Chemistry (Theory)

Time Allowed: 3 hours Maximum Marks: 70

General Instructions:
(i) All questions are compulsory.
(ii) Questions number 1 to 5 are very short answer questions and carry 1 mark each.
(iii) Questions number 6 to 10 are short answer questions and carry 2 marks each.
(iv) Questions number 11 to 22 are also short answer questions and carry 3 marks each.
(v) Question number 23 is a value based question and carry 4 marks.
(vi) Questions number 24 to 26 are long answer questions and carry 5 marks each.
(vii) Use log tables, if necessary. Use of calculators is not allowed

1. (CH3)3C—CHO does not undergo aldol condensation. Comment. 1

2. In the process of wine making, ripened grapes are crushed so that sugar and 1
enzyme should come in contact with each other and fermentation should
start. What will happen if anaerobic conditions are not maintained during
this process?

3. A coordination compound with molecular formula CrCl3.4H2O precipitates 1

one mole of AgCl with AgNO3 solution. Its molar conductivity is found to be
equivalent to two ions. What is the structural formula and name of the
compound?

4. How is Brownian movement responsible for the stability of sols? 1

5.  Ea 1
In the Arrhenius equation, what does the factor e RT
corresponds to?

6. (i) Allyl cholride can be distinguished from Vinyl chloride by NaOH and silver 2
nitrate test. Comment.
(ii) Alkyl halide reacts with Lithium aluminium hydride to give alkane. Name
the attacking reagent which will bring out this change.

7. Which of the following solutions has higher freezing point? 2

0.05 M Al2(SO4)3 , 0.1 M K3[Fe(CN)6] Justify.

8. Calculate the emf of the following cell at 298 K : 2

Cr(s) / Cr3+ (0.1M) // Fe2+ (0.01M) / Fe(s)
0
[Given : ECell = + 0.30 V]
OR
The conductivity of 10 mol /L acetic acid at 250C is 4.1 x 10 -5 S cm-1.
-3

Calculate its degree of dissociation, if  0m for acetic acid at 250C is 390.5 S

cm2 mol-1.

9. What happens when: 2

 (i) Orthophosphorus acid is heated?
(ii) XeF6 undergoes complete hydrolysis?

10. Identify the following: 2

(i) Oxoanion of chromium which is stable in acidic medium.
(ii) The lanthanoid element that exhibits +4 oxidation state.
(iii)
11. Give the IUPAC name of the product formed when: 3
(i) 2-Methyl-1-bromopropane is treated with sodium in the presence of
dry ether.
(ii) 1- Methyl cyclohexene is treated with HI.
(iii) Chloroethane is treated with silver nitrite.

12. The freezing point of benzene decreases by 2.12 K when 2.5 g of benzoic acid 3
(C6H5COOH) is dissolved in 25 g of benzene. If benzoic acid forms a dimer in
benzene, calculate the van’t Hoff factor and the percentage association of
benzoic acid. (Kf for benzene = 5.12 K kg mol-1)

13. Explain the following behaviours: 3

(i) Alcohols are more soluble in water than the hydrocarbons of
comparable molecular masses.
(ii) Ortho-nitrophenol is more acidic than ortho-methoxyphenol.
(iii) Cumene is a better starting material for the preparation of phenol.

14. The rate constant for a first order reaction is 60 s-1. How much time will it 3
take to reduce 1g of the reactant to 0.0625 g?

15. (i) Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The limiting 3
molar conductivity of ‘B’ increases 1.5 times while that of ‘A’
increases 25times. Which of the two is a strong electrolyte? Justify
your answer.
(ii) The products of electrolysis of aqueous NaCl at the respective
electrodes are :
Cathode : H2
Anode : Cl2 and not O2. Explain.

16. (i) Write the expression for Freundlich’s equation to describe the 3
behaviour of adsorption from solution.
(ii) What causes charge on sol particles?
(iii) Name the promoter used in the Haber’s process for the manufacture
of ammonia.

