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    Surf PAC

    Uploaded by

    Hayat Shaikh
    This document provides a package for determining surfactants using potentiometric titration methods. It includes titration methods, instructions for different Metrohm titration instruments, and electrodes for various surfactant types. The package aims to provide standard operating procedures for surfactant analysis in laboratories.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Surf PAC

    Uploaded by

    Hayat Shaikh
    112 views4 pages
    This document provides a package for determining surfactants using potentiometric titration methods. It includes titration methods, instructions for different Metrohm titration instruments, and electrodes for various surfactant types. The package aims to provide standard operating procedures for surfactant analysis in laboratories.

    Original Description:

    Surfactant Analysis

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    © © All Rights Reserved

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    This document provides a package for determining surfactants using potentiometric titration methods. It includes titration methods, instructions for different Metrohm titration instruments, and electrodes for various surfactant types. The package aims to provide standard operating procedures for surfactant analysis in laboratories.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    112 views4 pages

    Surf PAC

    Uploaded by

    Hayat Shaikh
    This document provides a package for determining surfactants using potentiometric titration methods. It includes titration methods, instructions for different Metrohm titration instruments, and electrodes for various surfactant types. The package aims to provide standard operating procedures for surfactant analysis in laboratories.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    Surf PAC

    Surfactant
    Potentiometric Analysis
    Collection

    SURF PAC
    6.6041.003

    Know-how package for the determination of surfactants with Metrohm


    Titrinos in
    raw materials
    cooling lubricants
    washing agents
    cleaners
    cosmetics

    Potentiometric titration

    Surf PAC is up to date

    Surf PAC contains the titration methods most used in surfactant analysis
    in an attractive and practical form. The
    methods are up to date, as they
    take into account the latest standards,
    apply the most appropriate methods,
    use the Metrosensors especially
    developed for surfactant analysis.
    By using these methods directly as
    SOPs (Standard Operating Procedures) in your laboratory, you will save
    both time and money.
    Depending on the Metrohm Titrinos
    available or to be purchased, you have
    two different possibilities:
    799 GPT Titrino, 798 MPT Titrino,
    785 DMP Titrino or 751 GPD Titrino
    (instrument program version
    5.751.0020 or higher)
    Using the methods memory card
    that is included in the package, you
    load all the methods (complete parameter sets including calculations
    and reports) into the Titrino. You
    then equip the Titrino with the corresponding Exchange Unit and electrodes, load the method into the
    working memory, prepare the first
    sample and start the determination
    by pressing a key. As soon as the
    titration is concluded and the
    sample weight entered, the Titrino
    outputs the titration curve and a
    complete result report on the connected printer.

    Metrosensor surfactant electrodes, from left to right:


    6.0507.010 NIO Electrode for non-ionic surfactants; 6.0504.150High Sense surfactant
    electrode for anionic and especially cationic surfactants; 6.0507.120 Ionic Surfactant
    electrode for cationic and especially anionic surfactants. The two electrodes 6.0507.130
    Surfactrode Resistant and 6.0507.140 Surfactrode Refill are used for the two-phase
    titration of anionic and cationic surfactants.

    716 DMS Titrino, 736 GP Titrino,


    794 Basic Titrino or 751 GPD Titrino
    (instrument program version
    <5.751.0020)
    Using a PC and the demo version
    of Metrodata VESUV 3.0 contained
    in the package, you load the methods into your Titrino. You then continue using the extremely simple
    procedure described above.

    Surf PAC comprises a ring binder with the method collection, two CD-ROMs and the method
    memory card.

    Surf PAC

    One of the many applications for your Metrohm Titrinos

    Dishwashing is fun...
    The determination shown here is one of the many applications of potentiometric surfactant titration and concerns
    the anionic surfactants in a dishwashing agent. Surf PAC
    places at your disposal the methods listed below for your
    applications. Please consult your Metrohm supplier; you
    can find the contact details under
    www.metrohm.com Agencies.

    fr
    785 DMP Titrino
    date

    0P1/101

    2000-09-26

    U(init)
    smpl size
    Titration curve and result report obtained during a determination of
    the anionic surfactants in a dishwashing agent using potentiometric two-phase titration with c(Hyamine 1622) = 0.005 mol/L. A
    6.0507.140 Surfactrode Refill was used as the indicator electrode
    together with a 6.0726.107 Ag/AgCl reference electrode. Starting
    solution: 20 mL buffer pH = 3.0 + 0.2 mL TEGOadd + 20 mL
    ethanol/MIBK 1:1 + 50 mL dist. H2O.

