Fkasa - Nor Hidayah Binti Muhamad Asri (CD9308)
Fkasa - Nor Hidayah Binti Muhamad Asri (CD9308)
Fkasa - Nor Hidayah Binti Muhamad Asri (CD9308)
Project submitted in fulfillment of the requirements for the award of the degree of
JUNE 2015
viii
ABSTRACT
ABSTRAK
TABLE OF CONTENTS
Page
SUPERVISOR’S DECLARATION iv
STUDENT’S DECLARATION v
ACKNOWLEDGEMENTS vii
ABSTRACT viii
ABSTRAK ix
TABLE OF CONTENTS x
LIST OF TABLES xiii
LIST OF FIGURES xiv
LIST OF ABBREVIATIONS xv
CHAPTER 1 INTRODUCTION
2.1 Introduction 5
2.2 Concept Definition
2.2.1 Industrial Effluents 6
2.2.2 Water Pollution due to Industrial Activities 7
2.4.3 pH 11
2.4.4 Electrical Conductivity 11
2.4.5 Dissolved Oxygen 12
2.4.6 Total Suspended Solids 12
3.1 Introduction 16
3.2 Study Area 16
3.3 Flowchart Description 18
3.4 Sample Collection 19
3.5 In-situ Analysis 20
3.6 Laboratory Analysis 20
3.6.1 BOD Testing Procedure 20
3.6.2 COD Testing Procedure 21
3.6.3 TSS Testing Procedure 21
3.6.4 AN Testing Procedure 21
3.6.5 Phosphate Testing Procedure 22
3.6.6 Sulphate Testing Procedure 22
4.1 Introduction 24
4.2 Sampling Stations 24
4.3 Average Results 25
4.4 Analysis of In-Situ Parameter 26
4.4.1 Temperature 26
4.4.2 pH 27
xii
5.1 Conclusions 39
5.2 Recommendations 39
5.2.1 Industrial Effluent Recycling 39
5.2.2 Installing Water treatment Plant 40
5.2.3 Role of Government 40
REFERENCES 41
APPENDICES 42
xiii
LIST OF TABLES
LIST OF FIGURES
LIST OF ABBREVIATIONS
AN Ammoniacal Nitrogen
DO Dissolved Oxygen
EC Electrical Conductivity
CHAPTER 1
INTRODUCTION
The availability of quality water has become critical day by day. Recently, a
number of activities affecting the quality of water is increasing. Apparently, agricultural
and industrial activities effluent are considered as one of the worst effluent to the water
(Elhassadi. A, 2008). Water pollution is primarily coming from industrial and domestic
waste. Industrial waste contain high hazardous and toxic chemical which will highly
effect human health. These also include heavy metal such as copper, zinc, iron,
cadmium and manganese. In Japan, there was a case of the “Minamata disease” around
1950. It caused by mercury that being used to produce plastic had been released to
Minamata bay, Japan (Olayini et. al, 2012).
Indera Mahkota Industrial Park is one of the areas for industrial development
around Kuantan, Pahang. In the Third Malaysia Plan (RMK3) around 1976-1980, Indera
Mahkota being one of the targeted industrial area with 52 hectare area (Mohamed. R,
1996). The industrial activities around this area are food processing, chemical industries
and metal industries. Surface water in Indera Mahkota Industrial Park (IMIP) industrial
2
area that received high contaminations of effluent from industries will be affected from
this industrial activities. Proper waste water management need to be carried in order for
the surface water not to be polluted.
A river that struggles with the industrial effluent pollution discharge from IMIP
is The Tiram River. The Tiram River is starts from Kuala Pahang and flows around
Kampung Sungai Tiram and IMIP. As The Tiram River also flows to Sungai Kuantan,
there is some possibilities it will carry along the toxic effluent to the main river in
Kuantan. Most of industries there are small and moderate sector. Most of them do not
have legitimate waste water treatment plant and released industrial effluent to the
nearby river.
The The Tiram River feeds into Kuantan River which is main outlet of the city
of Kuantan. The The Tiram River receiving the industrial effluent without proper
treatment which cause the level of toxic compound is high. As the number of population
grow wider at Indera Mahkota and Kuantan area, IMIP expanding the development of
industrial factories for offering job to the community, caused widespread of polluted
water.
