Safety Data Sheet according to Regulation (EC) No.

1907/2006/EC
ECSO 8811
Revision Date: 22.04.2015 Version: 01 Print Date: 22.04.2015

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY / UNDER-

TAKING

ECSO 8811
1.1. Product identifier

Trade name: ECSO 8811

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance/preparation: Biocide and oxidation product in water treatment

1.3. Details of the supplier of the safety data sheet

Company: EnviroChemie GmbH

In den Leppsteinswiesen 9
64380 Rossdorf / GERMANY
Phone: +49 (0) 61 54 / 69 98-0
Fax: +49 (0) 61 54 / 69 98-11
Homepage: www.envirochemie.com
E-mail: [email protected]

1.4 Emergency telephone number:

Emergency phone: D: +49 (0)6154 / 69980 (Mo-Do 8:00 - 17:15; Fr 8:00 - 16:00)

Responsible: [email protected]

2. POSSIBLE DANGERS

2.1. Classification of substance/preparation

Classification according to Regulation (EC) No 1272/2008

Met. Corr.1 H290 Can be corrosive in contact with metals

Skin Corr. 1B H314 Causes severe burns to skin and severe eye damages
Acute Tox. 4 H302 Injurious to health if swallowed
Aquatic Acute 1 H400 Very toxic for aquatic organisms

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 Safety Data Sheet according to Regulation (EC) No. 1907/2006/EC
ECSO 8811
Revision Date: 22.04.2015 Version: 01 Print Date: 22.04.2015

Classification according regulation 67/548/EWG or regulation1999/45/EG

C; Corroding;
N; Dangerous for the environment
R22: Harmful if swallowed
R34: Causes burns
R50: Very toxic for aquatic organisms
R31: Contact with acids liberates toxic gas

Classification system:
The classification is according to actual EG-lists, it is completed by details from specific literature and
company details.

2.2. Elements of classification

Classification according to regulation (EG ) no.1272/2008

The product is classificated according to CLP-regulation.

Danger pictograms

Signal word: Danger

Danger determined components for labelling Chlorine Oxides (ClO2)

Danger hints H290 Can be corrosive on metals

H314 Causes severe burns of skin and severe
eye damages
H400 Very dangerous for aquatic organisms
H302 Harmful if swallowed

Safety hints P280 Wear suitable protective gloves/clothes/

eye/face protection.
P303 + P361 + P353 AFTER CONTACT WITH SKIN (or hair):
Take off immediately all contaminated cloth-
ing. Wash skin with water.
P305+P351+P338 AFTER CONTACT WITH EYES: Rinse
some minutes carefully with water. Remove
existing contact lenses if possible. Rinse
more.

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ECSO 8811
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P301 + P330 + P331 AFTER HAVING SWALLOWED: Rinse

mouth. Do not induce vomiting.
P310 Call immediately poison information center

Additional hints:

EUH031 Contact with acids liberates toxic gas.

2.3. Other dangers

Chemicals in principle are dangerous. Only trained persons should handle with them.

3. COMPOUNDS / DETAILS OF INGREDIENTS

3.1. Substance

not usable

3.2 Mixture:

Description: Watery solution

Dangerous ingredients: According to regulation 1999/45/EG

Chlorine oxides (ClO2) w = >10%<25%

INDEX-No.: 017-026-01-0
Danger symbol: C;N
R-Sets: R22-31-34-50

Sodiumhydroxide (NaOH)w= >0,1%- <1%

INDEX-No.: 011-002-00-6
Danger symbol: C;N
R-sets: R35

Other datas: The wording of the dangerous references please find in chapter 16

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 Safety Data Sheet according to Regulation (EC) No. 1907/2006/EC
ECSO 8811
Revision Date: 22.04.2015 Version: 01 Print Date: 22.04.2015

4. FIRST AID MEASURES

4.1. Description of first aid measures

Symptoms and effects: Causes corrosions on eyes, skin and upper respiratory system. Harmfull to cornea
and eyelids.

After skin contact: Take off immediately all contaminated clothes. Flush immediately with plenty of water
and soap, if necessary obtain medical attention.

After eye contact: Flush immediately for 15minuteswith gently flowing water, obtain medical attention.

After inhalation: Take person to fresh air and lay quiet. If without conscience lay and transport in
stable side position.

After having swallowed: Only if conscious: Flush immediately the mouth and drink (200-300ml) of water. Do
not induce vomiting. Obtain medical attention immediately.

Medical hints: Treatment according to symptoms. No specific antidot. For prophylaxis of pulmonary
edema: corticosteroid - dosing aerosol

4.2. Most important acute and delayed occurring symptoms and effects
No more relevant informations available.

4.3. Hints for medical first aid or specific treatment:

No more relevant informations available.

