The Usage of Domestic Water Filtration Systems in Malaysia
The Usage of Domestic Water Filtration Systems in Malaysia
The Usage of Domestic Water Filtration Systems in Malaysia
A dissertation submitted by
Water is closely related to human health as there is about 70% of water found in
human bodies. In the recent years, consumers are concern about the quality of tap
water due to the water pollution issues published in the mass media. Manufacturers
and distributors of domestic water treatment systems took this opportunity to
promote their own water filtration systems. Different types of domestic water
treatment systems have been introduced to the public.
In this research project, six types of domestic treatment methods were identified,
namely activated carbon filter, membrane filter, reverse osmosis system, distillation
system, ultraviolet light system and combination unit. The theories and technologies
involved in each type of water treatment system are being studied. From the
literature review, the mechanisms involved are convincing and almost ideal. In order
to investigate the effectiveness of each water treatment system, laboratory
experiments have been conducted to justify the reported results.
The laboratory experiments take into account parameters such as apparent colour,
turbidity, total free chlorine, total aluminium, total iron and total chromium. Three
samples of each treatment method are collected in order to obtain the average value.
The percentage removal of each parameter is obtained by taking readings before and
after treatment. Then, the average value of percentage removal is calculated to
evaluate the efficiency of each treatment method. Hopefully this research project can
raise the interest of consumers to be more aware of the water quality that they
consume everyday and in choosing a correct domestic water treatment system that
suits their lifestyle requirement.
ii
University of Southern Queensland
Limitations of Use
Persons using all or any part of this material do so at their own risk, and not at the
risk of the Council of the University of Southern Queensland, its Faculty of
Engineering and Surveying or the staff of the University of Southern Queensland.
Prof G Baker
Dean
Faculty of Engineering and Surveying
iii
Certification
I certify that the ideas, designs and experimental work, results, analyses and
conclusions set out in this dissertation are entirely my own effort, except where
otherwise indicated and acknowledged.
I further certify that the work is original and has not been previously submitted for
assessment in any other course or institution, except where specifically stated.
_____________________________
Signature
_____________________________
Date
iv
ACKNOWLEDGMENTS
Firstly, I would like to thank my supervisor, Dr Ernest Yoong for his patience and
guidance throughout this entire project. My supervisor had given me lots of advice
and suggestion from time to time on how to write this report.
I would like to thank my parents for their financial and moral support during this
project. Then, I would also like to thank individuals who had provided me the
information of various types of water treatment systems. I really appreciated their
kindly help.
I also want to thank all my readers who had spent their time in reading this report
patiently. Hopefully this report will provide them some knowledge in various
treatment systems and their filtration process.
v
TABLE OF CONTENTS
Abstract ii
Disclaimer Page iii
Certification Page iv
Acknowledgements v
List of Figures x
List of Tables xii
CHAPTER 1 INTRODUCTION 1
1.1 Project Aims 2
1.2 Specific Objectives 2
1.3 Background 3
1.4 Dissertation Overview 4
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2.4 Other Parameters 17
2.4.1 pH 17
2.4.2 Hardness 17
2.4.3 Iron 17
2.5 Water Quality Standards 18
2.5.1 Comparison of Malaysian Drinking Standard and WHO Drinking 18
Standard
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CHAPTER 5 EXPERIMENTAL TECHNIQUES 71
5.1 Sample collection, Preservation and Storage 71
5.1.1 Water Collection 72
5.1.2 Types of Containers 72
5.1.3 Storage and Preservation 72
5.2 Apparent Colour 73
5.2.1 Introduction 73
5.2.2 Equipment and Required Materials 74
5.2.3 Test Procedures 75
5.3 Turbidity 76
5.3.1 Introduction 76
5.3.2 Equipment and Required Materials 76
5.3.3 Test Procedures 78
5.4 Total Free Chlorine 78
5.4.1 Introduction 78
5.4.2 Equipment and Required Materials 78
5.4.3 Test Procedures 79
5.5 Total Aluminium 80
5.5.1 Introduction 80
5.5.2 Equipment and Required Materials 80
5.5.3 Test Procedures 81
5.6 Total Chromium 82
5.6.1 Introduction 82
5.6.2 Equipment and Required Materials 83
5.6.3 Test Procedures 83
5.7 Total Iron 84
5.7.1 Introduction 84
5.7.2 Equipment and Required Materials 85
5.7.3 Test Procedures 86
viii
6.4 Total Aluminium 91
6.5 Total Chromium 92
6.6 Total Iron 93
APPENDICES
Appendix A- Project Specification 114
Appendix B- Questionnaire 116
ix
LIST OF FIGURES
x
Figure 5.3: 2100N Laboratory Turbidimeter 77
Figure 5.4: Hach 2100P Portable Turbidimeter 77
Figure 5.5: Aluminium testing 82
Figure 7.1: Percentage removal of colour for different treatment systems 95
Figure 7.2: Percentage removal of turbidity for different treatment systems 97
Figure 7.3: Percentage removal of chlorine for different treatment systems 99
Figure 7.4: Percentage removal of aluminium for different
treatment systems 101
Figure 7.5: Percentage removal of total chromium for different
filtration systems 103
Figure 7.6: Percentage removal of total iron for different filtration systems 105
xi
LIST OF TABLES
xii
Table 7.1: The lowest, highest and average percentage removals of apparent 95
Colour
Table 7.2: The lowest, highest and average percentage removals of turbidity 97
Table 7.3: The lowest, highest and average percentage removals of total free 99
chlorine
Table 7.4: The lowest, highest and average percentage removals of
aluminium 101
Table 7.5: The lowest, highest and average percentage removals of total 103
chromium
Table 7.6: The lowest, highest and average percentage removals of
total iron 105
xiii
CHAPTER 1
INTRODUCTION
Water is very important to human beings. We can live for a while without food but
we can not survive without water as there is about 70 % of water in our bodies.
Since water is closely related to our life, therefore we are concerned with the quality
of our supplied drinking water. In the past, consumers used the supplied water
without any doubts. In recent years, consumers focus on the safety of their tap water
due to the increasing numbers of complaints of water contamination.
In Malaysia, highland forests act as the natural water towers providing a clean
supply of fresh water for domestic, agricultural and industrial demands. There are
many unplanned and unsustainable developments in the highland forests in Malaysia
such as road building and excessive highland resort development. Excessive clearing
of forests and construction of highland road have lead to the contamination of water
supply.(Source:http://www.tve.org)
1
Manufacturers and distributors of domestic water filter systems have mushroomed in
the market. They have advertised their products in the mass media in order to attract
more consumers in buying it. Consumers are willing to spend money on the water
filter systems to assure that the tap water is always clean and safe for human
consumption.
The aim of this research project is to investigate the current use of domestic water
filters and compare the technologies of the various filtration systems.
This study will investigate various types of commonly used water filter such as
activated carbon filter, membrane filter, reverse osmosis system, distillation system,
ultraviolet light system and combination unit (i.e. combination of few treatment
methods into one unit).
This project also aimed at investigating the effectiveness of various water filters
through laboratory experiments.
• Study the mechanism and technology behind a few popular types of domestic
water filter available in Malaysian market. Comparisons will be made based
on quality, technology, price and maintenance.
2
• Conduct a survey on public’s opinion about the supplied water quality, the
reasons households install water filter systems and gauge public attitude
towards these systems.
• Collect water samples and conduct lab tests to compare the quality of water
before and after treatment.
1.3 Background
Water filters have been introduced for many centuries; they are closely related to the
history of water. Water has become more contaminated with the growth of industry
and increase in population; human beings realized that water filters are needed in
order to provide pure and clean water for drinking and cooking purposes. This is
because we want to ensure that only the clean water is being consumed. Several
treatment alternatives have been introduced for water treatment.
According to the history, the use of water filters began more than 4000 years ago.
Early Sanskrit writings outlined some methods to generate pure water such as
boiling, placing hot metal instruments in water, exposing to sunlight and filtering
water through crude sand or charcoal filters. As early as 1500 years ago, Egyptians
recommended the application of coagulant alum to settle out the suspended solids
from water. (Source: www.historyofwaterfilters.com)
The famed father of medicine, Hippocrates conducted his own crude water filter.
The filter was a cloth bag used to trap any sentiments in the water when water was
poured through it. Several experiments in water purification were carried out during
the Middle Ages. However, there is lack of scientific innovations in this period of
time. Sir Francis Bacon in 1627 began the experiment of desalination of seawater;
his experiment did mark rejuvenation in water filter experimentation.
(Source: www.historyofwaterfilters.com)
3
During the 1800s, European began using slow sand filtration to remove taste and
odour from water. During 1960s, standard drinking water treatment techniques such
as aeration, flocculation and granular activated carbon adsorption were used for
removal of organic contaminants. In the 1970s and 1980s, membrane filtration was
used in reverse osmosis system.
Throughout the centuries, new technologies have developed and emerged in the
water treatment. The popular types of water filter used nowadays are activated
carbon filter, membrane filter, reverse osmosis system, distillation system,
ultraviolet light unit and combination unit. Currently, lead and disinfection
byproducts are the major concerns in regard to water quality. Chlorine byproducts
are harmful chemicals to humans’ health as they are cancer causing compounds. The
future of water filtration will focus on removal of both chemical substances and
microorganisms from drinking water.
Chapter two of this research project focuses on the safety of drinking water for
human consumption. Sources of water, physical quality and chemical quality of
drinking water are discussed in this chapter. In chapter three, six types of domestic
water filtration systems are investigated, namely activated carbon, membrane,
reverse osmosis, distillation, ultraviolet light and combination. Comparisons of
various filtration systems are made based on the technologies, price, maintenance
and limitation.
The public survey results are analyzed in the chapter four based on the random
questionnaire of 100 respondents. The survey is to identify the public’s opinion
about the supplied water quality and the use of domestic water filtration systems in
Malaysian market nowadays.
4
Laboratory experiments such as apparent colour, turbidity, total iron, total chromium,
total aluminium and total chlorine are set out in chapter five. The equipments used,
materials required and test procedures are discussed in this chapter. The
experimental results of those parameters are outlined in the chapter six. Then, the
discussion and analysis of the experimental results of each parameter are given in
chapter seven.
5
CHAPTER 2
Quality of drinking water depends on where we live, the source of the raw water, the
water supplier and exposure to contamination as the water travels from its source
through distribution system to our faucet. In Malaysia, water pollution is an
alarming issue to the public.