All factories are built along the stream which originates the industrial waste
water. The chemical toxic from the effluent effect the aquatic life and vegetation. It
leads to the death of corps at some part of The Tiram River. It may be effect of low
dissolved oxygen in the river. The result of biological activity is depend on dissolved
3
oxygen. The river is highly turbid and colored. The light is not penetrating through the
water. Highly turbid water will affect the photosynthetic process and respiration for the
aquatic life.
Discharge of industrial effluent with bad contaminate are problem all over the
world (Yasmin et. al, 2012). Under certain water pollution condition, polluted water
may give high impact towards man health. There is several cases of Malaria disease
around house area near The Tiram River. Malaria is dangerous diseases that can cause
high fever and without proper treatment and medical advices will lead to dead. The
problem of waste water released to stream is mosquito can easily breed on it.
Clean water is one of the most necessary resources to any living thing. The
importance of clean river for all living thing cannot be denied. Rivers provide wide
habitat to animal and plant. Clean and healthy streams are also important for humans for
daily activities such as drinking water, food and agricultural activities.
Access to safe and clean drinking water will initiate to healthy and productive
lifestyle. Clean drinking water and clean river is linked because limited access to clean
river will affect safe drinking water as The Tiram River also sources of drinking water.
Our body part are functioning well with water. For example, digestion and cooling.
Therefore, clean drinking water is very important to human body. High contaminated
water will bring many serious disease to human. In Nigeria, many families lost their
member due to diarrhea diseases. More than 2 million children dying from diarrhea
diseases due to lack of access to clean water (Yang H. J et. al, 2007).
Water is adversely affect if the large amount of toxic material discharge on it. If
the water is incapable for its original purposes, it is polluted water. Polluted water is bad
for aquatic life. The ecosystem of the aquatic life will be affect if high contaminant of
water is their habitat. Clean river is important for aquatic life. In Oka River, Siberia an
analysis prove that there is irregularity metal allocate in the fish organ. The metals goes
into aquatic life body via their food. From this study, the pollution level, chemical and
4
biological status of the The Tiram River will be determined and the proper treatment of
effluent will be suggested to the government in order to minimize the risk.
1.4.1 To identify the status of water quality at the The Tiram River
1.4.2 To classify the river by assessing the Department of Environmental Water
Quality Index and National Water Quality Standards
The Tiram River is a river located at Indera Mahkota 3, Kuantan Pahang and is
tributary to Kuantan River. The length of river is 4.8 km and 40.0 m width. The scope
of this study is to determine the water quality of The Tiram River and the impact of
industrial effluent from IMIP towards the receiving river. It is important to classify the
level of pollution of The Tiram River as it is receiving bad contaminant from industrial
activities.
CHAPTER 2
LITERATURE REVIEW
2.1 INTRODUCTION
Water plays a major basic needs in human life. A plentiful of water is one of the
important factors in the development of urban societies. Nowadays, the quantity of
water is more needed than the quality of water. The availability of water can improve
human life. Water is used for domestic, industrial, commercial, agricultural activities
and public used. In general, the amount of water supplied to residence is 150-480
L/capita/day.
Surface waters include rivers, lake, oceans and ice or snow. According to
Department of Irrigation and Drainage, the number river in Malaysia is around 1800
rivers with a total length of 38,000km. River quality characteristics change from time to
time. Rivers is one of the major sources for generating electrical conductivity,
transportation and habitat for aquatic life. Rivers also used as a basic need for human
being for drinking, agricultural, household activities (cooking and bath) and habitat for
aquatic life.
High contaminant in water caused by many sources such as direct storm run-off
and effluent released before being treated. The concentrations of toxicity in rivers is
increasing because most of the waste water from residential and industrial area are
disposed to the river. Aquatic life needs to be preserved from todays because it will
generate nation income through tourism and natural sight-seeing for next generation.
