Effectiveness of Durian Peel As Biomass Briquette
Effectiveness of Durian Peel As Biomass Briquette
Effectiveness of Durian Peel As Biomass Briquette
A Research Project
Presented to the Faculty of the Senior High School Department
University of Mindanao, Davao City
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singlespaces
spaces
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March 2019
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ABSTRACT
increases energy demands' and problem as well as its effects on daily use are
is encouraged. In connection to this, the aim of this study was to determine the
properties. Wherein, pure paper briquette was assigned as the control variable
specifically parallel group design where each subject is randomly assign to one
energy content and specific fuel consumption. However, fixed carbon content
and burning rate results showed that there is no significant difference among
and has the ability to be used as fuel; therefore, future researchers should
JOBERT C. REGIDOR
Research Instructor
PANEL OF EXAMINERS
CATHERINE DE LOYOLA
Chairperson
A CKNOWLEDGEMENT
This endeavor would not be made possible without the help of various
individuals. Without them, the researchers might not meet their objectives in
this study. The researchers would like to express their heartfelt appreciation to
Mr. Jobert C. Regidor, their research adviser, with whom they are
and reviewing the content of this study for the development of this paper;
Mr. Joey C. Oliveros, their Senior High School Principal, for the approval
of this endeavor;
Mr. John Rannilo Ortiz, their research statistician, for making their
research result be possible and the interpretation of data, for imparting his
knowledge, the guidance and the support for the betterment of the study. His
full support, their financial assistance, and for always being there for their ups
Above all, to the Almighty God who gave them the strength and wisdom,
hope and courage to pursue their studies and for guiding them throughout their
-Researchers
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TABLE OF CONTENTS
Page
Title Page i
Abstract ii
Approval and Endorsement Sheet iii
Acknowledgement iv
Table of Contents v
List of Tables and Figures vii
Chapter 1 Introduction
Background of the Study 1
Statement of the Problem 3
Hypothesis 3
Conceptual Framework 4
Significance of the Study 5
Scope and Limitation of the Study 5
Definition of Terms 6
Literature Review 7
Chapter 2 Methods
Research Design 18
Statistical Treatment 19
Research Procedure 19
References 49
Appendices
A Effectiveness of Durian Peel using Ash Content 57
Effectiveness of Durian Peel using Fixed Carbon
B 58
Content
C Effectiveness of Durian Peel using Energy Content 59
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vi
Table Page
Figure Page
Chapter 1
Introduction
increases energy demands' and problem and its effects on daily use are
deteriorating. The reason that strategies and endeavors are sought after to
keep up the supply balance and energy demand throughout the world that
Nuriana, Anisa and Martana (2014) stated that the stock of energy is very
definite to fossil fuel source which is not a sustainable resource for future life.
Hence, there are about 197 million metric tons of oil equivalent of energy that
the world consumes in a span of the year 2000 to 2017 (Enerdata, 2017). In
able to anticipate the crisis, there is a need for improved alternative energy
sources, namely solar energy, wind energy, biofuel, hydropower, and biomass
and must be applied productively. For instance, utilizing hydropower would not
devour the water utilized, rather it will just serve as a material or power to make
form of seeds and peels. Also, Wahyono (2009) stated that according to its
amylose which are considered as good binder agents. However, the potential
of durian residues such as its peels was rarely been considered and promoted
oxygen and 8.47% hydrogen, where the said results support the energy
fruit, but recently, it can be produced at any time of the year with the help of
2010). Durian residues came from its peel was almost covering around 60-76%
of the entire fruit (Foo & Hameed, 2012). In addition, in the entire area of Davao
region, the production of durian has reached up to 58.80571 metric tons and
about 69% or 37, 181.04 of it was produced only from Davao City (Arado, 2017).
Furthermore, Chandra et al. (2009) stated that a high number of the durian
diseases, due to its pungent smell. In response to this problem, utilizing durian
residue such as peel into solid biofuel, also known as biomass briquette has
been promoted to reduce the waste product of durian as well as its pungent
smell, and acquire its maximum capacity (Wahidin & Anisa, 2014).
Due to the growth of energy demand and depletion rate of fossil fuels to
through biomass briquetting. This study will be conducted to test the capability
of:
biomass briquette in terms of the resulting ash content, fixed carbon content,
Conceptual Framework
durian peel in regards to its amount to the change on the creation of thermal
combustion properties are composed of its ash content, fixed carbon, energy
INTERVENING
VARIABLE
Time
The figure illustrates that the amount of durian peel affects the
durian peel and the dependent variable is the combustibility rate with ash
content, fixed carbon, energy content and water boiling test as indicators. The
researchers will have a set-up with different amounts of durian peel for
briquetting. Each set-up will be tested by its combustibility rate through its
a substitute for the common use of coals that will contribute to minimizing the
pollution. The application of biomass briquettes will help lessen and recycle the
Family. The result of this study can be a useful guide for them to
understand that using biomass briquette will help minimize the pollution in the
environment through the given data. The given data would help them choose
ups with different durian peel amount mixture: 0%, 25%, 50%, 75%, and 100 %
durian peel. The primary data gathering method used was an experiment to
indicated by ash content, energy content, fixed carbon and water boiling test.