17. An organic aromatic compound ‘A’ with the molecular formula C6H7N is 3
sparingly soluble in water. ‘A’ on treatment with dil HCI gives a water soluble
compound ‘B’. ‘A’ also reacts with chloroform in presence of alcoholic KOH
to form an obnoxious smelling compound ‘C’. ‘A’ reacts with benzene
sulphonyl chloride to form an alkali soluble compound ‘D’.’A’ reacts with
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CBSE Sample Papers for Class 12 Chemistry 2019

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 NaNO2 and HCl to form a compound ‘E’ which on reaction with phenol forms
an orange red dye ‘F’. Elucidate the structures of the organic compounds
from ‘A’ to ‘F’.

18. (i) Which vitamin deficiency causes rickets? 3

(ii) Name the base that is found in nucleotide of RNA only.
(iii) Glucose on reaction with acetic acid gives glucose penta acetate. What
does it suggest about the structure of glucose?

19. Name the type of reaction involved in the formation of the following 3
polymers from their respective monomers
(i) PVC.
(ii) Nylon6.
(iii) PHBV.

20. Describe the role of 3

(i) NaCN in the extraction of gold from its ore.
(ii) Cryolite in the extraction of aluminium from pure alumina.
(iii) CO in the purification of Nickel

21. A metal ion Mn+ having d4 valence electronic configuration combines with 3
three bidentate ligands to form a complex compound. Assuming  o  P :
(i) Write the electronic configuration of d4 ion.
(ii) What type of hybridisation will Mn+ ion has?
(iii) Name the type of isomerism exhibited by this complex.

22. The magnetic moments of few transition metal ions are given below: 3
Metal ion Magnetic moment(BM)
Sc3+ 0.00
2+
Cr 4.90
2+
Ni 2.84
Ti3+ 1.73
(at no. Sc = 21, Ti =22, Cr = 24, Ni = 28)
Which of the given metal ions :
(i) has the maximum number of unpaired electrons?
(ii) forms colourless aqueous solution?
(iii) exhibits the most stable +3 oxidation state?

OR

Consider the standard electrode potential values (M2+ / M) of the elements of

the first transition series.
Ti V Cr Mn Fe Co Ni Cu Zn
-1.63 -1.18 -0.90 -1.18 -0.44 -0.28 -0.25 +0.34 -0.76
Explain:
(i) Eo value for copper is positive.
(ii) Eo value of Mn is more negative as expected from the trend.
 (iii) Cr2+ is a stronger reducing agent than Fe2+.

23. Ashwin observed that his friend Shubham was staying aloof, not playing with 4
friends and becoming easily irritable for some weeks. Ashwin told his teacher
about this, who, in turn, called Shubham’s parents and advised them to
consult a doctor. Doctor after examining Shubham prescribed antidepressant
drugs for him.
After reading the above passage, answer the following questions:
i) Name two antidepressant drugs.
ii) Mention the values shown by Ashwin.
iii) How should Shubham’s family help him other than providing medicine?
iv) What is the scientific explanation for the feeling of depression?

24. (a) Arrange the following in the order of property indicated against each 5
set:
(i) F2, Cl2, Br2, I2 (increasing bond dissociation enthalpy)
(ii) H2O, H2S, H2Se, H2Te (increasing acidic character)
(b) A colourless gas ‘A’ with a pungent odour is highly soluble in water
and its aqueous solution is weakly basic. As a weak base it
precipitates the hydroxides of many metals from their salt solution.
Gas ‘A’ finds application in detection of metal ions. It gives a deep
blue colouration with copper ions. Identify the gas ‘A’ and write the
chemical equations involved in the following:
(i) Gas ‘A’ with copper ions
(ii) Solution of gas ‘A’ with ZnSO4 solution.

OR

Answer the following questions

(a) Write the formula of the neutral molecule which is isoelectronic with
ClO-.
(b) Draw the shape of H2S2O7.
(c) Nitric acid forms an oxide of nitrogen on reaction with P4.Write the
formula of the stable molecule formed when this oxide undergoes
dimerisation.
(d) Bleaching action of chlorine is permanent. Justify.
(e) Write the disproportionation reaction of that oxoacid of nitrogen in
which nitrogen is in +3 oxidation state.

