Production of Hydrogen Using WGSR
Production of Hydrogen Using WGSR
Production of Hydrogen Using WGSR
ABSTRACT
Hydrogen happens to be one of the most promising sources of energy. Hydrogen is a
propitious source of energy because it can be combusted, similar to gasoline and natural gas,
or converted to electricity in a fuel cell without any carbon emissions at the point of use. The
production of hydrogen can be achieved via various process technologies, Steam Methane
Reforming is the best industrial method to produce Hydrogen till date.
Water Gas Shift Reaction is a major part of Steam Methane Reforming process, the
flue gases after methanation has Carbon Monoxide and major part of unconverted steam.
WGSR increases the yield of Hydrogen produced by reacting carbon monoxide with the
remaining steam. This process is important for two reasons, firstly, it increases yield.
Secondly, converts CO to CO2, hence the emission of poisonous CO gas is avoided.
WGSR is divided into two parts, High Temperature Shift(HTS) and Low Temperature
Shift(LTS).Flues gases from SMR enters HTS Reactor which operates at 500-700K, where it
converts remaining steam by 35%, then the overhead is passed through a cooler to bring
down the temperature to 400K. Later, the cooled stream is taken into LTS Reactor which
operates at 300-400k, this is industrially used to increase the H2 yield by 2-3%. The vapor
outlet is cooled and sent to Gas-Liq Separator, where remaining steam is condensed to water
and the product gas is taken out, Pressure Swing Adsorption is done and the obtained
Hydrogen is liquified.
FLOWSHEET
RESULTS
High Temperature Shift Reaction
Compound Amount
Methane 0.016
Oxygen 0
Nitrogen 0.283
Water 0.1656
Hydrogen 0.3949
Carbon Monoxide 0
Carbon Dioxide 0.132
AKNOWLEDGEMENTS
1. Dr C. T. Puttaswamy, HOD, Department of Chemical Engineering, BMSCE.
2. Mr.Shivakumar R, Assistant Professor, Dept. of Chemical Engineering, BMSCE.
3. Dr. Kannan M. M., Professor, IIT Bombay, Mumbai.