DOI 10.1515/pac-2012-0609Pure Appl. Chem.

2014; 86(4): 545553

IUPAC Recommendations

Trevor Lever, Peter Haines, Jean Rouquerol*, Edward L. Charsley, Paul Van Eckeren
and Donald J. Burlett

ICTAC nomenclature of thermal analysis

(IUPAC Recommendations 2014)
Abstract: The widespread use of thermal analysis (TA) by scientists as a laboratory technique carries with it a
working vocabulary. This document is intended to provide those working in the field with a consistent set of
definitions to permit clear and precise communication as well as understanding. Included in the document
are the definitions of 13 techniques, 54 terms within the glossary, as well as symbols and units.

Keywords: differential scanning calorimetry; differential thermal analysis; evolved gas analysis; Interna-
tional Confederation for Thermal Analysis and Calorimetry (ICTAC); IUPAC Physical and Biophysical Chemis-
try Division; sample-controlled thermal analysis; thermal properties; thermodilatometry; thermogravimetry.

*Corresponding author: Jean Rouquerol, Aix-Marseille Universit-CNRS, Laboratoire MADIREL, Marseille, France,
e-mail: [email protected]; [email protected]
Trevor Lever: Trevor Lever Consulting, Wells, Somerset, UK
Peter Haines: Oakland Analytical Services, Weybourne, Farnham, Surrey, UK
Edward L. Charsley: Centre for Thermal Studies, University of Huddersfield, Queensgate, Huddersfield, UK
Paul Van Eckeren: Safety and Security Department, TNO Defence, Rijswijk, Netherlands
Donald J. Burlett: Gates Corporation, Rochester Hills, MI, USA

Article note: Sponsoring body: IUPAC Physical and Biophysical Chemistry Division: see more details on p. 552.

1 Scope
The scope of this document is to provide scientists working in the field of thermal analysis (TA) with a con-
sistent definitions of terms that are commonly used within the field to allow precise communication and
understanding. Since the scope of the International Confederation for Thermal Analysis and Calorimetry
(ICTAC) also covers calorimetry, a further document dealing with this latter part of nomenclature is planned,
once a satisfactory international consensus is reached on this matter.
In considering all the matters of nomenclature, the current ICTAC Nomenclature Committee has followed
the advice of the late Robert Mackenzie in that
terminology should be simple, and
names based on particular instruments should be discouraged.

2 Intent
This document acknowledges that nomenclature develops without regulated definition as the field of thermal
analysis develops. Some terms used by authors and scientists rapidly become accepted by the scientific com-
munity, even if the term is not consistent with past definitions or is not grammatically correct. However, if
such a term is widely used and understood, it is reported here.

2014 IUPAC & De Gruyter

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546T. Lever etal.: ICTAC nomenclature of thermal analysis

3 Definition of the field of thermal analysis

Thermal analysis (TA) is the study of the relationship between a sample property and its temperature as the
sample is heated or cooled in a controlled manner.

4 Techniques
A technique exists for each property or physical quantity that is measured versus temperature. A summary of
some of these are presented below.

Property or physical Technique Technique Notes

quantity acronym

Heat Scanning calorimetry

Temperature Thermometry May also be described as heating or cooling
curves.
Temperature difference Differential thermal analysis DTA A technique where the temperature difference
between a sample and a reference material is
measured.
Heat flow rate difference Differential scanning DSC A technique where the difference between heat
calorimetry flow rates into a sample and a reference material
is measured.
Mass Thermogravimetry TG In any work where a confusion may arise
or Thermogravimetric analysis TGA between TG and Tg (the glass transition
temperature), the abbreviation TGA or the full term
thermogravimetry should be used.
Dimensional and Dynamic mechanical analysis DMA Moduli (storage/loss) are determined.
mechanical properties Thermomechanical analysis TMA Deformations are measured.
Thermodilatometry TD Dimensions are measured.
Electrical properties Dielectric thermal analysis DEA Dielectric constant/dielectric loss is measured.
Thermally stimulated current TSC Current is measured.
Magnetic properties Thermomagnetometry Often combined with TGA.
Gas flow Evolved gas analysis EGA The nature and/or amount of gas/vapour are
determined.
Emanation thermal analysis ETA Trapped radioactive gas within the sample is
released and measured.
Pressure Thermomanometry Evolution of gas is detected by pressure change.
Thermobarometry Pressure exerted by a dense sample on the walls
of a constant volume cell is studied.
Optical properties Thermoptometry A family of techniques in which an optical
characteristic or property of a sample is studied.
Thermoluminescence TL Emitted light measured
Acoustic properties Thermosonimetry or Techniques where the sound emitted (sonimetry)
Thermoacoustimetry or absorbed (acoustimetry) by the sample is
studied.
Structure Thermodiffractometry Techniques where the compositional or chemical
Thermospectrometry nature of the sample are studied.

