BENZENE: Shell MSDS (2011)

Benzene
Version 5.
Effective Date 21.02.2011
Regulation 1907/2006/EC
Safety Data Sheet
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product Identifier
Material Name
Product Code
REACH Registration No.
:
:
:
Benzene
Q9112, Q9169
01-2119447106-44-0023, 01-2119447106-44-0019,
01-2119447106-44-0022, 01-2119447106-44-0020,
01-2119447106-44-0021
1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use
Raw material for use in the chemical industry.

The substance/product is registered with strictly controlled
conditions as defined in Article 18(4) of Regulation (EC) No.
1907/2006 (REACH Regulation) and must therefore be handled
as such.
1.3 Details of the supplier of the substance or mixture

Manufacturer/Supplier
SHELL TRADING INTERNATIONAL LIMITED

80 Strand
London
WC2R 0ZA
United Kingdom
Telephone
Email contact for

MSDS
+44 (0)20 7546 5000

[email protected]
1.4 Emergency Telephone Number

:
+44 (0) 151 350 4595
2. HAZARDS IDENTIFICATION
2.1 Classification of substance or mixture
Regulation (EC) No 1272/2008 (CLP)

Hazard Class & Category
Hazard statement
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Print Date 23.02.2011
MSDS_GB
Benzene
Version 5.
Safety Data Sheet

Flammable liquids, Category 2
Harmful in contact with skin., Category 2
Causes serious eye damage., Category 2
ASPIRATION HAZARD, Category 1
Germ Cell Mutagenicity, Category 1B
CARCINOGENICITY, Category 1A
Specific target organ toxicity - repeated
exposure, Category 1; Blood.; Blood-forming
organs.
H225
H315
H319
H304
H340
H350
H372
67/548/EEC or 1999/45/EC
Hazard characteristics
R-phrase(s)
Highly flammable. Toxic.
R45, R46, R11, R36/38, R48/23/24/25, R65
2.2 Label Elements
Label Name
EC Number
EC Annex I Number
:
:
:
BENZENE
200-753-7
601-020-00-8
Labeling according to Regulation (EC) No 1272/2008

Symbol(s)
:
Signal Words
Danger
CLP Hazard statements
PHYSICAL HAZARDS:
H225: Highly flammable liquid and vapor.
HEALTH HAZARDS:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H340: May cause genetic defects.
H350: May cause cancer.
H372: Causes damage to organs through prolonged or repeated
exposure.
H304: May be fatal if swallowed and enters airways.
ENVIRONMENTAL HAZARDS:
Not classified as environmental hazard according to CLP
criteria.
CLP Precautionary statements

Prevention
P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P243: Take precautionary measures against static discharge.
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P280: Wear protective gloves/protective clothing/eye

protection/face protection.
P202: Do not handle until all safety precautions have been read
and understood.
Response
P303+P361+P353: IF ON SKIN (or hair): Remove/take off

immediately all contaminated clothing. Rinse skin with
water/shower.
P301+P310: IF SWALLOWED: Immediately call a POISON
CENTRE or doctor/physician.
P331: Do NOT induce vomiting.
Labeling according to Directive 1999/45/EC

EC Symbols
F Highly flammable.
T Toxic.
EC Classification
EC Risk Phrases
EC Safety Phrases
Highly flammable. Toxic. Carcinogenic, category 1. Mutagenic,

category 2.
R45 May cause cancer.
R46 May cause heritable genetic damage.
R11 Highly flammable.
R36/38 Irritating to eyes and skin.
R48/23/24/25 Toxic: danger of serious damage to health by
prolonged exposure through inhalation, in contact with skin and
if swallowed.
R65 Harmful: May cause lung damage if swallowed.
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible).
2.3 Other Hazards
Health Hazards
Aggravated Medical
Condition
Toxic: danger of serious damage to health by prolonged

exposure through inhalation, in contact with skin and if
swallowed. Slightly irritating to respiratory system. Vapours may
cause drowsiness and dizziness. Irritating to skin. Irritating to
eyes. Harmful: may cause lung damage if swallowed. Possibility
of organ or organ system damage from prolonged exposure; see
Chapter 11 for details. Target organ(s): Blood. Blood-forming
organs. Immune system. May cause heritable genetic damage.
May cause cancer. May cause leukaemia (AML - acute
myelogenous leukaemia).
Pre-existing medical conditions of the following organ(s) or
organ system(s) may be aggravated by exposure to this
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Safety Hazards
Environmental Hazards
Other Information
:
:
material: Blood. Blood-forming organs. Eyes. Skin.