6
odourless, free from pathogenic organisms, not saline and free from chemical
compounds that may affect human health.
Due to the poor water quality, consumers often resort to the use of domestic water
filters. Therefore, to safe guard public health we need to know about the quality of
water in terms of physical and chemical properties. We have the technology and
ability to treat water to a high standard. However, owing to deteriorating water
delivery infrastructures i.e. reticulation, trunk mains and storage tanks, water
delivered at the household may be of a diminished quality due to intervening
contamination.
Water is known as the universal solvent due to its ability to slowly dissolve anything
that comes into contact with. The total volume of water in the world remains
constant through the hydrological cycle. There is about 97.5 % of the world’s water
is sea water and only 2.5 % of the total volume is non-saline. Although it appears
that plenty of water in the world, but there is only very little which is readily
available for human consumption.
In general, water supply in Malaysia comes from two main resources, i.e. surface
water and groundwater. Each of these resources has its own advantages and
disadvantages as a source of drinking water.
7
2.1.1 Surface Water
Surface water is any water which is found flowing or standing on the surface such as
river, streams, ponds, lakes and reservoir. Origin of surface water is surface runoff,
direct precipitation, interflow and water table discharge.
Quality of surface water is dependent upon the geological factor. Waters from chalk
and limestone catchments result in hard waters, whereas impervious rocks such as
granite result in soft waters. Suspended solids content of surface water vary widely
depending on the season and flow.
During periods of heavy precipitation, the river water may be muddy and high in
bacterial content. Clay soils tend to produce muddy streams resulting in a change in
water quality due to the washing of silt into the streams. Forests retard run off and
tend to equalize stream flow.
8
Sector withdrawals of surface water
Domestic
11%
Industry
13%
Agriculture
Industry
Domestic
Agriculture
76%
2.1.2 Groundwater
Groundwater is the precipitation that seeps down through the soil until it reaches
rock material that is saturated with water. In general, groundwater is much cheaper
than surface water as it does not require construction of reservoir or long pipelines.
Groundwater usually has better quality than surface water; it is usually free from
suspended solids, bacteria and other pathogens except in areas where it has been
affected by pollution.
In Malaysia, the potential aquifers may be found in alluvium and hard rock. In
alluvium, the aquifer occurs in layers of sand and gravel. This kind of aquifer is
capable to supply water in the range from 45 m3 to 100 m3 of water/ hour/ well.
9
rock fractures, bedding and voids between grains. In igneous and volcanic rock, the
aquifer occurs in rock fractures including joints and faults. This is not a good aquifer
as the discharge rate seldom exceeds 10 m3/ hour/ well. The Figure 2.2 below shows
the withdrawals of ground water by different sectors in Malaysia.
Agriculture
5%
Industry
33% Agriculture
Industry
Domestic Domestic
62%
Physical parameters define those characteristics of water that respond to the senses
of sight, touch, taste or smell. Physical quality of water is referred to the
measurement of parameters such as colour, turbidity, taste, odour, suspended and
dissolved solids. Majority of the consumers always make sure that they only
consume water which has good physical quality.
Physical quality of water may not seriously affect human health in short term.
However, if we consume poor quality of water for long period of time, then there
will be detrimental effect to our health as the contaminants accumulated. Therefore,
10
we need to know about the causes and health effects of some physical parameters of
drinking water.
2.2.1 Colour
Iron oxides cause reddish water and manganese oxides cause brown or blackish
water. Presence of yellowish-brown colour may cause by organic debris such as
leaves, weeds or woods, where water picks up tannins, humic acid and humates.
Less than 2.5 mg/l of humic and fulvic acid in drinking water is considered safe for
human consumption. The acceptable colour in drinking water is less than 15 TCU
(True Colour Units). However, about half of Malaysian rivers contain more than 50
TCU. Colour in water can be reduced to acceptable level by conventional treatment
if the raw water does not contain more than 75 TCU.
2.2.2 Turbidity
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flocculation, sedimentation and filtration are able to reduce the turbidity in raw
water to acceptable level.
Other suspended materials may come from domestic wastewater which contains
large quantities of organic suspended solids and industrial wastewater. Suspended
material is aesthetically unpleasant and provides adsorption sites for chemical and
biological agents.
12
unpalatable mineral taste and hardness whereas extremely low total dissolved solids
may give flat taste. The acceptable value of total dissolved solids is 1000 mg/l.
2.3.1 Arsenic
In certain types of metalliferous ore area, the surface waters contain certain amount
of arsenic. It is mainly due to pollution of weed killers, pesticides containing arsenic
compounds or runoff from mining waste tips. The maximum allowable content of
arsenic is 0.05 mg/l. Arsenic concentration in Malaysian rivers and lakes are well
below 0.01 mg/l but some instances can be as high as 1.0 mg/l.
13
2.3.2 Cadmium
Excessive exposure to cadmium has resulted in severe health effects. The maximum
allowable content of cadmium is 0.005 mg/l. Cadmium can be removed effectively
by coagulation at pH greater than 8.0 during water treatment.
2.3.3 Chromium
Chromium is widely distributed in soils and plants, but it is rare in natural waters.
Concentration of chromium in household tap water may increase due to plumbing
materials. Other potential sources are including fossil fuel combustion, solid waste
and sewage sludge incineration and cement plant emission.
Chromium (VI) is much more toxic than chromium (III) and does not have any
nutritional value. Chromium (VI) causes hemorrhage of the gastrointestinal tract,
ulceration of the nasal septum and respiratory cancer. The maximum allowable
value is 0.05 mg/l.
2.3.4 Fluoride
Fluoride is the most electronegative element; small amounts of fluoride are present
in most soils. Fluoride has been added to drinking water to reduce the potential for
dental caries. Fluoride content in Malaysian surface water is in the range of 0.02 to
0.78 mg/l.
14
fluorosis occurs when fluoride is in the range of 10 to 40 mg/l. The maximum
allowable value is in the range of 0.5 to 0.9 mg/l.
2.3.5 Lead
Lead concentration in natural waters is rarely more than 0.02 mg/l except in areas
where soft and acidic waters come into contact with galena or other lead ores. Lead
contamination in drinking water is mainly results from corrosion of lead pipes and
solders especially in areas of soft water.
Lead in solution is odourless, tasteless and colourless, which makes high levels in
drinking water undetectable unless chemically analysed. Lead is a cumulative body
poison to humans. Children, infants, foetuses in utero and pregnant women are most
sensitive to lead exposure. Lead can attack the nervous system and result in mental
retardation and behavioural abnormalities in the young and unborn. The maximum
allowable content of lead is 0.05 mg/l.
2.3.6 Mercury
Mercury occurs in drinking water as an inorganic salt and it is poorly absorbed into
the adult, but it is highly absorbed in infants and young children. Mercury is a toxic
element and has no beneficial physiological function in man.
Organic forms of mercury are readily absorbed and easily enter the central nervous
system, causing death or mental and motor dysfunctions. The maximum allowable
value is 0.001 mg/l. Organic mercury may be removed by activated carbon
adsorption.
15
2.3.7 Pesticides
Pesticides include organic compounds which are potentially toxic even in small
amounts. Some organic compounds particularly the chlorinated hydrocarbons are
very resistant to chemical and biochemical degradation. Accidental discharges of
pesticides in bulk to water courses can be more serious causing fish death and
making it necessary for a temporary shut down of water intakes.
Chlorine has been used to disinfect drinking water since the beginning of the century.
Some of the organic compounds in water could react with the chlorine during
disinfection process at the treatment plant to form new, complex and dangerous
chemicals. Trihalomethanes (THMs) is one group of these which has attracted
considerable attention.
16
2.4 Other parameters
2.4.1 pH
2.4.2 Hardness
According to the research, consumption of hard water may have some health
benefits. Consumption of water without mineral in long term may result in the
lowering of the bone calcium saturation level. In Malaysia, most of river waters are
soft with less than 60 mg/l of hardness. In raw water, hardness of up to 500 mg/l is
permitted.
2.4.3 Iron
17
the accumulation of large deposits in a distribution system which can give rise to
iron bacteria and further deteriorate the water quality.
Levels of iron in most of the Malaysian river water are in the range of 1 to 5 mg/l.
However, the maximum allowable value is 0.3 mg/l. Therefore, water exceed the
acceptable limit needs to be treated. Iron salts can be reduced to the permissible
level by standard water treatment processes of aeration, coagulation and filtration,
pH adjustment, oxidation with chlorine and lime softening.
Water for drinking and cooking should meet certain standards before it is supplied to
the consumer to ensure the human health. World Health Organization (WHO) has
outlined a standard for safe drinking water; all the parameters should not exceed the
maximum acceptable levels. Many countries have their own standards and WHO
standards are only a guideline to them. The parameters measured are divided into a
few categories. The comparison of WHO standards and Malaysian standards is
shown as below.
Group I - Physical
Turbidity 5 NTU 5 NTU
Colour 15 TCU or HU 15 TCU
pH 6.5 – 9.0 6.5 – 8.5
Free residual chlorine Not less than 0.2 mg/l Not less than 1.0 mg/l
Combined residual chlorine Not less than 1.0 mg/l Not less than 1.0 mg/l
Group II - Inorganic
Total dissolved solids 1000 mg/l 1000 mg/l
CCE 0.5 mg/l 0.5 mg/l
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Chloride 250 mg/l 250 mg/l
Anionic detergent MBAs 1 mg/l 1 mg/l
Ammonia as N 0.5 mg/l 1.5 mg/l
Nitrate as N 10 mg/l 10 mg/l
Iron 0.3 mg/l 0.3 mg/l
Fluoride 0.5 – 0.9 mg/l 1.5 mg/l
Hardness as CaCo3 500 mg/l 500 mg/l
Aluminium 0.2 mg/l 0.2 mg/l
Manganese 0.1 mg/l 0.1 mg/l
Group III
Mercury 0.001 mg/l 0.001 mg/l
Cadmium 0.005 mg/l 0.003 mg/l
Selenium 0.01 mg/l 0.01 mg/l
Arsenic 0.05 mg/l 0.01 mg/l
Cyanide 0.10 mg/l 0.07 mg/l
Lead 0.10 mg/l 0.01 mg/l
Chromium 0.05 mg/l 0.05 mg/l
Silver 0.05 mg/l 0.05 mg/l
Copper 1.0 mg/l -
Magnesium 150 mg/l 150 mg/l
Zinc 5 mg/l 5 mg/l
Sodium 200 mg/l 200 mg/l
Sulphate 400 mg/l 400 mg/l
Mineral oil 0.30 mg/l 0.3 mg/l
phenol 0.002 mg/l 0.03 mg/l
Chloroform 0.03 mg/l 0.03 mg/l
Group IV
Total biocides 0.1 mg/l 0.1 mg/l
Organochlorine pesticides:
Aldrin / dieldrin 0.03 µg/l 0.03 µg/l
Chlordane 0.3 µg/l 0.3 µg/l
DDT 0.001 mg/l 0.001 mg/l
Heptachloro & heptachloro
epoxide 0.1 µg/l 0.1 µg/l
Hexachlorobenzene 0.01 µg/l 0.01 µg/l
Lindane 0.003 mg/l 0.003 mg/l
Methoxychlor 0.03 mg/l 0.03 mg/l
Herbicides:
2, 4-D 0.1 mg/l 0.1 mg/l
Radioactivity:
Cross α 0.1 0.1
Cross β 1 1
Table 2.1: Comparison of Malaysian Drinking Standard and WHO Drinking Standard
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CHAPTER 3
Actually, each type of water treatment system is designed to treat specific water
quality problems. No single water treatment system is able to treat all the water
problems as all systems have their own limitation. Some of the common type of
water treatment systems sold in the market will be discussed here. The name of the
filter systems and the manufacturers will not be revealed as to protect their
confidentiality.
