13

th
VXY (Date: 04-03-2012) Final Test
PAPER-1
Code-A
ANSWER KEY
PHYSICS
SECTION-2
PART-A
Q.1 B
Q.2 B
Q.3 A
Q.4 B
Q.5 C
Q.6 C
Q.7 D
Q.8 A
Q.9 D
Q.10 C
Q.11 A,C
Q.12 C
Q.13 B,C
Q.14 B,D
Q.15 C,D
PART-C
Q.1 0050
Q.2 0006
Q.3 0006
Q.4 0400
Q.5 1000
Q.6 0003
MATHS
SECTION-1
PART-A
Q.1 C
Q.2 C
Q.3 D
Q.4 C
Q.5 A
Q.6 B
Q.7 B
Q.8 C
Q.9 A
Q.10 C
Q.11 B,C,D
Q.12 A,C,D
Q.13 B,C
Q.14 A,B,C
Q.15 B,C
PART-C
Q.1 0004
Q.2 0055
Q.3 0025
Q.4 0019
Q.5 0641
Q.6 0020
CHEMISTRY
SECTION-3
PART-A
Q.1 B
Q.2 C
Q.3 B
Q.4 B
Q.5 C
Q.6 A
Q.7 C
Q.8 B
Q.9 A
Q.10 C
Q.11 A,B,C
Q.12 A,B,C
Q.13 B
Q.14 A,B,C,D
Q.15 A,C
PART-C
Q.1 0050
Q.2 0009
Q.3 Bonus
Instruction for Q.4
Partial Marks will be awarded (+2) for correct
value of 'ab' (+2) for correct value of 'cd' and
(+1) as bonus if both are correct.
Q.4 ab = 20 and cd = 28
Q.5 0006
Q.6 0094
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. I = ( )
}

+ + +
1
1
x x x x
dx 6 3 2 1 n x l
Using King
I = ( )
}

+ + +
1
1
x x x x
dx 6 3 2 1 n x l

2I =
}

|
|
.
|

\
|
+ + +
+ + +
1
1
x x x
x x x
dx
6 3 2 1
6 3 2 1
n x l
=
( )
}

|
|
.
|

\
|
+ + +
+ + +
1
1
x x x
x x x x
dx
1 2 3 6
6 3 2 1 6
n x l
(Multiplying N
r
and D
r
by 6
x
)
=
}

1
1
2
dx 6 n x l
2I = 2 ln 6
}
1
0
2
dx x =
3
2
ln 6 I =
3
1
ln 6. Ans.]
Q.2
[Sol.
Let g(x) = e
x
f(x)
g'(x) = e
x
(f '(x) f(x)) > 0 R xe
x x
0
g
I
g(x) is increasing on R
g(x) > g(x
0
)
0
x x > e
x
f(x) >

0
0
x
) x ( f e
0

f(x) > 0
0
x x > [given f (x
0
) = 0]
Q.3
[Sol. Since f(x) is continuous at x = 0, so at x = 0, both left and right limits must exist and both must be
equal to 3.
Now,
2
x
5 x cos ) x sin x 1 ( + | + o
=
2
2
x
..... x
2
) 5 ( +
|
.
|

\
| |
o + + | + o
(Using series expansion of sin x and cos x)
If ) x ( f Lim
0 x

exist, then o + | + 5 = 0 and ) x ( f Lim

= 3
2
|
o = 3
o = 1, | = 4.
Since, 3
x
x x
1 Lim
x
1
2
3
0 x
=
|
|
.
|

\
|
|
.
|

\
|
o +
+
+

0
x
x x
Lim
2
3
0 x
=
|
|
.
|

\
|
o +
+

Now,
( ) ) 1 ( x 1 Lim
x
1
0 x

+
+
= e
o
= 3 e
2o
= 9
Hence, o
2
+ |
2
+
2
+ e
2o
= ( 1)
2
+ ( 4)
2
+ (0)
2
+ (3)
2
= 1 + 16 + 0 + 9 = 26. Ans.]
MATHEMATICS
Code-A Page # 2
Q.4
Sol. Domain is x e [1, 1]
Given, sin
1
x = 2tan
1
x

