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    This document summarizes the results of experiments testing the reactions of various anions with silver nitrate and barium chloride. When reacted with specific anions, silver nitrate and barium chloride form precipitates of different colors. For example, chloride ions form a white precipitate of silver chloride with silver nitrate. The document is organized into groups based on the anion tested. It provides the chemical formula for each precipitate formed and notes its color and solubility.

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    9

    Uploaded by

    Christine Trinidad
    343 views2 pages
    This document summarizes the results of experiments testing the reactions of various anions with silver nitrate and barium chloride. When reacted with specific anions, silver nitrate and barium chloride form precipitates of different colors. For example, chloride ions form a white precipitate of silver chloride with silver nitrate. The document is organized into groups based on the anion tested. It provides the chemical formula for each precipitate formed and notes its color and solubility.

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    Phar Chem 1

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    This document summarizes the results of experiments testing the reactions of various anions with silver nitrate and barium chloride. When reacted with specific anions, silver nitrate and barium chloride form precipitates of different colors. For example, chloride ions form a white precipitate of silver chloride with silver nitrate. The document is organized into groups based on the anion tested. It provides the chemical formula for each precipitate formed and notes its color and solubility.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    343 views2 pages

    9

    Uploaded by

    Christine Trinidad
    This document summarizes the results of experiments testing the reactions of various anions with silver nitrate and barium chloride. When reacted with specific anions, silver nitrate and barium chloride form precipitates of different colors. For example, chloride ions form a white precipitate of silver chloride with silver nitrate. The document is organized into groups based on the anion tested. It provides the chemical formula for each precipitate formed and notes its color and solubility.

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    of 2

    EXPERIMENT 9: REACTIONS OF THE ANIONS

    GROUP I ANIONS
    Group I

    AgNO3
    Formula of Ppt.
    AgCl
    AgBr
    AgI
    AgCN
    Ag4Fe(CN)6
    Ag3Fe(CN)6
    AgSCN

    ClBrICNFe(CN)6-4
    Fe(CN)6-3
    SCNAnion
    9-3 Cl9-4 CN9-5 Br9-6 I-

    9-7 Fe(CN6)49-8 SCN9-9 Fe(CN6)3-

    Color
    white
    light yellow
    canary yellow
    white
    white
    orange
    white

    Reagents
    Hg2(NO3)2, HNO3
    Hg2(NO3)2, HNO3
    KMnO4, H2SO4, chloroform
    a) KMnO4, H2SO4, chloroform
    b) CH3COOH, NaNO2, starch
    soln
    FeCl3
    FeCl3
    FeSO4

    GROUP II ANIONS
    Group II
    9-10 AgNO3
    Formula of ppt
    Color and Nature
    9-10a Solubility in HNO3
    9-11 BaCl2

    Fe4[Fe(CN6)]3
    Fe(SCN)2+
    Fe3[Fe(CN6)]2

    NO2AgNO2

    black
    soluble
    no

    white
    soluble
    no

    white crystalline
    soluble
    no

    Formula
    H2S

    conc. H2SO4
    a) C2H5OH

    GROUP III ANIONS


    Anions
    9-15 AgNO3
    Formula of ppt

    Color & Nature


    white gray
    white gray
    orange brown CHCl3
    layer
    violet/purple layer
    iodo-starch complex
    blue soln
    Prussian blue
    blood red soln
    Turnbulls blue

    Ag2S

    Pb(CH3COO)2
    CH3COOH, FeSO4

    9-14 CH3COO-

    no
    no
    no
    no
    no
    no
    no

    CH3COOCH3COOAg

    6N H2SO4

    9-13 NO2-

    insoluble
    insoluble
    insoluble
    insoluble
    insoluble
    insoluble
    insoluble

    Formula
    Hg2Cl2 Hg0
    Hg2Cl2 Hg0
    Br2 reddish-brown or
    brown gas
    I2 violet gas
    I2

    Reagents

    9-12 S

    9-2 BaCl2

    S2-

    Anion
    2-

    9-1a Solubility in HNO3

    PbS
    PbS
    FeNOSO4 or
    FeSO4.NO
    CH3COOH
    CH3COOC2H5

    Color & Nature

    9-15a Solubility in
    HNO3
    soluble

    SO32-

    Ag2SO3

    white

    CO32-

    Ag2CO3

    white yellow

    soluble

    BO33-

    Ag3BO3 Ag2O

    white brown

    soluble

    C2O42-

    Ag2C2O4

    white

    soluble

    C4H4O62-

    Ag2C4H4O6

    white

    soluble

    C6H5O73-

    Ag3C6H5O7

    white

    soluble

    Color & Nature


    Colorless gas w/ rotten
    egg odor
    black
    black
    brown ring
    vinegar odor
    fruity odor