25. Write the products of the following reactions: 5

(b) Give simple chemical tests to distinguish between the following pairs of
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 compounds:
(i) Benzaldehyde and Benzoic acid
(ii) Propanal and Propanone
OR
(a) Account for the following:
(i) CH3CHO is more reactive than CH3COCH3 towards reaction with HCN.
(ii) 2-Fluorobutanoic acid is a stronger acid than 3-Fluorobutanoic acid.
(b) Write the chemical equations to illustrate the following name reactions:
(i) Etard reaction.
(ii) Rosenmund’s reaction.
(c) Give the mechanism of cyanohydrin formation when carbonyl
compounds react with HCN in the presence of alkali.
26. (i) Following is the schematic alignment of magnetic moments: 5

Identify the type of magnetism. What happens when these substances

are heated?
(ii) If the radius of the octahedral void is ‘r’ and radius of the atoms in
close packing is ‘R’. What is the relation between ‘r’ and ‘R’?
(iii) Tungsten crystallizes in body centred cubic unit cell. If the edge of the
unit cell is 316.5 pm. What is the radius of tungsten atom?
OR
(i) Identify the type of defect shown in the following figure:

What type of substances show this defect?

(ii) A metal crystallizes in a body centred cubic structure. If ‘a’ is the
edge length of its unit cell, ‘r’ is the radius of the sphere. What is
the relationship between ‘r’ and ‘a’?
(iii) An element with molar mass 63 g / mol forms a cubic unit cell
with edge length of 360.8 pm. If its density is 8.92 g/ cm3. What is
the nature of the cubic unit cell?
Class 12 Chemistry
NCERT Solutions NCERT Exemplar CBSE Notes
Chapter 1 The Solid State Solid State The Solid State
Chapter 2 Solutions Solutions Solutions
Chapter 3 Electro chemistry Electrochemistry Electro chemistry
Chapter 4 Chemical Kinetics Chemical Kinetics Chemical Kinetics
Chapter 5 Surface Chemistry Surface Chemistry Surface Chemistry
Chapter 6 General Principles and General Principles and Processes General Principles and Processes
Processes of Isolation of Elements of Isolation of Elements of Isolation of Elements
Chapter 7 The p Block Elements The p-Block Elements The p Block Elements
Chapter 8 The d and f Block Elements The d- and f-Block Elements The d and f Block Elements
Chapter 9 Coordination Compounds Coordination Compounds Coordination Compounds
Chapter 10 Haloalkanes and
Haloalkanes and Haloarenes Haloalkanes and Haloarenes
Haloarenes
Chapter 11 Alcohols Phenols and
Alcohols, Phenols and Ethers Alcohols Phenols and Ethers
Ethers
Chapter 12 Aldehydes Ketones and Aldehydes, Ketones and Aldehydes Ketones and
Carboxylic Acids Carboxylic Acids Carboxylic Acids
Chapter 13 Amines Amines Amines
Chapter 14 Biomolecules Biomolecules Biomolecules
Chapter 15 Polymers Polymers Polymers
Chapter 16 Chemistry in Everyday
Chemistry in Everyday Life Chemistry in Everyday Life
Life

JEE Main Chemistry Chapter wise Previous Year Questions

Basic Concepts and Stoichometry Haloalkenes and Haloarenes
States of Matter: Gases,Liquids and Solids Alcohols,Ethers,Carobonyls and Carboxylic Acids
Atomic Structure and Electronic Configuration Nitro,Amine and Azo Compounds
Periodic Classification and Properties Solutions and Colligative Properties
Chemical Bonding and Molecular Structure Kinetics,Catalysis and Surface Chemistry
Elements of S-Block : Hydrogen,Group 1 and 2 Chemical and Lonic Equilibrium
Elements of p-Block: Groups 13,14,15,16,17 and 18 Redox Reactions and Electrochemistry
Elements of d-Block,f-Block and Complexes Thermodynamics and Chemical Energitics
Metallurgy and Environmental Chemistry Biomolecules and Polymers
General Organic Chemistry Chemistry in Everyday Life and Miscellaneous
Alkanes ,Alkenes ,Alkynes and Arenes