Cardiovascular system. Immune system.
Pre-existing medical conditions of the following organ(s) or
organ system(s) may be aggravated by exposure to this
material: Skin. Eyes. Immune system. Circulatory System
(including heart) Blood-forming organs. Blood.
Highly flammable. In use, may form flammable/explosive
vapour-air mixture. Electrostatic charges may be generated
during pumping. Electrostatic discharge may cause fire.
Not classified as dangerous under EC criteria.
as such. Refer to the industry guidance prepared by
Concawe/Cefic for advice on the demonstration of strictly
controlled conditions available from :
http://cefic.org/Industry-support/Implementing-reach/Document
s-and-Tools1/.
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substance
Material Formal Name
CAS No.
INDEX No.
EC Number
:
:
:
:
Benzene
71-43-2
601-020-00-8
200-753-7
3.2 Mixtures
Hazardous Components
Classification of components according to Regulation (EC) No 1272/2008
Chemical Name
CAS No.
EINECS
Benzene
71-43-2
200-753-7
Chemical Name
Benzene
REACH Registration
No.
01-2119447106-44
Conc.
100.00%
Hazard Class & Category

Hazard statement
Flam. Liq., 2; Carc., 1A; Muta., 1B;
H225, H350, H340, H372, H304,
STOT RE, 1; Asp. Tox., 1; H319, 2; Skin
H319, H315,
Irrit., 2;
Classification of components according to 67/548/EEC
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Chemical Name
Benzene
CAS
EINECS
REACH
Symbol(s)
Registration
No.
200-753-7 01-21194471 F, T
06-44
71-43-2
R-phrase(
s)
R45; R46;
R11;
R36/38;
R48/23/24/
25; R65
Conc.
100.00 %
4. FIRST AID MEASURES

4.1 Description of first aid measures
General Information
Inhalation
:
:
Skin Contact
Eye Contact
Ingestion
4.2 Most important

symptoms/effects, acute
& delayed
4.3 Indication of
immediate medical
attention and special
Keep victim calm. Obtain medical treatment immediately.

DO NOT DELAY. Remove to fresh air. If rapid recovery does not
occur, transport to nearest medical facility for additional
treatment.
Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.
Immediately flush eyes with large amounts of water for at least
15 minutes while holding eyelids open. Transport to the nearest
medical facility for additional treatment.
If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration. If
any of the following delayed signs and symptoms appear within
the next 6 hours, transport to the nearest medical facility: fever
greater than 101 F (38,3 C), shortness of breath, chest
congestion or continued coughing or wheezing. If vomiting
occurs spontaneously, keep head below hips to prevent
aspiration. Give nothing by mouth. Do NOT induce vomiting.
Eye irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blurred vision. Skin irritation
signs and symptoms may include a burning sensation, redness,
swelling, and/or blisters. If material enters lungs, signs and
symptoms may include coughing, choking, wheezing, difficulty
in breathing, chest congestion, shortness of breath, and/or
fever. The onset of respiratory symptoms may be delayed for
several hours after exposure. Breathing of high vapour
concentrations may cause central nervous system (CNS)
depression resulting in dizziness, light-headedness, headache,
nausea and loss of coordination. Continued inhalation may
result in unconsciousness and death. Damage to blood-forming
organs may be evidenced by: a) fatigue and anaemia (RBC), b)
decreased resistance to infection, and/or excessive bruising and
bleeding (platelet effect).
Potential for chemical pneumonitis. Potential for cardiac
sensitisation, particularly in abuse situations. Hypoxia or
negative inotropes may enhance these effects. Consider:
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treatment needed
oxygen therapy. Call a doctor or poison control center for

