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Chapter 1 Recycling Plastics from Municipal Solid Waste An Overview Downloaded via 3.235.21.12 on May 28, 2020 at 04:49:20 (UTC). See https://pubs.acs.org/sharingguidelines for options on how to legitimately share published articles. Wayne Pearson Plastics Recycling Foundation, P.O. Box 189, Kennett Square, PA 19348 Recycling means that we disposables, to someone. value. In fact, if it were fact that no one wants to are going to try to sell our garbage, or other The problem is that garbage has very little extremely valuable, it would be stolen. It is a buy garbage. Consequently, a lot of work must be done to the garbage pile to turn it into viable products. This work includes processing the garbage to quality raw materials that can be manufactured into products that can be sold to buyers who will buy it again, and again, and again. Recycling requires four elements: • • • • collection sorting of raw materials reclaiming the raw materials to make a product markets and paying customers for the product The Nation is producing 180 tons of municipal solid waste a year. Based on the EPA study, about 29 billion pounds of plastic entered the waste stream in 1988. This represented about 56% of what was produced that year. The lag is what would be expected, considering the different life cycles of the different uses. Because the life cycle of packaging is so very short, we can assume that virtually all of the production ends in the waste stream within one year, whereas the more durable uses would take longer to reach the waste stream. The EPA claims that eight percent of the 180 million tons of MSW or about 29 billion pounds of plastics in municipal solid waste accounts for about 20 percent of the volume (Figures 1 and 2). 0097-6156/92/0513-0001$06.00/0 © 1992 American Chemical Society Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 2 EMERGING TECHNOLOGIES IN PLASTICS RECYCLING Packaging, the element in the waste that is getting the most national attention and the highest concern, represents about 3 0 % (Figures 3 and 4)· The plastics share of packaging by weight is 13 percent (Figure 5). Packaging is dominated by paper and glass (Figure 6). The following recyclable items are reasonably viable in terms of technology and economics today: newspapers aluminum and steel cans glass bottles and jars plastic beverage containers It's interesting to note that on a volume basis the plastic beverage container is equal to about 1/3 of the volume of things that are recyclable today, namely: newspapers, non-plastic beverage containers and plastic beverage containers (Figure 7). Moreover, it is technically and economically viable to collect and sort plastic beverage bottles to reclaim the polymers contained therein which include polyethylene terephthalate (PET), high density polyethylene (HDPE) and polyvinyl chloride (PVC). The markets for these reclaimed polymers exist in far greater size than all the polymer used in the manufacture of beverage containers. Including plastics beverage containers with non-plastic beverage containers (glass, aluminum and steel) along with newspapers increases the volume that can be recycled by the home owner by about 50 percent, and it can be highly profitable because plastics beverage containers are second only to aluminum in value. This technology to collect and sort these commodities is available to hundreds of communities in the Nation who are redeveloping and implementing plans to collect and include them in their recycling programs. The infrastructure for reclaiming, cleaning up and producing products to sell is growing fast. There are a number of major companies involved in the business already, and the list is growingzyxwvutsrqponmlkjihgfedcbaZYXWVU (Table 1). Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. PEARSONzyxwvutsrqponmlkjihgfedcbaZYXWVUTSRQPONMLKJIHGFED Recycling Plastics from Municipal Solid Waste MzyxwvutsrqponmlkjihgfedcbaZYXWVUT Paper and paperboard Other Μ Figure 1. Materials Generated in MSW by Weight (180 million tons), 1988. • Paper &zyxwvutsrqponmlkjihgfedcbaZ ι Paperboard I = Other I Figure 2. Materials in MSW by Volume (Cubic Yards), 1988. I Packaging Figure 3. Percent of Plastics in MSW by Use (%). Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 4 EMERGING TECHNOLOGIES IN PLASTICS RECYCLING TABLE 1. M ajor U. S. a nd Canadian S crap Plastic Bottle Reclaimers (1991) E stima te d Annua l C a pa city in M illion Lbs. C ompa ny Loca tion Clean Tech Day Products Eagl ebrook Plastics Graham Recycling Johnson Controls M.A. Industries Dundee, Ml Bridgeport, NJ Chicago, IL York, PA Novi, Ml Peachtree City, GA Edgerton, Wl Odessa, TX Vancouver, WA Berthierville, PQ Philadelphia, PA 12 40 35 20 20 20 Chicago, IL 40 M i d w e s t Plastics Orion Pacific Partek Pelo Plastique Plastic Recycling Alliance Plastic Recycling Alliance Quantum Chemical Co. Star Plastics St. Jude Polymer Union Carbide United Resource United Resource Recovery Source: Heath, OH Albany, NY Frackville, PA Piscataway, NJ Findlay, OH Johnsonville, SC 10 7 5 15 40 40 32 25 50 8 175 Resource Recycling, 1991 In addition, the National Polystyrene Corporation has several polystyrene plants and more in the planning. There are also a number of manufacturers of plastic profiles for park and highway equipment using commi ngl ed plastic from the waste stream. Some driving forces are accelerating and expanding the demand for these recycled materials, particularly the activities of packagers who wish to use recycled plastic to achieve a more environmentally attractive package. In a word, the Nation is well positioned to recycle newspapers and beverage containers, including plastic beverage containers. Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. PEARSONzyxwvutsrqponmlkjihgfedcbaZYXWVUTSRQPONMLKJIHGFED Recycling Plastics from Municipal Solid Waste Figure 4 . Packaging Share of Municipal Solid Waste. DDzyxwvutsrqponmlkjihgfedcbaZYXW Other U Paper 11 Glass H Metals • Figure 5. Figure 6. Plastics Plastics Share of Packaging. Plastics Packaging by Volume. Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 6 EMERGING TECHNOLOGIES IN PLASTICS RECYCLING Figure 8. Trash Pile-Number of Items. Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 7 1. PEARSONzyxwvutsrqponmlkjihgfedcbaZYXWVUTSRQPONMLKJIHGFED Recycling Plastics from Municipal Solid Waste However, to fully understand the complexity of processing trash to useful products beyond these traditional items, it is helpful to gain a perspective. The trash pile can be viewed as a pyramid as shown below (Figure 8). At the top are ten items we commonly recycle, namely: - newspapers aluminum beverage cans steel beverage cans tin cans clear glass bottles brown glass bottles amber glass bottles green glass bottles PET soft drink bottles HDPE milk, water and juice bottles At the next level there are 100 items which include: colored plastic detergent bottles, pharmaceutical bottles, other papers, magazi nes, and bi -metal c o n t a i n e r s . Below that there are 1,00 items which include other glass, ceramics, multi-layer materials (foil, paper, etc.). At the next level there may be 10,000 items including household cl othi ng, industry, etc. The more items to process back to their original or "closed loop" applications, the more complex the collection, sorting and reclamation become and the more expensive it becomes. This is where the development of commingled products comes in. It may be necessary to work with mixed paper, mixed glass, mixed metal, and mixed plastics if we wish to go deeper into our trash. BE Y O N D BE V E R AG E BO T T LE S It is technically feasible to recycle, recover and reuse all of the discarded plastics packaging, but with the exception of beverage bottles, economics limit the degree of recycling at this time. Communi ti es are not enthusiastic about collecting materials if their alternate methods of garbage disposal cost less. Therefore, it is necessary to consider the cost to the community as well as the cost to the reclaimer to get the full cost of the recycled material. The fact that the recycled material must compete with virgin resin in quality and price must be taken into account when considering markets. The cost to the community includes the following: cost to collect recyclables cost to sort recyclables Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 8 EMERGING TECHNOLOGIES IN PLASTICS RECYCLING From these two costs the community is entitled to subtract: the cost of collecting trash that is avoided (by diverting it to recyclables) the cost of disposal avoided (e.g. tipping fee at landfill) The sum of these four items will be the cost to the community. The community can recover some or all of that cost by selling the recovered recyclables. The price that they need to cover the total cost is the theoretical price the reclaimer should pay for a raw material. The reclaimer will have the following costs: • • • • raw material (equals community cost) reclaiming cost (e.g. cost to convert the raw material to product marketing expenses and overheads profit and return on investment The sum of all these costs, including dividends needed to pay stockholders, becomes the minimum price required to make an economically attractive venture for manufacturing a product derived from feedstock obtained from processing trash. The next question becomes: Is the price higher or lower than the price of virgin material? The processing technologies today are good enough to manufacture a product essentially equal in quality to virgin. However, in a normal free market situation a manufacturer will insist on receiving a discount to use what is deemed to be inferior quality material. If we take a look at the economic viability of plastics packaging recycling consid­ ering the virgin prices based on oil at nominally $20/barrel (Figure 9) we see clearly that beverage containers are economically viable with current cost to landfill which is between $50 and $100 ton. However, it is also clear that beyond beverage bottles it is not economically attractive at today's price of oil, alternative disposal costs and current recycling technology. If, however, the price of oil were to rise to $35 per barrel (Figure 10), then the cost associated with manufacturing virgin polymers from high priced oil-related feedstocks would increase substantially. Therefore, even if recycled material were discounted, versus virgin prices, the price would be high enough to make it economic to collect, sort, and reclaim many plastic components from the waste stream. This suggests that there is a "future value" to recycling that should be given consideration from the point of view of "stock piling" material going into the trash stream to be utilized in a future time when the price of oil might be higher than $20/barrel. Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 1. PEARSONzyxwvutsrqponmlkjihgfedcbaZYXWVUTSRQPONMLKJIHGFE Recycling Plastics from Municipal SolidWaste 9 PRICE ' ,zyxwvutsrqponmlkjihgfedcbaZYXWVUTSRQPONMLKJIHGFEDC PET Oil at $20 per barrel zyxwvutsrqponmlkjihgfedcbaZYXWVUTSRQPONML zyxwvutsrqponmlkjihgfedcbaZYXWVUTSRQPONMLKJIHGFED CO ST g OfJ I T s Package Ethylene Plastic Lumber Figure 9. Viability of Plastics Packaging Recycling vs. Today's Virgin Prices Based on Oil at $20/Barrel. Figure 10. Viability of Plastics Package Recycling vs. Virgin Prices Based on OiTat$35/barrel. Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 10 EMERGING TECHNOLOGIES IN PLASTICS RECYCLING Another issue that surfaces here is that if the public decides to purchase recycled material, despite quality deficiencies, then the price of recycled material need not be discounted versus virgin. In fact, the price of recycled material could exceed the price of virgin. That would change economics substantially, as shown with non-beverage bottles (Figure 11). This new marketing factor can be labelled "green". Simply stated, it means that a product that can trace its pedigree to the post-consumer garbage pile will be preferentially purchased versus one whose pedigree is traced to natural gas or oil. R E S E AR C H P R O G R AM S To go beyond beverage bottles is needed to develop next generation technology. We must reduce the cost of collection and sorting and upgrade the quality of the generics recovered through improved processing technologies so as to increase the value. The process for deriving products with a garbage pile origin can be d i a g r a m m e d as follows: Garbage Pile I Collect and Separate Recyclables Generics Separating Plastics Non-Generics Macro Unrefined Commingled M icro Refined Commingled M olecular M a rke ts- Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 1. 11 PEARSONzyxwvutsrqponmlkjihgfedcbaZYXWVUTSRQPONMLKJIHGFED Recycling PlasticsfromMunicipal Solid Waste PRICE Cents/Lb. 50 40 Virgin Price (oil at $20/barrei) Recycle Cost 30 Free Market Recycle Price (Oil at $20/barrel) 20 10 0 Landfill 50 Price-$/Ton 100 Figure 11. Economic Viability-Plastics Package Recycling/Non-Beverage Bottles. Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 12 EMERGING TECHNOLOGIES IN PLASTICS RECYCLING Once the plastics are separated from the non-plastic recyclables, there are a number of technologies for separation of the plastics to generic components and there are technologies for dealing with commingled (unseparated) plastics. Research programs that are underway focus on the issue of collection, sorting/reclaiming a n d end-use markets. C O LLE C T I O N In collection the issues are: collection of all clean col l ecti on c o n t a i n e r packer trucks truck routing plastics The question is: "What will the consumer give when asked to deliver all clean plastics?" This includes all rigid containers (beverage bottles, detergent bottles, and rigid tubs) and non-rigid materials such as film. Types of trucks and truck routing are also being studied. S O R T I N G / R E C LAI M I N G In the sorting and reclaiming of generics, the research is focused on three types of separation: macro micro molecular Micro-sorting is Macro-sorting is the separation at the container level. the separation of chips of containers after the containers have been shredded and chopped up. Molecular sorting involves dissolving polymers in an organic solvent. It has been demonstrated that five or more polymers can be separated for packaging from each other in a solvent system. Some polymers will be de-polymerized (sorted at the monomer molecule level). Condensation polymers are among the more easily depolymerized molecules, so it is not surprising to see commercial operation in place or planned to de-polymerize PET (from SODA BOTTLES) to the monomers dimethyl terephthalate and ethylene glycol. Purification of these molecular separations can be high. Monomer derived from post-consumer PET bottles has been found acceptable by the FDA. Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 1. 