|
|
.
|

\
|

2
1
x 1
x
tan = |
.
|

\
|

2
1
x 1
x 2
tan

2
x 1
x 2

=
2
x 1
x 2

x = 0 or (1 x
2
)
2
= 4 (1 x
2
) (1 x
2
) (3 + x
2
) = 0
x = 1, 0, 1 .......(1)
tan
1
) 1 x ( x + cosec
1
2
x x 1 +
=
2
t
x(x 1) > 0 x x
2
> 0 x(x 1) = 0
x = 0, 1 .......(2)
Now, (1) (2) gives x = 0, 1
Hence, number of common solution are 2. Ans.]
Q.5
[Sol. Equation of tangent at M
|
.
|

\
|
2
1
, 3 is 3 x + 2y = 4
Also, distance of PQ from (0, 0) =
7
4
O
x
y
P
Q
M
x + y = 5
2 2
1
1
y
4
x
2 2
= +
|
.
|

\
|
2
1
, 3
Now, PQ = 2
7
16
5
= 2
7
19
Area of (AOPQ) =
7
19
2
7
4
2
1

=
7
19 4
. Ans.]
Q.6
[Sol. f(x) = sin
1
x + cos
1
x + tan
1

|
.
|

\
|
x
1
+ tan
1
(x)
x e [ 1, 0) f(x) =
2 2
t
+ t
t
= 0
y
(1, )
(1,0) (1,0)
x
(0, /2)
x e (0, 1] f(x) =
t =
t
+
t
2 2
Required area (shaded region)
= 2
2
1
2 2
1 t
=
t

sq. units. Ans.]

\
|

t
) x 1 (
2
cos
x = 2nt
|
.
|

\
|
+
t
x 1
2
(+) Reject
() 2x = 2nt
2
t
+ 1
x = nt
4
t
+
2
1
n = 1 (out of domain)
n = 2 x =
2
1
4
7
+
t
B is correct.]
Paragraph for Question no. 8 to 10
[Sol. L
1
:
1
4 z
0
y
3
2 x

= =

= l
(3l + 2, 0, l + 4)
L
2
:
1
2 z
0
y
2
7 x
= =

= r
(2r + 7, 0, + r + 2)
For point of intersection of L
1
= 0 & L
2
= 0
3l + 2 = 2r + 7 l + 4 = r + 2
3l + 2r = 5 (i) l + r = 2 (ii)
From (i) & (ii)
l = r = 1
P (5, 0, 3)
Equation of plane P
1
containing L
1
= 0 & L
2
= 0 is -
1 0 2
1 0 3
4 z y 2 x

= 0 y = 0
Plane P
1
is y = 0 i.e. z-x plane
Equation of plane P
2
containing points (3, 2, 0), (2, 0, 0) & (0, 5, 0) is z = 0 i.e. x-y plane.
Line of intersection of x-y plane & z-x plane is x-axis i.e.
0
z
0
y
1
x
= =
(i) Projection of the point P on the line P
1
= 0 = P
2
(x-axis) is M (5, 0, 0)
Area of AOPM
3 5
2
1
=

z
x
y
M(5, 0, 0)
P
4
O
(5, 0, 3)
z
2
=
2
15
Ans.
MATHEMATICS
Code-A Page # 4
(ii) Acute angle between L
1
= 0 and P
1
= 0 = P
2
(x-axis)
cos u =
0 0 1 1 0 9
0 ) 1 ( 0 0 1 3
+ + + +
+ +
0 0, 1, : axis - x of s Dr'
1 0, 3, : 0 L of s Dr'
1
=
cos u =
10
3
cot u = 3 u = cot
1
3 = cot
1

= 3 Ans.
(iii) Image of the point (5, 0, 3) in the plane P
2
(x-y plane) is (5, 0, 3)
Point of intersection of the line L
1
= 0 with x-y plane is -
(3l + 2, 0 l + 4) l + 4 = 0 l = 4
(14, 0, 0)
Now line passing through (5, 0, 3) & (14, 0, 0) is
3
z
0
y
9
14 x
= =