6
Wastewater from industries is the mixing of solid substances, oil and chemical
reagent. Basically, industrial effluents can be classified into inorganic industrial
effluents and organic industrial effluents. Inorganic effluents is released from steel and
metal industries. Metal industries produce cyanide and acid waste before being treated.
7
Water is one of basic need for industrial survival. Water is used for heating,
cooling, manufacturing product and solvent. Industrial effluents that being released to
water bodies is a world major problem in developing countries. Industrial waste contain
toxic and poisonous substances that can effect human health. The presence of unwanted
substances in water can low the quality of water. Water pollution can affect the
usefulness of the water. Water pollution is a dangerous threat to all life being.
River pollution comes from many sources. It may come from natural resources
or human activities. Inorganic matter naturally exist in water due to weathering of
mineral and soil. pH value will affect the solubility of minerals in water. For example,
aluminium hydroxide will increase together with pH. Organic material react with other
chemical pollutant from industrial effluents will cause water more polluted.
Source of water pollution can be divided into two, namely by point source
pollution and non-point source pollution. Examples of point sources pollution is
domestic waste water and industrial waste water while examples non-point source
pollution is runoff from agricultural areas and runoff from urban areas.
Water pollution that caused by point source is coming from municipal water
treatment, domestic waste water and effluents from industrial activities. It may come
from any specific pipe, drainage, tunnel or channel from where it’s being discharged.
High demand of product by customer grow industrial activities day by day. Waste water
treatment plant for industrial effluents is quite expensive to be installed near the
industrial park. Due to that circumstances, some of factories released their effluents
directly to water bodies without any proper treatment.
Effluents from sewage treatment plant can be a point source pollution. During
excessive rain, surface runoff will cross this treatment plant and carry along the
chemical substances and run directly to stream. Besides, high volume of sewer plant is
possible to be handle properly will caused mixing of sewer and runoff. This
combination will overflow to nearest stream.
Runoff is a complex process including the removal and transport of soil practical
and chemicals. The rain water carries soil particles together causing muddy creeks,
streams and rivers causing a blockage caused by sediment. The quantity of pollutants
carried from the ground into water stream affected by the slope and slope length. Runoff
from agricultural and urban areas are classified as non-point sources pollution. This type
of contamination usually occurs through the process of diffusion through the
underground of agricultural areas, construction areas, septic tanks, acid deposition,
farming areas, deforestation area and many others. In addition, the use of fertilizers,
pesticides and other contaminants is the cause of river water pollution which difficult to
identify and controlled.
10
2.4.1 Temperature
2.4.2 Turbidity
The first thing that can be seen about water is its cloudiness. Turbidity is the
clarity of water. The clear waters allow people to see clearly the image of aquatic life in
the water. Suspended particle (Example: clay, organic matter, human waste and
microorganism) mixed with water will caused turbidity. The higher amount of
11
suspended matter, the higher the measure of turbidity. The size of suspended particle,
the characteristics of suspended particle and the content of suspended particle will affect
the turbidity of the water.
2.4.3 pH
pH value is an alkaline and acidic index that is very important in determining the
qualities of water. The content of hydrogen ions (H+) in water are the factors that
determine the pH reading. The scale used is from 1 indicating the most acidic and ended
up with 14 that is, the most alkaline. Neutral value measured at 7. Appropriate pH range
will allow the decomposition of organic matter by both types of anaerobic and aerobic
bacteria occur at optimum. The optimum pH range is between 6 and 8.5. pH readings
were less than that will cause the bacteria to die.
Sudden large pH value changes will cause aquatic life die due to adjustment
cannot be done perfectly. As the pH value low, metals will become more soluble in
waste water or water. Higher dissolve metals in water will affect the health of aquatic
life. Alkaline waste water generate from textile effluents also can cause level of pH.
Any changes of pH level will also affect alkaline value in the water (Yang. H. J et. al,
2012)
(such as chloride and sodium) presence in water. High value of EC show high ion
content in water. EC will not disturb human and aquatic life literally but it is one of the
fast way to find out any changes of water quality. Rivers contain dissolved solid which
coming from soil and rock weathering process. The unit use for EC is Siemen per meter
(S/m). EC can be effect by the temperature. Higher temperature will produce high EC in
water.
