ANSWER KEY

12th ABCD (Date: 25-09-2011) Review Test-5

PAPER-2
Code-B
CHEMISTRY

MATHS

PHYSICS

SECTION-1

SECTION-2

SECTION-3

[INTEGER TYPE]

[INTEGER TYPE]

[INTEGER TYPE]

Q.1

0194

Q.1

0020

Q.1

0010

Q.2

0003

Q.2

0002

Q.2

0025

Q.3

0003

Q.3

0007

Q.3

0015

Q.4

2000

Q.4

0010

Q.4

0087

Q.5

0006

Q.5

0020

Q.5

0016

Q.6

0448

Q.6

0005

Q.6

0006

Q.7

4003

Q.7

0025

Q.7

0006

Q.8

2636

Q.8

0017

Q.8

0400

Q.9

1500

Q.9

0065

Q.9

0001

Q.10

0064

Q.10 0003

Q.10

0119

Q.11

2866

Q.11

0009

Q.11

0240

Q.12

5008

Q.12 0007

Q.12

0050

Q.13

0654

Q.13 0009

Q.13

0005

Q.14

4330

Q.14 0003

Q.14

0008

Q.15

7564

Q.15 0021

Q.15

0100

Q.16

8462

Q.16 0021

Q.16

0001

CHEMISTRY
[INTEGER TYPE]
Q.1
[23 + 45 + 81 + 33 = 182]
Q.2
[Sol.

Carbon reduction method is/are mainly applicable for Sn, Pb and Zn

Q.3

[Sol.

CH3

CH3

CH3
NaNH2
liq. NH3

CH3

Cl

NH2

NH2

CH3

CH3

CH3

NH2

+
NH2

NH2
NH2

Identical
Q.4
[Sol.

Na2SO4.10H2O Na2SO4 + 10H2O;

500 mole
Heat atm = 20 500 = 10000 KCal
Gas saved =

Q.5
[Sol.

10000
= 2m3 = 2000 Ltr..
5000

K2[PtCl6]

H = + 20 K cal

[Sol.

Q.6
Vinyl magnesium bromide CH 2 = CH MgBr
Mol. wt. = 131
Moles of Grignard =

2.62
= 0.02
131

224
= 0.01
HC C H
22400
It will have 0.02 moles of acidic H+
CH2 = CHMgBr
+
H+ CH2 = CH2
0.02
0.02
0.02 moles
Code-B

Moles of ethyne =

Page # 1

CHEMISTRY
Volume of ethane produced = 0.02 22.4 L
X = 0.448 L
1000 X = 0448 Ans.
]
Q.7
[Sol.

V V0
ln
kt = V V

t
120 k = ln
k=

40
5

3 ln 2
ln 2
=
120
40

ln 2
40 = 4 sec
ln 2
40 ml NaOH is required for compute H+ form ester

t1/2 =

40 MNaOH = V 6 MNaOH =

6V
40

Fro H+ from HCl

V MHCl = 20 MNaOH
V MHCl = 20
MHCl = 3M
Q.8
[Sol.

6V
40

[Na2 [Fe(CN)5NO] oxidation state of NO = +1

Oxidation state of Fe = +2
Coordination number = 6
Effective atomic number = Atomic number Oxidation state +2 Coordination number
= 26 2 + 2 6 = 36
]

Q.9
[Sol.

(C6H10O5)x + 6xO2
6xCO2(g) + 5xH2O
4 162x = 6x94 5x 65 4 f H
fH = 243x Kcal/mole
Per gm =

Code-B

24300x
= 1500 cal/gm
162x

Page # 2

CHEMISTRY
Q.10
[Sol.

CO is 2 electron donor and NO is 3electron donor so maximum 6 CO replaced by 4 NO.

Cr(CO)6
6CO are present
number of CO molecule 2 = number of NO molecule 3
6 2 = x 3 (x = number of NO molecule )
x=4 ]

Q.11
Cl
CH3 CH CH2 Cl CH3 C CH3

[Sol.(a)

CH3
(1)

CH3
(1)

Cl

CH2 CH Ph

(b)

Cl

Cl
*
CH2 C Ph CH2 CH

Ph
(1)

Ph
o,m and para (2 each)

Ph
(1)

(6)

Cl

(c)

*
CH3 CH CH2 CH2 Cl ; CH3 CH CH
CH3 ;
CH3
CH3 Cl
(1)
(2)

CH 3 C CH2 CH3
CH3
(1)

H
CH3 C CH2 CH3
*
CH3Cl
(2)

(d)

CH CH2 CH2 Cl
(1)

Et

*
Ph CH CH3
Cl
(2)

]
Cl
o, p, and meta
(3)

Q.12
[Sol.