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 T. Lever etal.: ICTAC nomenclature of thermal analysis547

5 Terminology and glossary

Note: For all the techniques listed here, the terminology defines the property that is measured, and each defi-
nition of a technique may be completed by adding as a function of temperature. For example: dynamic
mechanical analysis (DMA), a technique where storage and loss viscoelastic moduli are determined with the
help of a periodical stress as a function of temperature.

Note: Each entry listed below is followed by n. or adj. indicating if the term is either a noun or an adjective.

atmosphere, n.
Gaseous environment of the sample, which may be controlled by the instrumentation or generated by the
sample.

combined, adj.
Application of two or more techniques to different samples at the same time. This can include thermal and
nonthermal analytical techniques. Different from simultaneous.

controlled-rate thermal analysis (CRTA), n.

Sample-controlled method where the feedback used to control the heating is the rate of transformation.

controlled temperature program, n.

Temperature history imposed on the sample during the course of the thermal analysis experiment.

cooling curve, n.
Experimental result of measuring the temperature of the sample as a function of time during cooling. Heating
curves are obtained for temperature-time experiments during heating.

derivative, adj.
Pertaining to the 1st derivative (mathematical) of any curve with respect to temperature or time.

dielectric thermal analysis (DEA), n.

Technique where dielectric properties are measured.

differential, adj.
Pertaining to a difference in measured or measurable quantities usually between a sample and a reference or
standard material.

differential scanning calorimetry (heat-flow DSC), n.

Technique where the difference between the heat-flow rates into a sample and a reference material is
measured.

differential scanning calorimetry (power compensation DSC), n.

Technique where the difference between the electrical powers into a sample and a reference material is
measured.

differential thermal analysis (DTA), n.

Technique where the temperature difference between a sample and a reference material is measured.

dynamic, adj.
Indicates, especially in the mechanical analysis of materials, that a parameter changes continuously during
the experiment; opposite of static.

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548T. Lever etal.: ICTAC nomenclature of thermal analysis

dynamic mechanical analysis (DMA), n.

Technique where storage and loss viscoelastic moduli are determined with the help of a periodical stress.

emanation thermal analysis (ETA), n.

Special type of evolved gas analysis (EGA) where the emanation of previously trapped radioactive gas is
measured.

evolved gas analysis (EGA), n.

Family of techniques where the nature and/or amount of gas or vapour evolved is determined. The term
evolved gas detection (EGD) has also been used where the nature of gas is not determined.

gas flow, n.
Passage of gas from one part of the system to another. The gas may be either inert (carrier gas) or reactive,
either introduced into the system or evolving from the sample.

isothermal, adj.
Applied to a technique to indicate that the temperature is maintained constant throughout the experiment

material, n.
The substance which is studied and from which the sample is taken.

micro-, prefix
Prefix used to denote that the technique measures small quantities, either with respect to the amount of
sample studied, or with respect to the change in the properties measured. Mathematically, 1 micro =1 =106.

Note 1: This prefix has been applied to many thermal methods, and the equipment associated with
them, for example, microbalance, microreactor, microcalorimeter and also to the technique
itself: microthermal, microscopic, and the property studied: microstructural.
Note 2: The opposite prefix, macro-, is also occasionally used.

modulated, adj.
Indicates that a parameter changes in a periodic manner during the experiment.

modulated temperature (MT), adj.

Applied to the technique name to indicate that a temperature modulation has been applied to the tempera-
ture program.

Note 1: As an example, a DSC experiment carried out with a modulated temperature program would
be modulated temperature differential scanning calorimetry (MT-DSC).
Note 2: Other modulated techniques are possible, such as modulated force TMA, modulated rate
SCTA, etc.
Note 3: The prefix TM is occasionally used instead, but not recommended.

photo-, prefix
Indicates that the experiment involves the illumination of the sample or measures the amount of light emitted
from a sample. Where possible, the wavelength range of the light should be specified.

sample, n.
The material under study during the entire experiment (starting material, intermediates, and final products)
and its close atmosphere. This is equivalent to the thermodynamic system.