20
3.1 Activated Carbon Filter
The most common base materials used to produce carbon are wood, coal, and
coconut shell. These materials are subjected to carbonization process where the base
material is heated to the high temperature. In order to activate the carbon, base
material is subjected to a second heat and steam treatment.
i) Physical properties:
The amount and distribution of pores determine how well contaminants are filtered.
Size of pores must large enough to admit contaminant molecules because
contaminants come in all different sizes.
21
iv) Water temperature and pH:
Low pH value and low temperature result in better adsorption because organic
chemicals are in more adsorb able form.
v) Exposure time:
The longer the contact time of carbon surface with contaminants in water, the
greater amount of contaminant will be removed from water. Contact time can be
improved by increasing the amount of activated carbon and reducing the flow rate of
water through filter.
Activated carbon is a porous material which has a high surface area for the
contaminant adsorption. Activated carbon removes contaminants in two mechanisms,
namely as adsorption process and catalytic reduction reaction.
There are two principal types of adsorption, i.e. physical and chemical adsorption.
Physical adsorption is caused by Van der Waals forces and chemical adsorption is
commonly resulting in a transformation of the adsorbate.
22
Figure3.1: Adsorption process of activated carbon [www.activated-carbon.com]
Van der Waals forces are extremely short- ranged and sensitive to the distance
between carbon surface and adsorbate molecule. The attractive forces can be altered
by increasing the density of carbon or reducing the distance between carbon surface
and substance being adsorb.
When attractive forces between carbon surface and contaminant are stronger than
forces keeping contaminant dissolved in water, the organic materials will be
attached to the surface of carbon and therefore adsorption takes place.
23
solubility of the organic compound results in stronger bond and smaller extent of
adsorption.
24
3.1.2 Case Study 1: Granular Activated Carbon Filter
Mechanism:
Activated carbon surface are both hydrophobic (water hating) and oleophilic (oil
loving), where they hate water but love oil. This type of filter is used with a
sediment filter to remove larger particles such as dust and rust and therefore protects
the carbon filter from being clogged. Water flows through the sediment filter before
entering carbon filter. When water flows through the carbon filter, dissolved
organics in water are adsorbed to the carbon surface.
Cost:
This type of carbon filter costs about RM 130 per unit.
25
Maintenance:
Granulated activated carbon is not cleanable, therefore high solids or turbidity in raw
water will reduce its useful life. The filtering capacity of granular activated carbon is
about 6800 L. Therefore, the granulated activated carbon should be replaced at
intervals of 6800L usage to maintain at its optimal performance. The cartridge of
this filter costs about RM 20 per unit.
Mechanism:
This is a simple filtration system where only one cartridge is used to treat the water.
Carbon in powder form is fixed into a cartridge. Water enters the filter from the
bottom end and flows through the cartridge. The contaminants are attracted and
attached to the surface of carbon particles.
Cost:
This kind of powdered activated carbon filter costs about RM 150 per unit.
26
Maintenance:
Powdered activated carbon is also not cleanable. The filtering capacity of the
cartridge is 12800 L or it can last about 6 months, and then the old cartridge should
be replaced by a new one. The cartridge costs about RM 40 per unit.
Carbon filters do not remove iron content and heavy metals such as silver, copper
and lead. Offensive taste, odour and colour in supplied water also can be removed
by carbon filter.
Membrane filtration process has been used for many years in water treatment
process. The typical membrane materials used are polymer and ceramic.
Membrane is a thin film of porous material that allows water to pass through and
traps contaminants larger than pore size on the top surface of the membrane.
27
Membrane can be used to prevent larger and undesirable molecules such as virus,
bacteria, salt and metal.
Membranes can be classified into three main types, namely as micro filtration, ultra
filtration and nano filtration. Nano filtration (NF) is a lower pressure process that
removes substances with molecular weight above 100-500 and is capable of
removing hardness, pathogens and originally derived colour. Ultra filtration (UF) is
a low pressure process for removal of microorganisms, colloids, and high molecular
weight compounds while salts and water will pass through. Micro filtration (MF) is
similar to ultra filtration except that the pore size is slightly larger and operating
pressures are lower. Micro filtration can remove contaminants in the range of 0.025
to 10.0 µm from fluid by passage through the micro- porous medium.
There are two forms of separation in membrane filtration. One form is cross flow
separation and the other form is dead end filtration.
In cross flow separation, the fluid stream runs parallel to the membrane. There is
pressure differential across the membrane and the filtrate passes through the
membrane and the remainder continues across the membrane.
In dead end filtration, all the fluid will pass through the membrane; those particles
that cannot fit through the membrane pores are being stopped. The efficiency of
28
filtration is dependent on the pore size of the membrane. There are several
mechanisms by which a ceramic element filters out particles as a dead end filtration.
ii) Bridging:
Particles that smaller than 0.5 µm may be too small to be intercepted, however two
particles hitting the obstruction at the same time will form a bridge across the pore
adhering to each other. The topmost blocked layer can be removed with brush for
many times before the filter has to be changed.
29
Micro filtration has the largest pore size of membrane and it is operated at low
pressure. Micro filtration can remove Giardia and Cryptosporidium but is less
effective at removing viruses. Ultra filtration can remove microorganisms, colloids,
high molecular weight compounds, trihalomethane, disinfection products and some
ionic material. Nano filtration can remove hardness, pathogens and organically
derived colour.
Membrane filter can be used both at point of use (POU) and point of entry (POE).
Ceramic is the common material used as the membrane for point of use filter which
is located in the kitchen. Whereas fiber is the common material used as filter stem
for point of entry.
Fiber filters are usually made of cellulose, rayon or other thread like material spun
into a mesh with small pores. Fiber filters are designed to remove suspended solids
from fluid. This kind of filter is usually installed at the main pipe outside the house
to filter out the big particles before entering the piping systems in the house.
Unwanted
Water Filtered
water
30
Mechanism:
Water flows into a cartridge at high pressure and makes its way into the fiber stem.
The tightly wrapped fibers form a cylinder around a tubular opening and pressure
forces water through the wrappings to the inner opening that leads to the faucet. The
fiber will then filter out the larger particles such as organic matter, sand, mud and
silt. After that, filtrate will pass to the opening that leads to the faucet. Normally, the
flow rate is high with higher pressure as it is on the main pipe.
Cost:
Membrane filter is quite cheap where the cost ranges from RM 75 to RM 200 per
unit.
Maintenance:
When the old fiber stem is worn out, then a new fiber stem has to be replaced.
Clogged filter can reduce the flow pressure of water and interrupt the water flow
into the house. The fiber stem is costs about RM 39 per unit. The life expectancy of
the filter is depends on the quality of feed water. More particles will be trapped in
finer mesh membrane compared to coarse mesh; therefore more frequent filter
change is required.
Since this filter is exposed to the sunlight, it might encourage bacteria and algae
growth. This will contaminate further the water flowing through it. Bacteria will
affect health of the users and hence fiber filters need frequent replacement. If proper
attention is given to the filter, then it can stop the unwanted larger particles flow into
31
the house piping system. This system is economical since no electric energy is being
used during the filtration process.
Mechanism:
This filter used ceramic as the membrane to filter the feed water. The pressure and
flow rate of the water are relatively lower than the point of entry. Tap water will
flow into the filter via an input hose, and then the pressure in the cartridge will force
water into the ceramic stem to retain the unwanted contaminants. Ceramic filtration
technology is often called dead end filtration. The filtrate in the stem will flow out
through the output hose and use for cooking and drinking purposes.
32
Cost:
This kind of filter costs in the range from RM 165 – 300 per unit dependents upon
the brand of the filter.
Maintenance:
The ceramic stem should be brushed and washed regularly to prevent it from being
clogged. The ceramic will become thinner and thinner, and then users need to
replace the old stem with a new one. Normally, a ceramic stem can last for about 12
months depends on how frequent is the cleaning process.
The tiny pores of a ceramic filter element make it an extremely efficient filter for
removal of particulate matter and fine sediment from the water. This ceramic filter is
effective in removing mud, silt and other suspended matter. It is less effective in
removing dissolved solids, organic and chemical pollutants.
33
3.3 Reverse Osmosis
Normal Osmosis
Lower
Contaminant
Concentration
Semi permeable
Membrane
Reverse Osmosis
Pressure
Membrane
Water Flow
34
Reverse osmosis is a water purification process where untreated water flows
thorough several filters and elements, and one of them is semi-permeable membrane.
Reverse osmosis system is effective in removing impurities in water such as heavy
metals, chemical toxin, pesticides, bacteria and viruses. This system is used to
separate the pure water from salt and other contaminants.
In order to understand the reverse osmosis system, we need to know about the
osmosis process first. For two aqueous solutions of different concentrations of
dissolved solids which are separated by a semi-permeable membrane, water will
pass through the membrane in the direction of more concentrated solution until both
sides of concentrations are reaching at equilibrium state. This process is called
osmosis.
Dirty water left behind is drained off at a constant rate capillary waste water
controller. Rejection efficiency of R.O. system is affected by both ionic charge and
concentration gradient. Rejection rates of single-charged ions are ranged in 90 to 96
%, whereas multi-charged ions having rejection rates exceeding 99 %. Rejection
efficiency is reducing as the concentration gradient increasing.