13 PEARSONzyxwvutsrqponmlkjihgfedcbaZYXWVUTSRQPONMLKJIHGFED Recycling PlasticsfromMunicipal Solid Waste While molecular separation technology may not be economically viable today, it will become more economically viable as the price of oil increases, and/or as costs can be reduced for this methodology. Industry and recycling communities are working on these same issues so that the number of high quality generic plastic items in the trash pile that will become economically viable will increase with time. In connection with minimizing cost of collecting and sorti ng, technologies that simplify collection, sorting and cleaning are surfaci ng. Two of these technologies are: the molecular separation of commi ngl ed plastics the development of new compounds and families of products based on "refined commi ngl ed" plastics It has been demonstrated at the Center for Plastics Recycling Research at Rutgers University, that mixed or commingled plastics from the postconsumer waste stream can be used to make a wide range of plastic products using traditional virgin plastics processing equi pment. The commingled plastic material requires no macro sorting and collecting can be simplified. Thus the cost of collection and sorting can be reduced substantially. Once collected, the commingled plastic materials are "refined" by chopping the plastics and washing them free of paper, metal and any other non-pl asti c materi al s. The "refined" (clean) commingled materials can then be modified by mixing in one of the polymers or compatibilizers to achieve desired end properties. The compatibilized mixture is melt-filtered as it is blended to produce a high purity pellet which can be processed on conventional plastics processing equi pment. It is desirable to segregate blow molding resin types from injection or extrusion resins which can be accomplished at the "refined" commingled plastic reclamation plant. Thus a broad range of "new" products can be designed which expand the recycling potential for post-consumer plastics. There are a few commercial products we would define as "refined c o m m i n g l e d " . These include mixtures of reclaimed polymer with virgin polymer and compatibilizers added to achieve a specific property. These molecular separation and refined commingled technologies do not require plastics to be sorted. Moreover, the range of plastics collected from the householder could be enlarged substantially. Bales containing a Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992. 14 EMERGING TECHNOLOGIES IN PLASTICS RECYCLING wide range of unsorted post-consumer plastics would be shipped to a plant that could separate them into generic resins at the molecular level or could manufacture new compounds from the commi ngl ed, unseparated materials. Both of these technologies will drive the cost of collecting and sorting down and at the same time will provide some reasonable level of value for the recovered generics and/or non-generic (commingled) plastics. END U S E End use market research programs continue to focus on and expand the market opportunities for the full range of polymers from the waste including polyethylene terephthalate (PET), high density polyethylene (HDPE), polyvinylchloride (PVC), polystyrene (PS), and polypropylene (PP), and market research on non-generic uses including the previously mentioned new family of compounds and profiles is continuing. C O N C LU S I O N In conclusion, in 1985, very few people believed that plastics from the post-consumer stream were recyclable, let alone were being recycled. Today, the amount that is recycled is still in an early stage. Approximately 300 million pounds of PET bottles are being recycled, which represents about 3 0 % of that container, and probably about 1 0 % of the milk, water and juice bottles are being recycled. However, the technology has been researched sufficiently so that we can say confidently that the entire packaging stream is recyclable. That is to say, we have the technology for collecting, sorting, cleaning it up and finding markets for it. The economics for recycling plastic beverage containers are very favorable making it highly desirable for communities to include them in their recycling programs right now. Should they elect to do that, they will be able to have the potential for increasing the volume they can remove from the waste stream by 5 0 % , assuming that they are collecting newspapers and non-beverage containers. Looking beyond plastic beverage containers, we see that the technology is viable but that there is a lot of work to do to reduce the cost of collection, sorting and reclamation, and there is also work to do on the market development. However, with time, the rising costs of virgin material, and alternative disposal costs will provide the driving forces that will increase the percent of post-consumer plastics that are recycled. RECEIVED June 10, 1992 Andrews and Subramanian; Emerging Technologies in Plastics Recycling ACS Symposium Series; American Chemical Society: Washington, DC, 1992.