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 T. Lever etal.: ICTAC nomenclature of thermal analysis549

sample controlled, adj.

Applied to the technique to indicate that a property of the sample is used either continuously or discon-
tinuously to control the sample heating. Without this term, it is assumed that the experiment is following a
controlled-temperature program.

Note: The generic term for all TA techniques making use of such feedback is sample-controlled TA
(SCTA), whereas specific names will be of the form sample-controlled TGA (SC-TGA), etc.

scan, n.
(Discouraged) A term used to describe the data produced from a thermal analysis experiment. More correct
usage is a thermal analysis curve, or, for a specific technique thermogravimetric curve, etc.

scanning, adj.
Indicates that a specified experimental parameter, if not temperature, is changed in a controlled manner.

scanning calorimetry, n.
Techniques where heat is measured as a function of temperature.

simultaneous, adj.
Indicates the measurement of two or more properties of a single sample at the same time. Different from
combined.
Note: A hyphen is used to separate the abbreviations of the techniques; for example, simultaneous
measurement of mass and heat flow rate (thermogravimetric analysis and differential scan-
ning calorimetry) would be TGA-DSC.

static, adj.
Indicates, especially in the mechanical analysis of materials, a constant parameter during the experiment.
The opposite of dynamic.

stepwise, adj.
Indicates discrete, discontinuous changes in an experimental parameter, e.g., force, temperature, etc.

tan , n.
The dimensionless ratio of energy lost to energy returned during one cycle of a periodic process. For example,
tan =E/E, in DMA.

temperature-programmed desorption (TPD), n.

EGA using an inert atmosphere or vacuum, in the absence of sample decomposition.

temperature-programmed oxidation (TPO), n.

Experiment using an oxidising atmosphere, usually oxygen. Oxidation is monitored by any appropriate tech-
nique (EGA, TGA, gas sorption, etc.).

temperature-programmed reduction (TPR), n.

Experiment using a reducing atmosphere, usually hydrogen. Reduction is monitored by any appropriate tech-
nique (EGA, TGA, gas sorption, etc.).

thermal curve, n.
(Discouraged) Any graph of any combination of property, time, temperature derived from a thermal analysis
technique.
Note: Thermal curve is a loose abbreviation of the more correct term thermoanalytical curve.

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550T. Lever etal.: ICTAC nomenclature of thermal analysis

thermally stimulated current (TSC), n.

Electrical current observed during heating and caused by the thermally initiated relaxation of the frozen-in
electrical polarization of a sample.

Note 1: By extension, the same name and abbreviation (TSC) are given to the thermal analysis tech-
nique based on the measurement of this current.
Note 2: See also thermally stimulated depolarization.

thermally stimulated depolarization, n.

Relaxation of frozen-in electrical polarization caused by a temperature increase.
Note: The effect is measured through the thermally stimulated current.

thermo-, prefix
Indicating the use of changing temperature during the experiment, when in the name of a thermal analysis
technique.

thermoacoustimetry, n.
A technique whereby the characteristics of sound waves passing through the sample are measured.

thermoanalytical, adj.
Of, or pertaining to, thermal analysis.

thermodiffractometry, n.
A technique where the X-ray diffraction of the sample is measured.

thermodilatometry (TD), n.
A technique where one or more dimensions of the sample are measured under negligible load.

thermogravimetric analysis (TGA), n.

A technique where the mass of the sample is measured, also known as thermogravimetry.

thermogravimetry (TG), n.
See thermogravimetric analysis.

thermoluminescence, n.
A technique where light emission from the sample is measured.

thermomagnetometry, n.
A technique where a magnetic property of the sample is measured.

thermomanometry, n.
A technique where the gas pressure is measured.

thermomechanical analysis (TMA), n.

A technique where the deformation of the sample is measured under constant load.

thermomicroscopy, n.
A technique where the optical properties of the sample are observed and measured through a microscope.

thermoptometry, n.
A technique where the optical properties of a sample are measured.