1
z
0
y
3
14 x
= =

Ans. ]
Q.11
[Sol. As, | cc
1
cc
2
| = | (r + r
1
) (r + r
2
) | = constant
where | r
1
r
2
| < c
1
c
2
locus of C is a hyperbola with foci c
1
and c
2
i.e., (4, 0) and (4, 0).
Also, 2a = | r
1
r
2
| = 2 a = 1
Now, e =
a 2
ae 2
=
2
8
= 4
C
2
C
1
(4, 0)
( 4, 0)
C
So, b
2
= 1
2
(4
2
1) = 15
Hence, locus of centre of circle is hyperbola, whose equation is
15
y
1
x
2 2
= 1.
Now, verify the options. Ans.]
Q.12
Sol. Coordinates of B (p, q p
2
)
Coordinates of C
|
|
.
|

\
|

a
b
1 ,
a
b
2
Since mid point of B and C is origin. Hence
2
a
b
p
= 0 ap + b = 0 (D)
Similarly q p
2
+
a
b
1
2
= 0 (C)
Since a > 0 and abscissa of point C is positive. Hence
a
b
> 0 b is negative
Hence ab < 0 (Option B is false).
Sum of the roots of equation (x
2
+ 2px + q) (ax
2
+ 2bx + 1) = 0 is
|
.
|

\
|
+
a
b 2
p 2
= 2
|
.
|

\
|
+
a
b
p
=
|
.
|

\
|
a
2
(ap + b) = 0 (A) is true. ]
MATHEMATICS
Code-A Page # 5
Q.13
[Sol.
514/bin

10
2
2
2
x
1
x
|
.
|

\
|
+
=
20
x
1
x
|
.
|

\
|

[11th, 02-01-2011,P-2, PQ]
T
r + 1
=
20
C
r

x
20 r
(1)
r

r
x
1
=
20
C
r

x
20 2r
(1)
r
20 2r = 0 r = 10
So, term independent of x =
20
C
10
. Now verify alternatives. Ans.]
Q.14
[Sol. f(x) = x
2

} } }

1
0
1
0
1
0
2 2
dt x dt ) t ( f x 2 dt ) t ( f
f(x) = x
2
+ A + 2Bx x
2
= A + 2Bx
A =
( )
} }
+ =
1
0
1
0
2 2
dt Bt 2 A dt ) t ( f
B = ( )
} }
+ =
1
0
1
0
dt Bt 2 A dt ) t ( f
f(x) = 3x 3
Now verify all the option. Ans.]
Q.15
[Sol.
(A) disjoint mutually exclusive
Two mutually exclusive events E and F with P(E) and P(F) > 0 cannot be independent
(B) P(E) + ) F E ( P + ) F E ( P = P(E) + P(F) P(E F) + ) F E ( P = 1 Exhaustive
(C) ( ) F E P > P(E) or
) F ( P
) F E ( P
> P(E) ......(1)
Now,
) E ( P
) E F ( P
>
) E ( P
) F ( P ) E ( P
> P(F) (C) is correct.
(D) Every element of set of positive integer can be of the form 6n, 6n + 1, ......., 6n + 5.
But favourable are 6n + 1 or 6n + 5.
So, required probability =
6
2
=
3
1
. Ans.]
MATHEMATICS
Code-A Page # 6
PART-C
Q.1
[Sol. Applying cosine rule, 2ab cosC = a
2
+ b
2
c
2

2 2

2 2 +
cos
8
t
= 2 + 2 +
2
c
2
using cos
8
t
=
2
2 2 +

( )
2
2 2 2 2
/
+ /
= 4 +
2
c
2
c
2
= 2
2
c =
2 2
Hence abc= ( ) |
.
|

\
|
|
.
|

\
|
+ 2 2 2 2 2 = 2 (abc)
2
= 4 Ans.]
Q.2
[Sol. A =
(
(

w w 0
b 1 1
c a 1
| A | = w(1 + b a c) = 0 (for non-singular matrices)
1 + b = a + c
Now total matrices = 4 4 4 = 64 and 1 + b = a + c
2
2
4
1
i
i
1
i
1
i
i
1
i
i
i
1
1
i
i
1
1
1
1 1 1
c a b
)
`