This study will be performed specifically in Davao City, where raw materials
were gathered from various fruit vendors that disposes their fruit peelings in
Ramon Magsaysay Fruit stand and offices for paper waste. Personal
6
consumption of durian fruits and paper waste also contributed to the quantity of
the raw materials. Materials and equipment needed for the experiment are
aluminum cans.
Definition of Terms
The following terms used in this study are conceptually and operationally
Durian Peel. In this study, the term refers to the outermost covering
layer of durian.
energy and as an organic material that comes from plant and animals. (Biomass
Explained, 2018).
matter used as fuel to start and maintain a fire (Alam, Islam, Hasan, & Siddique,
2011).
references of the variables under study: the amount of durian peel and
combustion rate.
Amount of Durian Peel. The higher the mass fraction of durian peel,
based on the study they conducted, where the different ratio of durian peel and
rice straw has experimented. Among the ratio of 1:9, 2:8, 3:7, 4:6, 5:5, 6:4, 7:3,
8:2 and 9:1, durian and rice straw, the results showed that the briquette made
of durian peel and rice straw at ratio 9:1 achieved 24.674 MJ/kg which
considered as the highest heating value among the other ratio. In addition, the
result also showed the lowest ash content of the briquette durian peel and rice
a biomass briquette made from the high amount of durian peel over rice straw
bio fuel briquette made from durian peel has a high heating value that can
(Sathitruangsak, 2003).
briquette made of pure durian peel without binder has 5883 cal/g calorific value,
which is higher than a briquette made from durian peel with binder, where
increases its compressive strength. A low calorific value briquette is not good
durian peel is one of the fruit waste samples that have high energy potential,
for having 17.60 MJ. kg. net calorific value. Wilaipon (2009) also pointed out
regarding the characteristics and heating value of durian peel that it has high
reaction includes the presence of oxygen as a reactant then carbon dioxide and
the change of time as stated from the website of Chemistry Libre Texts (2015).
Temperature, pressure, and concentration are factors that affect the rate of
combustion rate, and it affects the heat capacity. Combustion rate can be the
indicators: ash content, fixed carbon, energy content and water boiling test.
9
Ash Content. According to Tamilvanan (2013), the higher the ash the
fuel possess the lower the calorific value it has, for the reason that it is the non-
and Okonkwo (2013) stated that for the briquettes to have high heating values,
the ash content should be low. Whereas high ash content was believed to
potassium, magnesium, and phosphorus elements that affect the ash fusion
and was considered as an organic component that remains after the biomass
completed its combustion process. Minerals present in the ash when subjected
to high temperature and certain conditions can agglomerate and deposit inside
the thermal device leading to slag formation, fouling and bed agglomeration.
Ashes are usually formed of Cao, k2O, Na2O, MgO, SiO2, SO3, Fe2O3,
P2O5and Cl. The slagging behavior of briquettes was strongly affected by the
ash content, the reason why in briquetting the agricultural residues which
contain less than 4% ash content were more preferable because slagging do
not occur during densification (Mitan et al., 2004). In addition, Mitan et al. (2004)
stated that a biomass contain high ash content is not good to be an alternative
Fixed Carbon. The low fixed carbon content has a tendency to drag out
cooking time by its low warmth discharge, additionally the higher the fixed
carbon content the better the charcoal created because the relating calorific
vitality is normally high (Raju, Praveena, Sathya, & Jyothi, 2014). Moreover,
10
Nuriana et al., (2014) stated that the higher the temperature is, the more
content and high calorific value signifies that a fuel has a decent quality
matter. In addition, Cahyono, Santoso, and Miliati (2017) proposed that the
Kumar, Subbaiah, and Rao (2010) proposed that the level of fixed
example, moisture, volatile matter and ash content, of the aggregate biomass
in rate. Basically, the fixed carbon of a fuel is the level of carbon accessible for
ignition after all the volatile matter is expelled from the biomass. This is not
equivalent to the total amount of carbon present in the fuel because there is an
there is a high percentage of fixed carbon, the briquette’s heat value will
enhance, but the fixed carbon content and the calorific value of briquettes are
commercialized fuels and fire wood; however, the cost of briquette is cheaper
standard measure of the energy content of a fuel (Ikelle, Chukwuma, & Ivoms,
parameter that forms the energy content. High calorific value means the energy
11
(Raju et al., 2014). Hence, the greater calorific value, the easier and the better
will the briquette burn. Higher density also makes the briquette to last long and
the study of Onuegbu (2011), where a sample is burned and will show the
Water Boiling Test. Time is the variable for finding the burning rate speed
and the ignition of time was test by water boiling test. According to Onuegbu,
Ekpunobi, Ogbu, Ekeoma and Obumselu (2011), the potential of boiling water
at the same ignition time with the fastest time in a record was used to determine
the burning rate increased. Water boiling test was used to test which among
the set-ups is productive. In this way, the test was able to measure the time
taken for each set of briquettes to boil an equal quantity of water, under identical
Khandetod, Mohod, & Dhande, 2014). As stated by Onuegbu et al. (2011), the
factors that regulate the water boiling time are burning rate (how fast the fuel
burns) and the calorific value (how much heat is released). Furthermore,
burning rate can also be affected by the structural form of a briquette for it is
the ratio of the mass of the bio-fuel burnt (in grams) to the total time taken (in a
minute). Calorific value is also important for heat production and a factor for the
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Tanoh, Sidibe, Kpail and Tankoano (2018) stated that specific fuel consumption
is also a factor to be tested in the water boiling test which determines the
The amount of durian peel offers a great rate of combustion such as its
heating value. Whereas, combustion rate is the rate of burning a substance that
can be indicated by the following which are ash content, fixed carbon, energy
content and water boiling test. Ash content affects the rate of combustion by its
concentration; the higher the ash content, the lower the combustion rate.