The membrane used in R.O. system is a thin micro- porous surface that rejects all
impurities but only allows water molecules to pass through. The three types of
commonly used membranes are tubular, spiral wound and hollow fiber.
The two most common base materials used to produce membranes are cellulose
acetate and polyamide polymers. Polyamide polymer membranes produce both
35
higher rejection and flux; tolerate a wider pH range and higher continuous
temperature than cellulose acetate.
Membrane
Outer Wrap
Spiral wound membrane is the most popular membranes used in household R.O.
systems. In the design of spiral wound, two flat sheets of membrane are placed back
to back to form an envelope that contains a porous sheet of material called a
permeate carrier. Then, envelope is glued together on three sides only. The fourth
side is attached to a perforated tube.
Water that passes through membrane is then flows along the permeate carrier toward
open end of envelope and leaves through permeate tube. The pores of membrane can
range from atomic dimensions (<10 angstroms) to 100+ microns. Membrane can
reject bacteria and 85 to 95 % of inorganic solids but it allows dissolved solids to
pass through.
36
ii) Hollow fiber membrane:
Permeate Flow
Hollow fiber is one of the semi permeable membranes used in reverse osmosis
system. It is usually produced using aromatic polyamides or cellulose triacetate.
Membrane material is spun into hair like hollow fibers with outer diameter of
between 85 to 200 microns. The fibers are bundled together in either a U-shaped
configuration or straight configuration.
Pressure is applied to pump raw water through the distributor tube and flows
outward through the fiber bundle. The pressurized feed water permeates through the
wall of each hollow fiber and leaving the dissolved solids, organics and bacteria to
discharge as reject water.
The major disadvantage of the hollow fiber membrane is its susceptibility to fouling.
Therefore, feed water that containing turbidity, iron and manganese need to be
treated before passing through the hollow fiber.
37
The performance and life of membrane will be affected by the influent water supply.
i) Pressure:
Both the quantity and purity of product water will be affected by the pressure of feed
water. Lower product flow rate and lower product purity is caused by lower feed
water pressure.
ii) pH:
If the feed water is basic, acidic or unstable, it is recommended to use the wider pH
range membranes.
iv) Temperature:
The performance of membrane is based on temperature of 25 ˚C. Quantity of
product water is reduces by 3 % for every 1 ˚C below 25 ˚C. Feed water should not
exceed 35 ˚C because most membranes damage at that temperature.
Household reverse osmosis systems in the market can be classified as undersink and
tabletop. Undersink system is much cheaper than tabletop. Household R.O. systems
usually can treat between 1 to 9 gallons of water. R.O. system is also equipped with
a booster pump to apply high pressure to the water and a tank is needed to store pure
water due to its slow operation.
38
Figure 3.11: Typical counter top R.O. system [http://yourwaterneeds.com]
39
Figure 3.13: Typical arrangement of R.O. system [www.jousui-souchi.com]
Mechanism:
This reverse osmosis system consists of five elements as below:
• Stage 2: Pre-carbon – coconut based activated carbons are used to trap large
sediments and extract excessive contents of chlorine from the water supply.
40
• Stage 4: R.O. membrane – the membrane consists of a skin about 0.0001
microns and a support layer about 100 microns. This element only allows
water molecules to pass through.
• Stage 5: Post-carbon – this element removes the residue unpleasant smell and
maintains fresh water taste.
Cost:
This R.O. system costs about RM 2500 per unit.
Maintenance:
The frequency and cost of replacing parts are shown in the table below.
Mechanism:
This R.O. system is similar to the previous system, but this system consists of six
filters instead of typical five filters.
41
• Stage 2: Pre-carbon filter – reduces chlorine to prevent hydrolysis of
membrane and absorbs volatile organic compounds from water supply.
• Stage 3: TFC membrane filter – thin film composite membrane with pores of
up to 0.0001 micron used to reduce heavy metals and waterborne
microorganisms such as viruses and bacteria. Chlorine will destroy TCF
membrane; therefore it is always equipped with carbon pre-filter to remove
chlorine.
• Stage 5: Fine filter – minimizes contamination and reduces fine dust that
flows into storage tank by passing it first through post-carbon filter.
Cost:
This six filtration system costs about RM 3100 per unit.
Maintenance:
The frequency and cost of replacing parts are shown in the table below.
42
Advantages and disadvantages:
Reverse osmosis treatment system can provide consumers with pure water, free from
any dissolved solids, organic and chemical matter and mineral. Some typical
removal rates for R.O. system are shown in the table below.
As R.O. system removes large amounts of beneficial minerals from the water, we
might lack of minerals in our body if we consume R.O. water for a long period of
time. Removal of alkaline mineral will produce acidic water. This may result in
pulling of minerals from our bone and teeth to form bicarbonates to neutralize the
acid in the body.
R.O. system wastes a lot of water, it only recovers 5 to 15 % of the water that
entering the system, and the remainder is discharged as waste water. The waste
water is contains rejected contaminants in supplied water.
R.O. system takes time in the treatment process, most of the point-of-use systems
produce less than 1 gallon of water per hour. R.O. system requires regular
43
maintenance and monitoring to perform satisfactorily over an extended period of
time. The maintenance cost can be considered very high.
3.4 Distillation
Distillation is a natural process that exists since the earth began. In natural,
distillation is responsible for the hydrologic cycle. Surface water on the earth’s
surface such as lakes, oceans and streams is evaporates into the atmosphere when it
is heated up by the sun. Impurities of the water are leaving behind during
evaporation process. As the vapor is cools, it is condenses and falls back to the earth
as rain, snow or other forms of precipitation.
Distillation is one of the earliest types of water treatment systems, and it is still a
popular treatment system until today. Distillation process is easy to understand and
it is one of the effective treatments to remove the water contaminants. Distillation in
water treatment also applied the same theory as natural distillation.
44
Water Supply
Inlet
Air Vent
Condensing
Coil
Evaporation Heating
Chamber Coil
Distilled Water
Drain
Most of the household distillation systems use single stage distillers which are
simple in design and effective in contaminants removal. Tap water is heated to 100
˚C to kill bacteria and viruses by continuous boiling. Then, steam is rises and
leaving behind the impurities of water in the boiling chamber.
The low boiling gases will escape through the gaseous vent. Rising steam is then
passes into cooling section and condenses back into liquid. The condensed liquid
will flows into a storage container for drinking and cooking purposes. Household
distillers are not economical to distill water for other uses like flushing toilets,
bathing, washing clothes and cleaning due to its slow operation.
45
Figure 3.15: Typical countertop distiller [www.happyherbalist.com]
Mechanism:
Tap water is fed into the distiller, and then water is heated by heating element to the
boiling point. When the water reaches boiling point, steam is rises and contaminants
are leaves behind. Steam is rises and enters cooling coils, where it is cooled and
condensed back to the water. The pure water then flows into storage container.
Electric power is used to heat the tap water into steam.
Cost:
One set of distiller costs about RM 1000.
46
Maintenance:
Mineral and other residues accumulated in boiling chamber during boiling process
need to be removed periodically to ensure optimal performance. Mineral scales build
up from hard water need to remove by using acid type cleaner. The life span of a
distiller is depends on the levels of impurities in raw water supply, how often
distiller is operates and how often distiller is cleaned. Common repair for a distiller
is replacing of heating element.
Similar to R.O. system, distillation process also removes large amounts of minerals
that needed by our human body such as calcium and magnesium. If we consumed
distilled water over a long period, it is detrimental to health of bones, teeth and
tissues. Since distilled water contains no minerals, it may taste flat when we
consume.
However, distilled water can help to dissolve the toxic poisons that accumulate in
our bodies, clean out the body cells and organs. Distilled water is suitable to
consume by patients who need to dissolve kidneys or gallstones. Distilled water is
enters the body and picks up mineral deposits accumulated in the joints or artery
walls and carry them out. This can help to decrease gallstones and kidney stones
until they can safely pass through their ducts.
Distillation can produce almost 99.5 % extremely pure water, but it is not effective
at removing volatile organic compounds because many of them re-condense back
into liquid. Bacteria can also accumulate in the cooling coils when a distiller has not
been used for a period of time.
47
Distiller uses electric power all the time to keep it operating, therefore the operating
cost for distillation units are generally higher than other forms of home water filter
such as activated carbon and membrane. Distiller takes time to purify water, it takes
about 8 hours to produce a few gallons of water; therefore it is limited to point-of-
use systems.
Ultraviolet light is also one of the common techniques used in water treatment
systems. UV light has been used for many years as an environmental friendly route
to water disinfection. Sun is the main source of natural UV light on the earth. Apart
from sun, stars also produce some amount of UV light.
Earth’s atmosphere produces natural UV light when the very energetic particles
from sun strike the air molecules. UV light is invisible to human eye, the short wave
light having wavelength ranging from x-ray region (100 nm) to blue end of visible
light (400 nm).
48
Ultraviolet light used in water treatment system is aimed to kill the bacteria, viruses
and microorganisms in supplied water. The recent research in USA shown that 271
nm light to 263 nm light are the most effective UV wavelengths for deactivation of
particular target organisms. (Source:http://www.hanovia.com)
DNA is consists of a linear chain of nitrogen bases known as purines (adenine and
guanine) and pyrimidines (thymine and cytosine). Sugar-phosphate components are
used to link these compounds along the chain. Adenine is always linked with
thymine in opposite by hydrogen bond and guanine is always paired with cytosine
by hydrogen bond.
Purine combines with pyrimidine to form base pairs. Hydrogen bond will be
ruptured when UV light is absorbed by pyrimidine bases. Disruption in DNA chain
means cell undergoes mitosis (cell division) and DNA is not be able to replicate
again. Therefore, microorganism is considered dead and it is harmful less to human
health.
49
Figure 3.16: Disruption of DNA structure [www.hanovia.com]
UV light is generated either from low pressure or medium pressure lamp. Low
pressure lamp usually has a single line output at 253.7 nm and medium pressure
lamp has a continuous output from 200 nm up to long wave visible light.
Most of the commercially available units use low pressure mercury vapor lamps.
The operation of these lamps is very similar to the fluorescent lighting with which
we are all familiar.
i) Suspended solids:
Suspended solids in feed water cause a shielding problem during the treatment
process, where microbes may pass through the sterilizer without actually expose to
the direct UV penetration. This problem can be resolved by using pre-filtration of at
least 5 microns.