)
`

Total possibility = 9
Total possibility of 1 + b = a + c are 9
Hence 64 9 = 55 Ans.]
Q.3
[Sol.
2
2
2
2
1
1
at
at 2
at
at 2

= 1
t
1
t
2
= 4
M
T
90
Q(t )
2
P(t )
1
at t , a(t + t )
1 2 1 2
O
N
x
y
(
h
,

k
)
Now T a t
1
t
2
, a(t
1
+ t
2
)
and N a ) 2 t t t t (
2 1
2
2
2
1
+ + + , a t
1
t
2
(t
1
+ t
2
)
Hence 2h = a((t
1
+ t
2
)
2
+ 2)
& 2k = a(t
1
+ t
2
) (1 t
1
t
2
)
2k = 5a(t
1
+ t
2
)
t
1
+ t
2
=
a 5
k 2
2h =
(
(

+ |
.
|

\
|
2
a 5
k 2
2
2h =
(

+
2
2 2
a 25
a 50 k 4
50ah = 4k
2
+ 50a
2
25ah = 2k
2
+ 25a
2
25 2(h 2) = 2k
2
or y
2
=
2
25
(x 1)
Hence latus rectum =
2
25
2L = 2
2
25
= 25. Ans.]
MATHEMATICS
Code-A Page # 7
Q.4
[Sol. Bowl A
6R
4B
5 balls
Put in
Bowl B
Let A : One ball drawn from the bowl B found to be blue.
B
1
: 1 R + 4 B from bowl A to B.
B
2
: 2 R + 3 B from bowl A to B.
B
3
: 3 R + 2 B from bowl A to B.
B
4
: 4 R + 1 B from bowl A to B.
B
5
: 5 R + 0 B from bowl A to B.
P (B
1
) =
5
10
4
4
1
6
C
C C
=
5
10
C
6
; P (B
2
) =
5
10
3
4
2
6
C
C C
=
5
10
C
60
; P (B
3
) =
5
10
2
4
3
6
C
C C
=
5
10
C
120
P (B
4
) =
5
10
1
4
4
6
C
C C
=
5
10
C
60
; P (B
5
) =
5
10
0
4
5
6
C
C C
=
5
10
C
6
( )
1
B A P =
5
4
; ( )
2
B A P =
5
3
; ( )
3
B A P =
5
2
; ( )
4
B A P =
5
1
; ( )
5
B A P = 0
( ) A B P
2
=
( ) ( )
( ) ( )

=
5
1 i
i i
2 2
B A P B P
B A P B P
( ) A B P
2
=
12 48 36
5
24
36
+ + +
=
1 4 3
5
2
3
+ + +
=
5
40 2
3
+
=
42
15
=
14
5

n
m
Hence (m + n) = 19. Ans.]
Q.5
[Sol. log
2
| z 3 | > log
2
| z 3 | > 0
log
2
| z 3i | > log
2
| z 3 | (z = 3, 3i)
put z = x + iy
| z 3i | > | z 3 |
| x + i (y 3) | > | x 3 + iy |
x
2
+ (y 3)
2
> (x 3)
2
+ y
2
x > y
| amp ( z ( 1 + i)) | s
4
t
(3, 0)
(5, 0)
(0, 2)
(1, 1)
A
| z | = 5
O
B
(0, 5)
x
y
x = y
y > x
x > y
4
t
s amp (z (1 + i)) s
4
t
Region enclosed by z satisfying all the three given inequalities is sector AOB in which point (3, 0) and the
points on the line segment OB are not included.
Area of the sector AOB = Area of quater circle =
4
25t
=
16
625
t
a + b = 625 + 16 = 641. Ans.]
MATHEMATICS
Code-A Page # 8
Q.6
[Sol. If o and | are the roots of x
2
+ t
2
x 2t = 0, then we have
o + | = t
2
and o| = 2t
so that
2
2
2
2 2
) (
2 ) (
) ( o|
o| | + o
=
o|
| + o
=
t
1
4
t
2
+
and
t 2
1
t 4
1 1
) (
1
2 2
=
o|
+
o|
.
Now, I =
dx
1 1
x
1
x
2
1
2 2 }