Q + H2O
(0.05 x)M
pH = 9.70
Kb =

Code-B

QH+ +
xM
OH
P = 4.30

OH
xM
[OH] = 5 105 M = x

x.x
x2
= 5.0 1008 = 5008 Ans]

(0.05 x )
0.05

Page # 3

CHEMISTRY
Q.13
[Sol.

Co

36.875
0.620
= 0.62 ;
=2
59
0.3125

NH3

53.125
3.125
= 3.125;
= 10
14
0.3125

10
0.3125
= 0.3125 ;
=1
32
0.3125
The molecular formula of compound is Co2 (NH3)10O2
O2 having possibility to change oxidation state so it have a possibility to show 0, 1 and 2 oxidation
state becouse in O2[PtF6], O2 has + 1 oxidation state OO bond length in complexess more than O2+.
Co2(NH3)10 O2

O2

(i)

(iii)

H3N
H3N
H3N
H3N

H3N

H3N

H3N
H3N
H3N
H3N

O2

+3

Co

0
+3

Co

(ii)

NH3

H3N
O2

Co+3

Co+3

HN
H3N 3
H3N
+3
Co
H3N
H3N

+6

NH3
NH3
NH3
NH3

NH3
O2

1
+3

Co

NH3
NH3
NH3
NH3

+5

+4

NH3
NH3
NH3
NH3

Q.14
O

[Sol.

(1)

HOOC
HOOC

COOH

COOH

Gem and -Keto acid

4 moles CO2
HOOC

COOH

COOH
4

+ 2CO2

O + CO2

(2)

HOOC

COOH

COOH
(1,4-dicarboxylic)

3 moles CO2

Code-B

Page # 4

CHEMISTRY
Me
HOOC

(3)

Me
COOH

COOH

HOOC

COOH

COOH

CMe

Me

+ 2CO2

+ CO2

CMe

Gem

CMe

COOH

-Keto

3 mole of CO2

CH2 = CH COOH

(4)

Zero

No effect

Q.15
[Sol.

1
mv 2 = 0.08 1.6 1019
2
v = 4000 m/sec
128000
= 32 sec
4000
ab = 75% for 2 half lives

time =

t1/2 = 16 sec

16 ln 2

4000 = 64
ln 2 1000
= 7564 Ans. ]

cd =

Cl
[Sol.

Mg/ether

(8)

Q.16

PhMgCl

CO2/H

(4)

Ph C OH
O
(6) SOCl
Ph C Cl
O

Ph CH2 C OH
O

Code-B

CH 2N 2/Ag, /H 2O

(2)

Page # 5

MATHEMATICS

PART - C
Q.1
[Sol.

For number of solutions of given equation to be 9, so n must be 5.

2

Now (3 + cosec2x) + 2sin y = 5

possible only if cosec2x = 1 and sin2y = 0
3 5 7
,
,
,
2 2
2
2
possible values of y = 0, , 2, 3, 4
Hence number of ordered pairs (x, y) = 4 5 = 20 Ans.]

possible values of x =

Q.2
[Sol.

Equation of S is (x 1)2 + (y 1)2 + (x + y 2) = 0

x2 + y2 + x( 2) + y( 2) + 2(1 ) = 0 ........(1)
x2 + y2 + 2x + 2y 2 = 0
........(2)
Given (1) and (2) are orthogonal, so

S=0

P(1,1)

y=2x

2( 2)
2
(1) 2
1 = 2 (1 ) 2 2 + 2 = 2
2
2
4 = 4 = 1
Hence equation of S is x2 + y2 x y = 0.

Now, length of tangent from (2, 2) is

Q.3
[Sol.

4 4 2 2 = 2. Ans.]

Put f (x) = t
f (t) = 4 t = 2, 0, 4
Hence
f (x) = 2

2 values of x.
or
f (x) = 0

2 values of x.
or
f (x) = 4

3 values of x.
Hence, the number of real solutions of the equation f (f(x)) = 4 are 7. Ans.]

Q.4
100

[Sol.