determined by calorific value. Fixed carbon helps the briquette to stand high
burning rate increase in reaching the boiling point of water. The indicators are
briquettes.
year (Tembe, Otache, & Ekhuemelo, 2014). The growing interest for biomass
getting more expensive. Biomass are all living matter from plants and animal
waste material (Shreya & Sevita, 2015). Processing biomass into a form of
briquette which is effective and efficient for heating purposes. Briquette from
content, low density and energy values which people in many parts of the world
method in creating bio fuel to prevent shortage of materials due to the increase
of population.
Kathuria, and Grover (2012) stated that these wastes can be recycled as a
durian is produced each day and briquetting these wastes can be a solution to
pollution problems.
problem in the energy source. For many countries were looking for
energy resources, Sriram et al., (2014) stated that briquettes are of most
interest and expected to play a key role in global energy infrastructure in the
Philippines with 1,265,890 bearing trees. In the Davao region, about 8344
Act, was constituted in the Philippines in year 2000 in order to give guidelines
in dealing the increase problems of solid waste in the country, thus, most
14
as, sugar, rice and fruits. According to Lacrosse and Shakya (2004), most
lumber and agricultural operations in South East Asia, produces residues in the
Bujang and Safuan (2014), the edible portion of fruit like durian is only around
ripening of the fruits that have climacteric nature such as tropical fruits like
durian, mangosteen, jackfruit and mango occurred rapidly after the harvest, that
causes a decrease in edible and economic value of the fruits in short selling
window. Also, due to the seasonal nature of the fruits mentioned above,
it creates waste problems. Therefore, Bujang and Safuan (2014) stated that
utilizing the fruit biomass is very helpful not only in regulating the fruit prices in
a way of diversification of products came from the fruits and its waste, but also
the process of converting the chemical composition of durian peel into heat
energy, like the conversion of plants into bio-fuel. The ways of thermochemical
hydrolysis. Bujang and Safuan (2014) added that one of the chemical
Hidayah, Abdullah, and Latif (2010) stated that the varying release of thermal
energy or its heat energy was due to the effects of different measurement of
activated carbon or durian peel. Apart from its unique and strong smell, durian
is also easy to recognize due to its spiky look. Durian look of intimidating yet
special, because of the prickly and thorny appearance of its outer shell. The
durian peel, helps neutralize the hotness cause by eating durian and cool the
body down, just by drinking water from its peel. In addition, durian peel also
helps in removing the strong smell of the durian simply by washing with durian
peel or scrubbing against the peel that also remove the stench.
decreases the demand for firewood and charcoal (Wilaipon, 2008). Ilavsky and
Oravec (2000) stated that briquetting the biomass improves its handling
five main types; piston densification, screw press densification, roll press
a binder.
attain knowledge due to the fact of technical limits involved and knowledge
raw material used can determine its economic success. Briquettes can be used
in many ways; both domestic and industrial applications. Also, it is often used
as an alternative solid bio-fuel due to energy source shortage and rising prices
of common solid fuels like charcoals and firewood (Ahmed, 2008). Briquettes
are cheaper than coal, where it does not contain sulfur considered as 100%
eco-friendly. Furthermore, it has higher practical thermal value and lower ash
flying ash. It is more uniform in terms of combustion than coal and also gives
much higher boiler efficiency because of its low moisture and higher density
(Manoj, 2015).
is easier but it takes higher cost due to equipment used which is unsuitable for
starch, cow dung, newspaper, etc. Paper possesses the following advantages:
it does not add a smoke producing material to the briquette, non-volatile, widely
available and holds the briquette together. According to Michalovic (2005) and
17
used as a binding agent, where cellulose and starch are very similar polymers
but cellulose is much stronger than starch because starches can be dissolved
when mixed together in liquid and its varieties tend to be highly viscous, to
agglomerate, and have poor flow properties, making their handling difficult
other traditional binders that slow down the process of disintegration, cellulose
are not present in any other binding agents and may vary in different factors
like usage.
production source of durian waste like the peel that contributes as an additional
energy in a form of biomass briquettes, as well as utilizing durian peel into such
unique product that is not yet developed in the country. The study was expected
combustion rate that may affect the quality of the briquettes to be produced. As
supported by the researchers cited and mentioned above, this study positively
Chapter 2
Methods
conducting the study. It discussed the research design, the statistical treatment
for data analysis and the procedures that emphasizes the gathering of data and
Research Design
design, where each subject is randomly assigned to one of two or more different
different treatment, all groups are still treated equally as possible in all other
factors and undergoes complete same procedures all throughout the study.