|
|
.
|

\
|
o|
+
|
|
.
|

\
|
|
+
|
.
|

\
|
o
+
=
dx
t 2
1
t 4
1
x
t
1
4
t
x
2
1
2
2
2
}

(
(

|
.
|

\
|
+
|
|
.
|

\
|
+ +
=
3
t 4
3
8
t 3
2
2
+ +
.
Now
2
2
t 4
3
8
t 3
+
>
32
6
=
4
2 3
(Using A.M. > G.M.)
Hence, I >
8
9
+ 3
Hence a = 3, b = 9 and c = 8.

a + b + c = 20. Ans.]
PHYSICS
Code-A Page # 1
PART-A
Q.4
[Sol. P
1
A = P
2
A + mg
P
1
> P
2
P
1
P
2
]
Q.5
[Sol. F = qE = 5 10
6

d
9
= 1.5 10
4
d =
4
6
10 5 . 1
10 45

= 0.30 m ]
Q.6
[Sol.
y
x
+ve x-direction. ]
Q.7
[Sol. I
A
= I + 4I +
2
I 4 2
cos
2
t
= 5I
I
B
= I + 4I +
2
I 4 2
cos t = I
I
A
I
B
= 4I ]
Q.8
[Sol. n = 4 3 E = 3eV
=
3
1242
= 414 nm ]
Q.9
[Sol. AE = exactly the energy difference ]
Q.10
[Sol. E
4 2
= 8eV
E
2 1
= 10 eV
| < 8eV
E
3 2
= 5eV
| > 5eV ]
PHYSICS
Code-A Page # 2
Q.11
[Sol. Current leads the voltage
i V
R
V
0
V V
C L
V
0
=
2
R
2
C L
V ) V V ( +
=
25 100+
=
5 5
V
P.F. =
0
R
V
V
=
5 5
5
=
5
1
]
Q.12
[Sol. T
2
=
GM
4
2
t
R
3
T =
GM
2t
R
3/2
]
Q.13
[Sol. r = 90 I
r
I
I
sin I = 1 sin r = cos I
= cot I
sin Q
C
= 1 sin 90
sin Q
C
= 1
sin Q
C
=

1
= tan I
Q
C
= sin
1
(tan I) = sin
1
(cot r) ]
Q.14
[Sol. v = e
2
2
2
A
A
|
.
|

\
|

=
2
3
v
max
a = e
2
x =
2
A
2
e
=
2
a
max
]
PART-C
Q.1
[Sol. 6tqrv = B =
3
4
tr
3
P
L
g
q =
9
2
r
2

v
g P
L
=
9
2

7 . 0
1000 75 . 1 ) 9 . 0 (
2

= 50 poise ]
PHYSICS
Code-A Page # 3
Q.2
[Sol. f = mg
8
R 3
cos 60
30
60
mg
3R/8
30
N
1
N
2
60
N
2
= f
N
1
= mg
f =
16
mg 3
f s N
1
>
16
3
32 = 6 ]
Q.3
[Sol. q = q
1
1 1
C R
t
e

= q
2
2 2
C R
t
e

2
1
q
q
=
|
|
.
|

\
|

2 2 1 1
C R
1
C R
1
t
e
R = 6 O ]
Q.4
Sol. P
L
6 10
2
g = 600 g
mg + 600 g = P
L
1000 g
m = 1000 600 = 400 gm
Q.5
[Sol.
dt
dE
= oATT
4
T
4
=
) 10 67 . 5 ( ) 05 . 0 ( 4
) 10 67 . 5 (
8 2
2

t
t
= 10
12
[A = 4tr
2
]
T = 1000 K ]
Q.6
[Sol. L
1
= L
2
=
2
L
= 9 10
5
H
R
1
= R
2
=
2
R
= 3O
eq
L
1
=
1
L
1
+
2
L
1
L
eq
=
2
L
1
=
2
9
10
5
H
eq
R
1
=
1
R
1
+
2
R
1
R
eq
=
2
R
1
= 1.5 O
t =
R
L
=
2
3
10
2
9
5

