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Beyond Fracking

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The paper discusses the significant impact of natural gas availability and petrochemical advancements in North America, particularly propelled by the extraction of shale gas. It highlights new investments in fertilizer and petrochemical manufacturing driven by lower energy costs, as well as shifts in transportation industries towards natural gas. Furthermore, it addresses future potentials in gas transportation and storage through innovative technologies, the underestimated U.S. shale gas reserves, and the geopolitical consequences of these developments on traditional oil suppliers.

Beyond Fracking: The Mining of Methane Hydrates Dr. Gary K. Busch The o ld s p ess is full of the latest de elop e ts i the f a ki g of shale oil and gas from large deposits in North America and the promise of access to oil and gas in pockets beneath the surface of the earth across the globe. There is a substantial amount of oil and gas trapped in shale below a hard crust of rock not very far below the surface. In recent years there has been the development of a technology which can access these shale oil deposits and deliver the entrapped oil and gas to the su fa e. These te h ologies i lude ho izo tal oil f a ki g . The fi st e ell d illi g a d h d auli f a tio i g o te h olog is ho izo tal d illi g, hi h allows one vertical well to tap widely into a whole layer of oil or gas. The second is hydraulic fracturing, or "fracking," which involves pumping mixtures of water and chemicals into certain rock formations, particularly shale rock. This breaks up the shale to release the oil and gas that had been trapped in the rock. This "fracking" is a game-changer, unleashing our access to oil and gas that were hitherto out of reach. Most of these are on dry land and do not require deep sea wells or pumping stations. The e ha e ee assi e fi ds of o ti uous fo atio s of oil a d gas i the o ti e tal U.“. Within a short period of time the US will be self-sufficient in oil and natural gas. Rather than build the planned LNG receiving trains for the import of gas, the U.S. has begun to build liquefaction plants and trains for the export of natural gas to the rest of the world. U.S. energy costs have shrunk dramatically and remain stable. This availability of lower cost gas is creating many new jobs and attracting industry investments into North America from across the globe as energy costs are reduced and feed stocks of a variety of petrochemical derivatives are dramatically less expensive. In September, 2012 a large Egyptian construction company announced that it would build a new nitrogen fertilizer production plant in southeast Iowa to supply customers in the U.S. Corn Belt; it said the $ . illio pla t ould e the fi st the United States in nearly 25 yea s a d o ld-scale, natural gas-based fertilizer plant built in ould edu e U.“. depe de e o i po ted fe tilize s. Royal Dutch Shell announced plans for a $2 billion petrochemical plant northwest of Pittsburgh, he e it a use atu al gas supplies f o the state s e o ous Ma ellus shale fo atio . Many German companies are moving their plants to access the U.S. shale gas opportunities. Several transport industries are switching from petroleum and diesel to gas, both for savings and for reducing the carbon burden on the environment. The use of generating clean energy using gas will greatly reduce the emission of carbon dioxide. It can also improve the efficiencies of renewable energy sources as a back-up to solar and wind-power stations which stop or slow down when the wind drops and the sun sets. These developments have already had a major effect on world trade and development. The technologies which have been introduced have radically shrunken natural gas imports. By 2020, the U.S. is expected to produce more gas than it needs The oil and gas companies are pushing for more than fifteen new export shipping terminals, sufficient to send a full third of current domestic LNG consumption around the world. More than a half-million gas wells are operating in the U.S., a 50% increase since 2000, according to the Energy Information Administration In 2000, shale gas was 2 per cent of the U.S. natural gas supply; by 2012, it was 37 per cent. EIA says the U.S. has 300 trillion cubic feet of gas in proven reserves and potentially ten times that amount in unproven reserves, much of which is in shale deposits. By comparison, the U.S. currently consumes about 25 trillion cubic feet of natural gas annually. If current trends continue, EIA estimates, the U.S. will be producing more gas than it consumes within the next seven years. Indeed, the U.S. reserves of shale gas are probably a gross underestimate. Oil companies have found that there are vast entrapped gas reserves underneath the current shale gas formations. The Utica Gas play lies beneath the huge Marcellus field. The Marcellus Shale captured public attention when leasing and drilling activities began pumping billions of dollars into local economies in 2004. Now, just a few years later, the Marcellus Shale is being developed into one of the world's largest natural gas fields. However, what geologists have found shows that the Marcellus is only the first step in a sequence of natural gas plays. The second step is starting in the Utica Shale. The Utica Shale is a rock unit located a few thousand feet below the Marcellus Shale. It also has the potential to become an enormous natural gas resource. The Utica Shale is thicker than the Marcellus, it is more geographically extensive and it has already proven its ability to support commercial production. There are several more shale oil and gas plays beneath existing shale oil and gas fields. There are many other shale oil and gas fields around the world but they are developing more slowly; partially because of the fears of its potentially harmful environmental impact and partially because of the cost The cost is not only in drilling the wells it is the inadequate national and international pipeline systems which will have to be expanded or created before this shale gas can reach consumers. The U.S. and Canada have already made heavy investments in pipelines which is a distinct advantage. And yet, this growth in the