5. FIREFIGHTING MEASURES

5.1. Extinguishing media

Suitable extinguishing media: Water sprayjet, foam

Unsuitable extinguishing media: Water jet

5.2. Special hazards by the substance or mixture

Fire in environment can cause dangerous gases: Chlorine dioxide gas development.

5.3. Hints for fire fighting

Special protective equipment for Do not inhale fire gases during fire fighting, use gas mask, independent
fire-fighters: from circulating air.

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 Safety Data Sheet according to Regulation (EC) No. 1907/2006/EC
ECSO 8811
Revision Date: 22.04.2015 Version: 01 Print Date: 22.04.2015

General information: Fire residuals and contaminated tempering water are to be removed in
accordance with local authority regulations.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protection and accidental methods:

Wear suitable protective clothes, keep away from persons, not protected

6.2. Environmental protective measures

Do not allow chemical to enter sewers or water ways

6.3. Methods and materials for holding back and cleaning procedures
Pump larger amounts into PE-container-pumps. Dilute residue with water, then remove with absorbent
material (sand), and remove in accordance with regulations.

6.4. Reference to other passages

Informations for safe handling see chap. 7

Informations for personal protection see chap. 8
Informations for removing see chap. 13

7. HANDLING AND STORAGE

7.1. Protection measures for safe handling

Keep container tightly closed.

7.2. Conditions for safe storage, considering of intolerances

Store in closed original container in dry and well-ventilated areas, avoid contact with acids (gase-
development), or metals (corrosion), protect against heat, UV, and frost. Keep only in original container.

7.3. Specific endusing

Nomore relevant informations available

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1.Controlling of following parameters

Additional hints for technical equipments: LeafletsBG-Chemie:M004,T015

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ECSO 8811
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Components with limit values to be controlled concerning workplace

3 3
Workplace limiting value according to TRGS900 for chlorine 0,1ml/m resp.0,28mg/m
dioxide:

8.2. Limitation and Controlling of Exposition:

Technical protective measurements

Technical measurements and using of suitable working method have priority before using personal protective
equipment.

Personal protective equipment

Gasmask: If gases/steamoccur put on a gas mask, DIN EN 141, (gas filterB/grey)

Handguard: Wear prooved safety gloves out of PVC (polyvinylchloride) or PE (poly-

ethylen).
Only wear chem. safety gloves with CE-sign inclusive four-digit test
number. It is recommended to clarify the chemical persistence with the
gloves manufacturer. Breakthrough times and soaking qualities of the
material are to be considered.

Eyeguard: Tightly closing safety goggles

Bodyguard: Protective clothing

General protective hygiene When handling with chemicals observe general protective measure
measures:

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Statements to basic physical and chemical properties:

Physical state: liquid

Colour: yellowish
Odour: Lightly stinging own odour

State changes

Boiling point/boiling area: 103°C

Melting point/melting area: -25 °C
Flashpoint: ./.

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ECSO 8811
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Ignition:

Explosionsgrenzen lower: n.a. upper: n.a.

Fire promoting properties: By chlorine oxides aplit of fire promoting (only dry product)
Steam pressure: (20 °C) appr. 14mbar
Relative density: (20 °C) 1.20
Solubility in water: (20 °C) mixable
pH-value: (20 °C) >11
Viscosity: (25 °C) appr.2.4mPa.s

9.2. Other information

Mixing with water: any (means: < = 90 %)

10. STABILITY AND REACTIVITY

10.1. Reactivity
No dangerous reactions if regulations / hints for storage and handling are observed.

10.2. Chemical stability

The product is stable, if regulations / hints fo storage and handling are observed.

10.3. Possibility of hazardous reactions

Reaction with acids.Exotherme reaction.

10.4. Conditions to avoid

Protect against heat and uv-rays.

10.5. Incompatible materials

Product acts corrosive on metals.

10.6. Hazardous decomposition products

ClO2

11. TOXICOLOGICAL INFORMATION

11.1. Statements totoxicologigal effects

Mutagenity: Test over 4 generations -not mutagen-

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ECSO 8811
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Subacutetoxicity: No toxic reactions at 100 ppmas ClO2

Chronic toxicity: No toxic effects at 25 ppmduring 2 years (mouse)

Further information: ECSO 8811 acts strongly corrosive on skin, eyes, and mucous membranes. When
chlorine oxides are released, respiratory ducts can be strongly irritated or burned.