guidance.
5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.
5.1 Extinguishing Media
Unsuitable Extinguishing
Media
5.2 Special hazards
arising from substance or
mixture
5.3 Advice for fire-fighters
Additional Information
Foam, water spray or fog. Dry chemical powder, carbon dioxide,

sand or earth may be used for small fires only.
Do not use water in a jet.
The vapour is heavier than air, spreads along the ground and
distant ignition is possible. Will float and can be reignited on
surface water. Carbon monoxide may be evolved if incomplete
combustion occurs.
Wear full protective clothing and self-contained breathing
apparatus.
Keep adjacent containers cool by spraying with water.
6. ACCIDENTAL RELEASE MEASURES

Observe all relevant local and international regulations. Avoid contact with spilled or released
material. For guidance on selection of personal protective equipment see Chapter 8 of this
Material Safety Data Sheet. See Chapter 13 for information on disposal.
6.1 Personal Precautions,
Protective Equipment and
Emergency Procedures
6.2 Environmental
Precautions
Isolate hazard area and deny entry to unnecessary or

unprotected personnel. Stay upwind and keep out of low areas.
6.3 Methods and Material

for Containment and
Clean Up
Additional Advice
Shut off leaks, if possible without personal risks. Remove all

possible sources of ignition in the surrounding area. Use
appropriate containment (of product and fire fighting water) to
avoid environmental contamination. Prevent from spreading or
entering drains, ditches or rivers by using sand, earth, or other
appropriate barriers. Attempt to disperse the vapour or to direct
its flow to a safe location for example by using fog sprays. Take
precautionary measures against static discharge. Ensure
electrical continuity by bonding and grounding (earthing) all
equipment. Ventilate contaminated area thoroughly.
For large liquid spills (> 1 drum), transfer by mechanical means
such as vacuum truck to a salvage tank for recovery or safe
disposal. Do not flush away residues with water. Retain as
contaminated waste. Allow residues to evaporate or soak up
with an appropriate absorbent material and dispose of safely.
Remove contaminated soil and dispose of safely.
For small liquid spills (< 1 drum), transfer by mechanical means
to a labelled, sealable container for product recovery or safe
disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur. Local authorities should
be advised if significant spillages cannot be contained. The
vapour is heavier than air, spreads along the ground and distant
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ignition is possible. Vapour may form an explosive mixture with

air.
7. HANDLING AND STORAGE
General Precautions
7.1 Precautions for Safe

Handling
7.2 Conditions for safe

storage, including any
incompatibilities
7.3 Specific End Uses
Product Transfer
Recommended Materials
Unsuitable Materials
Avoid breathing vapours or contact with material. Only use in