Let I =

Put,

f (x)
dx =
x

10

100

f (x)
dx
x
1

10

f (x )
dx =
x

10

f (x)
dx
x
1

100 f

10

100

x
dx
x

100
dx
dx dt
100

dx
=t
=
dt

t
=
dt

x
x
x
t
x2

10

10

f (x )
f (t)
f (x )
dx
dt = 2
dx = 2 5 = 10. Ans.]
I=
x
x
t
1
1
10

Q.5
[Sol.

Given a1 > 0.
Let d = common difference of A.P.
Now, 3a8 = 513 3 (a1 + 7d) = 5(a1 + 12d) 2a1 + 39d = 0
As,
a1 > 0 so d < 0.

.......(1)

n
n
39d n 1 d = d n 2 40n = d n 20 2 400
2a1 n 1 d =
2
2
2
2
Clearly, Sn will maximum when n = 20. (As d < 0). Ans.]

Now, Sn =
Code-B

Page # 1

MATHEMATICS
Q.6
[Sol.

The system has a non-zero solution if | A | = 0 k = 0.

Clearly, the solutions are (2a, 3a, 5a).
So, the smallest positive integral value of z = 5. Ans.]

Q.7
[Sol.

Given, r

a b

But a b

a b sin x b c cos y 2 c a and r a b c = 0

c (sin x + cos y + 2) = 0

c 0, so sin x + cos y = 2, which is possible when sin x = 1 and cos y = 1

For (x2 + y2) to be minimum, x2 =

Hence, the minimum value of

2
and y2 = 2.
4

20 2 2 20 2
20 52
2

(x
+
y
)
=
=
2 4 = 25. Ans.]
2
2 4

Q.8

[Sol.

1 x 1
f ( x ),
g ( x ),
x ,1 1,
f (1) g (1)
,
x 1
F(x) =
2

f (1) g (1)
,
x 1

2
continuous at x = 1

b a = 3.
continuous at x = 1

F(1) = F(1+) = F(1)

f (1) g (1)
f(1) = g(1+) =
2
( 4 a ) (1 b)
5a b
4+a=1+b=
=
.
2
2
.......(1)
F(1) = F(1+) = F(1)
( 4 a ) (b 1)
b1=4a=
2
3 b a
b1=4a=
2
.......(2)

a+b=5
(1) and (2)

a = 1, b = 4 a2 + b2 = 17. Ans.]

Code-B

Page # 2

MATHEMATICS
Q.9
[Sol.

Given, x + 5y y5 = 0

dy 1

=
dx 5 y 4 5
1

Now, when x = 0, y = 54 or y = 0.
But, y =

1
54

(Rejected)

So, slope of tangent at (0, 0) =

1
.
5

x
5
Now, equation of normal is y = 5x
Also, given line is y = 5

Equation of tangent is y =

.......(1)
.......(2)
.......(3)

1
x
5

y = 5x
(1, 5)

( 25, 5)

Clearly, area of triangle =

Q.10
[Sol.

1
(26) (5) = 13 (5) = 65. Ans.]
2

Using cosine law in BKC,

18
4 1
B
4
cos =
2
3 2
2
2
2

9
2 = 15 = 5
=
12 2 4 2
6 2
Now,
3

c= 2m x 3 2
2

x=

( 2 2 2 m)
5
2ac
B
cos =

ac
2
2m 2
4 2

5
4m
5m
3 2
=

3=
3m + 3 = 5m
m 1 4 2
m 1
2

m=

Code-B

a=2

m
K

3
2

AB = 2m
c = 3 . Ans.]
Page # 3

MATHEMATICS
Q.11
[Sol.

Let y = f 2(x) g2(x)

dy
= 2 f ( x ) f ' ( x ) g ( x )g ' ( x ) = 2 f ( x ) g ( x ) g ( x ) f ( x ) = 0
dx
f 2(x) g2(x) = k (constant)
So, f 2(3) g2(3) = k (5)2 (4)2 = k k = 9, x R
Hence, f 2() g2() = 9. Ans.]

Now,

Q.12
[Sol.

Equating the components,

3x + 2y+ 4z = x ; 2x + 2z = y & 4x + 2y+ 3z = z
hence (3 )x + 2y + 4z = 0
2x y + 2z = 0
4x + 2y + (3 )z = 0
for non trivial solution

3 2
4
2
2 =0

4
2 3

Use : C1 C1 C3 and C3 C3 2C2

( 1) 2
0
2(1 ) = 0
0
1
2 ( 1)

1 2
0
( + 1)2 0 2
1
2 1

( + 1)2[ 1( 4) 2( 2)] = 0
Hence = 1 or 8 sum = 7. Ans. ]

( + 1)2 ( 8) = 0

Q.13
x

[Sol.

