Chemical Spills Training

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Hazardous Material Spill

Response Training

Responsibilities

Researchers are responsible for:

Ensuring spills are reported or cleaned up in a timely manner


Cleaning up nuisance spills of materials in their area, even if
someone else spills them(janitors, service people)
knowing the properties of the materials they are working with
taking reasonable steps to prevent spills

HazMat team will:

Assist researchers who are not comfortable cleaning up spills in


their areas (even nuisance spills)
Clean-up serious (HazMat) spills

Nuisance Spills

Spills of
less than 4 liters of material that you know the
hazards of and that you have the ability to clean
up
assess the hazard
wear appropriate PPE

Potentially Hazardous Spills

Spills of
greater than 4 liters
smaller spills of materials of

low LD50

Carcinogens- cancer-causing agent


flammable liquids or metals
compounds of unknown toxicity

Preventing Spills
Eliminate clutter
Know proper work practices for biological,
chemical materials you use
Use unbreakable secondary containers
Store chemicals properly
Dispose of waste and excess chemicals in
a timely manner

Hazards
Toxic
Flammable
Caustic
Reactive/Explosive
Other?

You are the expert on the hazards


of materials in your possession.

Know properties of biologicals/chemicals you use before


you handle them
Know what appropriate work practices are & use them
Know what the worst case scenario is for a spill of the
chemicals you use
Think about how you will react to a spill of the materials
you use
know what appropriate clean-up procedures are for the
materials you use

Toxic Materials
Assessing the risks due to the toxic effects
of biologicals/chemicals
Route of exposure
Acute Toxicants
Corrosive Substances, Irritants and
Allergens
Carcinogens
Infectious materials

Flammability Hazards
Location
Ignition sources
Ventilation
Other fuels in the area

Dont store more than 10 gallons of flammable


liquids outside of flammable liquid storage
cabinets per laboratory

Caustic Chemical Hazards


Acids & Bases (organic and inorganic)
ex. : HCl, NaOH
skin burns
permanent eye damage
inhalation hazards

Chemical Spill Response


Nuisance Spill

Alert people in immediate area of spill


Wear appropriate protective gloves, goggles, long sleeve lab coat
Avoid breathing vapors from the spill
Confine spill to small area& absorb on absorbent pads &/or kitty
litter
Clean spill area with soap & water
Collect all contaminated absorbent, gloves & residues in plastic
bag lined garbage can
Label and dispose of properly (call Safety)

Chemical Spill Response


Potentially Hazardous Spill

Attend to injured or contaminated persons and remove them from


the exposure if you can do so without endangering yourself
Alert persons in the immediate area to evacuate the lab
If spilled material is flammable, turn off heat and ignition sources
Call Campus Police Department/ Public Safety
Close doors to affected area
Have a person knowledgeable of incident and laboratory assist
HazMat personnel.

Biological Spill Response

BSL1 Spill

Wear disposable gloves


Soak paper towels in disinfectant and place over spill area
Place towels in Biohazard bag for disposal
Clean spill area with fresh towels soaked in disinfectant.

BSL 2 Spill

Alert people in the immediate area of the spill


Put on appropriate protective equipment
Cover spill with paper towels soaked in absorbent materials
Pour a freshly prepared 1:10 bleach solution around the edges of the
spill, then into center area
Allow a 20 minute contact period
Dispose of as in BSL 1 procedure

Estimating Potential Hazards

Research hazards before you use a new


biological or chemical agent
Consider the toxicity, flammability, physical state
and the amount of the material involved.
Consider the location of the spill
Consider your knowledge and skills
Ask for help in estimating hazards call Safety

Summary

Know the properties of all the hazardous materials you


handle
Prevent spills
If a potentially hazardous spill occurs, protect people first,
evacuate & ask for help
Call Campus Police/Safety for spill/fire assistance
Call Safety for information and non-emergency
assistance
You are responsible for reporting or cleaning up spills of
materials you use

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