Whereas, one group will receive the treatment of interest and another group a
Statistical Treatment
results from different samples or the results of the study in order to accurately
using ANOVA, another statistical technique will be used for analyzing the
Test). This technique was considered as a post hoc test that will measure and
Research Procedure
elaborated below:
Section 1. Pre-Experimentation
from durian sellers in Davao city. Durian skins are sliced and dried in the sun (
3 days ), and the dried durian peels are carbonized in a makeshift furnace for
sieved (using 5 mesh) to have uniformity in terms of particle sizes. Paper and
water will be cooked as the adhesive, with a ratio of 400g mashed paper mixed
with 1200 ml of water until boiled. Afterwards, the adhesive with a 20% total
20
amount of the weight of the briquette will be added to the carbonized product
and then molded in the makeshift briquette molder. The whole phase will
produce 5 set of briquettes, where each briquette weights 100 grams and a set
consist of different proportions of paper waste: durian peel, the 1st briquette
contains 0:100 ratio, 2nd briquette contains 25:75, 3rd briquette contains 50:50
ratio, 4th briquette contains 75:25, and 5th briquette contains 100:0. Aluminum
can is the packing material for the durian peels when it was burned in the
furnace. The equipment used was a knife, sieve, pots, makeshift furnace for
contains different paper:durian peel ratios; 0:100, 25:75, 50:50, 75:25, 100:0.
100% durian peel. Before the test begins, each sample will be placed in
a triple beam balance and weighed. The set-up used was based on the
framework of Water Boiling Test (WBT). The whole procedure will start
briquette. A timer will be prepared to record the amount of time the water
Thereafter, the mass of fuel consumed will be weighed. Then the burning
process for the briquette continues and the heat produced by the
briquette is totally burned, the ash weight will be measured. Then, the
75% durian peel. Before the test begins, each sample will be placed in
a triple beam balance and weighed. The set-up used was based on the
framework of Water Boiling Test (WBT). The whole procedure will start
briquette. A timer will be prepared to record the amount of time the water
Thereafter, the mass of fuel consumed will be weighed. Then the burning
process for the briquette continues and the heat produced by the
briquette is totally burned, the ash weight will be measured. Then, the
50% durian peel. Before the test begins, each sample will be placed in
a triple beam balance and weighed. The set-up used was based on the
framework of Water Boiling Test (WBT). The whole procedure will start
briquette. A timer will be prepared to record the amount of time the water
Thereafter, the mass of fuel consumed will be weighed. Then the burning
process for the briquette continues and the heat produced by the
briquette is totally burned, the ash weight will be measured. Then, the
25% durian peel. Before the test begins, each sample will be placed in
a triple beam balance and weighed. The set-up used was based on the
framework of Water Boiling Test (WBT). The whole procedure will start
briquette. A timer will be prepared to record the amount of time the water
Thereafter, the mass of fuel consumed will be weighed. Then the burning
process for the briquette continues and the heat produced by the
25
briquette is totally burned, the ash weight will be measured. Then, the
0% durian peel. Before the test begins, each sample will be placed in a
triple beam balance and weighed. The set-up used was based on the
framework of Water Boiling Test (WBT). The whole procedure will start
briquette. A timer will be prepared to record the amount of time the water
Thereafter, the mass of fuel consumed will be weighed. Then the burning
process for the briquette continues and the heat produced by the
briquette is totally burned, the ash weight will be measured. Then, the
Each of the briquettes will have its own set-up, in which the set-
ups will be identical five replications and properly observed based on the
usual Water Boiling Test. This test was conducted in the University
biomass briquettes that have been produced will be tested using the
different test tube, then each test tube with water will be heated by the
use of 5 different biomass briquettes, until the water boils. The time each
container takes to boil the water using the 5 different biomass briquettes
of durian peel and adhesive. The shorter the time it takes to boil the
Section 3. Post-Experimentation
part will discuss further the ash content, fixed carbon, energy content, burning
content is one of the indicators that will determine the quality of the
briquettes in water boiling test will be used for computing the amount of
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Formula:
fixed carbon is the level of carbon accessible for ignition after all the
Nuriana, Anisa and Martana (2014), that a briquettes with high fixed
specific formula given below will be used for computing the amount of
Formula:
28
Where:
FC – Fixed carbon
MC – Moisture content
AC – Ash content
the parameter that forms energy content is the heat capacity of the
one of the quality indicators for a good briquette, for the reason that it
for the computation of calorific value and determining the energy content
obtained through the use of the formula provided on the study of Prabhu
(2016).
Formula:
29
peel and adhesive as an alternative coal. The said test will served as a
addition, this test will be the basis for the researchers to determine the
of biomass briquette. The data can be obtained through the use of the
Formula:
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Table 2. Test for Effectiveness of Durian Peels as Biomass Briquette Using Ash
Content
(Experimental Groups) (Control Group)
Percentage (%) (%)
Table 3. Test for Effectiveness of Durian Peels as Biomass Briquette using Fixed
Carbon Content
(Experimental Groups) (Control Group)
Percentage (%) (%)
5
32
Energy Content
(Experimental Groups) (Control Group)
Calorific Value (kj/kg) (kj/kg)
5
33
5
34
Chapter 3
data in the study, conclusion and recommendation. Statistical data which were
used in the analysis and interpretation of the results are presented in tabular
form.