50
ii) Iron and manganese:
Iron or manganese will cause staining on the lamp or quartz sleeve at levels as low
as 0.3 ppm of iron and 0.05 ppm of manganese. In order to eliminate the staining
problem, proper pretreatment is required.
v) Temperature:
The optimal operating temperature of UV lamp must be approximate 40 ˚C. UV
levels will fluctuate with excessively high or low temperature levels.
In water treatment systems, UV light is always enclosed in the quartz sleeve. There
are three purposes of using quartz sleeve:
• It is used to isolate the UV lamp from water, so that electrical contacts are
not shorted out by water.
51
Figure 3.17: Typical UV treatment arrangement [www.pure-pro.com]
Mechanism:
This UV ray treatment system has three different components; they are control
circuit, power electronics and UV chamber. Consumer can control the intensity of
UV ray through the control circuit. UV lamp is enclosed in quartz sleeve. Water
enters one end of the sleeve, flows through the sleeve around UV lamp and then
exits the other end within a few second.
Water must flow very close to the UV light in a thin layer and at slow flow rate to
assure that bacteria and viruses are destroyed. Bacteria and viruses exposed to the
UV ray will be killed or rendered inactive.
Cost:
The ultraviolet light treatment system costs about RM 1300 per unit.
52
Maintenance:
Ultraviolet light water treatment system does not require much maintenance. The
sleeve does not need to replace unless it gets broken, but outside of the sleeve need
to be cleaned several times per year. UV lamp requires replacement once a year to
ensure its optimal performance.
UV water treatment does not effective against lead, asbestos, chlorine and many
other organic chemicals. This system does not suitable for water with high levels of
suspended solids as these materials could shade bacteria from the direct UV rays.
Therefore some bacteria could still pass through the water and this is harmful to
human health if the water is consumed directly.
UV water treatment system requires electric current for operation, and it is also need
regular inspection and maintenance to ensure that the treated water is bacteria. This
system should use with other forms of water filter to provide clean and safe water to
consumers.
Combination water treatment systems use a few kind of treatment into one. Filtrate
from these kinds of systems usually can be consumed straight away. The
combination filter consists of several cartridges, water need to pass through those
cartridges one by one and finally reach at consumers.
53
3.6.1 Case Study 1: Combination 1
Mechanism:
This treatment system consists of six filters as below:
• Filter1, ceramic membrane filter- pore size of 0.9 micron with silver element
used to filter the residues and bacteria in supply water.
Cost:
One set of the treatment unit costs about RM 2500.
Maintenance:
Filter 1, 2, 3, 4 and 5 need to be changed once a year. Consumers only need to
change filter 6 every two years.
54
Advantages and disadvantages:
This treatment system added silver to the activated carbon filter to prevent bacteria
growth, therefore boiling is not necessary. This system used activated carbon
repetitively; there are three activated carbon filters in the whole system of six filters.
With so many times of carbon filtration, no doubt the water is clean.
Mineral stones used in filter 6 are said to provide minerals and calcium to the
drinking water, but it is not sure that the stones are really omit minerals. It may
become the bacteria breeding ground which is harmful to human health.
Mechanism:
This combination treatment system is combining carbon filter with the ultra-violet
light. Carbon filter is shaped into a block stem and inserted into a cartridge. When
water flows into the cartridge, carbon filter is removes the chlorine, lead and organic
chemicals such as trihalomethanes. Besides that, carbon also improves the taste and
odour of drinking water.
After that, water will flow through the ultra-violet cartridge which puts out up to 80
millijoules of ultra-violet light to destroy the bacteria and viruses in drinking water.
Ultra-violet light is switches on when electro-magnetic connection is activated by
turning the tap.
Cost:
This type of water treatment system costs about RM 3000 per unit.
Maintenance:
The frequency and cost of replacing parts are shown in the table below.
55
Parts Frequency Price
Carbon block Every 12 months RM 275.00
UV light Every 12 months RM 344.00
Ultra-violet light is not on all the time; therefore it does not waste energy. This
system is equipped with monitor technology; it gives both audio and visual
indication when it is time for replacement.
The initial cost of this water treatment system is high; the maintenance costs are also
very high too. Not many consumers afford to invest in this type of water treatment
system due to its high cost.
This whole filtration system consists of three cartridges. The first cartridge is a
ceramic pre-filter while the second cartridge is consists of activated carbon filter.
The third cartridge totally has four different layers, namely KDF, calcium ionized
clay, energizing ceramic and natural mineral stones.
Mechanism:
• The first cartridge, ceramic pre-filter is used to block the suspended solids
like silt and clay in the supplied water just like any normal ceramic
membrane filter.
56
• The second cartridge, activated carbon is used to remove organic
contaminants, chlorine and some organic chemicals like explained previously.
• In third cartridge, the mineral stones are generally to replenish the essential
minerals like calcium into the water. This water filter is not only removes
water pollutants, chlorine, bacteria and harmful heavy metals in the water,
but it also further energizes the water by releasing essential minerals and
calcium ions into the water.
Cost:
One set of this filtration system costs about RM 1600.
Maintenance:
The changing frequency of cartridges is depends on the water quality and water
consumption rate. First cartridge needs to be clean frequently by using toothbrush
once the sediment is covering its surface.
Ceramic pre-filter will become thinner and thinner, consumers need to change it
when the carbon block inside ceramic pre-filter exposes to the surface. Normally,
ceramic pre-filter can last about one year. The second cartridge needs to be changed
every one year while the third cartridge needs to be changed every three years.
KDF together with GAC can partially remove hardness, destroy fungi and algae, and
control bacteria growth. If contact time is sufficient, both GAC and KDF will clean
the feed water from most of the contaminants.
57
It is wondering that why this filtration system needs to be equipped with calcium
ionized clay, mineral stones and energizing ceramic. The manufacturer claimed that
these substances are able to provide minerals and release energy to the water. It is
probably a marketing tactic to lure in customers into believing its benefits to health.
This system is overpriced considering the technology involved.
PPF Filter
PPF Filter
KDF
Activated
Carbon
Natural Mineral Stones
Input
58
Required R.O. Ultraviolet Granular Carbon Powdered Distillation
Function unit activated block activated unit
carbon carbon
Absolute
filtration to 0.2 Yes No No No No Yes
microns
59
CHAPTER 4
SURVEY RESULTS
A public survey was conducted in order to collect public’s opinion about the
supplied water quality and their understanding about the domestic water filtration
systems. There were 100 respondents.
This community questionnaire survey also aimed to study the reasons why
households install water filter systems and gauge public attitude towards these
systems. The public survey was done in the form of questionnaire. The questionnaire
form was delivered directly to the public to collect their feedback in order to do the
analysis. The results of the questionnaire are discussed further in this chapter.
60
4.1 Statistical Results
Question 1: Are you satisfied with the quality of tap water in your house?
Yes
24%
Yes
No
No
76%
From the Figure 4.1 above, 76 % of the respondents are not satisfied with the
supplied tap water and only 24 % of the respondents are satisfied with the current
supplied tap water. Quality of tap water is differs from place to place. The results
show that there is only small percentage of consumers satisfied with the quality of
water supplied by government.
The unsatisfied water quality issue may due to several reasons. Water pollution is
the main reason that causes unsatisfied water quality. Pollution rate in city is higher
than rural area; therefore water contamination problem is more serious than rural
area. Unsatisfied supplied water might also due to the distribution system that
carrying water to consumers at home rather than efficiency of treatment process at
water treatment center.
61
Question 2: Do you boil the tap water before consuming it?
120
100
Percentage(%)
80
60
40
20
0
Yes No
Refer to the Figure 4.2 above, the survey results show that all the respondents boil
the supplied tap water before consuming it and they would not drink water directly
from the water tap.
The result shows that consumers in this country do not trust the quality of tap water.
In Australia, majority of the consumers drink water directly from the tap, they are
confident with the tap water quality and drink water without boiling it.
62
Question 3: What are the problems with the locally supplied tap water do you
encountered?
100
90
80
Percentage(%)
70 62
60
50
40
30 25
20 9
10 4
0
Yellow ish Colour Contain Chlorine Smell Skin Irritation
Suspended
Solids
From the Figure 4.3 above, 62 respondents complained that the supplied tap water is
in yellowish colour. Presence of colour in water may due to the presence of organic
compounds and colloidal forms of iron and manganese. Other complaints are
chlorine smell 25 %, skin irritation 9 % and contain suspended solids 4 %.
Chlorine is the common disinfection used in the water treatment process in order to
disinfect the tap water. However, byproducts of the chlorine in drinking water might
bring side effects to the body systems as Thrihalomethane is the cancer-causing
compound.
63
Question 5: Do you use water filter at home?
100
86
90
Number of Respodents
80
70
60
50
40
30
20 14
10
0
Yes No
Refer to the Figure 4.4 above, the results show that 86 respondents have household
water treatment appliances at home, only 14 respondents do not install water filter at
home. More and more households installed domestic water filters to treat the
supplied tap water before consuming it.
In recent years, consumers begin to focus on the safety of their tap water due to the
increasing number of complaints on water contamination issue. This result shows
that in the consumers’ point of view, the supplied drinking water is no longer safe to
consume due to the water pollution issue.
64
Question 6: How many water filters do you installed in your house?
100
90
Number of Respondents
80
70 64
60
50
40
30 22
20
10
0
One Two More than two
From the Figure 4.5 above, 64 respondents of the total users have installed one unit
of water filter, 22 respondents have installed two water filters and no respondent
installed more than two units of water filter at home.
For the respondents with two units of water filters at home, one unit is installed at
the main pipe outside the house and the other unit is installed in the kitchen.
Respondents with one unit of water filter at home are installed their filters in the
kitchen. All of the consumers installed water filters in the kitchen; this is probably
because that kitchen is the main source of water for drinking and cooking.
65
Question 7: Do you test the tap water before purchasing the water filter?
100
90
Number of Respodents
80 75
70
60
50
40
30
20 11
10
0
Yes No
From the figure 4.6 above, most of the consumers did not carry out water testing
before purchasing the water filter. Actually, laboratory tests should be conducted on
the current supplied tap water in order to find out the water contamination level.
Base on the experimental results, consumers can make decision and choose a correct
water filter to overcome the water quality problems that encountered by them.
Refer to the Figure 4.6, the results show that 11 respondents have been tested the tap
water before purchasing the water filter. However, they only carried out the simple
chlorine test. This simple test is not sufficient in determination of a correct water
filter to suit their requirement.