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Class 12 Chemistry Lab Manual
1. Introduction to Basic Laboratory Equipment
1. Viva Questions with Answers.
2. Surface Chemistry
1. Exp-2.1 : To prepare colloidal solution (sol) of starch.
2. Exp-2.2 : To prepare a colloidal solution of gum.
3. Exp-2.3 : To prepare colloidal solution (or sol) of egg albumin.
4. Exp-2.4 : To prepare ferric hydroxide, [Fe(OH)3] sol.
5. Exp-2.5 : To prepare aluminium hydroxide, [Al(OH)3] sol.
6. Exp-2.6 : To prepare colloidal solution of arsenious sulphide, [As2 S3].
7. Exp-2.7 :To study the dialysis of starch sol containing sodium chloride through a cellophane or
parchment paper.
8. Exp-2.8 : Compare the precipitation values of sodium chloride, barium chloride and aluminium
chloride for arsenious sulphide sol.
9. Exp-2.9 : To study the effectiveness of different common oils (castor oil, cotton seed oil,
coconut oil, kerosene oil, mustard oil) in forming emulsions.
10. Exp-2.10 : To compare the effectiveness of a number of emulsifying agents in forming
emulsions.
11. Surface Chemistry Viva Questions with Answers.
3. Chemical Kinetics
1. Exp-3.1 : To study the effect of concentration on the rate of reaction between sodium
thiosulphate and hydrochloric acid.
2. Exp-3.2 : To study the effect of change in temperature on the rate of reaction between sodium
thiosulphate and hydrochloric acid.
3. Exp-3.3 : To study the reaction rate of reaction of iodide ions with hydrogen peroxide at
different concentrations of iodide ions.
4. Exp-3.4 : To study the reaction rate of the reaction between potassium iodate (KIO3) and
sodium sulphite (Na2S03) using starch solution as indicator.
5. Chemical Kinetics Viva Questions with Answers.
4. Thermochemistry
1. Exp-4.1 : Determine the calorimeter constant (W) of calorimeter (polythene bottle).
2. Exp-4.2 : Determine the enthalpy of dissolution of given solid copper sulphate (CuS04.5H20) in
water at room temperature.
3. Exp-4.3 : Determine the enthalpy of neutralisation of hydrochloric acid with sodium hydroxide
solution.
4. Exp-4.4 : Determine the enthalpy change during the interaction (hydrogen bond formation)
between acetone and chloroform.
5. Thermochemistry Viva Questions with Answers.
5. Electrochemistry
1. Exp-5.1 : To set up simple Daniell cell and determine its emf .
2. Exp-5.2 : To set up simple Daniell cell using salt bridge and determine its emf .
3. Exp-5.3 : To study the variation of cell potential in Zn | Zn2+ || Cu2+ | Cu cell with change in
concentration of electrolytes (CuS04 and ZnS04) at room temperature.
4. Electrochemistry Viva Questions with Answers.
6. Chromatography
1. Exp-6.1 : Separate the coloured components present in the mixture of red and blue inks by
ascending paper chromatography and find their Rf values .
2. Exp-6.2 : Separate the coloured components present in the given grass/flower by ascending
paper chromatography and determine their Rf values .
3. Exp-6.3 : Separate Co2+ and Ni2+ ions present in the given mixture by using ascending paper
chromatography and determine their Rf values .
4. Chromatography Viva Questions with Answers.
7. Preparation of Inorganic Compounds
1. Exp-7.1 : To prepare a pure sample of ferrous ammonium sulphate (Mohr’s salt), [FeSO4 .
(NH4)2 SO4.6HO20] .
2. Exp-7.2 : To prepare a pure sample of potash alum (Fitkari), [K2SO4.Al2 (SO4)3. 24H20] .