Results
According to the data given by the table above, set-up E has the highest
ash content value of 34.09% while set-up A got the lowest ash content value of
10.90% with the total mean of 23.12%. For the biomass briquette to be
effective, the ash content should be low. Therefore, Set-up A is the most
The table above shows that in fixed carbon content, set-up A has the
highest value of 51.73% and in contrast, set-up E got the lowest value of 31.27
% with the total mean of 39.73%. For the biomass briquette to be effective, the
fixed carbon content should be high. Therefore, Set-up A is the most effective
The table shows the data for energy content, wherein calorific value
serves as the way of getting the values. The data shows that set-up B got the
highest value of 2.41 kJ/kg among the other set-up while set-up E got the lowest
value of 1.83 kJ/kg with the total mean of 2.13 kJ/kg. For the biomass briquette
The table above shows the data for burning rate wherein set-up A got
the highest value among the other set-up with a value of 0.00014188 kg/s, while
set-up E has the lowest value of 0.00006447 kg/s with the total mean of
0.000102636 kg/s. For the biomass briquette to be effective, the burning rate
The table above shows that in specific fuel consumption, set-up A got
the highest amount that reach up into 7.54 kg/l while set-up D got the lowest
amount of 5.66 kg/l with the total mean of 6.51 kg/l. For the biomass briquette
briquette.
COMBUSTIBILITY RATE
Ash Content (%) Fixed Carbon content (%)
Energy Content (kj/kg) Burning Rate (kg/s)
Specific Fuel Consumption (kg/l)
51.73
46.41
34.76
34.49
34.09
31.27
25.85
22.48
22.26
10.9
0.00014188
0.00013324
6.5592E-05
6.4474E-05
7.54
0.000108
6.51
6.35
5.66
6.5
2.41
2.36
2.05
1.97
1.83
SET-UP A SET-UP B SET-UP C SET-UP D SET-UP E
The figure shows the data for the mean of the overall variable of
combustibility rate which are the ash content, fixed carbon content, energy
content, burning rate and specific fuel consumption for all the five set-ups A, B,
highest value of fixed carbon content, burning rate and specific fuel
consumption among the other set-ups but it also possessed the lowest ash
which is composed of 100% paper possessed the lowest value of fixed carbon
content, energy content and burning rate among the other set-ups but also
possessed the highest amount of ash content, thus it is the least effective as
the highest energy content among the other while set-up D has the lowest
Tabulated F
Source of Degrees Sum of Mean of Computed
Variation of Squares Squares F 5%
Freedom
Total 24 1598.83
in terms of ash content. The computed f value for the ash content is 40.104
Data shown in table 8.1 supports the hypothesis that there is a significant
difference on the mean ash content of the biomass briquette treated with five
(5) set-ups namely; Set-up A= 0% paper and 100% durian peel; Set-up B= 25%
paper and 75% durian peel; Set-up C= 50% paper and 50% durian peel; Set-
up D= 75% paper and 100% durian peel: and Set-up E= 100% paper and 0%
the mean ash content of the biomass briquette in five (5) trials treated with the
same set-ups. The rejection of the null hypothesis which indicates that there is
39
no significant difference between and among the treatments in terms of the ash
follows.
Table 8.1.1. Duncan’s Multiple Range Test (DMRT) on the Mean Ash Content
E 34.09 E
The table shows that any two means having a common letter are not
showed that Set-up A and Set-up E are significantly different from other
different from Set-up A and Set-up E and not significantly different from Set-up
Total 24 4766.05
in terms of fixed carbon content. The computed f value for the fixed carbon
of 2.87. This value means that there is no significant difference. It indicates that
hypothesis is accepted.
41
Total 24 2.77
in terms of energy content. The computed f value for the energy content is 6.98
Data shown in table 8.3 supports the hypothesis that there is a significant
difference on the mean energy content of the biomass briquette treated with
five (5) set-ups namely; Set-up A= 0% paper and 100% durian peel; Set-up B=
25% paper and 75% durian peel; Set-up C= 50% paper and 50% durian peel;
Set-up D= 75% paper and 100% durian peel: and Set-up E= 100% paper and
on the mean energy content of the biomass briquette in five (5) trials treated
with the same set-ups. The rejection of the null hypothesis which indicates that
of the energy content of the biomass briquette led to the application of Post-
42
Hoc Analysis specifically the Duncan’s Multiple Range Test (DMRT) which
resulted to as follows.
Table 8.3.1. Duncan’s Multiple Range Test (DMRT) on the Mean Energy
E 1.766 e
The table shows that any two means having a common letter are not
showed that Set-up B is significantly different from Set-up C, Set-up D and Set-
different from Set-up D and Set-up E and not significantly different from Set-up
Tabulated
F
Source of Degrees Sum of Mean of Comp
Variation of Squares Squares uted F 5%
Freedom
Treatment 4 0.00000117 0.00000029
2.87
Experimental 20 0.00000114 - -6.10
Error 0.0000000475
Total 24 0.000000031
in terms of burning rate. The computed f value for the burning rate is -6.10 which
accepted.
44
Tabulated
F
Source of Degrees Sum of Mean of Compute
Variation of Square Square dF 5%
Freedom s s
Total 24 10.39
in terms of specific fuel consumption. The computed f value for the specific fuel
significance level of 2.87. This value means that there is a significant difference.
It indicates that there is a great variation between the treatment and replication.
