Alkanes, Alkenes and Alkynes
Alkanes, Alkenes and Alkynes
Alkanes, Alkenes and Alkynes
I
Subject: Chemistry I
Unit: III(A)
Organic Chemistry - Introduction
Organic chemistry is the study of carbon
compounds.
Intro
Bonding in Organic Compounds
Besides carbon, the most common elements in
organic compounds are hydrogen, oxygen,
nitrogen, sulfur, and the halogens.
Section 14.2
Hydrocarbons
Aliphatic Aromatic
Hydrocarbons
Aliphatic Aromatic
Alkanes are
hydrocarbons in which
all of the bonds are
Aliphatic
single bonds.
H H
Alkanes H C C H
H H
Hydrocarbons
Alkenes are
hydrocarbons that
contain a carbon-
Aliphatic
carbon double bond.
H H
Alkenes C C
H H
Hydrocarbons
Alkynes are
hydrocarbons that
contain a carbon-
Aliphatic
carbon triple bond.
Alkynes
HC CH
Hydrocarbons
H H
H H
H
Aliphatic Hydrocarbons
Aliphatic hydrocarbons are hydrocarbons having
no benzene rings.
Aliphatic hydrocarbons can be divided into four
major divisions:
Alkanes
Cycloalkanes
Alkenes
Alkynes
Classification of Hydrocarbons
Alkanes
Alkanes are hydrocarbons that contain only single
bonds.
Alkanes are said to be saturated hydrocarbons
Because their hydrogen content is at a maximum.
Ball-and-Stick models – 3D
models that can be built by
students
Models of Three Alkanes
Names, Structural Formulas, Condensed Structural
Formulas, and Ball-and-Stick Models
Methane – Tetrahedral Geometry
Ball-and-
Stick &
Space-
Filling
Models
Carbon’s
four single
bonds form
angles of
109.5o
2
Alkyl Group
Alkyl group contains one less hydrogen than the
corresponding alkane.
General abbreviation “R” (for Radical, an
incomplete species or the “rest” of the molecule)
Section 14.3
Alkyl Group
This group does not exist independently but occurs bonded to another
atom or molecule.
Types of Alkyl groups
Ball-and-Stick
Model
Isobutane (2-methylpropane)
Branched-chain Structure
Structural C4H10
Formula
Ball-and-
Stick
Model
Organic Compound Nomenclature
Due to the large number, variety, and complexity of
organic compounds, a consistent method of
nomenclature has been developed.
Section 14.3
IUPAC System of Nomenclature
For Alkanes
Identify the longest chain -- parent
number from the end closest to first branch
Name the groups attached to the chain, using the
carbon number as the locator.
Alphabetize substituents.
Use di-, tri-, etc., for multiples of same substituent
combine number and name of substituent with
parent name, separating with hyphen
An Example to Consider
The longest continuous chain of C atoms is five
Therefore this compound is a pentane derivative
with an attached methyl group
Start numbering from end nearest the substituent
The methyl group is in the #2 position
The compound’s name is 2-methylpentane.
Longest Chain
The number of carbons in the longest chain
determines the base name: ethane, hexane.
If there are two possible chains with the same
number of carbons, use the chain with the most
substituents.
H3C
CH CH2 CH3
CH3
H3C CH2 C CH CH2 CH2 CH3
CH3
Find the longest continuous
carbon chain
1 2 3
CH3 CH2 CH CH3
CH2 CH3
4 5
3-methylpentane
You must choose the longest
continuous carbon chain
4 3 2 1
CH3 CH2 CH CH2 CH2 CH3
4-ethylheptane
Number from the end nearest
the first substituent
CH2 CH3
4-ethyl-3-methylheptane
Number from the end nearest
the first substituent
CH3
3-ethyl-5-methyloctane
Use “di-” with two substituents
CH3
CH3 CH CH CH3
CH3
2,3-dimethylbutane
Every substituent must get a number
CH3
3,3-dimethylhexane
Number from the end nearest
first substituent
CH3
2,7,8-trimethyldecane
Number from the end which has
the “first difference”
CH3
3,4,8-trimethyldecane
A More-Highly-Substituted
Carbon Takes Precedence
CH3 CH3
2,2,4-Trimethylpentane
Which end do we number from?