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 3. Exp-7.3 : To prepare a pure sample of the complex potassium trioxalatoferrate(III),
Kg[Fe(C2O4)3l . 3H20 .
4. Preparation of Inorganic Compounds Viva Questions with Answers.
8. Preparation of Organic Compounds
1. Exp-8.1 : To prepare a sample of acetanilide from aniline.
2. Exp-8.2 : To prepare a sample of dibenzalacetone.
3. Exp-8.3 : To prepare a sample of p-nitroacetanilide from acetanilide .
4. Exp-8.4 : To prepare 2-naphthol aniline or phenyl-azo-β-naphtholdye .
5. Preparation of Organic Compounds Viva Questions with Answers.
9. Tests for the Functional Groups Present in Organic Compounds
1. Exp-9.1 : Identify the functional group present in the given organic compound.
2. Tests for the Functional Groups Present in Organic Compounds Viva Questions with Answers.
10. Tests of Carbohydrates, Fats and Proteins in Pure Samples and Detection of Their Presence in Given
Food Stuffs
1. Exp-10.1 : To study some simple tests of carbohydrates .
2. Exp-10.2 : To study some simple tests of oils and fats .
3. Exp-10.3 : To study some simple tests of proteins .
4. Exp-10.4 : To detect the presence of carbohydrates, fats and proteins in the following food
stuffs : Grapes, potatoes, rice, butter, biscuits, milk, groundnut, boiled egg .
5. Tests of Carbohydrates, Fats and Proteins in Pure Samples and Detection of Their Presence in
Given Food Stuffs Viva Questions with Answers.
11. Volumetric Analysis
1. Exp-11.1 : Prepare 250 ml of M/10 solution of oxalic acid from crystalline oxalic acid .
2. Exp-11.2 : Prepare 250 ml of a N/10 solution of oxalic acid from crystalline oxalic acid .
3. Exp-11.3 : Preparation of 250 ml of M/20 solution of Mohr’s salt .
4. Exp-11.4 : Preparation of 250 ml of N/20 solution of Mohr’s salt .
5. Exp-11.5 : Prepare M/20 solution of ferrous ammonium sulphate (Mohr’s salt). Using this
solution find out the molarity and strength of the given KMn04 solution.
6. Exp-11.6 : Prepare a solution of ferrous ammonium sulphate (Mohr’s salt) containing exactly
17.0 g of the salt in one litre. With the help of this solution, determine the molarity and the
concentration of KMnO4 in the given solution.
7. Exp-11.7 : Prepare M/20 ferrous ammonium sulphate (Mohr’s salt) solution. Find out the
percentage purity of impure KMnO4 sample 2.0 g of which have been dissolved per litre .
8. Exp-11.8 : Determine the equivalent mass and number of molecules of water of crystallisation
in a sample of Mohr’s salt, FeSO4(NH4)2 SO4 . nH20. Provided KMnO4.
9. Exp-11.9 : Prepare M/50 solution of oxalic acid. With its help, determine 50 the molarity and
strength of the given solution of potassium permanganate (KMnO4).
10. Exp-11.10 : Find out the percentage purity of impure sample of oxalic acid. You are supplied
M/100 KMnO4 solution.
11. Exp-11.11 : The given solution has been prepared by dissolving 1.6 g of an alkali metal
permanganate per litre of solution. Determine volumetrically the atomic mass of the alkali
metal. Prepare M/20 Mohr’s salt solution for titration.
12. Exp-11.12 : Determine the percentage composition of a mixture of sodium

oxalate and oxalic acid . Provided M/100

KMnO4 solution.
13. Exp-11.13 : You are provided with a partially oxidised sample of ferrous sulphate
(FeSO4.7H20) crystals. Prepare a solution by dissolving 14.0 g of these crystals per litre and
determine the percentage oxidation of the given sample. Given M/100 KMnO4 solution.
14. Exp-11.14 : Calculate the percentage of Fe2+ ions in a sample of ferrous sulphate. Prepare a
solution of the given sample having strength exactly equal to 14.0 g/litre. Provided M/100
KMnO4 .
15. Exp-11.15 : Prepare N/20 Mohr’s salt solution. Using this solution, determine the normality
and strength of the given potassium permanganate solution.

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 16. Exp-11.16 : Prepare N/20 solution of oxalic acid. Using this solution, find out strength and
normality of the given potassium permanganate solution .
17. Exp-11.17 : Determine the percentage purity of the given sample of oxalic acid. Ask for your
requirement .
18. Exp-11.18 : Determine the percentage composition of a mixture of sodium

oxalate and oxalic acid . Provided N/20 KMnO4 .

19. Exp-11.19 : Determine the equivalent mass and number of molecules of water of
crystallisation in a sample of Mohr’s salt FeSO4 (NH4)2 SO4.nH20. Provided N/20 KMnO4.
20. Volumetric Analysis Viva Questions with Answers.
12. Chemistry Qualitative Analysis
1. Exp-12.1 : To analyse the given salt for acidic and basic radicals .
2. Exp-12.2 : To analyse the given salt for acidic and basic radicals CO, Zn.
3. Qualitative Analysis Viva Questions with Answers.