= 3 10
5
sec. ]
CHEMISTRY
Code-A Page # 1
PART-A
Q.1
[Sol. (B) Trigonal also called Rhombohedral
o = | = = 90 and a = b = c ]
Q.2
[Sol. (A)
A
Hybridisation : sp
3
d
Number of angles at 90 = 12
2
x x
x x
x
x
90
90
(B)
A
Hybridisation : sp
3
d
2
Number of angles at 90 = 12
x x
x x
x
x
(C)
A
Hybridisation : sp
2
d
Number of angles at 90 = 4
x x
x x
90
(D)
A
x
x
x
x
Hybridisation : sp
3
d
Number of angles at 90=6
x 120
90
]
Q.3
[Sol. Cl C C H HO C C H
Na O C C ONa
+ +
Na O C CH OH
+
2

Cl C C H
O O
O O
O O
O
O
more
reactive
OH
O
OH
NaOH Cannizaro
+
]
Q.4
[Sol. (B) 0.3 M K
2
Fe[Fe(CN)
6
] will give maximum number of ions in the solution. ]
CHEMISTRY
Code-A Page # 2
Q.5
[Sol.
A

+
4 2 3
SO H HNO
Ar
N
S ,
ONa CH
3
A

]
Q.6
[Sol. (A)
7
N
15
n/p = 8/7
n/p > 1 so
7
N
15
will be |-emitter ]
Q.7
[Sol.
OH OH
H H
H
OH
H
CH OH
2
O
O
OH
H OH
H
OH
H
O
H
CH OH
2
Glycosidic
linkage
Due to this it will be reducing sugar
the ring can open into aldehydic
form and it can undergo mutarotation.
]
Q.8
[Sol.
ClBeCl ClBeOH H O
2
sp
+
slow HCl
HCl
Fast
Be
B
Cl
Cl
Cl
OH
OH
2
OH
2
+
+
H O
2
Be(OH)
2
[Be(OH) ]
2 n
or
white ppt
OH
[Be(OH) ]
4
2
Beryllate ion is formed in basic medium
]
Q.9
[Sol. BCl
3
+ 3H
2
O H
3
BO
3
+ 3HCl
H
3
BO
3
+ 2H
2
O H
3
O
+
+

4
) OH ( B
During the hydrolysis of BCl
3
the medium becomes acidic due to formation of HCl hence in the presence
HCl feasibility of second reaction ie formation of

4
) OH ( B
is least.]
CHEMISTRY
Code-A Page # 3
Q.10
[Sol. (i) Under ordinary condition, H
2
O molecule can not approach to the vaccant antibonding M.O. of
ClCl bond (yet having low energy) due to steric crowding over central carbon atom.
(ii) CCl bond dissociation energy is not very high as its magnitude is less than that of CF. ]
Q.11
[Sol. (A) K
4
[Fe(CN)
6
] 4K
+
[Fe(CN0
6
]
4
Na
2
HPO
3
2Na
+
+ HPO
3
2
higher negative charge over [Fe(CN)
6
]
4
so it can cause more coagulation in a basic dye.
(B) Starch aqua-sol is a lyophilic sol so it can be used as protective colloid.
(C) Freundlich adsorption isotherm fails at high pressure ]
Q.12
[Sol. (A)
O O O
O O
O O
Si Si
(B)
O O O
O O
O O
Cr Cr
(C)
O O O
O O
O O
S
S
(D) or
Si
Si Si
O
O
O
O
O
O O
O O
]
Q.13
[Sol.
H
H
Me
Me
It can show GI It do not posses COS
It posses POS It can show OI (it is meso isomer) ]
CHEMISTRY
Code-A Page # 4
Q.14
[Sol. (A) Z =
C
C C
RT
V P
=
8
3
Z < 1
attractive forces are dominating
(B)
T
C
T
1
T
2
(L+G)
Gas
Liquid
P
V
Liquid and gas can not be distinguished above critical temperature.
(C) At very high pressure , Z > 1

