rdrd f
1 E p /2
tan21 ~ b/a !
E 0
b/sin f r sin f 3 ~ r sin f 2b ! 3d 2
f ~ r,x,d, f !
rdrd f 1 E
0
tan21 ~ b/a !
E
0
a/cos f r sin f 3 ~ r sin f 2b ! 3d 2
f ~ r,2x,d, f !
rdrd f
1 E p /2
tan21 ~ b/a !
E 0
b/sin f r sin f 3 ~ r sin f 2b ! 3d
f ~ r,2x,d, f !
2
rdrd f . G ~23!