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 T. Lever etal.: ICTAC nomenclature of thermal analysis551

thermosonimetry, n.
A technique where the sound emitted by the sample is measured.

thermospectrometry, n.
A group of techniques where a spectrum of the sample is measured.

torsional braid analysis (TBA), n.

A dynamic mechanical analysis technique where the sample is supported on a braid.

6 Reporting experimental data

For the experimental conditions to be fulfilled and reported, the reader is referred to the specific guidelines
given in the ICTAC publications [1, 2], which are reproduced and progressively updated and complemented
on the ICTAC website [www.ictac.org].
For reporting uncertainties, it is recommended to follow the guidelines published by the Joint Committee
for Guides in Metrology [3, 4].
For the conventions on quantities, units and symbols to be used when reporting any work in thermal
analysis, the reader is referred to IUPAC recommendations, especially the Green Book Quantities, Units and
Symbols in Physical Chemistry [5].

7 Symbols used in thermal analysis

Quantity Symbol for quantity Symbol (and name) for unit

length l m (metre)
mass m kg, g*, mg* (kilogram, gram, milligram)
time t s, min*, h* (second, minute, hour)
electric current I A (ampere)
thermodynamic temperature T K (kelvin)
Celsius temperature C (degree Celsius)
heating rate =(dT/dt) Ks1 (kelvin per second)
fraction reacted
heat q, Q J (joule)
heat flow rate =(dq/dt) W (watt)
heat capacity at constant pressure Cp JK1mol1 (joule per kelvin and per mole)
heat capacity at constant volume CV JK1mol1 (joule per kelvin and per mole)
pressure p Pa (pascal)
modulus of elasticity E Pa (pascal)

*Denotes a non-SI unit accepted for use with the SI.

7.1 Symbols describing specific events or materials

In general, symbols for physical quantities should be in italic type, or, if vectors, in bold italic type.
The symbols for units do not take plural.
Subscripts should generally be restricted to single letters.
If the subscript relates to an object or property, it should be a CAPITAL letter:
mS =mass of sample S
TR =temperature of reference R
TC =Curie temperature

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552T. Lever etal.: ICTAC nomenclature of thermal analysis

If the subscript refers to a phenomenon, it should be lower case:

Tfus =melting temperature
Tg =glass transition temperature

If the subscript refers to a specific event, time or point, it should be lower case or figures:
Ti =initial temperature
mf =final mass
Tp =peak temperature
t1/2 =half-life of the reaction

Changes in extensive thermodynamic quantities X due to an event y should be represented by yX:

vapH =enthalpy of vaporization
rG =Gibbs energy of reaction

Symbols for the physical state of the material should be put in brackets after the formula symbol:
vapH =H(g) H(l)

8 Overview and historical matters

This document is concerned with providing definitions of common terms that are used by thermal analysts to
report, present, and explain their work.
The ICTAC Nomenclature Committee was initiated in 1965 under the guidance of Robert Mackenzie and
with the secretarial expertise of Cyril Keattch. This document acknowledges the debt to previous members of
the Committee under their succeeding Chairs, including John Sharp (19841988), Ed Gimzewski (19881992),
and Wolfgang Hemminger (19922001), who continued the discussions and published their findings as listed
in the references [616].
The task of the current committee has been to rationalise the work of all preceding committees and to
deliver a document that covers current practice in thermal analysis that can be accepted internationally.
Thanks are due to recent members of the Nomenclature Committee listed for their contributions to the
deliberations and to others for the advice received.
Recent members of the ICTAC Nomenclature Committee are as follows:
R. Blaine (20012006); D. Burlett (20012006); E. Charsley (20012006); V. Fernandez (20012006); P. C.
Gravelle (19922001); B. O. Haglund (19922001); P. Haines (19972006, Secretary, 20032006); W. Hemminger
(Chair, 19922001); G. Hakvoort (19922001); T. Lever (Chair, 20012006); M. Odlyha (19912001); T. Osawa
(20012006); D. Price (20012006, Secretary, 20012003); M. Reading (19912007); S. Sarge (19922001, Secre-
tary, 20002001); J. Simon (19922001); F. Wilburn (19922006, Secretary, 19912000).