Data shown in table 8.5 supports the hypothesis that there is a significant
treated with five (5) set-ups namely; Set-up A= 0% paper and 100% durian peel;
Set-up B= 25% paper and 75% durian peel; Set-up C= 50% paper and 50%
durian peel; Set-up D= 75% paper and 100% durian peel: and Set-up E= 100%
paper and 0% durian peel. Furthermore, it also applies that there is a significant
five (5) trials treated with the same set-ups. The rejection of the null hypothesis
which indicates that there is no significant difference between and among the
Table 8.5.1 Duncan’s Multiple Range Test (DMRT) on the Mean Specific Fuel
The table shows that any two means having a common letter are not
different from Set-up C; Set-up C is significantly different from Set-up E and not
from Set-up D.
Discussion
The amount of durian peel added in the biomass briquette mixture has
data was obtained from the experiment, with five (5) treatments and a
replication of five (5) times. Data analysis use ANOVA (Analysis of Variance)
In the ash content, set-up A has the lowest value and is significantly
varied from other treatments. Based on the study conducted by Obi, Akubuo,
and Okonkwo (2013), for the briquettes to have high heating values, the ash
content should be low. Therefore, set-up A is the most effective in terms of ash
content and the results were based on the standard set by Tamilvanan (2013).
Furthermore, in fixed carbon content, set-up A has the highest value and does
Sathya, and Jyothi (2014), the higher the fixed carbon content, the better the
carbon content and the results were based on the standard set by Nuriana
(2014). However, in the energy content, set-up B has the highest value and is
significantly varied from other treatments. High calorific value means the energy
(Raju et al., 2014). Hence, the greater calorific value, the easier and the better
will the briquette burn. Therefore, set-up B is the most effective and the result
was based on the standard set by Huang (2014). Moreover, in the burning rate,
set-up A has the highest value and does not significantly vary from other
burning rate. Therefore, set-up A is the most effective and the result was based
consumption, Set-up A has the highest value and is significantly varied from
Based on our own observations, it was foreseen that when more durian
peel was added to the biomass briquette mixture, it will become more
combustible, which means that the briquette is effective. On the other hand, if
47
less durian peel is added, it can be noticed that the biomass briquette product
Conclusion
answers to the question and these are the following: Set-up A is the most
effective in terms of the ash content of the briquette; Set-up A is the most
effective in terms of the fixed carbon content of the briquette; Set-up B is the
most effective in terms of the energy content of the briquette; Set-up A is the
most effective in terms of the burning rate of the briquette; and Set-up A is the
concluded that durian peel has the ability to be effective as biomass briquette.
48
Recommendation
equations due to the absence of the needed equipment in the school laboratory
and lack of financial fund. It is therefore recommended for the future researcher
equipment such as oven and hi-tech compressor to ensure the same outcome
of the product. Upon testing the product, the researcher also recommend to
needed in the research. Based on the findings, durian peel as biomass briquette
is effective and has the ability to be used as fuel, therefore, future researchers
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8DCM9zSwhyRw
56
APPENDIX A
APPENDIX B
APPENDIX C
ENERGY CONTENT
APPENDIX D
APPENDIX E
APPENDIX F
Step 1: Group the data by treatments and calculate the treatments totals (T)
577.9
GrandTotal
23.116
