Double Layer Electrolytic Capacitors: Design Team 10 Technical Lecture

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Double Layer Electrolytic Capacitors

Design Team 10
Technical Lecture
ECE_480_FS08

Overview

History of Capacitors
Electrolytic Capacitors
History of Supercapacitors
Double Layer Electrolytic Capacitor
Battery vs. Supercapacitor
Application of Supercapacitors

History of Capacitors

In 1740, Ewald Georg von


Kleist constructed the first
capacitor.
In the same year Pieter von
Musschenboek invented the
Leyden Jar.
Ben Franklin soon found out a
flat piece of glass can be used
in place of the jar model

Electrolytic Capacitors

Two parallel plates with


dielectric in between
Capacitance limited by
flat surface area and
dielectric properties

C is the capacitance
A is the area
r is the relative static permittivity
(dielectric constant)
o is the permittivity of free space
(8.854x10-12 F/m)
d is distance

History of Super Capacitors

The Electric Double Layer Capacitor


effect was first noticed in 1957 by
General Electric.
Standard Oil of Ohio re-discovered this
effect in 1966.
Standard Oil of Ohio gave the licensing
to NEC, which in 1978 marketed the
product as a supercapacitor.

Carbon Aerogel
- Aerogel is a low-density solid derived from gel that has had
the liquid component replaced with a gas.

Composed of
nanometer sized
particles covalently
bonded together
High porosity
(>50% under 100 nm)
Large surface area
(4001000 m/g)

Activated Carbon:

Extremely porous with a very large surface area.


Surface resembles a sponge.
Area allows more electrons to be stored than other
conductors.

Activated Carbon
( Activated Charcoal )

Double Layer Electrolytic Capacitors


Using Activated Carbon

Two layers consisting


of nanoporous
electrodes
Separator is
impregnated with an
organic electrolyte
Thin separator can
only withstand low
voltages

Carbon Nanotubes

Approximately
1/50,000th the
width of a human
hair
Strongest and
stiffest material on
earth (>300 X Steal)
Low density
Semiconductor

Double Layer Electrolytic Capacitors


Using Carbon Nanotubes

Under development
at MIT
Replaces activated
charcoal with carbon
nanotubes
Aligned in a regular
pattern that exposes
greater surface area
Dramatically
increases effective
area of electrodes
Greatly increases
power density

Comparing Batteries & Supercapacitors

Energy density is the amount of energy stored per unit volume or mass.
- Power density combines energy density with the speed that
energy can be drawn out of a device.
-

Rechargeable Batteries Vs.


Supercapacitors
Supercapacitors:

Higher power density


Much faster charge and
discharge rate
Environmentally friendly
Extremely low internal
resistance or ESR
High efficiency (97-98%)
Over a million chargedischarge cycles

Batteries:

Have higher energy density


Typically 2001000 chargedischarge cycles
Contain highly reactive and
hazardous chemicals
Negatively effected by low
temperatures

Applications for Supercapacitors

Back up for
uninterruptable power
supplies (UPS)
Light weight power
supplies for small
aircraft
Provide short duration
power for various
vehicle systems such
as breaking or steering
Used to absorb power
during short periods of
generation such as
Regenerative Braking
Extend range and
battery life in Hybrid
Electric Vehicles
(HEV)

Hybrid Electric Vehicles

The CSIRO in Australia


[national science
agency] has developed
the UltraBattery, which
combines a
supercapacitor and a
lead acid battery in a
single unit
4x longer life cycle, 50%
more power, 70%
cheaper than batteries
used in HEVs

Questions?

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