2
x
y
Given, f(x) = ex e f ' ( y) dy ( x x 1)e

..........(1)

differentiating both the sides

x

f '(x) = ex ex f '(x) + e x e y f ' ( y) dy x 2 x 1 e x e x 2x 1

f '(x) = f '(x) + e x y f ' ( y) dy e x x 2 x

0 = f(x) + (x2 x + 1) ex ex (x2 + x) [Substituting

x y

f ' ( y) dy = f (x) + (x2 x + 1) ex from (1)]

f(x) = ex (x2 + x x2 + x 1)
f(x) = ex (2x 1) f(1) = e.
Also, f '(x) = ex 2 + (2x 1) ex f '(1) = 2e + e = 3e
and f '' (x) = 2ex + (2x 1)ex + 2ex
f '' (1) = 2e + e + 2e = 5e.
Hence f(1) + f '(1) + f '' (1) = 9e k = 9. Ans.]

Code-B

Page # 4

MATHEMATICS
Q.14
[Sol.

f (x h) f (x)
h0
h

We have f '(x) = Lim

2 x 2h 2 x 2 0
f ( 2 x ) f ( 2 h ) f ( 2 x ) f ( 0)
f
f

2
h
= Lim
2
2
f '(x) = Lim
h

0
h0
h
h

f (2h ) f (0)
= f '(0) = k (say)
h0
2h

= Lim

f '(x) = k
f(x) = kx + c ; f(0) = 0 c = 0

f(x) = kx
2
2
kx sin x dx

Now, I =

x3
= k

3
0
2

= k2

2k

2 2

x 2kx sin x sin 2 x dx

x sin x dx sin
0

x dx

8 3
8k 2 3
2k 2 =
4 k .
3
3

8 3 2
k (4) k .
Hence I(k) =

This is a quadratic in k and its minimum value occurs when k =

f(x) = 2 x ;
4

4 3
16

3
4 2

f( 42) = 3. Ans.]

Q.15
[Sol.

1
2i j
An = 2 n = 2n [2i + j]
3 3
3n An =

1
3n

[2i + j]

18
1
n (3 + 6 + 9) = n n N
3
3
2
n
Tr. (3A1 + 3 A2 + ...... + 3 An) = Tr. (3A1) + Tr. (32A2) + ........ + Tr. (3nAn)
Tr. (3nAn) =

=6+2+

Code-B

18
2
+ ...... + n
3
3

2
18
tr 3A1 32 A 2 ....... 3n A n = Lim 6 2 ....... =
l = nLim

n
3
3n

6
1
1
3

=9
Page # 5

MATHEMATICS
|||ly

Tr. (2nBn) =

(2 + 4 + 6) =

12

2
2n
Tr. (21B1 + 22B2 + 23B3 + .......+2nBn) = tr (2B1) + tr(22B2) + .......+ tr(2nBn)
=

6
12
12 12
m = Lim tr 2B1 2 2 B2 ...... 2 n Bn = Lim 2 ...... n =
= 12
n 2
n
2
2 1 1
2
l + m = 9 + 12 = 21. Ans.]

Q.16
[Sol. Given, y = x + 2
Equation of CD
y 2 = 1 (x 0)

y=2x
0
1 8
Area of triangle ABC =
2 3
8

0
1
8
=
6 8

2
14
6

1
3
1

0
1
0
=
6 8

2
20
6

1
2
1

.......(1)

Code-B

64
3 21 . Ans.]

.......(2)
2
14
3
6

1
8 16
64
84 20 =

=
= .
6
6
3

12 12
12
2 ......... n .
2 2
2

1
1
1

8 14
,
3 3

P2

C
P1 (0,2)

45

y = 2x + 10

y=2x
135
O

(0,2)

P3(8, 6)

D
m= 1
y= 2x+10

Page # 6

PHYSICS
[INTEGER TYPE]
Q.1
[Sol.

m1v1 + m 2 v 2 = m1u1 + m 2 u 2

0.173 10 j + 0.2 5 i = 0.2 u 2

5 3 i 5j v = 10 m/s

Q.2
[Sol.

P = Fv = vi
115 103 57.6
=

5
= 4 103 8 230
18

115 288
= 25%
1.8 3.6 8 230

Q.3
[Sol.

ac = g =
a2 =

m1a1 m 2a 2
m1 m 2

4a2

42

60
= 15 m/s2
4

Q.4
[Sol.

prefl. =

2h
cos

pabs =

60
60

Total p = Nrefl p refl. + Nabs p abs.