11.2 Further informations

Further dangerous ingredients cannot be excluded. When handling with chemicals observe general protective
measures

12. ECOLOGICAL INFORMATION

Ecotoxical informations:

LC50 fish (96 hours):

Minimal value: 6400 mg/l

Maximal value: 6500 mg/l
Median value: 6450 mg/l
Number of studies: 2
Reference: Tooby, T.E., P.A. Hursey, and J.S. Alabaster 1975. Acute Toxicity of 102 Pesticides
and
Miscellaneous Substances to Fish.Chem. Ind. (Lond.) 21:523-526

LC50 crustacean (48 hours):

Min.value: 500 mg/l

Max.value: 610 mg/l
Med. value: 555 mg/l
Number of studies: 2
Reference: Portmann, J.E., and K.W.Wilson 1971. The Toxicity of 140 Substances to the Brown
Shrimp and Other Marine Animals. Shellfish Information LeafletNo.22 (2nd
Ed.),Ministry of Agric. Fish. Food, Fish. Lab. Burnham-on-Crouch, Essex, and Fish
Exp. Station Conway, North Wales: 12 p.; Office of Pesticide Programs 2000. Pesti-
cide Ecotoxicity Database Formerly: Environmental Effects Database
(EEDB)).Environmental Fate and Effects Division, U.S.EPA, Washington, D.C.

Mobility and bioaccumulation potential:

ECSO 8811 will be used in big quantities in open plants.

ECSO 8811 is water-soluble.
LID = 1 at application concentration of 30mg/l.

Ecotoxicological effects: ECSO 8811 will be almost completely decomposed in the biological cleaning stage.

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 Safety Data Sheet according to Regulation (EC) No. 1907/2006/EC
ECSO 8811
Revision Date: 22.04.2015 Version: 01 Print Date: 22.04.2015

General references: ECSO 8811 is a strong oxidation product, it is allowed to get in pre-flooders or fish
waters only prediluted (Meas.maxim.0,1mg/l).
Results of PBT-vPVB-judgement.
Not usable for inorganic substances.

Other references: The product is decomposing fastly in water and soil.

13. DISPOSAL CONSIDERATIONS

Product: The relation to waste key numbers/waste characterization is to be made branch-

and process specifically according to EAKV.
Little amounts can be released into canalization after diluting with water.

Unsuitable packing: Unsuitable empty containers are to be eliminated concerning authority regulations.

14. TRANSPORTATION INFORMATION

Classification according to ADR/GGVS and RID/GGVE:

Class: 5.1 (8)

UN-Nr.: 3098
Class code: OC1
Packing category: II

Name of goods: Explosive (oxidizing) working substance, corrosiven. a.g. (chlorine oxides) (E)

Special characteristics con- environmentally hazardous material: symbol „fish and tree“
cerning 5.2.1.8 ADR:

Other relevant informations for transport on land:

Limited quantity (LQ): LQ 10

Special directions: 274 Category of transport: 2

Mass goods transportion in accordance to Application II of MARLPOL-agreement 73/78 and according to IBC-
Code.
Transport only in authorized, according to traffic regulations, containers.

Further information: ECSO 8811 is not listed in the GGVS/ADR-register, it is listed independently.

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 Safety Data Sheet according to Regulation (EC) No. 1907/2006/EC
ECSO 8811
Revision Date: 22.04.2015 Version: 01 Print Date: 22.04.2015

15. REGULATORY INFORMATION

15.1. Regulations for safety, health- and environment protection / specific for substance or product:

National regulations:

Hints for limitation of employment: Pay attention to limitation of employment for pregnant and breast-
feeding women (MuSchArbV).
Pay attention to limitation of employment for young adults according to
§ 22 JArbSchG.

Storage class accord. to TRGS: 5.1B

Water danger class: (2) self-classification

Status: Mixing rule accord. To VwVwS, attachment 4, no. 3

15.2. Substance safety judgement: A substance safety judgement has not been made.

16. OTHER INFORMATION

Relevant sets:

H290 Can be corrosive in contact with metals

H314 Causes severe burns of skin and severe eye damages.
H302 Harmful if swallowed
H400 Very toxic to aquatic organisms.
R22 Harmful if swallowed
R31 Contact with acids liberates toxic gases
R34 Causes burns.
R35 Causes severe burns
R50 Very toxic to aquatic organisms

Conforming to raw material with EN12671:2000.

Baua: Reg.-Nr.: N-22565,N-22636,N-22638,N-22924

AbbreviationsandAcronyms:

ADR: Accord européen sur le transport des marchandises dangereuses par Route (Euro-
pean Agreement concerning the International Carriage of Dangerous Goods by
Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances

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ECSO 8811
Revision Date: 22.04.2015 Version: 01 Print Date: 22.04.2015

ELINCS: European List of Notified Chemical Substances

CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Letal concentration, 50 percent
LD50: Letal dosis, 50 percent
LD50*: Letal dosis, 50 percent (not relevant for classification)
LC50*: Letal concentration, 50 percent (not relevant for classification)
Met. Corr.1: Corrosive to metals, Hazard Category 1
Skin Corr. 1A: Skin corrosion/irritation, Hazard Category 1A
Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B
Aquatic Acute 1: Hazardous to the aquatic environment – Acute Hazard, Category 1

The a. m. data are basing on the present date of our knowledge. They are showing -not binding- the applica-
tion of our procedures. Existing rules and specifications have to be observed responsibly by the receiver of
our product.

# Indicates updated section.

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