well ventilated areas. Wash thoroughly after handling. On
guidance on selection of personal protective equipment see
Chapter 8 of this Material Safety Data Sheet. Use the
information in this data sheet as input to a risk assessment of
local circumstances to help determine appropriate controls for
safe handling, storage and disposal of this material.
Avoid inhaling vapour and/or mists. Avoid contact with skin,
eyes, and clothing. Avoid exposure. Obtain special instructions
before use. Extinguish any naked flames. Do not smoke.
Remove ignition sources. Avoid sparks. Electrostatic charges
may be generated during pumping. Electrostatic discharge may
cause fire. Ensure electrical continuity by bonding and
grounding (earthing) all equipment. Restrict line velocity during
pumping in order to avoid generation of electrostatic discharge
(<= 1 m/sec until fill pipe submerged to twice its diameter, then
<= 7 m/sec). Avoid splash filling. Do NOT use compressed air
for filling, discharging, or handling operations.
Vapours from tanks should not be released to atmosphere.
Breathing losses during storage should be controlled by a
suitable vapour treatment system. Bulk storage tanks should be
diked (bunded). The vapour is heavier than air. Beware of
accumulation in pits and confined spaces.
s-and-Tools1/.
Ensure that all local regulations regarding handling and storage
facilities are followed.
Electrostatic charges may be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical
continuity by bonding and grounding (earthing) all equipment.
Restrict line velocity during pumping in order to avoid generation
of electrostatic discharge (<= 1 m/sec until fill pipe submerged to
twice its diameter, then <= 7 m/sec). Avoid splash filling. Do
NOT use compressed air for filling, discharging, or handling
operations.
For containers, or container linings use mild steel, stainless
steel.
Natural, butyl, neoprene or nitrile rubbers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this
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document, it is provided for information only.
8.1 Control Parameters
Occupational Exposure Limits
UK Workplace Exposure Limits
Material
Benzene
Source
EH40 MEL
ACGIH
ACGIH
ACGIH
Type
TWA
TWA
STEL
SKIN_DES
ppm
1 ppm
0.5 ppm
2.5 ppm
EH40 WEL
EH40 WEL
TWA
SKIN_DES
1 ppm
EU OELIII
EU OELIII
TWA
SKIN_DES
1 ppm
SHELL IS
SHELL IS
TWA (8 h)
STEL
0.5 ppm
2.5 ppm
Material
Benzene
mg/m3
Notation
Can be absorbed through

the skin.
the skin.
3.25 mg/m3
the skin.
1.6 mg/m3
8 mg/m3
SHELL IS is the Shell Internal Standard.
Source
EU CARC.
Hazard Designation
Carcinogen/Mutagen
Predicted No Effect Concentration (PNEC)

Component
Exposure Route
Value
Remark
8.2 Exposure Controls

General Information
The level of protection and types of controls necessary will vary

depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances. Appropriate
measures include: Use sealed systems as far as possible.
Adequate ventilation to control airborne concentrations below
the exposure guidelines/limits. Adequate explosion-proof
ventilation to control airborne concentrations. Firewater
monitors and deluge systems are recommended. Eye washes
and showers for emergency use.
Occupational Exposure Controls

Personal Protective
Equipment
Eye Protection
Hand Protection
Personal protective equipment (PPE) should meet

recommended national standards. Check with PPE suppliers.
Chemical splash goggles (chemical monogoggles). Approved to
EU Standard EN166, AS/NZS:1337.
Where hand contact with the product may occur the use of
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Body protection
Respiratory Protection
Thermal hazards
Monitoring Methods
:
:
gloves approved to relevant standards (e.g. Europe: EN374,

US: F739, AS/NZS:2161) made from the following materials
may provide suitable chemical protection: Longer term
protection: Viton. Incidental contact/Splash protection: Nitrile
rubber. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced.
Personal hygiene is a key element of effective hand care.
Gloves must only be worn on clean hands. After using gloves,
hands should be washed and dried thoroughly. Application of a
non-perfumed moisturizer is recommended.
Chemical resistant gloves/gauntlets, boots, and apron. Where
risk of splashing or in spillage clean up, use chemical resistant
one-piece overall with integral hood.
If engineering controls do not maintain airborne concentrations
to a level which is adequate to protect worker health, select
respiratory protection equipment suitable for the specific
conditions of use and meeting relevant legislation. Check with
respiratory protective equipment suppliers. Where air-filtering
respirators are suitable, select an appropriate combination of
mask and filter. Select a filter suitable for organic gases and
vapours [boiling point >65 C (149 F)] meeting EN14387.
Where respiratory protective equipment is required, use a
full-face mask. Where air-filtering respirators are unsuitable
(e.g., airborne concentrations are high, risk of oxygen
deficiency, confined space) use appropriate positive pressure
breathing apparatus.
Not applicable
Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate. Examples of sources of recommended air
monitoring methods are given below or contact supplier. Further
national methods may be available. National Institute of
Occupational Safety and Health (NIOSH), USA: Manual of
Analytical Methods,
http://www.cdc.gov/niosh/nmam/nmammenu.html.
Occupational Safety and Health Administration (OSHA), USA:
Sampling and Analytical Methods,
http://www.osha-slc.gov/dts/sltc/methods/toc.html. Health and
Safety Executive (HSE), UK: Methods for the Determination of
Hazardous Substances,
http://www.hsl.gov.uk/publications/mdhs.aspx.
Berufsgenossenschaftliches Institut fr Arbeitssicherheit (BIA),
Germany http://www.hvbg.de/d/bia/index.html. L'Institut
National de Recherche et de Securit, (INRS), France
http://www.inrs.fr/securite/hygiene_securite_travail.html.
Environmental Exposure Controls