    9-16 BaCl2
    9-16a Solubility in
    HNO3
    BaSO3
    white
    a) soluble
    BaCO3
    white
    a) soluble
    Ba3(BO3)2
    white
    a) soluble
    BaC2O4
    white
    a) soluble
    BaC4H4O6
    white
    a) soluble
    Ba3(C6H5O7)2 white
    a) soluble

    GROUP III ANIONS continued


    Anions
    Reagents
    29-17 SO3
    a) 6N H2SO4
    blue litmus paper

    6N H2SO4
    Ca(OH)2
    H2SO4, CH3OH

    Formula
    SO2
    SO2 + H2O H2SO3
    H2SO4
    H2S2O6
    dithionic acid
    CO2
    CaCO3
    (CH3)3BO3

    CaCl2
    a) CH3COOH
    AgNO3, NH4OH, heat
    AgNO3, NH4OH, heat

    Ca2C2O4
    insoluble
    Ag0
    Ag0

    b) KMnO4, H2SO4
    9-18 CO329-19 BO339-20 C2O429-21 C4H4O629-22 C6H5O73GROUP IV ANIONS
    Anions
    9-23 AgNO3
    Formula
    Color & Nature

    9-23a Solubility in HNO3


    9-24 BaCl2
    Formula
    Color & Nature
    9-24a Solubility in HNO3
    Anions
    9-25 PO439-26 AsO439-27 AsO339-28 S2O32-

    9-29 CrO42-

    silver mirror
    silver mirror

    AsO43-

    AsO33-

    S2O32-

    CrO42-

    Ag3PO4
    yellow

    Ag3AsO4
    chocolate
    brown

    Ag3AsO3
    yellow

    Ag2CrO4
    brownish-red

    soluble

    soluble

    soluble

    Ag2S2O3 Ag2S
    white yellow
    brown
    black
    soluble

    BaHPO4
    white
    soluble

    Ba3(AsO4)2
    white
    soluble

    Ba3(AsO3)2
    white
    soluble

    BaS2O3
    white
    soluble

    BaCrO4
    yellow
    soluble

    Reagents
    a) NH4Cl, NH4OH, magnesia mixture
    b) HNO3, (NH4)2MoO4
    a) NH4Cl, NH4OH, magnesia mixture
    b) HNO3, (NH4)2MoO4
    a) NH4Cl, NH4OH, magnesia mixture
    b) HNO3, (NH4)2MoO4
    a) 6N H2SO4

    Formula
    MgNH4PO4
    (NH4)3PO4.12MoO3
    MgNH4AsO4
    (NH4)3AsO4.12MoO3
    ------SO2 + S

    b) KMnO4, H2SO4

    8KMnO4 + 5Na2S2O3 + 7H2SO4


    4K2SO4 + 8MnSO4 + 5Na2SO4 + 7H2O
    PbCrO4
    Na2PbO2

    Pb(CH3COO)2
    a) NaOH

    Reagents
    AgNO3
    AgNO3
    BaCl2
    BaCl2
    conc. H2SO4, FeSO4
    AgNO3, KNO2

    GROUP VI ANION
    Anion
    9-34 SO42-

    Reagent
    AgNO3

    9-34 SO42-

    violet color of KMnO4


    decolorized
    colorless gas
    white
    green tint
    green border flame
    white

    PO43-

    GROUP V ANIONS
    Anions
    9-30 NO3ClO39-31 NO3ClO39-32 NO39-33 ClO3-

    9-34 SO42-

    Color & Nature


    garlic-like odor
    BR

    BaCl2
    a) solubility in HNO3
    Pb(CH3COO)2
    a) solubility in
    CH3COONH4

    Formula
    --------FeNOSO4
    AgCl

    Formula
    dil. soln
    ---conc. soln Ag2SO4
    BaSO4
    insoluble
    PbSO4
    Pb(CH3COO)2

    soluble

    Color & Nature


    white crystalline
    yellow crystalline
    white crystalline
    yellow crystalline
    no
    no
    colorless gas w/ garliclike odor w/ yellow
    violet color of KMnO4
    decolorized
    yellow
    yellow soln

    Color & Nature


    no
    no
    no
    no
    brown ring
    white

    Color & Nature


    white
    white
    white
    soluble

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