GrandMean
63
Tabulated F
Source of Degrees Sum of Mean of Computed
Variation of Squares Squares F 5%
Freedom
Total 24 1598.83
trials, determine the degree of freedom (d.f.) for each source of variation as
follows:
= (5) (5) – 1
= 24
Treatment d.f. = t – 1
=5–1
=4
= 5(5 – 1)
= 20
64
Step 4: Using Xi to represent the measurement of the ith plot, Ti as the total of
the ith treatment, and n as the total number of experimental plots, calculate the
𝑮𝟐
Correlation factor (C.F.) = 𝒏
𝟓𝟕𝟕.𝟗𝟐
= 𝟐𝟓
= 13 358.7364
= 14 957.5666 – 13 358.7364
= 1598.8302
∑𝒕𝒊=𝟏 𝑻𝟐𝒊
Treatment SS = – C.F
𝒓
= 14 749.49516 – 13 358.7364
= 1390.75876
= 1598.8302 – 1390.75876
= 208.07144
Step 5: Calculate the mean square (MS) for each source of variation by
𝑻𝒓𝒆𝒂𝒕𝒎𝒆𝒏𝒕 𝑺𝑺
Treatment MS = 𝒕−𝟏
1390.75876
= 4
65
= 347.68969
𝑬𝒓𝒓𝒐𝒓 𝑺𝑺
Error MS = 𝒕(𝒓−𝟏)
208.07144
= 𝟐𝟒
= 8.67
difference as:
𝑻𝒓𝒆𝒂𝒕𝒎𝒆𝒏𝒕 𝑴𝑺
F= 𝑬𝒓𝒓𝒐𝒓 𝑴𝑺
347.68969
= 8.67
= 40.104
Step 7: Decision
Reject Ho
66
𝟐𝒔𝟐
𝒔−
𝒅 =
√
𝒓
𝟐(8.67)
𝒔−
𝒅 =
√
𝟓
𝒔𝒅− = 𝟏. 𝟖𝟔
(𝒓𝒑 )(𝒔−
𝒅)
𝑹𝒑 = for p = 2, 3,…, t
√𝟐
rp values with error d.f. of 20 and at the 5% level f significance and computed
Rp values:
67
p rp(.05) Rp
2 2.95 3.88
3 3.09 4.06
4 3.19 4.196
5 3.25 4.27
Step 4: Identify and group together all the treatment means that do not differ
Set-up Mean
E 34.09 a
D 25.846 b
B 22.48 c
C 22.26 d
A 10.904 e
A. Set-up E (E)
B. Set-up D (D)
C. Set-up B (B)
D. Set-up C (C)
A 10.904 a
B 22.48 bc
C 22.26 cd
D 25.846 bcd
E 34.09 e
Note *: Any two means having a common letter are not significantly different at
APPENDIX G
CONTENT
Step 1: Group the data by treatments and calculate the treatments total (T)
1057.04
Grand Total
42.2816
Grand Mean
70
Tabulated
F
Source of Degrees Sum of Mean of Compute
Variation of Square Square dF 5%
Freedom s s
Treatment 4 1503.65 375.91
2.77 2.87
Experimental 20 3262.4 135.93
Error
Total 24 4766.05
trials, determine the degree of freedom (d.f.) for each source of variation as
follows:
= (5) (5) – 1
= 24
Treatment d.f. = t – 1
=5–1
=4
= 5(5 – 1)
= 20
71
Step 4: Using Xi to represent the measurement of the ith plot, Ti as the total of
the ith treatment, and n as the total number of experimental plots, calculate the
𝑮𝟐
Correlation factor (C.F.) = 𝒏
0.00253623𝟐
= 𝟐𝟓
= 0.000000257
= 0.000000288 – 0.000000257
= 0.000000031
∑𝒕𝒊=𝟏 𝑻𝟐𝒊
Treatment SS = – C.F
𝒓
= 0.000001432 – 0.000000257
= 0.00000117
= 0.000000031 – 0.00000117
= -0.00000114
Step 5: Calculate the mean square (MS) for each source of variation by
𝑻𝒓𝒆𝒂𝒕𝒎𝒆𝒏𝒕 𝑺𝑺
Treatment MS = 𝒕−𝟏
0.00000117
= 4
72
=0.00000029
𝑬𝒓𝒓𝒐𝒓 𝑺𝑺
Error MS = 𝒕(𝒓−𝟏)
−𝟎.𝟎𝟎𝟎𝟎𝟎𝟏𝟏𝟒
= 𝟐𝟒
= -0.0000000475
Step 6: Calculate the F value for testing significance of the treatment difference
as:
𝑻𝒓𝒆𝒂𝒕𝒎𝒆𝒏𝒕 𝑴𝑺
F= 𝑬𝒓𝒓𝒐𝒓 𝑴𝑺
0.00000029
=−0.0000000475
= -6.10
Step 7: Decision
Accept Ho
73
APPENDIX H
Step 1: Group the data by treatments and calculate the treatments totals (T)
52.82
Grand Total
Tabulated
F
Source of Degrees Sum of Mean of Compute
Variation of Square Square dF 5%
Freedom s s
Total 24 2.77
trials, determine the degree of freedom (d.f.) for each source of variation as
follows:
= (5) (5) – 1
= 24
Treatment d.f. = t – 1
=5–1
=4
= 5(5 – 1)
= 20
75
Step 4: Using Xi to represent the measurement of the ith plot, Ti as the total of
the ith treatment, and n as the total number of experimental plots, calculate the
𝑮𝟐
Correlation factor (C.F.) = 𝒏
52.82𝟐
= 𝟐𝟓
= 111.598
= 114.371 – 111.598
= 2.77
∑𝒕𝒊=𝟏 𝑻𝟐𝒊
Treatment SS = – C.F
𝒓
= 113.09 – 111.598
= 1.49
= 2.77 – 1.49
= 1.28
Step 5: Calculate the mean square (MS) for each source of variation by
𝑻𝒓𝒆𝒂𝒕𝒎𝒆𝒏𝒕 𝑺𝑺
Treatment MS = 𝒕−𝟏
1.49
= 4
76
=0.3725
𝑬𝒓𝒓𝒐𝒓 𝑺𝑺
Error MS = 𝒕(𝒓−𝟏)
1.28
= 𝟐𝟒
= 0.053
Step 6: Calculate the F value for testing significance of the treatment difference
as:
𝑻𝒓𝒆𝒂𝒕𝒎𝒆𝒏𝒕 𝑴𝑺
F= 𝑬𝒓𝒓𝒐𝒓 𝑴𝑺
0.3725
= 0.053
= 6.98
Step 7: Decision