Environmental exposure
: Local guidelines on emission limits for volatile substances must
be observed for the discharge of exhaust air containing vapour.
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control measures
9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
Appearance
Odour
Odour threshold
Boiling point
Freezing Point
Flash point
Explosion / Flammability
limits in air
Auto-ignition temperature
Vapour pressure
Specific gravity
:
:
:
:
:
:
:
Density
Water solubility
n-octanol/water partition
coefficient (log Pow)
Kinematic viscosity
Vapour density (air=1)
Electrical conductivity
Evaporation rate (nBuAc=1)
Surface tension
Molecular weight
: 883 kg/m3 at 15 C / 59 F
: 1.8 kg/m3 at 25 C / 77 F
: 1.95 - 2.13
9.2 Other Information

Saturated Vapour
concentration (in air)
Colourless. Liquid.
Aromatic.
2.7 ppm
80.1 C / 176.2 F
5.5 C / 41.9 F
-11 C / 12 F (Abel)
1.4 - 7.1 %(V)
: 498 C / 928 F
: 10 hPa at 20 C / 68 F
: 0.8787 at 20 C / 68 F
:
:
:
:
:
:
0.65 mm2/s at 20 C / 68 F
2.7 at 15 C / 59 F
< 50 pS/m at 20 C / 68 F
2.8
0.03 N/m
78 g/mol
: 320 g/m3 at 20 C / 68 F
10. STABILITY AND REACTIVITY

10.1 Reactivity
: Stable under normal conditions of use.
10.2 Stability
10.3 Possibility of
Hazardous Reactions
10.4 Conditions to Avoid

10.5 Materials to Avoid

10.6 Hazardous
Decomposition Products
: Avoid heat, sparks, open flames and other ignition sources.

Prevent vapour accumulation.
: Strong oxidising agents.
: Thermal decomposition is highly dependent on conditions. A
complex mixture of airborne solids, liquids and gases, including
carbon monoxide, carbon dioxide and other organic compounds
will be evolved when this material undergoes combustion or
thermal or oxidative degradation.
Other Information
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Hazardous
Polymerisation
Sensitivity to Mechanical
Impact
Sensitivity to Static
Discharge
: No, hazardous, exothermical polymerization cannot occur.

: No, product will not become self-reactive.
: Yes, in certain circumstances product can ignite due to static
electricity.
11. TOXICOLOGICAL INFORMATION

11.1 Information on Toxicological effects
Basis for Assessment
Routes of Exposure
:
:
Acute Oral Toxicity
Acute Dermal Toxicity

Acute Inhalation Toxicity
:
:
Skin Irritation
Eye Irritation
Sensitisation
:
:
:
Aspiration hazard
Mutagenicity
Carcinogenicity
:
:
Reproductive and
Developmental Toxicity
Specific target organ

toxicity - single exposure
Specific target organ

toxicity - repeated
exposure
Information given is based on product testing.