NEET Chemistry Chapter wise Important Questions

Some Basic Concepts of Chemistry Chemical Kinetics

Atomic Structure Concept of Chemical Kinetics
Classification and Periodicity of Elements Order of Reaction
Chemical Bonding and Molecular Structure Effect of Temperature on Rate of Reactions
States of Matter ( Gaseous and Liquid State) Surface Chemistry
Unit Test 1(General Chemistry) Concept of Surface Chemistry
Chemical Thermodynamics Factors Affecting Adsorption of Gases on Solids
Thermodynamics Promoters and Inhibitors
First Law of Thermodynamics Preparation of Lyophobic Solution
Hess’s Law of Constant Heat Summation Unit Test 5(Physical Chemistry II)
Second Law of Thermodynamics General Principles and Processes of Isolation of Metals
Equilibrium Earth Crust
Equilibrium State Extraction of Crude Metal from Concentrated Ore
Le-Chatelier's Principle Thermodynamics of Metallurgy
Acids and Bases p-Block Elements
Salt Hydrolysis Group-15 Elements: Nitrogen Family
Redox Reactions Dinitrogen
Concepts of Oxidation and Reduction Phosphorus
Oxidation Number Group-16 Elements: Oxygen Family
Redox Reactions Allotropic forms of Sulphur
Unit Test 2(Physical Chemistry I) Group-17 Elements: Halogens
Hydrogen Group-18 Elements: Noble Gases
Occurrence of Hydrogen The d- and f- Block Elements
Compounds of Hydrogen d-Block Elements

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Hard and Soft Water General Properties of the Transition Elements
s-Block Elements Some Important Compounds of Transition Elements
General Introduction of S-Block Elements Coordination Compounds
Anomalous Properties of Lithium Complex or Coordination Compounds
Biological Importance of Sodium and Potassium Effective Atomic Number Rule
p-Block Elements (Inorganic Chemistry) Bonding in Coordination Compounds
Concept of p-Block Elements Crystal Field Theory (CFT)
Group 13 Elements: Boron Family Unit Test 6(Inorganic Chemistry II)
Some Important Compounds of Group 13
Haloalkanes and Haloarenes
Elements
Group 14 Elements: Carbon Family Alkyl and Aryl Halides
Unit Test 3(Inorganic Chemistry I) Preparation of Aryl Halides
Stereochemical Aspects of Nucleophilic Substitution
Some Basic Principles and Techniques
Reactions
Concept of Organic Chemistry Polyhalogen Compounds
Representation of Different Formula Alcohols, Phenols and Ethers
Isomerism Alcohols and Phenols
Free Radicals Chemical Properties of Alcohols
Types of Organic Reactions Phenols
Chromatography Ethers
Hydrocarbons Aldehydes, Ketones and Carboxylic Acids
Concept of Hydrocarbons Aldehydes and Ketones
Chemical Properties of Alkanes Preparation of Aldehydes
Alkenes Preparation of Ketones
Alkynes Properties
Aromatic Hydrocarbons Uses of Aldehydes and Ketones
Environmental Chemistry Organic Compounds Containing Nitrogen
Environmental Pollution Amines
Air Pollution Properties of Amines
Tropospheric Pollution Hofmann Mustard Oil Reaction
Water Pollution Cyanides
Unit Test 4(Oreganic and Environmental
Biomolecules
Chemistry I)
Solid State Concept of Biomolecules
Concept of Solids Structure of Fructose
Packing Efficiency Proteins
Defects or Imperfections in Solids Nucleic Acids
Magnetic Properties of Solids Polymers
Solutions Concept of Polymers

CBSE Sample Papers NCERT Solutions LearnCBSE.in

Solutions in Chemistry Polymerisation
Vapour Pressure Vulcanisation of Rubber
Ideal Solutions Polyesters
Electrochemistry Chemistry in Everyday life
Concept of Electrochemistry Chemicals in Medicines
Electrochemical Cell Antimicrobials
Representation of a Cell Soaps
Nernst Equation Unit Test 7(Organic Chemistry II)
Mock Test 1
Mock Test 2
Mock Test 3

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