Reject Ho
77
𝟐𝒔𝟐
𝒔−
𝒅 = √
𝒓
𝟐(0.053)
𝒔−
𝒅 =
√
𝟓
𝒔−
𝒅 = 𝟎. 𝟏𝟒𝟓𝟔
(𝒓𝒑 )(𝒔−
𝒅)
𝑹𝒑 = for p = 2, 3,…, t
√𝟐
rp values with error d.f. of 20 and at the 5% level f significance and computed
Rp values:
78
P rp(.05) Rp
2 2.95 0.304
3 3.09 0.318
4 3.19 0.328
5 3.25 0.335
Step 4: Identify and group together all the treatment means that do not differ
Set-up Mean
B 2.414 a
A 2.364 b
C 2.05 c
D 1.97 d
E 1.766 e
A. Set-up B (B)
B. Set-up A (A)
x̅ 𝐴− 𝑅𝑃4=2.364 − 0.328=2.036
C. Set-up C (C)
D. Set-up D (D)
A 2.364 bc
B 2.414 ab
C 2.05 c
D 1.97 de
E 1.766 e
Note *: Any two means having a common letter are not significantly different at
APPENDIX I
Step 1: Group the data by treatments and calculate the treatments totals (T)
0.00253623
Grand Total
0.0001014
Grand Mean 492
81
Tabulated
F
Source of Degrees Sum of Mean of Compu
Variation of Squares Squares ted F 5%
Freedo
m
Treatment 4 0.00000117 0.00000029
2.87
Experimental 20 0.00000114 - -6.10
Error 0.0000000475
Total 24 0.00000003
1
trials, determine the degree of freedom (d.f.) for each source of variation as
follows:
= (5) (5) – 1
= 24
Treatment d.f. = t – 1
=5–1
=4
= 5(5 – 1)
= 20
82
Step 4: Using Xi to represent the measurement of the ith plot, Ti as the total of
the ith treatment, and n as the total number of experimental plots, calculate the
𝑮𝟐
Correlation factor (C.F.) = 𝒏
0.00253623𝟐
= 𝟐𝟓
= 0.000000257
= 0.000000288 – 0.000000257
= 0.000000031
∑𝒕𝒊=𝟏 𝑻𝟐𝒊
Treatment SS = – C.F
𝒓
= 0.000001432 – 0.000000257
= 0.00000117
= 0.000000031 – 0.00000117
= -0.00000114
Step 5: Calculate the mean square (MS) for each source of variation by
𝑻𝒓𝒆𝒂𝒕𝒎𝒆𝒏𝒕 𝑺𝑺
Treatment MS = 𝒕−𝟏
0.00000117
= 4
83
=0.00000029
𝑬𝒓𝒓𝒐𝒓 𝑺𝑺
Error MS = 𝒕(𝒓−𝟏)
−𝟎.𝟎𝟎𝟎𝟎𝟎𝟏𝟏𝟒
= 𝟐𝟒
= -0.0000000475
Step 6: Calculate the F value for testing significance of the treatment difference
as:
𝑻𝒓𝒆𝒂𝒕𝒎𝒆𝒏𝒕 𝑴𝑺
F= 𝑬𝒓𝒓𝒐𝒓 𝑴𝑺
0.00000029
=−0.0000000475
= -6.10
Step 7: Decision
Accept Ho
84
APPENDIX J
Step 1: Group the data by treatments and calculate the treatments totals (T)
162.4
Grand Total
Tabulated
F
Source of Degrees Sum of Mean of Compute
Variation of Square Square dF 5%
Freedom s s
Total 24 10.39
trials, determine the degree of freedom (d.f.) for each source of variation as
follows:
= (5) (5) – 1
= 24
Treatment d.f. = t – 1
=5–1
=4
= 5(5 – 1)
= 20
86
Step 4: Using Xi to represent the measurement of the ith plot, T i as the total of
the ith treatment, and n as the total number of experimental plots, calculate the
𝑮𝟐
Correlation factor (C.F.) = 𝒏
162.4𝟐
= 𝟐𝟓
= 1054.95
= 1065.34 – 1054.95
= 10.39
∑𝒕𝒊=𝟏 𝑻𝟐𝒊
Treatment SS = – C.F
𝒓
= 1064.85 – 1054.95
= 9.9
= 10.39 – 9.9
= 0.49
Step 5: Calculate the mean square (MS) for each source of variation by dividing
𝑻𝒓𝒆𝒂𝒕𝒎𝒆𝒏𝒕 𝑺𝑺
Treatment MS = 𝒕−𝟏
9.9
=4
87
=2.475
𝑬𝒓𝒓𝒐𝒓 𝑺𝑺
Error MS = 𝒕(𝒓−𝟏)
0.49
= 𝟐𝟒
= 0.0204
Step 6: Calculate the F value for testing significance of the treatment difference
as:
𝑻𝒓𝒆𝒂𝒕𝒎𝒆𝒏𝒕 𝑴𝑺
F= 𝑬𝒓𝒓𝒐𝒓 𝑴𝑺
2.475
=0.0204
= 121.22
Step 7: Decision
Reject Ho
88
𝟐𝒔𝟐
𝒔−
𝒅 = √
𝒓
𝟐(0.0204)
𝒔−
𝒅 =
√
𝟓
𝒔−
𝒅 = 𝟎. 𝟎𝟗
(𝒓𝒑 )(𝒔−
𝒅)
𝑹𝒑 = for p = 2, 3,…, t
√𝟐
rp values with error d.f. of 20 and at the 5% level f significance and computed
Rp values:
89
P rp(.05) Rp
2 2.95 0.188
3 3.09 0.197
4 3.19 0.20
5 3.25 0.21
Step 4: Identify and group together all the treatment means that do not differ
A. Set-up A (A)
Set-up Mean
A 7.542 a
B 6.52 b
C 6.5 c
E 6.352 d
D 5.566 e
B. Set-up B (B)
C. Set-up C ©
D. Set-up E(E)
A 7.542 a
B 6.52 bc
C 6.5 cd
D 5.566 e
E 6.352 cd
Note *: Any two means having a common letter are not significantly different at
E-mail: [email protected]
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Jayson R. Galagar
E-mail: [email protected]
I. PERSONAL INFORMATION
Kayle T. Navaja
E-mail: [email protected]
I. PERSONAL INFORMATION
Josie T. Sameon
E-mail: [email protected]
I. PERSONAL INFORMATION