Exposure may occur via inhalation, ingestion, skin absorption,
skin or eye contact, and accidental ingestion.
Aspiration into the lungs when swallowed or vomited may cause
chemical pneumonitis which can be fatal.
Low toxicity: LD50 >5000 mg/kg , Rat
Low toxicity: LD50 >5000 mg/kg , Rabbit
Expected to be of low toxicity if inhaled.
High concentrations may cause central nervous system
depression resulting in headaches, dizziness and nausea;
continued inhalation may result in unconsciousness and/or
death.
Causes skin irritation.
Causes serious eye irritation.
Not expected to be a sensitiser.
Aspiration into the lungs when swallowed or vomited may cause

chemical pneumonitis which can be fatal.
May cause heritable genetic damage.
Known human carcinogen.
May cause leukaemia (AML - acute myelogenous leukaemia).
Does not impair fertility. Not a developmental toxicant.
Causes foetotoxicity in animals at doses which are maternally
toxic.
Inhalation of vapours or mists may cause irritation to the
respiratory system.
Causes damage to organs through prolonged or repeated
exposure.
Blood-forming organs: repeated exposure affects the bone
marrow.
Blood: may cause haemolysis of red blood cells and/or
anaemia.
Immune System: animal studies on this material or its
components have demonstrated immunotoxicity.
Myelodysplastic syndrome (MDS) was observed in individuals
exposed to very high levels (50 ppm to 300 ppm range) of
benzene over a long period of time in the workplace. The
relevance of these results to lower levels of exposure is not
known.
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Exposure to very high concentrations of similar materials has

been associated with irregular heart rhythms and cardiac arrest.
12. ECOLOGICAL INFORMATION
12.1 Toxicity
Acute Toxicity
Fish
Aquatic Invertebrates
Algae
Microorganisms
12.2 Persistence and
degradability
12.3 Bioaccumulative
Potential
12.4 Mobility
12.5 Result of the PBT
assessment
12.6 Other Adverse
Effects
:
:
:
:
:
Toxic: LL/EL/IL50 1-10 mg/l

Harmful: LL/EL/IL50 10-100 mg/l
Readily biodegradable.
Does not bioaccumulate significantly.
:
:
Floats on water.
The substance does not fulfill all screening criteria for
persistence, bioaccumulation and toxicity and hence is not
considered to be PBT or vPvB.
In view of the high rate of loss from solution, the product is

unlikely to pose a significant hazard to aquatic life.
13. DISPOSAL CONSIDERATIONS

13.1 Waste Treatment Methods
Material Disposal
Local Legislation
Recover or recycle if possible. It is the responsibility of the waste

generator to determine the toxicity and physical properties of the
material generated to determine the proper waste classification
and disposal methods in compliance with applicable regulations.
Do not dispose into the environment, in drains or in water
courses. Waste product should not be allowed to contaminate
soil or water.
Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
14. TRANSPORT INFORMATION
ADR
14.1 UN No.
14.2 Proper shipping name
14.3 Transport Hazard
Class
14.4 Packing group
Classification code
Hazard indentification no.
Danger label (primary risk)
14.5 Environmentally
Hazardous
:
:
:
1114
BENZENE
3
:
:
:
:
:
II
F1
33
3
No
RID
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14.1 UN No.
Class
14.4 Packing group
Classification code
Hazard indentification no.
Danger label (primary risk)
Hazardous
Sea transport (IMDG Code):

14.1 UN No.
Class
14.4 Packing group
14.5 Marine pollutant:
Air transport (IATA):

14.1 UN No.
Class
14.4 Packing group
Hazardous
:
:
:
1114
BENZENE
3
:
:
:
:
:
II
F1
33
3
No
:
:
:
1114
BENZENE
3
:
:
II
No
:
:
:
1114
Benzene
3
:
:
II
No
Sea (Annex II of MARPOL 73/78 and the IBC code)

: Y
Pollution Category
: 3
Ship Type
: Benzene and mixtures having 10% benzene or more.
Product Name
: Refer to Chapter 7, Handling & Storage, for special precautions
Special Precaution
which a user needs to be aware of or needs to comply with in
connection with transport.
15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Other regulatory Information
Chemical Inventory Status
AICS
:
DSL
:
Listed.
Listed.
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INV (CN)
ENCS (JP)
TSCA
EINECS
KECI (KR)
KECI (KR)
PICCS (PH)
:
:
:
:
:
:
:
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
OE_HPV
Listed.
Other Information
15.2 Chemical Safety
Assessment
:
:
Restricted to professional users.