Carbon dioxide + water (in the presence of light and chlorophyll) Oxygen + rich
foods
The solids that cannot pass through a filtration process is known as total
suspended solids. Suspended solids is measured by evaporating and weighing the solids
from filter paper. The unit use for suspended solids is milligram per litre (mg/L). Excess
TSS can low aesthetic value of the water by unpleasant scenery. The presence of TSS
will degrade the growth of aquatic life because it prevent the light to penetrate through
the bottom of the water. Some biological matter can survive in TSS will spread
dangerous diseases to the human health.
13
Nitrogen and phosphorus can increase BOD level. Nitrogen and phosphorus will
speed up the growth of algae and plant life. High BOD will be placed for organism that
can survive in low DO to perform. BOD can be measured by testing the water or waste
water sample on 5 days experiment. The DO of sample will be compared with the DO
value of water sample that had been experience 5 days in the dark incubator.
The value of BOD alone cannot be used to estimate the level of organic matter.
BOD value can be effect by the amount of toxic in the water. Hence, COD value is
always higher than BOD value because COD contains biodegradable and non-
biodegradable matter while BOD only have biodegradable.
Ammoniacal nitrogen is made from nitric acid and ammonia. It being used
widely in fertilizer due to low price. The nitrogen contain on AN is high and can
provide rapid growth of plant and fruit. AN is very soluble in water. Farmers releasing
waste water with high AN from agricultural activities without proper treatment can
cause polluted water. Active farm area and oyster pool around Huangpu River, China
14
cause high AN to the river (Yang. H. et. Al, 2007). AN can come from breakdown of
nitrogenous organic and inorganic matter in soil and gas exchange in atmosphere. The
amount of ammonia in unpolluted water is usually less than 0.1 mg/l. Ammonia
concentration in surface water are usually less than 0.2 mg/l but may reach 2-3 mg/l.
2.4.10 Phosphate
2.4.11 Sulphate
Sulphate is the product of sulphur and oxygen reaction. Sulphate is coming from
leach from the soil. Other sources of sulphate is decay process of animal and plants and
fertilizer used in agricultural activities. However, sulphate is classified as non-toxic
substances in a normal concentration. The presence of high sulphate in drinking water
can cause diarrhea and dehydration to human. Generally, sulphur may occure in the
form of hydrogen sulphide. Hydrogen sulphide produce rotten-egg odour and danger to
human and aquatic life.
Quality Standard for Malaysia, water quality data can classify river in Class I, II, III, IV
and V. Table 2.2, Table 2.3, Table 2.4, Table 2.5 and Table 2.6 shows water quality
based on WQI.
(Refer Appendix A)
Wastewater from industrial plant that does not go through proper treatment
process can contaminate streams with the presence of impurities in suspension. It can
lead to major problems such as turbidity, reduction on light penetration into the stream
and bring a threat to aquatic animals. When the wastewater discharged into the water
body through a pipes or sewers, organic matter will mix with the clean water at stream.
Organic materials then broken down by bacteria to get food so as to reproduction.
Organic matter will decompose in the presence of oxygen. Thus, the dissolved oxygen
in the water will degraded. This will increase the BOD in the river.
Oxygen depletion will result in death of aquatic creatures such as fish and the
growth of bacteria like bacteria and protozoa will occurred. This situation will destroyed
the original ecosystem. Water polluted by domestic waste and industrial waste have
pathogens. Bad diseases such as diarrhoea and malaria can spread and killed man
generally. The disease can pass through water through human drinking water or bathe.
In the aspect of economy, water pollution can also affect the nation economy.
River is a natural resources that rich with many usefulness. Therefore, any source of
disturbance and pollution in ecosystem of the river will create bad influence on the
country's economic system. Polluted river cannot generate economic income countries
because there was no source of aquatic animals and aesthetic value. Polluted stream is
prohibited to be a water supply for human consumption and agricultural activities. In
addition, the cost of treating polluted water is very high and uneconomical. Polluted
rivers cannot function as a place of recreation and tourism industry as well as reducing
national income. In addition, the government should bear the costs of treating polluted
river which is higher than maintaining a clean river.