66
Question 10: What kind of water filters you are using?
100
90
Number of Respondents
80
70
60
50
40 30
26
30
17
20 10
10 2 1
0
Activated Membrane Reverse Distillation UV Light Combination
Carbon Osmosis
Refer to the Figure 4.7 above; the most popular type of domestic water filter used by
consumers is activated carbon with 30 respondents. The second commonly used
water filter is combination filter with 26 respondents, followed by membrane,
reverse osmosis, distillation and ultraviolet light with 17, 10, 2 and 1 respondents
respectively.
There are several reasons that the consumers chose to install activated carbon filter.
The main reason might due to its cheaper price compare to other types of water
filters, therefore consumers are more affordable to install this kind of water filter.
Besides that, activated carbon is the easiest unit to install and maintain, the operating
costs are usually limited to filter replacement and their performance in removing
contaminants.
Combination filter users are on the rise because of the advertisement on the mass
media. Not many consumers install reverse osmosis treatment system at home. This
might due to its high initial and maintenance costs. Besides that, the maintenance
67
operation is more complex and it must be done by the operators. Distillation and
ultraviolet light treatment systems are remain unpopular in Malaysian market.
100
Number of Respondents
90
80
70
60 52
50
40
30
20 14
7 10
10 3
0
Health reason Influenced by Affordable Complaints Advertisement
friends and published in
relatives mass media
Refer to the Figure 4.8 above, the results show that 52 of the respondents said that
health is their main reason in choosing a water treatment system. As living standard
increases, bodies’ health becomes a priority in our lives.
We would like to improve our health by consuming clean and safe drinking water.
Many consumers aware that clean water plays an important role for our bodies’
health, therefore they chose to install water treatment system at home to make sure
the drinking water is always clean.
68
There are 14 respondents said that they are influenced by relatives and friends into
buying a water filter and 10 respondents said they bought water filter because of the
advertisement published in the mass media. From the figure 4.8 above, the results
show that 7 respondents installed water filter because of the water contamination
complaints published in the mass media and 3 respondents bought one because it is
affordable.
100
90
Number of Respondents
80
70
60 54
50
40
30 22
20 13 11
10
0
RM 100-500 RM 500-1000 RM 1000-1500 RM 1500 above
From the Figure 4.9 above, the results show that 54 respondents would only buy a
water filter in the range of RM 100 to RM 500. Most of the membrane filters and
activated carbon filters are in this price range. Therefore, membrane filters and
activated carbon filters become the main choice among the consumers.
69
combination filters are priced above RM 1500 per unit. This high initial cost
becomes the reason that those water filters are not as common as membrane and
activated carbon filters. For normal uses, membrane and activated carbon filters are
sufficient provided that the water must be boiled before consuming.
The survey results also show that many consumers do not clean their water filter
often. Many consumers do not really know when the time to replace the filter parts
is. This negligence is due to ignorance. For example, a normal membrane filter
should be clean as least once a month to get rid of the mud and silt on the membrane
surface to maintain the efficiency of the filter. Activated carbon does not need to be
clean but the carbon filter need to be replaced every 6 months. All the filter parts
need to be changed according to the life span. If the consumers do not change the
old filter with a new one, then the efficiency of a water filter would be affected.
70
CHAPTER 5
EXPERIMENTAL TECHNIQUES
Correct sampling and storage are critical for accurate testing. Containers and
sampling devices need to be thoroughly clean to prevent carryover from the previous
samples.
71
5.1.1 Water Collection
Water samples are collected from various houses in Kuala Lumpur. Water samples
are taken from different types of water filter systems. Water is allowed to run for a
few minute before collecting the sample. The water samples need to be filled into
the containers slowly with a gentle stream to avoid turbulence and air bubbles. A
volume of 1.25 liter of treated and untreated water samples are colleted for the
laboratory tests.
iii. Glass:
Glass is a good general- purpose container. Avoid using soft-glass containers to
collect samples for metals testing in the microgram-per-liter range.
72
5.2 Apparent Colour
5.2.1 Introduction
Colour of drinking water can be seen and judged with naked eye. Consumers will
consider water is dirty and not suitable for drinking if the water is yellowish or
brownish in colour. Pure water for consumption should be clear without any colour.
Apparent colour refers to colour of both dissolved and suspended matters in the
solution whereas true colour is the colour of solution without suspended matter.
The standard colour solutions are composed of potassium chloroplatine (K2 Pt Cl6)
tinted with small amounts of cobalt chloride. The colour produced by 1 mg/l of
platinum in combination with ½ mg/l of metallic cobalt is taken as 1 Standard
Colour Unit.
73
Lovibond colour comparator is the equipment used to compare colour of the samples
with standard colour by giving the value in colour units. The water sample is
inserted into the holder, and then the value of colour is adjusted until colour of
sample equal to the standard colour.
The laboratory equipment used is Hach Odyssey spectrometer with a few sample
cells. Distilled water is the material used to clean and rinse sample cells. The
74
precision and sensitivity of Hach Odyssey spectrometer are as stated in the tables
below.
Precision
Program 95 % confidence limits of distribution
125 245 – 255 units Pt-Co
Table 5.1: Precision of Hach Odyssey spectrometer for measuring apparent colour
Sensitivity
Program Portion of curve Δ Abs Δ Concentration
125 Entire range 0.010 17 Units Pt-Co
Table 5.2: Sensitivity of Hach Odyssey spectrometer for measuring apparent colour
1. A clean sample cell is rinsed with distilled water before it is filled with
distilled water. This cell is called a ‘blank’.
2. A second cell is rinsed and filled with collected water sample.
3. Both cells are wiped with a damp cloth followed by dry cloth to get rid of the
finger prints on the cells.
4. On the Hach Odyssey front menu, Hach Programs icon is pressed, followed
by 125 Colour, 465 nm and Start.
5. The blank cell is inserted into the cell holder in the Odyssey. The cover is
closed before Zero button is pressed.
6. The blank cell is removed before the sample cell is inserted into the cell
holder.
7. The Read button is pressed and the reading is recorded in units of Pt-Co
(Platinum-Cobalt).
8. The procedures are repeated for treated water sample.
75
5.3 Turbidity
5.3.1 Introduction
Turbidity of water indicates the interference of light passage through the water.
Presence of solids, organic particles, microorganisms or other materials in water can
block and adsorb the rays of light. Turbidimeter is the apparatus used for measuring
turbidity of water. Turbidity is measured as NTU (Nephelometric Turbidity Units).
The turbidimeter is in the range from 0 to 4000 NTU in the nearest three decimal
places. Turbidimeter is operates on the nephelometric principle of turbidity
measurement. The optical system is consisted of a tungsten-filament lamp, lenses
and apertures to focus the light, a 90˚ detector, forward-scatter light detector and a
transmitted light detector. The microprocessor of instrument uses a mathematical
calculation to ratio signals from each detector.
The specifications for Model 2100N Turbidimeter is shown in the table below.
76
Figure 5.3: 2100N Laboratory Turbidimeter
77
5.3.3 Test Procedures
The equipment used for measuring the presence of chlorine is Hach Odyssey
Spectrometer. The required reagent is DPD Free Chlorine Powder Pillows. The
required apparatus is sample cell. The precision and sensitivity of Hach Odyssey
Spectrometer are shown in the tables below.
78
Precision
Program 95 % Confidence Limits of Distribution
80 1.00 – 1.14 mg/l Cl2
Sensitivity
Program Portion of curve Δ Abs Δ Concentration
80 Entire range 0.010 0.02 mg/l Cl2
1. Firstly, an empty cell is rinsed with distilled water and followed by the
sample to increase the accuracy of the test.
2. On the spectrometer, Hach Program button is pressed, and then followed by
80 Chlor.F&T and Start.
3. A sample cell is filled with 10 ml of sample and marked as blank cell.
4. The blank cell is wiped to get rid of fingerprints before placing in the
spectrometer.
5. Zero is touched and the display will show 0.00 mg/l Cl2.
6. Another empty cell is filled with 10 ml of water sample and one sachet of
DPD Free Chlorine Powder Pillow.
7. The cell is swirled for 20 seconds to mix the reagent with water.
8. The cell is placed into the spectrometer for reading within one minute.
9. The procedures are repeated for the treated water sample.
79
5.5 Total Aluminium
5.5.1 Introduction
Aluminium is found in nature as alumino silicates such as kaolin, clay, mica and
feldspar. Aluminium is common in treated drinking water especially water treated
with alum which acts as coagulant. Besides that, the presence of aluminium in
drinking water is also due to corrosion of aluminium tanks, pipes and utensils.
Most experts agree that high levels of aluminium in dialysis fluids and medication
are responsible for the dementia. Aluminium has also been associated with severe
diseases of the nervous system such as Parkinson’s disease, amyotrophic lateral
sclerosis (Lou Gehrig’s disease) and Alzheimer’s disease, but the association is not
completely understood. Intake of large amounts of aluminium can also cause
osteomalacia (brittle or soft bones), glucose intolerance and cardiac arrest in humans.
(Source: http://www.esemag.com)
In this research project, the Hach Odyssey Spectrometer is used to measure the
aluminium levels in drinking water. Aluminium indicator combines with aluminium
in the water sample to form a red-orange colour. The intensity of colour is
proportional to the aluminium concentration. Ascorbic acid is added to remove iron
interference. The AluVer3 Aluminium Reagent which is packaged in powder form
shows exceptional stability and is applicable for fresh water applications.
The equipment used for measuring the presence of aluminium is Hach Odyssey
Spectrometer. The required reagents are ascorbic acid, AluVer3 Aluminium Reagent
and Bleaching 3 Reagent Powder Pillow. The required apparatus are sample cells
and cylinder. The precision and sensitivity of Hach Odyssey Spectrometer are
shown in the tables below.
80
Precision
Program 95 % Confidence Limits of Distribution
3+
10 0.383-0.417 mg/l Al
Sensitivity
Program Portion of Curve Δ Abs Δ Concentration
3+
10 Entire range 0.010 0.008 mg/l Al
81
Figure 5.5: Aluminium testing
Chromium is one of the heavy metals presented in drinking water. Heavy metals
such as lead, mercury, arsenic and cadmium are harmful to human’s health while
small amount of heavy metals such as zinc, copper, chromium, iron and manganese
are required in human bodies. However, the latter group can be toxic to our bodies if
they exceeded the acceptable limit.