A Chemical Safety Assessment was performed for this
substance.
(3)-1
200-753-7
97-1-99
KE-02150
National Legislation
16. OTHER INFORMATION

R-phrase(s)
R11
R36/38
R45
R46
R48/23/24/25
R65
Highly flammable.
Irritating to eyes and skin.
May cause cancer.
May cause heritable genetic damage.
Toxic: danger of serious damage to health by prolonged exposure through
inhalation, in contact with skin and if swallowed.
Harmful: May cause lung damage if swallowed.
CLP Hazard statements
H225
H304
H315
H319
H340
H350
H372
Highly flammable liquid and vapor.

May be fatal if swallowed and enters airways.
Causes skin irritation.
Causes serious eye irritation.
May cause genetic defects.
May cause cancer.
Causes damage to organs through prolonged or repeated exposure.
If this substance/product is sold onto third parties, confirmation

that the substance/product will be handled in accordance with
'strictly controlled conditions' needs to be obtained from the third
party prior to sale.
Other Information
Further information

s-and-Tools1/.
14/15
MSDS_GB
Benzene
Version 5.
Safety Data Sheet
MSDS Version Number
5.
MSDS Effective Date
21.02.2011
MSDS Revisions
MSDS Regulation
MSDS Distribution
Disclaimer
A vertical bar (|) in the left margin indicates an amendment from

the previous version.
The content and format of this safety data sheet is in accordance
with Regulation 1907/2006/EC.
The information in this document should be made available to all
who may handle the product
This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property of
the product.
15/15
MSDS_GB

BENZENE: Shell MSDS (2011)

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Benzene

Safety Data Sheet

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Raw material for use in the chemical industry.

1.3 Details of the supplier of the substance or mixture

SHELL TRADING INTERNATIONAL LIMITED

Email contact for

+44 (0)20 7546 5000

1.4 Emergency Telephone Number

+44 (0) 151 350 4595

Regulation (EC) No 1272/2008 (CLP)

Safety Data Sheet

Highly flammable. Toxic.

R45, R46, R11, R36/38, R48/23/24/25, R65

2.2 Label Elements

Labeling according to Regulation (EC) No 1272/2008

CLP Hazard statements

CLP Precautionary statements

P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.

Print Date 23.02.2011

Safety Data Sheet

P280: Wear protective gloves/protective clothing/eye

P303+P361+P353: IF ON SKIN (or hair): Remove/take off

Labeling according to Directive 1999/45/EC

Highly flammable. Toxic. Carcinogenic, category 1. Mutagenic,

2.3 Other Hazards

Toxic: danger of serious damage to health by prolonged

Print Date 23.02.2011

Safety Data Sheet

material: Blood. Blood-forming organs. Eyes. Skin.

Hazard Class & Category

Classification of components according to 67/548/EEC

Safety Data Sheet

4. FIRST AID MEASURES

4.2 Most important

Keep victim calm. Obtain medical treatment immediately.

Print Date 23.02.2011

Safety Data Sheet

oxygen therapy. Call a doctor or poison control center for

5. FIRE FIGHTING MEASURES

5.3 Advice for fire-fighters

Foam, water spray or fog. Dry chemical powder, carbon dioxide,

6. ACCIDENTAL RELEASE MEASURES

Isolate hazard area and deny entry to unnecessary or

6.3 Methods and Material

Shut off leaks, if possible without personal risks. Remove all

Print Date 23.02.2011

Safety Data Sheet

ignition is possible. Vapour may form an explosive mixture with

7.1 Precautions for Safe

7.2 Conditions for safe

7.3 Specific End Uses

Avoid breathing vapours or contact with material. Only use in

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Safety Data Sheet

Can be absorbed through

SHELL IS is the Shell Internal Standard.

Predicted No Effect Concentration (PNEC)

8.2 Exposure Controls