1
) ideal ( V
) real ( V
m
m
>
V
m
(real) > V
m
(ideal)
(D) For y-Intercept, X = 0
PV
m
T
P
When P O
Gas shows ideal behaviour
PV
m
= RT

R
T
PV
m
=
y = R ]
CHEMISTRY
Code-A Page # 5
Q.15
[Sol. (A) & (C) Mozingo & WolfKishner is applicable
(B) N
2
H
2
donot effect C
| |
O
(D) Ring expension take place ]
PART-C
Q.1
[Sol. Mole of H
2
O
2
at t = 0 1
K
t
693 . 0
2 / 1
=
t
1/2
= 10 sec.
Number of half lives in 20 sec. =
10
20
2
Mole of H
2
O
2
remaining after 20 sec. =
4
1
H
2
O
2
+ 2H
+
+ 2I I
2
+ 2H
2
O

= (Reactant) H (Product) H H
o
f
o
f
o
Reaction
= [60 +2 (290)] [200 + 2 (60)]
= 520 + 320 200 kJ
Energy released when
4
1
mole H
2
O
2
reacts
200
4
1
50 kJ Ans. ]
Q.3
[Sol.
O
H
O
O
O
8
7
6
5
4
3
2
1
+
HCHO
O
O
O
O
O
H
H
HCHO
+ CH CHO
3
8
7
6
5
4
3 2
1
]
CHEMISTRY
Code-A Page # 6
Q.4
[Sol. Ag
2
CrO
4
+ AgNO
3
0.5 litre 0.5 litre
saturated solution 2 10
6
M
Ag
2
CrO
4
2Ag
+
+ CrO
4
2
2S S
When mixed with 0.5 litre AgNO
3
, total volume 1 litre
AgNO
3
Ag
+
+ NO
3

2 10
6
2 10
6
In the solution:
[Ag
+
] =
2
S 2 10 2
6
+

= [S + 10
6
]
[CrO
4
2
] =
2
S
[NO
3
] =
2
10 2
6

= 10
6
Given :
2
10
2
S
6
=
S = 10
6
K
SP
[Ag
2
CrO
4
] = [Ag
+
]
2
[CrO
4
2
]
= [10
6
+ 10
6
]
2

2
10
6
= 4 10
12

2
10
6
= 2 10
18
ab =
19
18
10
10 2

= 20
In the solution we have
Ag
+
, CrO
4
2
, NO
3
, H
+
, OH
M
1000 K
] Ag [
Ag
m

=
+
+
;
6
Ag
10 2
1000 K
50

=
+

+
Ag
K = 10
7
;
M
1000 K
] CrO [
2
4
CrO
2
4 m

=


2 / 10
1000 K
100
6
CrO
2
4

=

; 0.5 10
7
= 2
4
CrO
K
6
NO
3 m
10
1000 K
] NO [
3

=

;
3
NO
K
= 0.75 10
7
CHEMISTRY
Code-A Page # 7
7
H
m
10
1000 K
] H [

+

=
+
; 350 =
7
H
10
1000 K

+
+
H
K
= 0.35 10
7
7
OH
m
10
1000 K
] OH [

=
;
7
OH
10
1000 K
200

=
OH
K = 0.2 10
7
K = 10
7
+ 0.5 10
7
+ 0.75 10
7
+ 0.35 10
7
+ 0.2 10
7
= 2.8 10
7
= 28 10
8

cd = 28 ]
Q.5
[Sol. Complex Number of geometrical isomers [CoCl
2
Br
2
]
2
0
[Rh(en)
3
]
3+
0
[Cr(en)
2
Br
2
]
+
2
[Pt(en)Cl
2
] 2
[Co(NH
3
)
3
(NO
2
)
3
] 2
[Pt(NH
3
)
2
(SCN)
2
] 2
[Cr(NH
3
)
2
Br
2
Cl
2
]

5 ]
Q.6
[Sol. Isoelectric pH of a aminoacid =
2
2 1
a a
pK pK +
8.2 =
2
7
2
a
pK +

2
a
pK = 16.4 7 = 9.4 ]