Chromium can exist as Cr (II) through Cr (VI) in the environment, but Cr (III)
predominates in natural waters. Large amounts of chromium can cause ulcers,
kidney and liver damage and increase the risk of lung cancer.
82
hexavalent form by hypobromite ion under alkaline conditions.
Precision
Program 95 % confidence limits of distribution
100 0.24 – 0.26 mg/l Cr
Sensitivity
Program Portion of curve Δ Abs Δ Concentration
100 Entire range 0.010 0.01 mg/l Cr
1. Firstly, a beaker is filled half full with pipe water. Water is treated to
boiling state by using hotplate.
83
2. On the spectrometer, Hach Programs button is pressed, followed by 100
Chromium, Total and Start.
3. A round sample cell is filled with 25 ml of water sample and chromium 1
Reagent Powder Pillow is added into it.
4. Then, the sample cell is placed into a boiling water bath. The cap of the
cell is tightly closed to prevent water going into it.
5. The timer icon on the spectrometer is pressed to allow a five minutes
reaction. When the timer beeps, the cell is removed from the bath and
cooled down to 25˚C by using running tap water.
6. After that, one packet of Chromium 2 Reagent Powder Pillow is added
into the cell.
7. Then, an Acid Reagent Powder Pillow is added; the cell is capped and
inverted.
8. Chromium 3 Reagent Powder Pillow is added into the cell.
9. On the spectrometer, the time icon is pressed for a five minutes reaction.
10. When the timer beeps, a blank sample cell is prepared. The cell is
contains water sample only.
11. The blank cell is placed into the cell holder in the spectrometer.
12. Zero is touched and the display will show 0.00 mg/l Cr.
13. Then, the sample is placed into the spectrometer for reading.
5.7Total Iron
5.7.1 Introduction
Iron ions also known as ferrous ions, which are highly objectionable in domestic
water usage. Iron ions will produce brownish colour oxides when oxidized and leave
an unaesthetic condition with water uses. The most common method to test total iron
is by using photoelectric colorimeter or spectrometer to measure the intensity of
colour developed in a treated sample, which can be related to the concentration of
the test substance.
84
In this research project, the Hach Odyssey Spectrometer is used. The samples are
treated with FerroZinc Iron Reagent that converts all soluble iron and most insoluble
forms of iron in the sample to soluble ferrous iron. The ferrous iron reacts with the 1,
10 phenanthroline indicator which gives the sample a slight orange colour with the
presence of iron. This orange colour is proportion to the iron concentration in the
sample and can be read easily using the spectrometer in the units of mg/l Fe.
The equipment used is Hach Odyssey Spectrometer. FerroVer Iron Reagent Powder
Pillow is required to convert all soluble iron and most insoluble forms of iron in
water sample to soluble ferrous iron. The required apparatus are beaker and sample
cells. The precision and sensitivity of Hach Odyssey Spectrometer in measuring
total iron are shown in the tables below.
Precision
Program 95 % confidence limits of distribution
265 0.989 – 1.011 mg/l Fe
Sensitivity
Program Portion of curve Δ Abs Δ Concentration
265 Entire range 0.010 0.022 mg/l Fe
85
5.7.3 Test Procedures
1. Hach Program is clicked on the screen and followed by 265 Icon, FerroVer
button and Start button.
2. A sample cell is rinsed with distilled water and then filled with 10 ml of
water sample.
3. One sachet of FerroVer Iron Reagent Powder Pillow is added into the sample
cell. The cell is swirled to mix the reagent with water.
4. The timer icon is pressed to start a three minutes reaction period.
5. Then, another sample cell is rinsed with distilled water and filled with the
same water sample. The cell is labeled as blank.
6. When the timer beeps, the blank cell is placed in the cell holder.
7. Zero is touched and the display will show 0.00 mg/l Fe.
8. The blank cell is replaced with the prepared sample in the cell holder. The
reading is taken and recorded.
86
CHAPTER 6
EXPERIMENTAL RESULTS
From the laboratory experiments, all the raw data was recorded in the table forms.
Then, the percentage removal was calculated by using the following formula.
The results are tabulated according to the parameters and types of filtration systems
used. Three samples are taken from three different locations for a variety of water
quality before treatment.
87
6.1 Apparent Colour
The results for apparent colour for different filtration systems are shown in the table
below.
Table 6.1: Experimental results for apparent colour for different filtration systems
88
6.2 Turbidity
The results for turbidity for different filtration systems are shown in the table below.
Table 6.2: Experimental results for turbidity for different filtration systems
89
6.3Total Free Chlorine
The results for total free chlorine for different filtration systems are shown in the
table below.
Table 6.3: Experimental results for total free chlorine for different filtration systems
90
6.4 Total Aluminium
The results for total aluminium for different filtration systems are shown in the table
below.
Table 6.4: Experimental results for total aluminium for different filtration systems
91
6.5 Total Chromium
The results for total chromium for different filtration systems are shown in the table
below.
Table 6.5: Experimental results for total chromium for different filtration systems
92
6.6 Total Iron
The results for total iron for different filtration systems are shown in the table below.
Table 6.6: Experimental results for total iron for different filtration systems
93
CHAPTER 7
From the experimental results tabulated in Chapter 6, the quality of water before and
after treatment is analyzed. The analysis is made based on the WHO and Malaysian
Drinking Water Standard as a guideline.
The highest and the lowest percentage removal are analyzed according to the
method of treatment used. The average percentage removal is calculated from the
readings obtained and the results are presented in the bar chart form. It can be seen
easily from the bar chart of the effectiveness in removing contaminants for each
treatment system.
94
7.1 Apparent Colour
The lowest, highest and average percentage removals of apparent colour for each
treatment method are shown in the table below.
Table 7.1: The lowest, highest and average percentage removals of apparent colour
% Removal of Colour
99.91
100
90
80 74.4
70
% Removal
60 56.36
48.61 51.59
50
40
24.96
30
20
10
0
Activated Membrane Reverse Distillation UV Light Combination
Carbon Osmosis
95
The results obtained from the laboratory test showed that colour of water samples
before treatment is differs from place to place. Water sample in some areas appeared
in yellowish colour which gave value above 30 Pt-Co, while water in some areas can
be considered clear with value less than 10 Pt-Co. However, the supplied tap water
is still considered unsatisfactory as the maximum permissible level in drinking water
is 15 True Colour Units (TCU).
The experimental results showed that distillation system is the best treatment method
in removing colour from drinking water. Distillation system removes almost 99.9 %
of colour and provides colourless drinking water for human consumption. This is
followed by activated carbon filter at 74.7 % of colour removal. Activated carbon
filter is proven to be an effective method in removing colour from drinking water.
Reverse osmosis system and combination treatment units give unsatisfactory results
as both treatment methods consist of activated carbon that should remove colour as
good as a simple activated carbon filter. Both treatment methods are expensive and
both mechanisms are expected to remove traces of colour.
Ultra violet light unit (UV) uses pre-filter before water is treated with UV light.
Therefore, it removes small percentage of colour from water. UV light treatment is
not expected to remove colour as the main concern for using UV light unit is to
remove microorganisms.
96
7.2 Turbidity
The lowest, highest and average percentage removals of turbidity for each treatment
method are shown in the table below.
Table 7.2: The lowest, highest and average percentage removals of turbidity
% Removal of Turbidity
60 51.67
50
40
30
20
10
0
Activated Membrane Reverse Distillation UV Light Combination
Carbon Osmosis
97
Turbidity level in drinking water should not exceed 5 Nephelometric Turbidity Units
(NTU) according to WHO and Malaysian Drinking Water Standard. Turbidity level
in water is also varies from place to place. Some samples collected are with high
turbidity level which gave value above 4 NTU. However, most of the water samples
are fall in the range of 1.00 to 3.00 NTU. Only a few sample give turbidity level less
than 1.00 NTU.
The experimental results showed that activated carbon filter is the most effective
method in removing turbidity from drinking water. Activated carbon is known as a
natural absorbent for dissolved, colloidal and particulate matters that cause turbidity
in water. Distillation system is also a good method in removing turbidity from water.
Distillation system gives positive result that matches its mechanism of treating water.
98
7.3 Total Free Chlorine
The lowest, highest and average percentage removals of total free chlorine for each
treatment method are shown in the table below.
Table 7.3: The lowest, highest and average percentage removals of total free chlorine
% Removal of Chlorine
60 52.15
50
40
30
20
10
0
Activated Membrane Reverse Distillation UV Light Combination
Carbon Osmosis
99
Residual chlorine is maintained in the distribution of water to ensure continues
disinfection throughout the distribution. Water samples collected give the free
chlorine concentration in the range from 0.01 to 0.64 mg/l.
Chlorine removal is essential in water treatment because chlorine and its by-product,
Trihalomethane (THM) is toxic to human’s health. Chlorine gives a displeasing
odour and it is corrosive when it presents in excessive amount.
All the treatment methods give a good percentage removal of chlorine at above 50 %
removal. However, reverse osmosis system is the most effective method in removing
chlorine from water at 96.63 % removal. Reverse osmosis system has been achieved
the expected result and hence provides drinking water with very low level of
chlorine. Activated carbon filter and combination units are also give positive result
in removing chlorine at 94.67 % and 92.33 % removal respectively.
Distillation system and UV light system are not very effective in removing chlorine
from drinking water as compared to other treatment methods. The result obtained is
disappointed because distillation system is expected to get rid of all constituents
from water.
100
7.4 Total Aluminium
The lowest, highest and average percentage removals of aluminium for each
treatment method are shown in the table below.
Table 7.4: The lowest, highest and average percentage removals of aluminium
% Removal of Aluminium
100
90
80 76.12
70 66.09
% Removal
60 56.5 55.94
50
40 31.09 30.4
30
20
10
0
Activated Membrane Reverse Distillation UV Light Combination
Carbon Osmosis
101
Aluminium level in drinking water should not exceed 0.2 mg/l according to the
WHO and Malaysian Drinking Water Standard. The aluminium levels of water
samples are in the range of 0.021 to 0.135 mg/l. The experimental results showed
that aluminium level in Malaysian tap water has met the Malaysian Drinking Water
Standard.
The experimental results also showed that not all the treatment methods give
satisfactory result in removing aluminium from drinking water. Among six treatment
methods, reverse osmosis system is the most effective method to remove aluminium
at 76.12 % removal. This is followed by distillation system at 66.09 %, combination
unit at 55.94 %, membrane filter at 56.5 %, activated carbon filter at 31.09 % and
UV light system at 30.4 % removal.