    14
    0.1420

    EP1
    Anion

    time

    9.613
    29.481

    mV

    785.0011

    12:45
    DET U

    20
    ********

    g
    ml

    199 mV

    mmol/100 g

    stop V reached
    ============

    List of methods
    Methods no. 1 to 21, arranged into groups A to E, can be found on the memory card:
    A Anionic surfactants

    C Nonionic surfactants (all the determinations


    performed with the NIO electrode)

    Titer determination of cationic titrants for the potentiometric two-phase titration of anionic surfactants
    and soaps

    Titer determination of the cationic titrant for the potentiometric aqueous titration of anionic surfactants

    Anionic surfactants and soaps in washing powders


    by potentiometric two-phase titration

    Anionic surfactants in oil-containing shower gels or


    bath additives by potentiometric two-phase titration

    14

    Betains by aqueous titration with STPB and by nonaqueous titration with HClO4

    Anionic surfactants in dishwashing concentrates by


    potentiometric aqueous titration

    15

    Polyacrylates by titration with TEGOtrant A100

    B Cationic surfactants
    6

    Titer determination of the anionic titrant for the potentiometric two-phase titration of cationic surfactants

    11

    Nonionic surfactants: calibration factor with Triton


    X-100 and polyethylene glycol 1000

    12

    Nonionic surfactants in household cleaners

    13

    Nonionic surfactants in wool shampoo

    D Betains and polyacrylates

    E Further ingredients in formulations


    16

    Sulfate in washing powders

    17

    Total phosphate in washing powders

    18

    Peroxo acids (perborate, percarbonate, persulfate)


    in washing powders

    Titer determination of the anionic titrant for the potentiometric aqueous titration of cationic surfactants

    19

    NTA and/or EDTA in washing powders

    Cationic surfactants in hair conditioners by potentiometric two-phase titration

    20

    Chloride (NaCl) in detergents and soaps

    21

    Carbonate in washing powders

    Cationic surfactants in cooling lubricant concentrates


    by potentiometric two-phase titration

    10

    Cationic surfactants in mouth rinses by potentiometric aqueous titration

    Surf PA C

    Ordering information

    Scope of delivery
    6.6041.003
    6.6041.001

    Surf PAC, English version


    Surf PAC, German version

    each consisting of:


    The printed collection with texts concerning the 21 titration methods most often used in surfactant analysis. Each method is
    extensively described and comprises parameter sets and curve examples; method-related icons facilitate orientation. The
    collection comes in an attractive, practical binder.
    Memory card containing the parameter sets of the 21 methods for loading into the 799 GPT Titrino, 798 MPT Titrino, 785 DMP
    Titrino or the 751 GPD Titrino (instrument program version 5.751.0020 or higher).
    Two Metrodata CD-ROMs containing:
    The contents of the above-mentioned binder, i.e. texts, parameter sets and curve examples (PDF files).
    The following Metrohm Application Bulletins:
    No. 101 Complexometric titrations with the Cu ISE
    No. 129 Potentiometric determination of orthophosphates, metaphosphates and polyphosphates
    No. 130 Chloride titrations with potentiometric indication
    No. 140 Titrimetric determination of sulfate
    No. 143 Potentiometric determination of nitrilotriacetic acid (NTA) and/or ethylenediaminetetraacetic acid (EDTA) in washing
    agents
    No. 230 Titrimetric/potentiometric determination of non-ionic surfactants based on polyoxyethylene adducts using the
    NIO electrode
    No. 233 Titrimetric/potentiometric determination of anionic and cationic surfactants
    No. 264 Titrimetric methods for the determination of betains
    No. 268 Potentiometric titration of surfactants and pharmaceutical compounds
    No. 269 Titrimetric/potentiometric determination of ionic surfactants by two-phase titration using the Metrosensor
    Surfactrodes
    No. 275 Potentiometric two-phase titration of anionic surfactants in washing powders and liquid washing agents
    The following Metrohm Application Notes:
    No. T-10 Anionic surfactants in shower lotions and shampoos
    No. T-11 Anionic surfactants in nickel plating bath
    No. T-12 Cationic surfactants in hair conditioner
    No. T-13 Cationic surfactant (cetrimid) in antiseptic disinfectant
    No. T-15 Non-ionic surfactants in liquid household cleaners
    No. T-16 Non-ionic surfactants in compact washing powders
    No. T-26 Perborate, percarbonate or persulfate in washing powder
    No. T-46 Soap content of soap noodles
    No. T-47 Soaps and anionic surfactants in washing powder by potentiometric two-phase titration
    No. T-48 Anionic surfactants in shower oil by potentiometric two-phase titration
    No. T-49 Cationic surfactants in household cleaner by potentiometric two-phase titration
    No. T-50 Non-ionic surfactant nonylphenol ethoxylate (8 EO)
    No. T-67 Non-ionic surfactant tallow ethoxylate
    No. T-68 Non-ionic surfactant coconut oil ethoxylate
    Demo versions of the Metrodata programs VESUV, TiNet, VA Database, IC-Net etc. Adobe Acrobat Reader for reading
    and printing the PDF files. Using the VESUV PC software you can load the parameter sets from the CD-ROM into the
    following Titrinos: 716 DMS Titrino, 736 GP Titrino, 794 Basic Titrino or 751 GPD Titrino (instrument software version
    <5.751.0020).

    8.006.6003
    Subject to modifications
    Printed by Metrohm Ltd., CH-9101 Herisau
    2001-12

    Surf PAC

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