supplies of shale gas and oil is not the end of technological achievements. The supply of natural gas using methane hydrates is on the brink of a major expansion with the success in reaching commercial exploitation in Japan. The Japan Oil, Gas and Metals National Corporation (JOGMEC) reported on March 12, 2013 that it had successfully extracted natural gas from methane hydrate deposits from around 1,000 feet under the seabed offshore Japan. Methane hydrate is a compound in which a large amount of methane is trapped within a crystal structure made up of water, so forming a solid that is similar to ice in its composition (although it looks like slush). For methane hydrate deposits to form the right conditions in terms of pressures and temperatures are required. These conditions are normally found in four kinds of environment:     Sediment and sedimentary rock under Arctic permafrost Sedimentary deposits along continental margins Deep-water sediments of seas and lakes (e.g. the fresh water Lake Baikal, Siberia) Beneath Antarctic ice There are some 40 trillion cubic feet of methane held in methane hydrate deposits under the sea in the eastern Nankai Trough, off the southern coast of the Japanese island of Honshu, according to JOGMEC. This is equivalent to around 11 years of the amount of liquefied natural gas that is currently imported into Japan.i A o di g to Mi i g I e That Bu s ii, methane is trapped in molecular cages resembling ice, at the bottom of the ocean and in terrestrial permafrost all over the world. It is a supply of natural gas that, by conservative estimates, is equivalent to twice the amount of energy contained in all other fossil fuels e ai i g i the ea th s ust. While o o e elie es that all of the o ld s etha e h d ates will be recoverable, the scale of global reserves has been described by the U.S. Department of Energy as stagge i g. The o u a he e that ate , etha e, lo te pe atu es, a d high p essu e o- occur–in other words, in the twenty-three per cent of the o ld s la d a ea o e ed pe af ost and at the bottom of the ocean, particularly the continental shelf. This why there has been such a keen interest in the energy resources of the Arctic. With global warming the retreat of the Arctic pack ice has made access to the marine deposits of permafrost much easier and attractive. Now, oil companies and the countries which have access to the Arctic are vying for the rights to explore this region for the commercial exploration of the vast methane reserves there. As the technology improves this struggle for rights to the methane will increase. There are many sites worldwide which hold vast reserves of methane hydrate. The sites are just recently beginning to produce commercial quantities of methane gas. The technology is improving but will require substantial investments before methane hydrates will o pete ith f a ked gas. Ho e e , the e has ee a additio al te h ological advance which will make both sources of methane more attractive as a fuel. Scientists have been able to capture methane i a d fo . Chemists at the University of Liverpool have developed a material made out of a mixture of silica and water which can soak up large quantities of methane molecules. The material looks and acts like a fine white powder which, if developed for industrial use, might be easily transported or used as a vehicle fuel. The abundance of the gas and its relatively clean burning process makes it a good source of fuel, but due to its gaseous state at room temperature, methane is difficult to transport from its source. Professor Andy Cooper, of the U i e sit s Depa t e t of Che ist , described the need for such a development, Ma atu al gas ese es a e geog aphi all e ote a d a o l e e t a ted ia pipelines, so there is a need to look for other ways to transport the gas. It has been suggested that methane gas hydrate could be used as a way of containing methane gas for transportation, To counteract these difficulties we used a method to break water up into tiny droplets to increase the surface area in contact with the gas. We did this by mixing water with a special form of silica – a similar material to sand – which stops the soaks up la ge ua tities of ate d oplets f o oales i g. This d etha e uite apidl at a ou d ate s o ate po de al f eezi g poi t. iii Methane capture in zeolite SBN. Blue represents adsorption sites, which are optimal for methane (CH4) uptake. Each site is connected to three other sites (yellow arrow) at optimal interaction distance. Zeolites are unique structures that can be used for many different types of gas separations and storage applications because of their diverse topology from various networks of the framework atoms. In the team's simulations, one specific zeolite, dubbed SBN, captured enough medium source methane to turn it to high purity methane, which in turn could be used to generate efficient electricity at power stations. In this way the problems of transporting methane gas over long distances and the storage of these gasses at industrial sites may well be overcome. This will have a dramatic effect on both the fracking of shale gas and the processing of methane hydrates. Remote areas will not require pipelines and gas holders or LNG trains. It may be unnecessary to build large connecting pipelines like Keystone. The processing of this methane into a dry powder will save vast infrastructural investments and will make the transportation of this powder amenable to the plethora of dry-cargo vessels for transport instead of dedicated gas carriers. Some of these developments will take a number of years to become commercially viable. However, the supply of shale oil and gas will continue to expand, as will the methane produced by processing the methane hydrates. This will also have a major impact on the o t ol of g ee house gasses as the d ate p o ess is also good fo aptu i g a o dio ide. The geopoliti al aspe ts of these developments will be very important as the traditional suppliers of crude oil will suffer diminishing power in the face of the new technologies. i Ice Gas: A Step Closer to Commercial Production , Jo Mai a i g, ‘igzo e Ap il ii Mining Ice That Burns,Christopher Minns, MIT 8/6/09 iii Scientists Discover New Materials to Capture Methane, Science Daily 16/4/13 Additional research – Gail Busch, Algepower ,