Reverse osmosis system and distillation system should give better result in removing
aluminium from water as both methods are expected to produce pure water after
treatment process. Activated carbon filter and UV light system are not the effective
methods in removing aluminium from water.
102
7.5 Total Chromium
The lowest, highest and average percentage removals of total chromium for each
treatment method are shown in the table below.
Table 7.5: The lowest, highest and average percentage removals of total chromium
100
90
80
70
% Removal
60
50 40.65
40 28.97 33.13 33.45
30 19.84
20 16.93
10
0
Activated Membrane Reverse Distillation UV Light Combination
Carbon Osmosis
Figure 7.5: Percentage removal of total chromium for different filtration systems
103
The maximum allowable value for total chromium is 0.05 mg/l according to WHO
and Malaysian Drinking Water Standard. The experimental results showed that most
of the water samples have exceeded the permissible value. The highest recorded
value is 0.10 mg/l whereas the lowest recorded value is 0.05 mg/l. Chromium is a
toxic substance and it is detrimental to human health. This is an alarming issue as
our supplied tap water does not abide the water drinking standard.
All the treatment methods do not give a satisfactory result in removing total
chromium from water. The experimental results showed that distillation system is
the most effective method in removing total chromium compared with other
treatment methods at 40.65 % removal. This is followed by combination unit at
33.45 %, reverse osmosis system at 33.13 % activated carbon filter at 28.97 %,
membrane filter at 19.84 % and UV light system at 16.93 % removal.
Distillation system and reverse osmosis system do not give positive results as
expected. Theoretically, both methods should remove chromium from water as they
can remove heavy metals and provide pure water for human consumption. The
chromium level of some water samples is still exceeded the permissible value even
though after treatment process. The mentioned treatment methods are not be able to
remove all chromium in drinking water but at least the total chromium level has
been reduced.
104
7.6 Total Iron
The lowest, highest and average percentage removals of total iron for each treatment
method are shown in the table below.
Table 7.6: The lowest, highest and average percentage removals of total iron
100
90
80 74.85
67.98 65.74
70
% Removal
60 52.9
50 40.48
40 33.73
30
20
10
0
Activated Membrane Reverse Distillation UV Light Combination
Carbon Osmosis
Figure 7.6: Percentage removal of total iron for different filtration systems
105
The maximum allowable value of iron concentration in drinking water is 0.3 mg/l.
The recorded values of water samples before filtration treatment process are well
below the permissible value. Most water samples have values lower than 0.15 mg/l.
Samples from the same area may differ greatly in iron concentration. Types and
conditions of pipes used in the distribution system might lead to the varying
concentration in iron. Household with old rusted iron pipes may experience a higher
level in iron concentration as opposed to PVC pipes users.
Removal of total iron is more successful than chromium removal as each treatment
method gives higher percentage removal. Distillation system is the most effective
treatment method in removing total iron from water at 74.85 %. This is followed by
reverse osmosis system, combination unit, membrane filter, activated carbon filter
and UV light system at 67.98 %, 65.74 %, 52.98 %, 40.48 % and 33.73 % removal
respectively.
Reverse osmosis system and distillation system give unsatisfactory results again as
both methods should remove higher percentage of iron from water. Theoretically,
reverse osmosis system should remove 95 % to 98 % of iron from drinking water.
However this method does not achieve the expected result. Activated carbon filter
and UV light system are not the effective method for removal of iron.
106
CHAPTER 8
CONCLUSION
8.1 Conclusion
This research project is focused on the currently used domestic water filtration
systems in Malaysian market. There is a need for consumers to have a better
understanding of the various filtration systems based on their technologies, price,
maintenance and limitation.
Nowadays, many consumers do not satisfy with the supplied tap water quality due to
the water contamination problems in the country. Most of the consumers
encountered problems such as turbidity, colour, excessive chlorine content, taste and
odour.
Both organic and inorganic substances at concentration above the acceptable levels
are detrimental to human’s bodies. Harmful chemical pollutants in water are arsenic,
107
chromium, cadmium, cyanide, mercury, lead and etc. Hence, manufacturers and
distributors of domestic filtration systems took this opportunity to introduce
consumers various methods to treat their tap water before consuming it.
Six types of domestic water filtration systems were studied in this research project.
These methods are activated carbon filter, membrane filter, reverse osmosis system,
distillation system, UV light system and combination unit. Based on the case studies,
activated carbon filter and membrane filter are the common and cheaper methods
compared to other filtration systems. These types of filtration systems are commonly
used by consumers because they are easy to install and maintain. Reverse osmosis
system, distillation system, UV light system and combination unit are expensive and
require higher maintenance cost.
The average percentage removal of apparent colour using activated carbon filter,
membrane filter, reverse osmosis system, distillation system, UV light system and
combination unit are 74.7 %, 48.61 %, 51.59 %, 99.91 %, 24.96 % and 56.35 %
respectively. The average percentage removal of turbidity using activated carbon
filter, membrane filter, reverse osmosis system, distillation system, UV light system
and combination unit are 90.42 %, 60.38 %, 79.69 %, 86.22 %, 51.67 % and 60.28
% respectively.
The percentage removal of total free chlorine using activated carbon filter,
membrane filter, reverse osmosis system, distillation system, UV light system and
combination unit are 94.67 %, 87.16 %, 96.63 %, 64.22 %, 52.15 % and 92.33 %
respectively. The average percentage removal of total aluminium using activated
108
carbon filter, membrane filter, reverse osmosis system, distillation system, UV light
system and combination unit are 31.09 %, 56.50 %, 76.12 %, 66.09 %, 30.40 % and
55.94 % respectively. The average percentage removal of total chromium using
activated carbon filter, membrane filter, reverse osmosis system, distillation system,
UV light system and combination unit are 28.97 %, 19.84 %, 33.13 %, 40.65 %,
16.93% and 33.45 % respectively. The average percentage removal of total iron
using activated carbon filter, membrane filter, reverse osmosis system, distillation
system, UV light system and combination unit are 40.48 %, 52.98 %, 67.98 %,
74.85 %, 33.73 % and 65.74 % respectively.
From the results obtained, activated carbon filter is the most effective method in
removing turbidity from water. Distillation system is the most effective method in
removing colour, total chromium and total iron. On the other hand, reverse osmosis
system is the most effective method in removing chlorine and total aluminium. Not
all the treatment units give expected result as mentioned in the literature review.
Reverse osmosis system and distillation system do not remove all the impurities and
give only the pure water as mentioned. According to the experimental results,
percentage removal of some parameters especially the chemical substances is low.
We can conclude that a single water treatment system is not able to treat all the
water problems. Water filter is the simplest way to improve drinking water quality.
Although it cannot remove all the impurities from water but at least it can reduce the
concentration level in the water. Water filter requires maintenance on a regular basis
in order to maintain at its optimum performance. Without regular maintenance,
water filter is not able to provide clean water to us.
For further work of this research project, I hope that students who are interested in
this topic would be able to carry out deeper research. In this research project, the
laboratory experiments are mainly focused on the physical properties and a few
109
chemical properties. For further research, laboratory experiments should focus on
the chemical properties of drinking water. This is because chemical substances
presented in drinking water are dangerous compounds to human’s health. We need
to investigate the effectiveness of various domestic filtration systems in removing
chemical substances from drinking water.
Besides that, biological aspect of the drinking water also should be taken into
consideration. Microorganisms, viruses and bacteria are major concern in regards to
the water quality. Drinking water should be free from all pathogenic microorganisms
as they are waterborne disease-causing organisms. More water samples should be
collected for the experiments in order to obtain accurate results.
On the other hand, consistency test of water parameters can be done to verify the
consistency of quality and treatment efficiency over a period of time. In order to
carry out the consistency test, one specific water treatment system with a single
source should be collected for few days, i.e. five days. Water samples are collect for
five consecutive days and test in the laboratory for the same parameters, i.e. colour,
turbidity, total aluminium, total chromium, total iron and total free chlorine. These
consistency tests are aimed at evaluating the consistency of supplied water quality
and treated water quality.
110
List of References
9. Joseph N. Ryan and Marc Edwards, editor, 1994, Critical issues in water and
wastewater treatment, American Society of Civil Engineers
111
11. MF 883 Activated Carbon Filters [Online], Available from
http://www.oznet.ksu.edu/library/H20QL2/MF883.PDF
[Viewed on 5 March 2005 ]
13. Nesh 2000, Nesh Water Filter [Online] Available from http://www. nesh.
com.my [ Viewed on 10 March 2005 ]
14. Robert M. Clark, Benjamin W. Lykins, Jr., 1989, Granular activated carbon,
Lewis Publishers, Inc.
16. Thomas M. Missimer, 1994, Water supply development for membrane water
treatment facilities, Lewis Publishers, Inc.
17. Thomas R, Camp, Cam, Dresser & Mc Kee, Consulting Engineers, Boston,
1963, Water and its impurities, Reinhold Publishing Corporation, Chapman
& Hall, Ltd, London.
20. 1 March 2005, Which Whole of House Water Filter [online], Available from
http://www.ecologic-my.com [ Viewed on 10 March 2005 ]
112
21. Doulton Water Filter Candle and Cartridge Technologies [Online],
Available from http://www.doultonusa.com [Viewed on 17 August 2005]
113
APPENDIX A
114
University of Southern Queensland
Faculty of Engineering and Surveying
PROJECT AIM : This project investigates the current use of domestic water
filters in Kuala Lumpur. The study will also compare the
technologies of the various filtration systems.
AGREED:
115
APPENDIX B
116
QUESTIONNAIRE
1. Are you satisfied with the quality of tap water in your house?
A. Yes
B. No
3. What are the problems with the locally supplied tap water do you encountered?
A. Yellowish colour
B. Contain suspended solid
C. Chlorine smell
D. Skin irritation
F. Others___________
4. If the water is yellowish colour but told that it is still clean, will you consume it?
A. Yes
B. No
7. Do you test the tap water before purchasing the water filter?
A. Yes
B. No
8. Where is your water filter installed?
117
A. Outside home on the main pipe
B. In the kitchen
C. In the shower
D. Others____________
9. Do you have an understanding about the water filter you are using?
A. Yes
B. No
13. Are you satisfied with the water filter you are using?
A. Yes
B. No
118
14. How often do you clean your water filter?
A. Weekly
B. Monthly
C. Every 3 months
D. Others__________
119