Dielectrics: Charge Storage Principles of Different Capacitor Types and Their Inherent Voltage Progression

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Dielectrics[edit]

Charge storage principles of different capacitor types and their inherent voltage progression

The most common dielectrics are:

Ceramics

Plastic films

Oxide layer on metal (Aluminum, Tantalum, Niobium)

Natural materials like mica, glass, paper, air, vacuum

All of them store their electrical charge statically within an electric field between two (parallel)
electrodes.
Beneath this conventional capacitors a family of electrochemical capacitors
called Supercapacitors was developed. Supercapacitors don't have a conventional dielectric.
They store their electrical charge statically in Helmholtz double-layers and faradaically at the
surface of electrodes

with static Double-layer capacitance in a double-layer capacitor and

with pseudocapacitance (faradaic charge transfer) in a Pseudocapacitor

or with both storage principles together in hybrid capacitors.

The most important material parameters of the different dielectrics used and the appr. Helmholtzlayer thickness are given in the table below.

Key parameters[4][5][6][7][8]

Capacitor
style

Dielectric

Relative
Permitti
vity
at 1 kHz

Maximum/real
ized.
dielectric
strength
V/m

Minimu
m
thicknes
s
of the
dielectri
c
m

Ceramic
capacitors,
Class 1

paraelectric

1240

< 100(?)

Ceramic
capacitors,
Class 2

ferroelectric

200
14,000

< 35

0.5

Film capacitors

Polypropylene ( PP)

2.2

650/450

1.9 3.0

Film capacitors

Polyethylene
terephthalate,
Polyester (PET)

3.3

580/280

0.70.9

Film capacitors

Polyphenylene
sulfide (PPS)

3.0

470/220

1.2

Film capacitors

Polyethylene
naphthalate (PEN)

3.0

500/300

0.91.4

Film capacitors

Polytetrafluoroethylene (
PTFE)

2.0

450(?)/250

5.5

Paper
capacitors

Paper

3.55.5

60

510

Aluminum
electrolytic

Aluminium oxide
Al2O3

9,6[9]

710

< 0.01
(6.3 V)

capacitors

< 0.8
(450 V)

Tantalum
electrolytic
capacitors

Tantalum pentoxide
Ta2O5

625

< 0.01
(6.3 V)
< 0.08
(40 V)

Niobium
electrolytic
capacitors

Niobium pentoxide,
Nb2O5

42

455

< 0.01
(6.3 V)
< 0.10
(40 V)

Supercapacitor
s
Double-layer
capacitors

Helmholtz double-layer

5000

< 0.001
(2.7 V)

Vacuum
capacitors

Vacuum

40

Air gap
capacitors

Air

3.3

Glass
capacitors

Glass

510

450

58

118

450

Mica capacitors Mica

26[9]

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