C) 2-Methyl-2-Propanol and Isobutyl Alcohol

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21. In which of the following pairs of names do both names represent the same alcohol?

A) 2-propanol and propyl alcohol


B) 1-propanol and isopropyl alcohol
C) 2-methyl-2-propanol and isobutyl alcohol
D) more than one correct response

In which of the following pairs of names do both names represent the same ether?
A) diethyl ether and 1,2-diethoxyethane
B) methyl isopropyl ether and 1-methoxypropane
C) ethyl isopropyl ether and 2-ethoxypropane
D) more than one correct response

Which of the following compounds contains two oxygen atoms?


A) 1,3-dimethoxybenzene
B) methoxycyclohexane
C) 2-ethoxy-1-propanol
D) more than one correct response

The hybridization of the central carbon in CH 3C≡N and the bond angle CCN are
a. sp2, 180°.
b. sp, 180°.
c. sp2, 120°.
d. sp3, 109°

What are the hybridizations of carbons 1 and 2 respectively in the following structure?

a. sp3 and sp2


b. sp2 and sp3
c. sp3 and sp
d. sp2 and sp2
What are the hybridizations of atoms 1 and 2 respectively in the following structure?

a. sp3 and sp2


b. sp2 and sp3
c. sp3 and sp
d. sp2 and sp2

Identify the orbital hybridization at the two indicated carbons in the molecule below.

a. C1: sp; C2: sp


b. C1: sp2; C2: sp2
c. C1: sp; C2: sp2
d. C1: sp2; C2: sp

Which substance would have the highest boiling point?


A) 2,2-dimethylpropane B) 2,3-dimethylpentane
C) heptane D) 2-methylheptane

Consider the three isomeric alkanes n-hexane, 2,3-dimethylbutane, and 2-


methylpentane. Which of the following correctly lists these compounds in order
of increasing boiling point?

a) 2,3-dimethylbutane < 2-methylpentane < n-hexane


b) 2-methylpentane < n-hexane < 2,3-dimethylbutane
c) 2-methylpentane < 2,3-dimethylbutane < n-hexane
d) n-hexane < 2-methylpentane < 2,3-dimethylbutane

Which are the correct orbital hybridizations for the carbon atoms in the following
structures ?
+
CH3CH3 CH2=CH2 CH3 HC N H2O
sp3 sp2 sp2 sp2 sp

III IV V
I II

(a) I, II, III (b) I, II, IV (c) II, III, V (d) III, IV, V

The relationship of the following two structures is

H3C Br Br Br
C C C C
Br CH3 H3C CH3

(a) structural isomers (b) geometric isomers (c) the same


(d) not isomeric (e) conformational isomers

The number of  bonds in the molecule shown below is


CH3CH=CHCH2C CH
(a) 1 (b) 2 (c) 3 (d) 4 (e) 5

Which is(are) the correct orbital hybridization(s) for the C and N atoms in the
following structures ?
CH3CH3 CH2=CH2 NH3 HC CH
sp3 sp sp2 sp2
I II III IV

(A) I (B) II, III (C) III, IV (D) I, III (E) II

Which name(s) is(are) acceptable for the following compound?

Cl CH3

(A) 5-chloro-2-methylcyclohexane
(B) 4-chloro-2-methylcyclohexane
(C) 1-chloro-3-methylcyclohexane
(D) 2-chloro-5-methylcyclohexane

The correct IUPAC name for is

CH3

a) 1-methyl-2-cyclopentene.
b) 2-methyl-1-cyclopentene.
c) 3-methylcyclopentene.
d) 1-methylcyclopentene

Cis-trans isomerism is possible for which of the following alkenes?


a) CH2=CH–CH2–CH2–CH3
b) CH3–CH=CH–CH2–CH3
c) CH3–CH=CH2
d) CH2=CH–CH2–CH3

Which of the following alkynes goes by the common name of acetylene?


a) ethyne
b) propyne
c) 1-butyne
d) 2-butyne

The IUPAC name for the hydrocarbon


CH3 CH2 CH2 CH CH2 CH3

is
a) 3-benzylhexane.
b) 4-benzylhexane.
c) 3-phenylhexane.
d) 4-phenylhexane.

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