Nhc
=E

N=

E
hc
2

2h
h
2h
h
E
E
E
E
0.5 cos
0.5 2
0.5 cos
0.5 cos
pT =

hc
hc
hc
hc
= 86.6 kg nm/s
]
Q.5
[Sol.

Kmax =
=

1240 1240
28

=
eV = qEd
93
310
3

d=
Code-B

hc
hc

th

28
3 5.83 10 2

280 10 2
= 1.6 102 m = 16 nm
175

]
Page # 1

PHYSICS
Q.6
[Sol.

Q0 = Cv0
Q0

v0

12
=6
2
kC
k
V = 12 6 = 6 volts

V=

Q.7
[Sol.

h
6.6 1034
p=
=
= 1.32 1024

5 10 10

p2
E=
= qV
2m

(1.32 1024 l) 2
2 9 10 31 1.6 10 19
1.32 1.32 10 48
18 1.60 10

50

=V

132 132 121

=
= 6.05 V ~ 6V
18 160
20

Q.8
[Sol.

K2max =

hc
1 ev0 = 1

K1max =

hc
2 + ev0 = 3

2hc
(1 + 2) = 4

2 1240
=
4 2 .2
= 400 nm

Q.9
[Sol.

Q.10
[Sol.

Fnet = 6 + 3 = 9
t = 6 2 3 1 = r F
t = 1 m
]

Q = CV
4

2 4
V = Edx = 20 x 3 dx

3
3

x 3 4x
V = 2Q 3 3

Code-B

Page # 2

PHYSICS
4
1
V = 2Q [64 27] [7]
3
3
Q
119
= 3Q

C
3
1
= 119 F1
C

Q.11
10

[Sol.

x
20

12V

6V

x
x6
x 12
+
+
=0
20
5
10
2 x 8x 48 4 x 48
=0
40
x=0
i1 = i2

i1 =
Q.12
[Sol.

12
10

i1 + i2 =

12
5

240 Ans. ]

F = 2T
F' = T
F + 2F' = S 2r 2
4T = S 2r 2

r/2
F'

F'

4T 2F 0.01
S=
=
=
= 0.05N/m = 50 mN/m
4r
4r
0 .2

Q.13
[Sol.

30 (25 + x0) = 5 x0
32
= 80 cc
0 .4
A = 16 cm2
kx0 + 103 16 104 x0 10 = 32 103 10
x0 (48 + 16) = 32 102

V=

x0 =

Code-B

32
cm = 5 mm
64

25 + x0

30cm

x0

Page # 3

PHYSICS
Q.14
[Sol.

Mg T 6r1v = 0
mg + T 6r2v = 0

mg

4 3 2
r r g
3 1 2
=v
6( r1 r2 )

v=

g
2 2
(r1 r1r2 + r22)

T = Mg 62r1

Mg

g
2 2
(r1 r1r2 + r22)

4
4
r13 g
g [r13 r12r2 + r22r1]
3
3

4
gr [r12 r2 r22r1]
3

r22
4
= rgr12 r2 r
3

2r2
dT
4
2 1
0
=
0

gr
1
dr2
r1
3

r1 = 2r2
M
=8
m

Q.15
[Sol.

v=

2gh

dp
dm
=
v
dt
dt

=
=

A 2
v
100

A
100

A
2gh
100

p=

A
A
dt
2g hdt =
2g h
dh
100
100
dh

dh
A=
dt

2gh

A
100

dh
2gh
=
dt
100
A
p=
100
5

Code-B

h
A
dh
=
20
2gh
20

A
H3 / 2
h dh =

2
20
3
Page # 4

PHYSICS
2
= A 20 H3/2
3

= 103 3 2 5

2
5 5 = 105 = 100 kNs
3

Q.16
[Sol.

3
1
2x dx cx 4
k
=

5 0
( 4 2 x 2 )3 / 2
0
3
1
x 2dx
42
5 0 = 2 0 C 0 (16 x 2 ) 3 / 2

dx

x = 4 tan = 0 to 37
1
C=
10
1
=
10

37

37

16 tan 2 4 sec 2 d
(16 16 tan 2 )3 / 2

tan 2 sec 2 d
sec 3

37
1 sec d cos d

=
10 0

n(sec tan ) sin 37

0
10

C=

Code-B

1
1
=
=1
10 0.93
0.93

Page # 5