3-ethyl-6-methyloctane
Substituents in Organic
Compounds
Section 14.3
Drawing a Structure from a Name
Draw the structural formula for
2,2,4trimethylpentane.
Note that the end name is pentane .
Draw a continuous chain of five carbon (C) atoms,
with four bonds around each.
Drawing a Structure from a Name
Section 14.3
Cycloalkanes
Members of the cycloalkane group possess rings of
carbon atoms.
They have the general formula CnH2n.
Each carbon atom is bonded to a total of four
carbon or hydrogen atoms.
The smallest possible ring consists of
cyclopropane, C3H6.
Section 14.3
The First Four Cycloalkanes
Section 14.3
Drawing the Structure of a
Cycloalkane
Draw the geometric figure indicated by the
compound’s name , “pentane.”
Section 14.3
Drawing the Structure of a
Cycloalkane
Place each substituent on the ring in the numbered
position “1 chloro-2-ethyl-”
1-chloro-2-ethylcyclopentane
Section 14.3
Classes of Carbon and
Hydrogen atoms
1o Carbon - primary carbon is attached to only
one other C atoms
48
Derivatives of Hydrocarbons
Organic molecule characteristics depend on the
number, arrangement, and type of atoms.
Functional Group – any atom, group of atoms,
or organization of bonds that determine
specific properties of a molecule
Generally the functional group is the reactive part of
the molecule.
Due to the functional group’s presence, certain
predictable properties rise.
Section 14.4
Alkenes
Members of the alkene group have a double bond
between two carbon atoms.
One hydrogen atom has been removed from two
adjacent carbon atoms, thereby allowing the two
adjacent carbon atoms to form a double bond.
C2H4
Section 14.3
Some Members of the Alkene
Series
Section 14.3
Physical properties:
Carbon-carbon double bond changes the physicals properties of
alkenes.
At R.T. , alkenes exist in all three phases, solid, liquids, and gases.
1. Physical state:
Ethene, Propene, and Butene exists as colorless gases.
Members of the 5 or more carbons such as Pentene, Hexene, and
Heptene are liquid
Members of the 15 carbons or more are solids.
Section 14.3
Example
Write the IUPAC name for each of the following:
CH3
B. CH3─CH2─C=CH─CH3 3 –methyl 2-pentene
6 5 4 3 2 1
CH3CH CH CH CH CH3
1 2 3 4 5 6
CH3 CH3
Note: Always number so that double bond gets the lowest number
Alkynes
Members of the alkyne group have a triple bond
between two carbon atoms.
Two hydrogen atoms have been removed from
each of two adjacent carbon atoms, thereby
allowing the two adjacent carbon atoms to form
a triple bond.
Section 14.3
Some Members of the Alkyne
Series
Section 14.3
Physical properties
1. Physical properties:
- First 3 members of alkyne : gaseous form
up to C8 : liquid,
more than 8 carbons: solid.
- Colorless & except ethyne all are odorless.
- Lighter than water
- Insoluble in polar and soluble in non polar organic
solvents.
- Melting point, Boiling point and increase with
molecular mass.
1 2 3 4 5 6 7
Name: 6-chloro-5-ethyl-4-methyl-2-heptyne
4-bromo-5-methyl-2-hexyne
6-chloro-3,3-dimethyl-4-octyne
GEOMETRICAL ISOMERISM
The geometrical isomerism arises when atoms or groups are
arranged differently in space due to restricted rotation of a
bond or bonds in a molecule.
E.g.,
1) Two different spatial arrangements of methyl groups about a
double bond in 2-butene give rise to the following geometrical
isomers.
i.e., cis-2-butene and trans-2-butene
Above two forms are not inter convertible due to restricted rotation of
double bond.
In the cis isomer, the two methyl groups are arranged on the same side of a
double bond.
Whereas in the trans isomer, they are on the opposite side.
2) There are two geometrical isomers (cis & trans) possible in case of 1,4–
dimethylcyclohexane as shown below:
3
In the above geometrical isomers, the methyl groups are arranged
differently about the plane of the cyclohexane ring. These isomers
are not inter convertible since it is not possible to rotate the bonds
in the cyclohexane ring.
In general, the trans isomers are more stable than cis isomers.
References
1.Organic Chemistry by Morrison and Boyd
2.https://www.google.com
3. https://sites.google.com