9 Membership of sponsoring body

Membership of the IUPAC Physical and Biophysical Chemistry Division Committee for the period 20122013
was as follows:
President: K. Yamanouchi (Japan), Vice President: R. Marquardt (France); Secretary: A. Wilson (USA);
Past President: A. McQuillan (New Zealand); Titular Members: K. Bartok (Belgium); A. Friedler (Israel); A.
Goodwin (USA); R. Guidelli (Italy); A. Russell (UK); J. Stohner (Switzerland); Associate Members: V. Barone
(Italy); A. Csszr (Hungary); V. Kukushkin (Russia); V. Mikovi-Stankovi (Serbia); . Mombr Rodrguez
(Uruguay); X. S. Zhao (China); National Representatives: K. Bhattacharyya (India); J. Cejka (Czech Republic);
S. Hannongbua (Thailand); M. Koper (Netherlands); A. J. Mahmood (Bangladesh); O. Mamchenko (Ukraine);
J. Mdoe (Tanzania); F. Quina (Brazil); N. Soon (Malaysia); V. Tomii (Croatia).

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 T. Lever etal.: ICTAC nomenclature of thermal analysis553

Acknowledgments: This work was sponsored by the International Union of Pure and Applied Chemistry,
through the International Confederation for Thermal Analysis and Calorimetry (ICTAC), an Associated Organ-
ization of IUPAC. The Recommendation received its final form with the help of the IUPAC Physical and Bio-
physical Chemistry Division and in particular Prof. Ron Weir whom we especially wish to thank.

References
[1] (a) G. Lombardi. For Better Thermal Analysis, 1st ed., ICTA, Rome (1977); (b) G. Lombardi. For Better Thermal Analysis, 2nd
ed., ICTA, Rome (1980).
[2] J. O. Hill. For Better Thermal Analysis and Calorimetry, 3rd ed., ICTAC (1991).
[3] BIPM. International Vocabulary of Metrology Basic and General Concepts and Associated Terms (VIM), 3rd ed., Bureau
International des Poids et Mesures, Geneva (2002); JCGM 200:2012 at http://www.bipm.org/en/publications/guides/vim.
[4] BIPM. Guide for Expression of Uncertainty in Measurement (GUM), Bureau International des Poids et Mesures, Svres
(2008); JCGM 100:2008 at www.bipm.org/en/publications/guides/gum.html.
[5] IUPAC. Quantities, Units and Symbols in Physical Chemistry, 3rd ed. (the Green Book). Prepared for publication by E. R.
Cohen, T. Cvita, J. G. Frey, B. Holmstrm, K. Kuchitsu, R. Marquardt, I. Mills, F. Pavese, M. Quack, J. Stohner, H. L. Strauss,
M. Takami, A. J. Thor, RSC Publishing, Cambridge, UK (2007).
[6] R. C. Mackenzie. Talanta 16, 1227 (1969).
[7] R. C. Mackenzie, C. J. Keattch, D. Dollimore, J. A. Forrester, A. A. Hodgson, J. P. Redfern. Talanta 19, 1079 (1972).
[8] H. W. Thompson. Pure Appl. Chem. 37, 439 (1974).
[9] R. C. Mackenzie, C. J. Keattch, T. Daniels, D. Dollimore, J. A. Forrester, J. P. Redfern, J. H. Sharp. Thermochim. Acta 12, 105
(1975).
[10] R. C. Mackenzie. Thermochim. Acta 28, 1 (1979).
[11] G. G. Guilbault. Pure Appl. Chem. 52, 2385 (1980).
[12] R. C. Mackenzie. Thermochim Acta 46, 333 (1981).
[13] R. C. Mackenzie. Pure Appl. Chem. 57, 1737 (1985).
[14] J. H. Sharp. Thermochim. Acta 104, 395 (1986).
[15] R. C. Mackenzie. In Treatise on Analytical Chemistry, P. J. Elving (Ed.), Part 1, Vol. 12, p. 1, John Wiley, New York (1983).
[16] W. Hemminger, S. M. Sarge. Handbook of Thermal Analysis and Calorimetry, Vol. 1, M. E. Brown (Ed.), Chap. 1, Elsevier,
Amsterdam (1998).

Note: Republication or reproduction of this report or its storage and/or dissemination by electronic means is permitted without the
need for formal IUPAC permission on condition that an acknowledgment, with full reference to the source, along with use of the
copyright symbol , the name IUPAC, and the year of publication, are prominently visible. Publication of a translation into another
language is subject to the additional condition of prior approval from the relevant IUPAC National Adhering Organization.

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