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    Question Paper Central Outside Delhi 2016 Set 2 CBSE Class 12 Chemistry

    Uploaded by

    anush Jain
    This document contains a chemistry question paper from CBSE Class 12 with 26 questions covering various topics like organic chemistry reactions, inorganic chemistry, electrochemistry, coordination compounds and transition metals. The questions range from very short answer questions carrying 1 mark to long answer questions carrying 5 marks. General instructions are provided regarding answering the questions, permissible resources and time duration.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Question Paper Central Outside Delhi 2016 Set 2 CBSE Class 12 Chemistry

    Uploaded by

    anush Jain
    47 views6 pages
    This document contains a chemistry question paper from CBSE Class 12 with 26 questions covering various topics like organic chemistry reactions, inorganic chemistry, electrochemistry, coordination compounds and transition metals. The questions range from very short answer questions carrying 1 mark to long answer questions carrying 5 marks. General instructions are provided regarding answering the questions, permissible resources and time duration.

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    This document contains a chemistry question paper from CBSE Class 12 with 26 questions covering various topics like organic chemistry reactions, inorganic chemistry, electrochemistry, coordination compounds and transition metals. The questions range from very short answer questions carrying 1 mark to long answer questions carrying 5 marks. General instructions are provided regarding answering the questions, permissible resources and time duration.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    47 views6 pages

    Question Paper Central Outside Delhi 2016 Set 2 CBSE Class 12 Chemistry

    Uploaded by

    anush Jain
    This document contains a chemistry question paper from CBSE Class 12 with 26 questions covering various topics like organic chemistry reactions, inorganic chemistry, electrochemistry, coordination compounds and transition metals. The questions range from very short answer questions carrying 1 mark to long answer questions carrying 5 marks. General instructions are provided regarding answering the questions, permissible resources and time duration.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 6

    Question

    Paper Central Outside Delhi 2016 set 2


    CBSE Class 12 Chemistry

    General Instruction:

    All questions are compulsory.


    Questions number 1 to 5 are very short answer questions and carry 1 mark each.
    Questions number 6 to 10 are short answer questions and carry 2 marks each.
    Questions number 11 to 22 are also short answer questions and carry 3 marks each.
    Question number 23 is a value based question and carry 4 marks.
    Questions number 24 to 26 are long answer questions and carry 5 marks each.
    Use log tables, if necessary. Use of calculators is not allowed.

    1. Write the IUPAC name of the given compound:

    2. Write the structure of an isomer of compound C4H9Br which is most reactive towards SN1

    reaction.
    3. What is the reason for the stability of colloidal sols?
    4. Give an example each of a molecular solid and an ionic solid.
    5. Pb(NO3)2 on heating gives a brown gas which undergoes dimerization on cooling?

    Identify the gas.


    6. For a reaction: H2+CI2 2HCI

    i. Write the order and molecularity of this reaction.


    ii. Write the unit of k.
    7. Write the chemical equations involved in the following reactions:
    i. Hoffmann-bromamide degradation reaction
    ii. Carbylamine reaction
    8. i. Gas (A) is more soluble in water than Gas (B) at the same temperature.
    Which one of the two gases will have the higher value of (Henry’s constant) and

    Material downloaded from myCBSEguide.com. 1 / 6


    why?
    ii. In non-ideal solution, what type of deviation shows the formation of maximum
    boiling azeotropes ?
    9. When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3 moles of AgCl are

    precipitated per mole of the compound. Write


    i. Structural formula of the complex
    ii. IUPAC name of the complex
    10. Write the structures of the following:
    i. BrF3

    ii. XeF4

    OR

    What happens when:

    i. SO2 gas is passed through an aqueous solution Fe3+ salt?

    ii. XeF4 reacts with SbF5?

    11. Write the final product (s) in each of the following reactions:

    (a)

    (b)

    (c) C6H5-OH

    12. How do you convert: (i) Chlorobenzene to biphenyl (ii) Propene to 1-iodopropane (iii) 2-
    bromobutane to but-2-ene

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    OR

    Write the major product(s) in the following:

    i.

    ii.

    iii. CH3-CH2-Br

    13. i. Write the structural difference between starch and cellulose.


    ii. What type of linkage is present in Nucleic acids?
    iii. Give one example each for fibrous protein and globular protein.
    14. i. Name the method of refining of nickel
    ii. What is the role of cryolite in the extraction of aluminium?
    iii. What is the role of limestone in the extraction of iron from its oxides?
    15. Give reasons:
    i. SO2 is reducing while TeO2 is an oxidizing agent.

    ii. Nitrogen does not form pentahalide.


    iii. ICl is more reactive than I2.

    16. a. For the complex [Fe(H2O)6]3+, write the hybridization, magnetic character and spin of

    the complex. (At. number: Fe=26)

    b. Draw one of the geometrical isomers of the complex [Pt(en)2CI2]2+ which is optically

    inactive.
    17. An element crystallizes in a b.c.c. lattice with cell edge of 500pm. The density of the

    element is 7.5g cm-3. How many atoms are present in 300 g of the element?
    18. i. What is the role of Sulphur in the vulcanization of rubber?
    ii. Identify the monomers in the following polymer:

    Material downloaded from myCBSEguide.com. 3 / 6


    iii. Arrange the following polymers in the increasing order of their intermolecular forces:
    Terylene, Polythene, Neoprene
    19. For the first order thermal decomposition reaction, the following data were obtained:
    C2H5Cl(g)→C2H4(g) + HCl(g)

    Time / sec Total pressure / atm

    0 0.30

    300 0.50

    Calculate the rate constant


    (Given: log 2=0.301, log 3=0.4771, log 4=0.6021)
    20. Give reasons for the following:
    i. Aniline does not undergo Friedal-Crafts reaction.
    ii. (CH3)2 NH is more basic than (CH3)3N in an aqueous solution.

    iii. Primary amines have higher boiling point than tertiary amines.
    21. Define the following terms:
    i. Lyophilic colloid
    ii. Zeta potential
    iii. Associated colloids

    22. Calculate the boiling point of solution when 4 g of MgSO4 (M=120 g mol-1) was dissolved

    in 100 g of water, assuming MgSO4 undergoes complete ionization.

    (Kb for water=0.52 K kg mol-1)

    23. Due to hectic and busy schedule, Mr. Singh started taking junk food in the lunch break
    and slowly became habitual of eating food irregularly to excel in his field. One day during
    meeting he felt severe chest pain and fell down. Mr. Khanna, a close friend of Mr. Singh.
    took him to doctor immediately. The doctor diagnosed that Mr. Singh was suffering from
    acidity and prescribed some medicines. Mr. Khanna advised him to eat home made food
    and change his lifestyle by doing yoga, meditation and some physical exercise. Mr. Singh
    followed his friend’s advice and after few days he started feeling better.
    After reading the above passage, answer the following:

    Material downloaded from myCBSEguide.com. 4 / 6


    i. What are the values (at least two) displayed by Mr. Khanna?
    ii. What are antacids? Give one example.
    iii. Would it be advisable to take antacids for a long period of time? Give reason.
    24. a. Write the structures of A and B in the following reactions:
    1. CH3COCl

    2. CH3MgBr

    b. Distinguish between:
    1. C6H5-COCH3 and C6H5-CHO

    2. CH3COOH and HCOOH

    c. Arrange the following in the increasing order of their boiling points:


    CH3CHO, CH3COOH, CH3 CH2OH

    OR

    a. Write the chemical reaction involved in Wolff-Kishner reduction.


    b. Arrange the following in the increasing order of their reactivity towards nucleophilic
    addition reaction:
    C6H5COCH3, CH3-CHO, CH3COCH3

    c. Why carboxylic acid does not give reactions of carbonyl group?


    d. Write the product in the following reaction
    CH3CH2CH=CH-CH2CN

    e. A and B are two functional isomers of compound C3H6O. On heating with NaOH and

    I2, isomer B forms yellow precipitate of iodoform whereas isomer A does not form

    any precipitate. Write the formulae of A and B.


    25. a. Calculate E°cell for the following reaction at 298K:

    2Al(s)+ 3Cu2+(0.01M)→2AI3+ (0.01M) +3Cu(s)


    Given: Ecell =1.98 V

    b. Using the E° values of A and B, predict which is better for coating the surface of iron

    [E°(Fe2+/Fe) =-0.44V] to prevent corrosion and why?

    Given: E° (A2+/A)5=-2.37V: E° (B2+/B)=-0.14V

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    OR

    a. The conductivity of 0.001 mol L-1 solution of CH3COOH is 3.905 10-5 S cm-1. Calculate

    its molar conductivity and degree of dissociation (∝).

    Given (H+)=349.6 S cm2 mol-1 and (CH3 COO-)=40.9 S mol-1

    b. Define electrochemical cell. What happens if external potential applied becomes


    greater than E°cell of electrochemical cell?

    26. a. Account for the following:


    i. Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows
    the highest oxidation state of +4.

    ii. Cr2+ is a strong reducing agent.

    iii. Cu2+ salts are coloured while Zn2+ salts are white.
    b. Complete the following equations:
    i. 2MnO2 4KOH+O2

    ii.

    OR

    a. The elements of 3d transition series are given as:


    Sc Ti V Cr Mn Fe Co Ni Cu Zn
    b. Answer the following:
    i. Write the element which shows maximum number of oxidation states.
    Give reason.
    ii. Which element has the highest m.p?
    iii. Which element shows only +3 oxidation state?
    iv. Which element is a strong oxidizing agent in +3 oxidation state and why?

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